• Title/Summary/Keyword: particle inversion

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A Study on the Characteristics of Microemulsion Containing Isoflavone (이소플라본을 함유한 마이크로에멀젼의 물성 연구)

  • Jeong, Noh-Hee;Moon, Young-Jin;Lee, Hyang-Woo;Kim, Hong-Soo
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.1
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    • pp.56-62
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    • 2002
  • Microemulsion is stable to aggregation, sedimentation, fusion and has $3nm{\sim}200nm$ of particle size which is transparent and semitransparent. The isoflavone as a derivatives of Flavone is colorless crystalline compounds. It has similar basic structure to steroid materials which is hormone that acts to skin physiological phenomenon. On this study, we tried to search and demonstrate system content rate of dermal translocation system for cosmetics using O/W type microemulsion containing isoflavone. We manufactured O/W microemulsions by phase inversion emulsification method. It's was found that POE(20) monostearate with HLB value 14 caused microemulsion to be formed, which had $4nm{\sim}18nm$ of average diameter and $3nm{\sim}33nm$ of particle size distribution. Apparent viscosities of the microemulsions have increased in proportion to add surfactant dose.

Properties of Microemulsion Containing Quaternary Ammonium Salt as Polishing Wax (광택용 왁스로서 4차 암모늄염을 함유한 마이크로에멀젼의 특성)

  • Lee, Jang-Weon;Kim, Myung-Soo;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.4
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    • pp.335-344
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    • 2004
  • In this work, the properties as polishing wax for automobile of O/W type microemulsion containing wax, liquid paraffine and quaternaryammonium salt was investigated. The microemulsions were prepared at $96{\sim}97^{\circ}C$ by the phase inversion method, and polyoxyethylene(20) sorbitan monooleate (POE(20)SMO) and distearyl dimethyl ammonium chloride(D.D.A.C) as the emulsifiers were used. The mean particle size of the rnicroemulsions was about 7${\pm}$0.5nm and as the properties of polishing wax, gloss increased degree, water resistant gloss degree, initial and final contact angle after water resistance were tested. The result was that the value of water resistantance and contact angle were decreased with increasing amount of POE(20)SMO and D.D.A.C., while the gloss degree values did not affected. And the rnicroemulsion blended with mono ethylene glycol(MEG) of 5${\sim}$15wt% showed smaller particle size and more stable particle size distribution than without MEG. Finally, this microemulsion showed more excellent values of gloss degree, the water resistant gloss degree and contact angle, than two kinds of commercial polishing wax for automobile.

Experimental Investigation on Flame Structure and Emission Characteristics in a Lean Premixed Model Gas Turbine Combustor (희박 예혼합 모형 가스터빈 연소기의 화염구조와 배기특성에 관한 실험적 연구)

  • Moon, Gun-Feel;Lee, Jong-Ho;Jeon, Chung-Hwan;Chang, Young-June
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.356-361
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    • 2003
  • The objective of this study is a qualitative comparison between line-integrated OH chemiluminescence ($OH{\ast}$) image and its Abel inversion image at different phase of the oscillating pressure field. PIV(Particle Image Velocimetry) measurements were conducted under non-reacting conditions to see the global flow structure. Also NOx emission was measured to investigate the effect of fuel-air premixing on combustion instability and emission characteristics. Experiments were carried out in an atmospheric pressure, laboratory-scale dump combustor operating on natural gas. Combustion instabilities in present study exhibited a longitudinal mode with a dominant frequency of ${\sim}341.8$ Hz, which corresponded to a quarter wave mode of combustor. Heat release and pressure waves were in-phase when instability occurred. Results gave an insight about the location where the strong coherence of pressure and heat release existed. Also an additional information on active control to suppress the combustion instabilities was obtained. For lean premixed combustion, strong correlation between $OH{\ast}$ and NOx emissions was expected largely due to the exponential dependence of thermal NOx mechanism on flame temperature.

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Study on Optimization and Skin Permeation of PIT Nanoemulsion Containing α-Bisabolol (α-Bisabolol을 함유한 PIT Nanoemulsion의 최적화 및 피부흡수연구)

  • Kim, HuiJu;Yoon, Kyung-Sup
    • Journal of the Korean Applied Science and Technology
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    • v.37 no.6
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    • pp.1738-1751
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    • 2020
  • The skin is divided into three parts: the epidermis, the dermis, and the subcutaneous fat, and the stratum corneum, which is located at the top of the epidermis, acts as a barrier that prevents drug delivery. Nanoemulsions are known to be effective in transdermal delivery of drugs through intercellular lipids because of their unique small particle size. In this study, phase inversion temperature (PIT) nanoemulsion containing α-bisabolol was optimized using response surface methodology (RSM) for effective skin absorption of α-bisabolol. As a preliminary experiment, the 25-2 fractional factorial design method and the 23 full factorial design method were performed. Box-Behnken design was performed based on the results of the factorial design method. The content of surfactant (6.3~12.6%), co-surfactant (5.2~7.8%) and α-bisabolol (0.5~5.0%) were used as factors, and the dependent variable was the particle size of the nanoemulsion. PIT nanoemulsion optimization was performed according to the RSM results, and as a result, the optimal nanoemulsion formulation conditions were predicted to be 10.4% surfactant content, 6.3% co-surfactant content, and 5.0% α-bisabolol content. As a result of the skin absorption test, the final skin absorption rate of the PIT nanoemulsion was 35.11±1.01%, and the final skin absorption rate of the general emulsion as a control was 28.25±1.69%, confirming that the skin absorption rate of the PIT nanoemulsion was better.

Application of Nanoemulsions upon Type of Cosmetic Oils for Convergence Type of Cosmetics (화장품용 오일 타입에 따른 나노에멀젼의 융복합 화장품 적용)

  • Cho, Wan-Goo
    • Journal of Digital Convergence
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    • v.13 no.4
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    • pp.369-375
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    • 2015
  • In this study, the formation potential and the stability of nano-emulsions were evaluated according to the structure of various cosmetic oils in Tween 80/Span 80 system using PIC method at 80 oC LP 70, Isopar H and Pripure 3759 of hydrocarbons were both form a stable nano-emulsion, particle size distribution of about 40 nm. A linear structure of silicone oil formed an unstable emulsion, but cyclic or short chain oil formed was a stable nano-emulsion. In ester oils, the particle size of emulsions increases with increasing molecular weight of oils and a stable nano-emulsion could not be obtained in the molecular weight of about 450. The particle size of the nano-emulsion against required HLB value for calculating in consideration of the lipophilic and hydrophilic oil was smaller in the HLB of 8-10.

Near-Infrared Photopolarimetry of Large Main Belt Asteroid - (4) Vesta

  • Bach, Yoonsoo P.;Ishiguro, Masateru;Takahashi, Jun;Naito, Hiroyuki;Kwon, Jungmi;Kuroda, Daisuke
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.1
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    • pp.45.1-45.1
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    • 2021
  • The polarization degree as a function of phase angle (the Sun-target-observer's angle), so-called the polarimetric phase curves (PPC), have provided priceless information on asteroids' albedos since B. Lyot (1929). Succeeding experimental works in 1970s have confirmed the Umow law: There is a universal and strong correlation between the albedo and the PPC slope (slope of the tangential line at the zero of the PPC at phase angle ~ 20 degrees). Experiments in 1990s (ref [1]), on the other hand, have demonstrated that the negative branch of PPC is dependent on the size parameter (X ~ π * particle-size / wavelength), especially when X <~5. The change in particle size changed the minimum polarization degree, location of the minimum, and the width of the negative branch (called the inversion angle). From polarimetry[2] and spectroscopy[3], large asteroids are expected to be covered with fine (<~ 10 ㎛ size) particles due to the gravity. The size parameters are X ~ 30 at the optical wavelength (λ ~ 0.5 ㎛) and X ~ 10 in near-infrared (J, H, Ks bands; λ ~ 1.2-2.2 ㎛), if the representative particle size of 5 ㎛ is considered. Accordingly, the near-infrared polarimetry has a great potential to validate the idea in ref[1]. We conducted near-infrared photopolarimetry of the large asteroid (4) Vesta using the Nishiharima Infrared Camera (NIC) at Nishi-Harima Astronomical Observatory (NHAO). NIC allows simultaneous polarimetric measurements in J, H, and Ks bands, and thus the change of PPC is obtained for three different size parameters. As a result, we found a signature of the change in the negative branch in the PPC of asteroid (4) Vesta. We will introduce our observation and the results and give an interpretation of the regolith on Vesta.

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Effect of pH on the Luminescence of $(Y,Gd)BO_3:Eu^{3+}$ Phosphor Prepared by the Coprecipitation Method

  • Lee, Gwan-Hyoung;Kang, Shin-Hoo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1514-1517
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    • 2005
  • The $(Y,Gd)BO_3:Eu^{3+}$ phosphor was made by coprecipitation method. The precipitated powders were amorphous. The value of pH in the process of coprecipitation was critical for the luminescence of phosphors. The particle size and morphology were influenced by pH value. The lower calcination temperature and hydrothermal synthesis leads to the distortion of lattices. The distorted lattices changed the symmetry of $Eu^{3+}$ site. The broken inversion symmetry in the distorted lattice caused the increased emission of $^5D_0{\rightarrow}^7D_2$ transition.

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Measurement of Velocity-Lag of Suspended-Sediment Particles in Turbulent Open-Channel Flows (난류 중 부유사의 속도 지체 측정)

  • Yu, Kwon-Kyu;Marian Muste;Robert Ettema;Yoon, Byung-Man
    • Journal of Korea Water Resources Association
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    • v.39 no.2 s.163
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    • pp.99-108
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    • 2006
  • To describe the behavior of suspended-sediment particles in turbulent open-channel flows, the advection-diffusion equation or its simplified form has been used. Though this equation was derived upon several assumptions, only a few studies tried to evaluate the limit of the assumptions. The reason is that it is very difficult to measure turbulence in open-channel flows and to discriminate the velocities of water and sediment particles. The present study aims to measure the velocity profiles of water and sediment particles in open-channel flows by using PTV (Particle Tracking Velocimetry), a kind of PIV (Particle Image Velocimetry). The measured results showed that sediment particles moved slower than water tracers did in the outer region. In the present study, the amount of velocity-lag reached about $5\%$ of the mom flow velocity and the position of the maximum velocity-lag was $g/h\approx0.05\;(g^{+}=30\~50)$ The main cause of the velocity-lag of sediment particles seems that the sediment particles have larger density than water has. On the other hand, in the viscous sublayer, sediment particle has a larger velocity than water tracers. The reason of the inversion of velocity-lag may be due to the no-sleep condition of water at the solid boundaries.

Recycling of Suspended Particulates by Atmospheric Boundary Depth and Coastal Circulation

  • Choi, Hyo
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.11a
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    • pp.19-26
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    • 2003
  • The dispersion of recycled particulates in the complex coastal terrain containing Kangnung city, Korea was investigated using a three-dimensional non-hydrostatic numerical model and lagrangian particle model (or random walk model). The results show that particulates at the surface of the city that float to the top of thermal internal boundary layer (TIBL) are then transported along the eastern slope of the mountains with the passage of sea breeze and nearly reach the top of the mountains. Those particulates then disperse eastward at this upper level over the coastal sea and finally spread out over the open sea. Total suspended particulate (TSP) concentration near the surface of Kangnung city is very low. At night, synoptic scale westerly winds intensify due to the combined effect of the synoptic scale wind and land breeze descending the eastern slope of the mountains toward the coast and further seaward. This increase in speed causes development of internal gravity waves and a hydraulic jump up to a height of about 1km above the surface over the city. Particulate matter near the top of the mountains also descends the eastern slope of the mountains during the day, reaching the central city area and merges near the surface inside the nocturnal surface inversion layer (NSIL) with a maximum ground level concentration of TSP occurring at 0300 LST. Some particulates were dispersed following the propagation area of internal gravity waves and others in the NSIL are transported eastward to the coastal sea surface, aided by the land breeze. The following morning, particulates dispersed over the coastal sea from the previous night, tend to return to the coastal city of Kangnung with the sea breeze, developing a recycling process and combine with emitted surface particulates during the morning. These processes result in much higher TSP concentration. In the late morning, those particulates float to the top of the TIBL by the intrusion of the sea breeze and the ground level TSP concentration in the city subsequently decreases.

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Stability of Nano-emulsions Containing Fatty Acid and Fatty Alcohol (지방산 및 지방알코올을 함유한 나노에멀젼의 안정성)

  • Cho, Wan Goo;Kim, Kyung Ah;Jang, Seon Il;Cho, Byoung Ok
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.43 no.4
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    • pp.273-279
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    • 2017
  • In this study, low viscous O/W (oil-in-water) nano-emulsion with fatty acid and fatty alcohol was prepared by phase inversion emulsification method using Tween 80 and Span 80 widely used in cosmetic products. The particle size of the nano-emulsion was increased as increasing the concentration of fatty alcohol in oil phase. Adjusting the HLB of mixed surfactants, a stable nano-emulsion with a narrow size distribution was produced. Similar change in viscosity and electrical conductivity in both systems containing fatty acid and fatty alcohol was shown in the vicinity of the phase inversion point. However, high viscosity was shown in a wide range of different aqueous fraction unlike the system consisting only oils and surfactants. The low viscous nano-emulsion with less than 100 nm droplet size was stable for one month or more at room temperature. O/W nano-emulsions with low viscosity containing fatty acid or fatty alcohol produced by low-energy emulsification method can be widely used as formulations of cosmetics.