• Journal of Environmental Science International
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• v.16 no.6
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• pp.683-688
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• 2007

In this study, N doped $TiO_2$ (TiO-N) thin film was prepared by DC magnetron sputtering method to show the photocatalytic activity in a visible range. Various gases (Ar, $O_2\;and\;N_2$) were used and Ti target was impressed by 1.2 kW -5.8 kW power range. The hysteresis of TiO-N thin film as a function of discharge voltage wasn't observed in 1.2 and 2.9kW of applied power. Cross sections and surfaces of thin films by FE-SEM were tiny and dense particle sizes of both films with normal cylindrical structures. XRD pattern of $TiO_2$ and TiO-N thin films was appeared by only anatase peak. Red shift in UV-Vis adsorption spectra was investigated TiO-N thin film. Photoactivity was evaluated by removal rate measurement of suncion yellow among reactive dyes. The photodegradation rate of $TiO_2$ thin film on visible radiation was shown little efficiency but TiO-N was about 18%.

• Membrane and Water Treatment
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• v.14 no.1
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• pp.11-18
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• 2023

This work addresses the development of microfiltration ceramic membrane from alumina using extrusion method. The membranes were sintered at different temperatures ranging between 1000 and 1300℃. The alumina was characterized with thermogravimetric analysis, particle size distribution, X-ray diffraction, Fourier transform infrared spectrometer and scanning electron microscope analysis. Subsequently, the effect of sintering temperature on the membrane properties such as porosity, flexural strength, and pure water permeability was investigated and optimized for the sintering temperature. It is observed that with increasing sintering temperature, the porosity of the membranes decreases and the flexural strength, and pure water permeability of the membranes increase. The uncoated and coated membranes were compared at constant flux mode of filtration. Under the turbidity solution recirculation alone at 100 NTU, trans-membrane pressure (TMP) of uncoated membrane remained constant when the filtration flux was below 121 Lm^-2 h ^-1 , while the coated membrane was 111 Lm_-2 h ^-1 . Although suction pressure increased more rapidly at higher turbidity, coated membrane filtration showed better removal efficiency of the turbidity.

• Journal of Korean Society of Environmental Engineers
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• v.34 no.12
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• pp.787-791
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• 2012

Characteristics of particle separation in water using labscale acoustic standing wave were studied. Acoustic standing wave is similar to either sound wave or ultrasonic, which makes a constant wave while returning to the origin by reflector. During that time, particulates dispersed in water are collected on the node of wave, where a sound pressure is zero. Acoustic standing wave transducer as of 28.0 kHz and 1.0 MHz were utilized and $6.8{\mu}m$ kaolin and $100.5{\mu}m$ redmud in average diameter were used as experimental materials in water. Once acoustic standing wave are generated in water, water temperature rises by $0.15{\sim}0.20^{\circ}C/min$ due to a sound pressure. Initial concentration of kaolin and redmud were controlled to have same as of 0.1, 0.2, 0.3, 0.4, 0.5 g/L, respectively. Removal efficiency of the turbidity in a reacting chamber after 5 minutes, when acoustic sound wave was formed in most distinct, was measured to have 18.2~56.2% for kaolin and 23.0~53.6% for redmud at 1.0 MHz. Particle separation was not observed at 28.0 kHz.

• Membrane Journal
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• v.18 no.1
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• pp.65-74
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• 2008

NOM and fine particles are the main target materials in water treatment using membranes. Particularly, humic substances extracted from soils are frequently used in many fundamental studies representing natural organic matter in raw water for drinking water treatment. In this study, ultrafiltration (UF) of artificial humic water and natural river water was conducted and the characteristics of removal efficiency and permeability were compared. In the UF of river water, the transmembrane pressure increased in the same pattern with that of 5 mg/L humic water. For the removal of organic matter and fine particles, however, two types of feed water had shown different trends. Kaolin particles and humic acids added to artificial water were better removed, while colloids and organics in natural water were relatively poorly removed. From the $UV_{254}$ and GPC analyses, it seemed that the hydrophobicity and size of humic substances contributed to the greater removal of organic matter. The UF membrane applied for humic water also showed a higher flux recovery by caustic chemical cleaning than that for river water.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.8
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• pp.420-427
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• 2016

This study was conducted on the sediment remediation using micro-bubble to remove fine particles. For this study, characteristics of contamination and release in sediment were analyzed. And then, the characteristics of bubbles on removal efficiency was investigated at various operation conditions. In particle size distribution of the sediment used for the study, the proportion of clay and silt (<0.075 mm) was about 7.7%, sand (0.075~4.75 mm) was about 67.8%, and gravel (${\geq}4.75$) was 24.5%. Total nitrogen (TN) and total phosphorus (TP) of the sediment were 2,790~3,260, 261~311 mg/kg respectively. Ignition loss and water content were 4.1~9.6, 32.9~53.2% respectively. In analysis of removal efficiency according to operation conditions of micro-bubble, it was the highest when operation condition is pressure 6 atm, pressurized water ratio 30%, and coagulant dosage 15 ppm. At the time, the sediment's removal efficiency was 19.9%. Accordingly removal efficiency of TN and TP were 21.4, 22.6% respectively. Finally a research was found that fine particles in sediment were almost removed by micro-bubble, which led to decrease nutrients' release at about 20.1~64.3% in comparison to sediment including lots of fine particles.

• Journal of Korean Society of Water and Wastewater
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• v.22 no.5
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• pp.531-540
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• 2008

The main advantage of dissolved air flotation (DAF) in water treatment process is the small dimension compared with conventional gravity sedimentation and it can be basically reduced by the separation zone performed with the short solid-liquid separation time. Fine bubbles make such a short time possible to carry out solid from liquid separation as a collector on the course of water treatment. Therefore, the dimension of separation zone in DAF process is practically determined by the rise velocity of the bubble-floc agglomerates, which is a floc attached with several bubbles. To improve flotation velocity and particle removal efficiency in DAF process, many researchers have tried to attach bubbles as much as possible to flocs. Therefore, the maximum number of attached bubble on a floc and the rise velocity of bubble-floc agglomerates considered as the most important factor to design the separation zone of flotation tank in DAF process was simulated based on the population balance theory. According to the simulation results of this study, the size and volume concentration of bubble influenced on the possible number of attached bubble on a floc. The agglomerates attached with smaller bubble was more sensitive to hydraulic loading rate in the separation zone of DAF process. For the design of a high rate DAF process applied over surface loading 40 m/hr. it is required a precise further study on the variation of bubble property and behavior including in terms of bubble size distribution.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.64.2-64.2
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• 2010

In order to improve the overall power conversion efficiency in dye-sensitized solar cells (DSSCs), it is very important to secure the sufficient surface area of photocatalytic nanoparticles layer for absorbing dye molecules. It is because increasing the amount of dye absorbed generally results in increasing the amount of light harvesting. In this work, we proposed a new method for increasing the specific surface area of photocatalytic titanium oxide ($TiO_2$) nanoparticles by using an inorganic templating method. Salt-$TiO_2$ composite nanoparticles were synthesized in this approach by spray pyrolyzing both the titanium butoxide and sodium chloride solution. After aqueous removal of salt from salt-$TiO_2$ composite nanoparticles, mesoporous $TiO_2$ nanoparticles with pore size of 2~50 nm were formed and then the specific surface area of resulting porous $TiO_2$ nanoparticle was measured by Brunauer-Emmett-Teller (BET) method. Generally, commercially available P-25 with the average primary size of ~25 nm $TiO_2$ nanoparticles was used as an active layer for dye-sensitized solarcells, and the specific surface area of P-25 was found to be ~50 $m^2/g$. On the other hand, the specific surface area of mesoporous $TiO_2$ nanoparticles prepared in this approach was found to be ~286 $m^2/g$, which is 5 times higher than that of P-25. The increased specific surface area of $TiO_2$ nanoparticles will absorb relatively more dye molecules, which can increase the short curcuit current (Jsc) in DSSCs. The influence of nanoporous structures of $TiO_2$ on the performance of DSSCs will be discussed in terms of the amount of dye molecules absorbed, the fill factor, the short circuit current, and the power conversion efficiency.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.12
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• pp.7438-7442
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• 2014

An assessment of flocculation was performed by measuring the distribution of the floc size during sedimentation in water works. The size and number of flocs have a greater effect on an evaluation of the efficiency of flocculation rather than the turbidity. The data was collected in situ using particle image velocimetry and image analysis. The measurements were carried out at a water depth of 1m. The removal efficiency of the total organic compounds, UV absorbance and turbidity depended on the size and floc size distribution in flocculation as the G value. The G value of 50 sec-1, 30 sec-1 and 10 sec-1 showed the highest degree of efficiency in the case of an inlet water turbidity of 5 NTU, and the highest degree of efficiency was observed at a G value of 65 sec-1, 40 sec-1 and 10 sec-1 when the inlet water turbidity was 263 NTU. The number of flocs with a distribution of above $1,200{\mu}m$ was 14. The dynamics between two important growth mechanisms were investigated as the energy input changed. This is a certain method that makes use of the size and number of flocs as an efficiency assessment.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.1
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• pp.159-167
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• 2000

In recent years, combined and separated sewer overflows (CSOs, SSOs) have been recognized as a significant pollution problem. To solve this problem a series of experiments were performed in a small scale Rapid Floc Settler (RFS) device to determine its ability in removing micro particles and dissolved materials from polluted waters. The RFS device is a compact physico-chemical wasterwater treatment system. Polyacrylamide (PAM) is used as a coagulant for treating stormwater in the RFS. The results of Jar test showed that PAM could be an excellent coagulant as compared with aluminum sulfate. and ferric chloride. In several experimental conditions, the influence of different variation parameters was tested to measure the efficiency of the RFS. Tests have been carried out with typical CSOs concentrations (50~1.000mg SS/L). The treatment efficiency with regard to SS and COD, which can be obtained at an overflow rate of $130m^3/m^2/day$, are 90% and 80%, respectively. Comparing other sedimentation technologies with RFS, the overflows rate of RFS is ten times faster. The distribution of particle size and number were analyzed. The RFS is suitable for the treatment of CSOs and also the removal of settleable and dissolved materials in urban stormwater runoff.

• Journal of Korean Society on Water Environment
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• v.35 no.2
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• pp.145-151
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• 2019

The purpose of this study was to investigate treatment characteristics of diatomite filtration, that would allow water recovery from biologically-treated effluent for reuse. Diatomite, Celpure 100, and acid clay were used as filter-aids, with a support filter manufactured from polyethylene (PE), and polypropylene (PP). This pre-coating process using diatomite filter-aids, is used in the filtration range of pressure filters, and has consistently provided high-quality separation. The results showed that variations in average removal efficiency of SS, and T-P from biologically treated effluent by the diatomite-coated PE filter, were approximately 82.2 ~ 88.9 % and 4.8 ~ 21.1 %, respectively. T-P treatment efficiency of the PP filter pre-coated with diatomite and $Celpure^{(R)}100$ at $57.64g/m^2$, was approximately $24{\pm}10%$ and $40{\pm}15%$ on average, respectively. Particle size distribution of secondary effluent varied from 0.05 to $200{\mu}m$, and $d_{50}$ value was $20.76{\mu}m$. The size distribution of particles in the diatomite filtrate ranged from 1.26 to $101.1{\mu}m$ when pre-coated with diatomite filter-aid, at a content of $57.64g/m^2$. Diatomite filter aids, i.e., the particles that form the pre-coating layer, capture very fine particles as well as macromolecules, owing to their complex structure with numerous fine microscopic pores, and surface properties. The filtration process using diatomite and $Celpure^{(R)}100$ as filter aids, has been successfully applied, to recover water from sewage for reuse. The disadvantage of the process, is that the particle size of the filter-aid is spent, because of pressurization.