• Title/Summary/Keyword: particle aggregation

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Effect of Particle Aggregation on Dynamic Response of An Electrorheological Fluid in Shear Mode (전단 유동을 하는 전기유변 유체의 동적 응답에 입자 응집이 미치는 영향)

  • Choi, Byung-Ha;Nam, Yun-Joo;Park, Myeong-Kwan
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2885-2889
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    • 2007
  • In this study, the effect of particle aggregation on dynamic response time of Electrorheological (ER) fluid is investigated. The particle aggregation time is defined as the time interval between the application of the field and the formation of the first chain bridging the two electrodes. The dynamic response times of an ER fluid sheared between two concentric cylinders have been obtained under two different experimental conditions: the one is that the electric field is induced before shearing, and the other is that the electric field is induced after shearing. From the difference between two response times, the particle aggregation times are determined under various electric fields and shear rates. The experimental results show that the aggregation rate is decreased with an increase of shear rate, while electric field has little effect on it. Therefore, it is verified that the hydrodynamic force hinders the formation of chain-like structures.

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Effects of Water Chemistry on Aggregation and Soil Adsorption of Silver Nanoparticles

  • Bae, Sujin;Hwang, Yu Sik;Lee, Yong-Ju;Lee, Sung-Kyu
    • Environmental Analysis Health and Toxicology
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    • v.28
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    • pp.6.1-6.7
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    • 2013
  • Objectives In this study, we investigated the influence of ionic strength and natural organic matter (NOM) on aggregation and soil adsorption of citrate-coated silver nanoparticles (AgNPs). Methods Time-resolved dynamic light scattering measurements and batch adsorption experiments were used to study their aggregation and soil adsorption behaviors, respectively. Results The aggregation rate of AgNPs increased with increasing ionic strength and decreasing NOM concentration. At higher ionic strength, the AgNPs were unstable, and thus tended to be adsorbed to the soil, while increased NOM concentration hindered soil adsorption. To understand the varying behaviors of AgNPs depending on the environmental factors, particle zeta potentials were also measured as a function of ionic strength and NOM concentration. The magnitude of particle zeta potential became more negative with decreasing ionic strength and increasing NOM concentration. These results imply that the aggregation and soil adsorption behavior of AgNPs were mainly controlled by electrical double-layer repulsion consistent with the Derjaguin-Landau-Verwey-Overbeek theory. Conclusions This study found that the aggregation and soil adsorption behavior of AgNPs are closely associated with environmental factors such as ionic strength and NOM and suggested that assessing the environmental fate and transport of nanoparticles requires a thorough understanding of particle-particle interaction mechanisms.

Numerical Study of Aggregation and Breakage of Particles in Taylor Reactor (테일러 반응기 내의 입자응집과 분해에 관한 수치 연구)

  • Lee, Seung Hun;Jeon, Dong Hyup
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.6
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    • pp.365-372
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    • 2016
  • Using the computational fluid dynamics (CFD) technique, we simulated the fluid flow in a Taylor reactor considering the aggregation and breakage of particles. We calculated the population balance equation (PBE) to determine the particle-size distribution by implementing the quadrature method-of-moment (QMOM). It was used that six moments for an initial moments, the sum of Brownian kernel and turbulent kernel for aggregation kernel, and power-law kernel for breakage kernel. We predicted the final mean particle size when the particle had various initial volume fraction values. The result showed that the mean particle size and initial growth rate increased as the initial volume fraction of the particle increased.

Effects of the Particle Electric Conductivity on the Aggregation of Unipolar Charged Nanoparticles (단극하전 나노입자의 응집성장 과정에서 입자의 전기전도도의 효과에 대한 연구)

  • Park, Hyung-Ho;Kim, Sang-Soo;Chang, Hyuk-Sang
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.27 no.2
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    • pp.173-180
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    • 2003
  • Effects of the electric conductivity of particles were studied for the aggregation process of charged particles with a Brownian dynamic simulation in the free molecular regime. A periodic boundary condition was used for the calculation of the aggregation process in each cell with 500 primary particles of 16 nm in diameter. We considered two extreme cases, a perfect conductor and a perfect nonconductor. The electrostatic force on a particle in the simulation cell was considered as a sum of electrostatic forces from other particles in the original cell and its replicate cells. We assumed that aggregates were only charged with pre-charged primary particles. The morphological shape of aggregates was described in terms of the fractal dimension. The fractal dimension for the uncharged aggregate was D$_{f}$= 1.761. However, the fractal dimension decreased from 1.694 to 1.360 for the case of the perfect conductor, and from 1.610 to 1.476 for the case of the perfect nonconductor, with the increase of the average number of charges on the primary particle from 0.2 to 0.3. These values were smaller than that of the centered charge case.e.

Fundamental study on cancer therapy by blocking newborn blood vessels by magnetic force control

  • KIRIMURA, Makoto;AKIYAMA, Yoko;NISHIJIMA, Shigehiro
    • Progress in Superconductivity and Cryogenics
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    • v.20 no.2
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    • pp.11-15
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    • 2018
  • In this study, a cancer treatment by accumulating and aggregating ferromagnetic particles in newborn blood vessels was examined. It is necessary for this treatment to control dispersion-aggregation property of ferromagnetic particles. Ferromagnetic particles required in this method disperse at low magnetic field, aggregate at high magnetic field and maintain the aggregation even after removal of the magnetic field. In order to control the dispersion-aggregation property, the surface of magnetite particles was modified with higher fatty acids having different lengths. As a result, we succeeded to prepare propionic acid-modified magnetite particles that form irreversible aggregation by magnetic field. The model experiments simulating newborn blood vessels showed that these particles can block the flow by the magnetic field, and the blockage was maintained after removal of the magnetic field.

Numerical Simulation for the Aggregation of Charged Particles (하전입자의 응집성장에 대한 수치적 연구)

  • Park, Hyung-Ho;Kim, Sang-Soo;Chang, Hyuk-Sang
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.605-611
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    • 2001
  • A numerical technique for simulating the aggregation of charged particles was presented with a Brownian dynamic simulation in the free molecular regime. The Langevin equation was used for tracking each particle making up an aggregate. A periodic boundary condition was used for calculation of the aggregation process in each cell with 500 primary particles of 16 nm in diameter. We considered the thermal force and the electrostatic force for the calculation of the particle motion. The morphological shape of aggregates was described in terms of the fractal dimension. The fractal dimension for the uncharged aggregate was $D_{f}=1.761$. The fractal dimension changed slightly for the various amounts of bipolar charge. However, in case of unipolar charge, the fractal dimension decreased from 1.641 to 1.537 with the increase of the average number of charges on the particles from 0.2 to 0.3 in initial states.

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Numerical Simulation far the Non-Spherical Aggregation of Charged Particles (하전 입자의 비구형 응집 성장에 대한 수치적 연구)

  • Park, Hyeong-Ho;Kim, Sang-Su;Jang, Hyeok-Sang
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.2
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    • pp.227-237
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    • 2002
  • A numerical technique for simulating the aggregation of charged particles was presented with a Brownian dynamic simulation in the free molecular regime. The Langevin equation was used for tracking each particle making up an aggregate. A periodic boundary condition was used for calculation of the aggregation process in each cell with 500 primary particles of 16 nm in diameter. We considered the thermal force and the electrostatic force for the calculation of the particle motion. The electrostatic force on a particle in the simulation cell was considered as a sum of electrostatic forces from other particles in the original cell and its replicate cells. We assumed that the electric charges accumulated on an aggregate were located on its center of mass, and aggregates were only charged with pre-charged primary particles. The morphological shape of aggregates was described in terms of the fractal dimension. In the simulation, the fractal dimension for the uncharged aggregate was D$\_$f/ = 1.761. The fractal dimension changed slightly for the various amounts of bipolar charge. However, in case of unipolar charge, the fractal dimension decreased from 1.641 to 1.537 with the increase of the average number of charges on the particles from 0.2 to 0.3 in initial states. In the bipolar charge state, the average sizes of aggregates were larger than that of the uncharged state in the early and middle stages of aggregation process, but were almost the same as the case of the uncharged state in the final stage. On the other hand, in the unipolar charge state, the average size of aggregates and the dispersion of particle volume decreased with the increasing of the charge quantities.

Effect of Homogenization Pressure on Plasmin Activity and Mechanical Stress-Induced Fat Aggregation of Commercially Sterilized Ultra High Temperature Milk during Storage

  • Kim, Sun-Chul;Yun, So-Yul;Ahn, Na-Hyun;Kim, Seong-Min;Imm, Jee-Young
    • Food Science of Animal Resources
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    • v.40 no.5
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    • pp.734-745
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    • 2020
  • Commercially sterilized ultra high temperature (UHT) milk was manufactured at different homogenization pressures (20, 25, and 30 MPa), and changes in fat particle size, mechanical stress-induced fat aggregation, plasmin activity, and lipid oxidation were monitored during ambient storage of the UHT milk for up to 16 wk. The particle sizes of milk fat globules were significantly decreased as homogenization pressure increased from 20 to 30 MPa (p<0.05). The presence of mechanical stress-induced fat aggregates in milk produced at 20 MPa was significantly higher than for UHT milk produced at either 25 or 30 MPa. This difference was maintained all throughout the storage. There were no significant differences in plasmin activity, trichloroacetic acid (12%, w/v) soluble peptides, and the extent of lipid oxidation. Based on these results, an increase of homogenization pressure from 20 (the typical homogenization pressure employed in the Korea dairy industry) to 25-30 MPa significantly decreased mechanical stress-induced fat aggregation without affecting susceptibility to lipid oxidation during storage.

Effects of hydrodynamics and coagulant doses on particle aggregation during a rapid mixing

  • Park, Sang-Min;Heo, Tae-Young;Park, Jun-Gyu;Jun, Hang-Bae
    • Environmental Engineering Research
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    • v.21 no.4
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    • pp.365-372
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    • 2016
  • The effects of hydrodynamics and alum dose on particle growth were investigated by monitoring particle counts in a rapid mixing process. Experiments were performed to measure the particle growth and breakup under various conditions. The rapid mixing scheme consisted of the following operating parameters: Velocity gradient (G) ($200-300s^{-1}$), alum dose (10-50 mg/L) and mixing time (30-180 s). The Poisson regression model was applied to assess the effects of the doses and velocity gradient with mixing time. The mechanism for the growth and breakup of particles was elucidated. An increase in alum dose was found to accelerate the particle count reduction. The particle count at a G value of $200s^{-1}$ decreased more rapidly than those at $300s^{-1}$. The growth and breakup of larger particles were more clearly observed at higher alum doses. Variations of particles due to aggregation and breakup of micro-flocs in rapid mixing step were interactively affected by G, mixing time and alum dose. Micro-flocculation played an important role in a rapid mixing process.

Cake Reduction Mechanism in Coagulation-Crossflow Microfiltration Process (Crossflow 방식 응집-정밀여과 공정의 케이크층 저감 메커니즘)

  • Kim, Suhan;Park, Heekyung
    • Journal of Korean Society of Water and Wastewater
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    • v.17 no.4
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    • pp.519-527
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    • 2003
  • Cake layer in crossflow microfiltration(CFMF) can be reduced by coagulation, enhancing membrane flux. This is because enlarging particle size by coagulation increases shear-induced diffusivity and the back-transport of rejected particles. However it is known that the enlarged particles are disaggregated by the shear force of the pump while passing through it. This study is to look at the disaggregation in relation with cake layer reducation. Kaolin and polysulfon hollow fiber microfilter are used for experiment. The reduction of cake resistance by coagulation is observed in a range of 17% to 53% at the various coagulation conditions. The particle size analysis results of the experiments show that aggregated particles in feed are completely disaggregated by pump but re-aggregation of particles occurs in membrane. This suggestes that the re-aggregation of particles is critical to cake reduction and flux enhancement, since the aggregated particles are completely broken. The mechanisms for re-aggregation in membrane are the same with those for coagulation in feed tank. Charge neutralization is better for CCFMF than sweep flocculation although it has two drawbacks in operation.