• 제목/요약/키워드: particles distribution

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상압에서 열분해법을 이용한 실리콘 입자 제조 (Formation of Silicon Particles Using $SiH_4$ pyrolysis at atmospheric pressure)

  • 우대광;남경탁;김영길;김광수;강윤호;김태성
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회A
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    • pp.126-129
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    • 2007
  • The particle formation using pyrolysis has many advantages over other particle manufacturing techniques. The particles by pyrolysis have relatively uniform size and chemical composition. Also, we can easily produce high purity particles. Thus, we studied the formation of silicon particles by pyrolysis of 50% $SiH_4$ gas diluted in Ar gas. A pyrolysis furnace was used for the thermal decomposition of $SiH_4$ gas at $800^{\circ}C$ and atmospheric pressure. The aerosol flow from furnace is separated into two ways. The one is to the Scanning Mobility Particle Sizer (SMPS) for particle size distribution measurement and the other is to the particle deposition system. The produced silicon particles are deposited on the wafer in the deposition chamber. SEM measurement was used to compare the particle size distribution results from the SMPS. Depending on the experimental conditions, particles of high concentration in the $30\sim80$ nm size range were generated.

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Monitoring of the Distribution of Ambient Air Particles in Seoul Using a Cascade Impactor and the Particle Toxicity

  • Park, Eun-Jung;Kim, Dae-Seon;Park, Kwang-Sik
    • Environmental Analysis Health and Toxicology
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    • 제25권2호
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    • pp.99-109
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    • 2010
  • The distribution of ambient air particles varies according to climate, industries, and other sources. In this study, ambient air particles (less than 12.1 ${\mu}m$) were monitored from February to August, 2007 as 12 different fractions sorted by a cascade impactor. Particles in the size range from 0.33 ${\mu}m$ to 0.76 ${\mu}m$ comprised the main fraction of ambient air particles in Seoul, Korea. On the day of an Asian dust event, the particle fraction size increased to 1.25~2.5 ${\mu}m$. The different sized particle fractions were also monitored for metals and were found to contain toxic heavy metals including Pb, Cd, Hg, Cr and As. Particle preparations were significantly cytotoxic when exposed to cultured BEAS-2B cells. Microarray analysis of the treated cells indicated a significant up-regulation of a number of genes associated with oxidative stress, including metallothionein, heme oxygenase-1, heat shock protein 70, and NAD(P)H dehydrogenase-1.

펄스 SiH4 플라즈마 화학기상증착 공정에서 입자 성장에 대한 펄스 변조의 영향 (Effects of Pulse Modulations on Particle Growth m Pulsed SiH4 Plasma Chemical Vapor Deposition Process)

  • 김동주;김교선
    • 산업기술연구
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    • 제26권B호
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    • pp.173-181
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    • 2006
  • We analyzed systematically particle growth in the pulsed $SiH_4$ plasmas by a numerical method and investigated the effects of pulse modulations (pulse frequencies, duty ratios) on the particle growth. We considered effects of particle charging on the particle growth by coagulation during plasma-on. During plasma-on ($t_{on}$), the particle size distribution in plasma reactor becomes bimodal (small sized and large sized particles groups). During plasma-off ($t_{off}$), there is a single mode of large sized particles which is widely dispersed in the particle size distribution. During plasma on, the large sized particles grows more quickly by fast coagulation between small and large sized particles than during plasma-off. As the pulse frequency decreases, or as the duty ratio increases, $t_{on}$ increases and the large sized particles grow faster. On the basis of these results, the pulsed plasma process can be a good method to suppress efficiently the generation and growth of particles in $SiH_4$ PCVD process. This systematical analysis can be applied to design a pulsed plasma process for the preparation of high quality thin films.

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Bimodal 방법을 이용한 하전입자 응집 모델링 (Development of Simple Bimodal Model for Charged Particle Coagulation)

  • 김상복;송동근;홍원석;신완호
    • 한국입자에어로졸학회지
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    • 제10권1호
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    • pp.27-31
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    • 2014
  • A simple bimodal model has been developed to analyze charged particle coagulation by modifying previously suggested bimdal model for evolution of particle generation and growth. In the present model, two monodisperse modes are used and 40 charge nodes are assigned to each mode to account both change of the particle size and charge distribution. In addition, we also implemented the effect of electrostatic dispersion loss in the present model. Based on the developed model, we analyzed coagulation of asymmetric bipolar charged particles by computing evolutions of particle number concentration, geometric mean diameter of particles, charge asymmetric ratio and geometric standard deviation of particle size distribution for various initial charge asymmetric ratios. The number concentration of asymmetric bipolar charged particles decreases faster than that of neutral particles but that does not give faster growth of particles since the electrostatic dispersion loss overwhelms particle growth by coagulation.

AC 전기장내 하전 액체 입자의 응집에 관한 실험적 연구 (Experimental Study on Electrical Agglomeration of Liquid Particles in an Alternating Electric Field)

  • 지준호;황정호;배귀남;김용진
    • 대한기계학회논문집B
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    • 제25권3호
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    • pp.442-450
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    • 2001
  • Experiments were carried out on agglomeration of bipolarly charged particles in an alternating current electric field. Laboratory-scale setup was built and experiments were conducted at atmospheric condition. DOS(Di-octyl Sebacate) particles with 100% purity were generated by an atomizer. The particles were branched into two, each of which passed through a wire-to-plate type charging section where a positive or a negative DC high voltage was applied and was charged positively or negatively. These bipolarly charged particles together passed through an agglomeration section where an $\pm$20kV AC power was applied between two plates. The resident time in the agglomeration section was adjusted as l sec. Particle sampling was made by a cascade impactor (MOUDI). The effect of agglomeration system on the reduction ratio of particles below l ㎛ was 42∼45%. Effect of AC frequency on the particle size distribution was found insignificant.

Al-Li-( Cu, Zr) 합금에서 시효에 따른 δ' 상의 형상 및 입자크기분포의 변화 (The Changes of the Shape and Particle Size Distribution of δ' Phase on Ageing in Al-Li-( Cu, Zr) Alloys)

  • 우기도;조현기
    • 열처리공학회지
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    • 제7권2호
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    • pp.96-102
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    • 1994
  • The present work was aimed to examine the changes of the shape and particle size distribution(PSD) of ${\delta}^{\prime}$ particles on ageing in Al-Li-(Cu, Zr) alloys which had low density, high specific strength and stiffness, Increasing ageing time and temperature resulted in particles whose aspect ratio tended toward 1. The aspect ratio of ${\delta}^{\prime}$ particles was not dependent upon the ageing temperature and time in Al-Li-Cu alloy but was dependent upon them in Al-Li-Zr alloy. The PSD of ${\delta}^{\prime}$ particles in Al-Li-Zr alloy skewed to the right hand compared with that in Al-Li-Cu alloy, because $Al_3Zr$ phase in Al-Li-Zr alloy formed before ageing promoted the precipitation and growth of ${\delta}^{\prime}$ phase. Therefore, the PSD of the ${\delta}^{\prime}$ particles was found to be affected by the presence of $Al_3Zr$ particles. The growth rate of ${\delta}^{\prime}$ phase was not affected by the existence of the third transition phase $T_1$ formed by the addition of Cu in Al-Li alloy but was affected by the existence of $Al_3Zr$ formed by the addition of Zr in Al-Li alloy.

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Effects of normal stress, shearing rate, PSD and sample size on behavior of ballast in direct shear tests using DEM simulation

  • Md Hussain;Syed Khaja Karimullah Hussaini
    • Geomechanics and Engineering
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    • 제35권5호
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    • pp.475-486
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    • 2023
  • Ballast particles have an irregular shape and are discrete in nature. Due to the discrete nature of ballast, it exhibits complex mechanical behaviour under loading conditions. The discrete element method (DEM) can model the behaviour of discrete particles under a multitude of loading conditions. DEM is used in this paper to simulate a series of three-dimensional direct shear tests in order to investigate the shear behaviour of railway ballast and its interaction at the microscopic level. Particle flow code in three dimension (PFC3D) models the irregular shape of ballast particles as clump particles. To investigate the influence of particle size distribution (PSD), real PSD of Indian railway ballast specification IRS:GE:1:2004, China high-speed rail (HSR) and French rail specifications are generated. PFC3D built-in linear contact model is used to simulate the interaction of ballast particles under various normal stresses, shearing rate and shear box sizes. The results indicate how shear resistance and volumetric changes in ballast assembly are affected by normal stress, shearing rate, PSD and shear box size. In addition to macroscopic behaviour, DEM represents the microscopic behaviour of ballast particles in the form of particle displacement at different stages of the shearing process.

The simulation of the liberation and size distribution of shredder products under the material characteristic coding method

  • Ni, Shiuh-Sheng;Wen, Shaw-Bing;Chu, Chung-Cheng
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.693-698
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    • 2001
  • This paper establishes a coding method system including the liberation and size distribution of recycling materials in the shredder operation. Every particle in the shredded product becomes a code number using the liberation model and size distribution equation transforming of weight percentage into particles number percentage. One set of database can be obtained after all particles have been coded. This database is suitable for the size reduction operation in the process simulation of waste recycling. Coupling with the developed air classification, sizing and separating operations, the whole process simulation will be completely established for diversified application. A typical simulation for the rolling cutting shredder product of waste TV had been demonstrated under this coding system. The breakage size distribution of Gaudin and Schumann equation were selected for the shredding operation simulation. The Gaudin's liberation model was suitable fur the liberation simulation. Both of these equations were transformed weight percentage into particles distribution for the necessary of particle coding method. A better recycling operation for this shredded solid waste can be concluded from the comparison of simulation results with their sorted grade, recovery or economic of materials in different processes.

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과공정 Al-Si합금의 원심주조시 용탕온도와 금형회전수가 경사기능 조직에 미치는 영향에 대한 해석적 고찰 (A Numerical Study of the Effect of Casting Temperature and Rotational Frequency of Mold on the Functionally Graded Microstructure in Centrifugal Casting of Hyper-eutectic Al-Si Alloy)

  • 박정욱;김헌주
    • 한국주조공학회지
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    • 제29권2호
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    • pp.78-85
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    • 2009
  • Functionally graded microstructure of centrifugal cast Al-Si alloy, especially distribution of primary Si particles according to the changes of melt pouring temperature and rotation frequency was investigated by numerical simulation. Moving velocity of Si particles increased as the melt pouring temperature and rotational frequency of mold increased. Therefore, segregation tendency of primary Si particles toward inner side of cylindrical sample increased as the melt pouring temperature and rotational frequency of mold increased. Rich distribution region of particles was located at 0.9, 0.7, 0.4 mm from inner surface of cylindrical sample under the centrifugal cast condition of $750^{\circ}C$ melt pouring temperature and 1500, 2000 and 2500 rpm mold rotational frequencies, respectively, by numerical simulation.

대기압 반응로 내 코로나 이온을 이용한 나노입자 형상의 제어 (Corona ion Assisted Nano-Particle Morphology Control in an Atmospheric Pressure Furnace Reactor)

  • 안강호;윤진욱;김영원
    • 대한기계학회논문집B
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    • 제26권5호
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    • pp.710-715
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    • 2002
  • The spherical nonagglomerated and uniform nanometer-size SiO$_2$particles are synthesized by the injection of TEOS vapor, irons and reaction gas in a furnace. Ions are generated by corona discharge and these ions charge SiO$_2$particles. As a result, spherical, nonagglomerated and ultrafine particles are generated in various conditions. Their morphology, charging portion and size distribution are examined by using TEM, ESP and SMPS. As the applied voltage of electrode changes from 0 to 5.0 kV, it is observed that the melon diameter of SiO$_2$particle decreases from 94 nm to 42 nm.