• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2003.11a
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• pp.227-230
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• 2003

Silicone rubber has very excellent chemical stability and hydrophobicity. A hydrophobic surface can prevent the formation of continuous water films on the surface in wet and heavily contaminated conditions. This phenomenon contributes to the suppression of leakage current and partial discharges on insulator surfaces. Silicone rubber has been used much for housing materials of polymer insulators. ATH is added to the silicone rubber for improvement of its resistance against surface discharge. In this paper, ATH with different particle size and content was added to the silicone rubber during compounding. Silicone rubber was deteriorated by a corona treatment. Hydrophobicity recovery rate after corona treatment and arc resistance of silicone rubber were investigated. Hydrophobicity recovery rate of silicone rubber was evaluated by the measurement of contact angle. Arc resistance was evaluated by measuring weight loss of silicone rubber after arc resistance test. It was observed that the hydrophobicity recovery rate and arc resistance of silicone rubber were different when different particle size and content of ATH were added.

• Macromolecular Research
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• v.17 no.5
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• pp.339-345
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• 2009

The core/shell type structure of the highly crosslinked poly(glycidylmetharylate-co-divinylbenzene) microspheres prepared in the precipitation polymerization in acetonitrile was thoroughly verified by means of swelling, $^1H$ NMR, XPS, TEM and TGA measurements. In the XPS measurement, the higher the GMA content, the higher the oxygen content was observed, implying that the higher content of GMA is observed in the particle surface. The further verification of the core/shell structure of the poly(GMA-co-DVB) particles was carried out using $^1H$ NMR and TEM techniques, resulting in the poly(GMA-co-DVB) particles with the GMA rich-phase and DVB rich-phase. In overall, the poly(GMA-co-DVB) microspheres consist of a highly crosslinked DVB rich-phase in the core and slightly or non-crosslinked GMA rich-phase in the shell part due to the different reaction ratios between two monomers and self-crosslinking density of DVB.

• Journal of the Korean Ceramic Society
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• v.31 no.2
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• pp.117-128
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• 1994

Hematite particles were obtained by hydrothermal reaction of ferric hydroxide in the presence of small amount of citric acid which is acted as crystal growth controller. The effects of hydrothermal reaction condition son the morphology and crystal structure of powder were investigated using X-ray, TEM and FT-IR. Ellipsoidal or rectangular hematite particles were formed in the range of pH 10.75~11.75 as initial basicity of reactants and 3$\times$10-5 ~9$\times$10-5 mol as citric acid content. Crystallization of hematite was inhibited in the range of pH9. 0~10.5 and above citric acid content of $1.5\times$10-4 mol. Hematite particle length and aspect ratio were decreased gradually with increasing of citric acid content. Hematite particles formed at 14$0^{\circ}C$ exhibited particle properties with the length of 0.7 ${\mu}{\textrm}{m}$ and aspect ratio of 8. Hematite particles having a good acicular-type were not obtained above 22$0^{\circ}C$.

• Proceedings of the Korea Concrete Institute Conference
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• 2003.11a
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• pp.449-452
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• 2003

The objective of this study is to investigate the basic properties of polyester mortars using ground calcium carbonate(GCC), blast furance slag(BFS), fly ash(FA), ordinary portland cement(OPC) as fillers. Particle size distribution, particle shape and resin absorption of GCC, BFS, FA and OPC are checked. Polyester mortars with GCC, BFS, FA and OPC are prepared with various MEKPO content and tested for working life. The flexural and compressive strengths of the polyester mortars with MEKPO content of 0.5phr are evaluated. As a test result, the average sizes of GCC, BFS, FA and OPC are 9.7$\mu\textrm{m}$, 11.6$\mu\textrm{m}$, 21.2$\mu\textrm{m}$, 29.9$\mu\textrm{m}$. Resin absorption of FA is 1.5times larger than other fillers. The polyester mortar with FA at a MEKPO content of 0.5phr has the longest working life and the maximum flexural and compressive strengths.

• Journal of the Korean Ceramic Society
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• v.32 no.1
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• pp.37-44
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• 1995

TiO2 fine powders were synthesized using oxygenolysis and hydrolysis reaction of TiCl4 vapor in gas phase. The TiO2 powder synthesized showed morphological differences depending on reaction system as follows: TiCl4-O2 reaction system produced the monosized particles having polyhedral shape with well-defined crystal planes and the particles did not agglomerate into secondary particles. TiCl4-H2O reaction system, whereas, produced the spherical secondary particles which consisted of fine primary particles. Other powder characteristics such as particle size, impurity content and rutile content are also reported in this study.

• Journal of the Korean GEO-environmental Society
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• v.21 no.11
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• pp.21-26
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• 2020

Natural soil is composed of particles of various sizes, and the shear behavior which is a kind of mechanical behavior of the soil is affected by the particle size distribution. In addition, since the natural soil contains a large mixture of coarse and fine grained soil, it is difficult to clearly understand the shear behavior of the soil. Therefore, a ring shear test was conducted on sandy soils that has various particle size distribution in order to identify the effect of the distribution on shear characteristics of soils. At this time, sand and silt were used for coarse and fine grained soils, respectively, to make sandy soils by changing the silt content. Also the water was supplied during the test to confirm shear characteristics of sandy soils with various particle size distributions. The result shows that the shear strength increases as the silt content increases, and the strength decreases as the silt content increases over the sand. Besides, residual shear strength gradually decreases because of the silt content when the water is supplied.

• Journal of the Korean Ceramic Society
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• v.40 no.3
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• pp.273-278
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• 2003

The effects of content and particle size of sewage sludge slag on the sound absorption was investigated and the physical$.$mechanical properties of porous ceramics for sound absorbent material was studied. The physical$.$mechanical properties of specimens have depended on sintering temperature and slag content without particle size effect of slag. As water glass content increase and particle size of slag decrease at the same slag content, physical$.$mechanical properties of them have been improved. The bulk density and compressive strength of specimens with the batch composition of 77∼89 wt% of slag content and particles with 1∼3 mm, and sintered at 1,050$^{\circ}C$ for 2 h were 1.48∼1.71 and 86∼163 kgf/$\textrm{cm}^2$, respectively. The specimens with 1∼3 mm and <1 mm of particles size showed good sound absorption property at low frequency and high frequency region. With increasing thickness of specimens, sound absorption properties at low frequency region were increased.

• Applied Chemistry for Engineering
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• v.8 no.4
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• pp.575-581
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• 1997

UDs were synthesized from two different polyols(PTMG, PBEAG), ionic chain extender(DMPA), EDA with $H_{12}-MDI$. PU/PMMA hybrids were prepared with free radical polymerization of MMA monomer in MMA-swelled PUD. PUD particle size and film properties were investigated ionic content and polyol type. Mechanical and thermal properties of PU/PMMA hybrid film were studied in terms of PU's ionic content and the venation of PU/PMMA compositions. As DMPA content increased from 2wt% to 10wt% in PUD, particle size of PUD decreased. PUD's particle size with ester type polyol was found to be smaller then ether type polyol used. Phase separation between hard segment(HS) and soft segment(SS) with ionic contents in PU was shown by the thermal, mechanical property measurement. Although the composition of MMA was changed from 0 to 40 wt% in PU/PMMA hybrid, the particle size of the hybrid did not increase. Using the ester type polyol, tensile strength of hybrid was found to increase by 2wt% - 6wt% DPMA content, but as higher content the strength of hybrid decreased. Moreover with the ether type polyol, tensile strength of hybrid was observed to increase by 2wt% - 4wt% DMPA content, while decreasing at higher content. PU and PMMA polymer molecule being mixed in molecular level was confirmed from the pattern of $T_g$ in DSC thermogram.

• Journal of the Korea Organic Resources Recycling Association
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• v.17 no.4
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• pp.103-111
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• 2009

Moisture is one of the important design factors that affects to the changes of physical properties and air permeability in the composting matrix. This study examines the effects of moisture during the wetting and drying procedure on physical properties like bulk density, particle size, free air space and air permeability in the sawdust used as the bulking agent in composting process. During both procedures of wetting and drying of the water, with increasing moisture content, bulk density and particle size increased, but FAS decreased. In the range of near 40 to 60% moisture content on a wet basis, particle size and FAS in wetting procedure were larger and higher than those in drying procedure. During wetting procedure, pressure drop continuously decreased ranging from near 20 to 60% moisture content, despite of decreasing FAS as a consequence of increasing moisture, and then over the range of 60% moisture content, pressure drop rapidly increased to the saturated moisture condition while the pore space was filled with the water. On the other hand, during drying procedure, pressure drop decreased from the saturated condition to 40% moisture content. In the recommended range of 50 to 60% moisture content for composting operation, pressure drop in wetting procedure were lower than in drying procedure. For the enhancement of the air permeability in the composting matrix, the wetting procedure was proper than the drying procedure, and the optimum moisture content for the efficient composting operation was appeared to be near 60%.

• Journal of the Korea Organic Resources Recycling Association
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• v.20 no.4
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• pp.106-117
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• 2012

Indirected heating dryer is used as one of the food waste treatment technologies for the production of the drier material supplied to the recycling facilities or end user. This study investigated the effect on drying efficiency for the operation of rotating screw with the circulating and falling movements on indirected drying process of food waste. The screw operating condition showed higher drying efficiency despite of the shorter drying time compared to the screw non-operating condition. The moisture content decreased to 14.4% from the initial moisture content of 77.1% after drying 5 hours in the screw operating condition. On the other hand, in the screw non-operating condition, the moisture content decreased slightly to 35.6% after drying 16 hours. During the drying process, variations of the water evaporation rate and particle size showed different tendencies depending on the moisture content regions. In the higher moisture content region above the glue zone(moisture content of about 50%-60%), the particle size increased and the water evaporation rate reached the highest peak. In the range of glue zone, the particle size maximized while the water evaporation rate decreased sharply. In the lower moisture content region below the glue zone, the water evaporation rate and particle size both decreased at the same time. The particle size distribution was widely ranged from 25.0mm to 0.25mm in the screw operating condition while it was narrowly distributed in the screw non-operating condition from 25.0mm to 3.56mm, especially highly concentrated to 25.0mm. It was regarded that the hygroscopic, capillary and gravitational water evaporated more easily from the intra-particle during the circulating and falling movement caused by the rotating of the screw and the difference of the cohesional force of water within intra-particle depending on the moisture content regions. Comparing the effect of the circulating and falling movement on drying efficiency, the water evaporation rates per time and per weight of dry solid in the screw operating condition were higher about 364% and 356%, respectively, than those of the screw non-operating condition.