• Title/Summary/Keyword: particle/surface interface

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Effect of Process Conditions on the Microstructure of Particle-Stabilized Al2O3 Foam

  • Ahmad, Rizwan;Ha, Jang-Hoon;Hahn, Yoo-Dong;Song, In-Hyuck
    • Journal of Powder Materials
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    • v.19 no.4
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    • pp.278-284
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    • 2012
  • $Al_2O_3$ foam is an important engineering material because of its exceptional high-temperature stability, low thermal conductivity, good wear resistance, and stability in hostile chemical environment. In this work, $Al_2O_3$ foams were designed to control the microstructure, porosity, and cell size by varying different parameters such as the amount of amphiphile, solid loading, and stirring speed. Particle stabilized direct foaming technique was used and the $Al_2O_3$ particles were partially hydrophobized upon the adsorption of valeric acid on particles surface. The foam stability was drastically improved when these particles were irreversibly adsorbed at the air/water interface. However, there is still considerable ambiguity with regard to the effect of process parameters on the microstructure of particle-stabilized foam. In this study, the $Al_2O_3$ foam with open and closed-cell structure, cell size ranging from $20{\mu}m$ to $300{\mu}m$ having single strut wall and porosity from 75% to 93% were successfully fabricated by sintering at $1600^{\circ}C$ for 2 h in air.

Numerical simulation on jet breakup in the fuel-coolant interaction using smoothed particle hydrodynamics

  • Choi, Hae Yoon;Chae, Hoon;Kim, Eung Soo
    • Nuclear Engineering and Technology
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    • v.53 no.10
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    • pp.3264-3274
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    • 2021
  • In a severe accident of light water reactor (LWR), molten core material (corium) can be released into the wet cavity, and a fuel-coolant interaction (FCI) can occur. The molten jet with high speed is broken and fragmented into small debris, which may cause a steam explosion or a molten core concrete interaction (MCCI). Since the premixing stage where the jet breakup occurs has a large impact on the severe accident progression, the understanding and evaluation of the jet breakup phenomenon are highly important. Therefore, in this study, the jet breakup simulations were performed using the Smoothed Particle Hydrodynamics (SPH) method which is a particle-based Lagrangian numerical method. For the multi-fluid system, the normalized density approach and improved surface tension model (CSF) were applied to the in-house SPH code (single GPU-based SOPHIA code) to improve the calculation accuracy at the interface of fluids. The jet breakup simulations were conducted in two cases: (1) jet breakup without structures, and (2) jet breakup with structures (control rod guide tubes). The penetration depth of the jet and jet breakup length were compared with those of the reference experiments, and these SPH simulation results are qualitatively and quantitatively consistent with the experiments.

Preparation of Kerosine-Based Magnetic Ferrofluid by Steric Stabilizaton (Steric Stabilization에 의한 석유분산매 자성유체의 제조)

  • 신학기;장현명;김태옥
    • Journal of the Korean Ceramic Society
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    • v.27 no.5
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    • pp.684-692
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    • 1990
  • Ultrafine magnetite powder for the ferromagnetic fluid was prepared by an addition of alkaline solution to the solution containing Fe2+ and Fe3+ ions at 6$0^{\circ}C$. The optimum condition of the magnetite synthesis was delineated by examining such various physico-chemical properties as Fe2+/Fe+3 ratio in the powder, phase characteristics, MHC and $\sigma$max. A new scheme for the steric stabilization of colloidal dispersion was proposed using the concept of the buffer group action for the increased interfacial density of the stabilizing moieties at colloid particle/dispersion medium interface. The proposed concept was successfully applied to the preparation of the kinetically stable kerosinebased ferrofluid using Tween and Span as dispersants. In the dispersion of magnetite particles in a kerosine, Tween(polyoxyethylene sorbitan oleate) acts as a primary stabilizer which provides an anchor group, whereas Span(sorbitan oleate) can be classified as a secondary stabilizer which adsorbs on the surface of magnetite particle through the action of the buffer group. Dispersion studies using various quantities of Tween and Span supported the concept of the buffer group action for increased dispersion characteristics of the kerosine based ferromagnetic fluid.

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HRTEM Study of Phase Transformation from Anatase to Rutile in Nanocrystalline $TiO_2$ Particles

  • Kim, Kyou-Hyun;Park, Hoon;Ahn, Jae-Pyoung;Lee, Jae-Chul;Park, Jong-Ku
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.466-467
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    • 2006
  • The anatase particle was facetted at the free surface and a neck formation between the anatase particles prior to the phase transformation occured. This resulted in the severe lattice distortion at the region of the interface near the neck and this can act as the nucleation sites for the phase transformation. The grain growth of rutile particles after the phase transformation grew very fast by the sweeping phenomena of grain boundary. Therfore, It leaded to the microstructure without the rutile phase located in anatase particle.

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Numerical Analysis of Anode Sheath Structure Shift in an Anode-layer Type Hall Thruster

  • Yokota, Shigeru;Komurasaki, Kimiya;Arakawa, Yoshihiro
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.602-605
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    • 2008
  • The anode sheath structure in the hollow anode of an anode-layer type Hall thruster was numerically computed using a fully kinetic 2D3V Particle-in-Cell and Direct Simulation Monte Carlo(PIC-DSMC) code. By treating both ions and electrons as particles, anode surface region, which is electrically non-neutral, was analyzed. In order to analyze in detail, the calculation code was parallelized using Message Passing Interface (MPI). The code successfully simulated the discharge current oscillation. In the low magnetic induction case, ion sheath appears in the anode surface because ionization is enough to maintain the plasma occurs in the anode hollow. As the magnetic induction increases, main ionization region move to outside of the anode. At the same time, anode sheath voltage decreases. In the high magnetic induction case, electron sheath appears on the anode surface periodically because the ionization occurs mainly in the discharge channel. This anode sheath condition shift can be explained using the simple sheath model.

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Magnetoresistance Characteristics due to the Schottky Contact of Zinc Tin Oixide Thin Films (ZTO 박막의 쇼키접합에 기인하는 자기저항특성)

  • Li, XiangJiang;Oh, Teresa
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.4
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    • pp.120-123
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    • 2019
  • The effect of surface plasmon on ZTO thin films was investigated. The phenomenon of depletion occurring in the interface of the ZTO thin film created a potential barrier and the dielectric layer of the depletion formed a non-mass particle called plasmon. ZTO thin film represents n-type semiconductor features, and surface current by plasma has been able to obtain the effect of improving electrical efficiency as a result of high current at positive voltage and low current at negative voltage. It can be seen that the reduction of electric charge due to recombination of electronic hole pairs by heat treatment of compound semiconductors induces higher surface current in semiconductor devices.

A Study of Characteristic of Friction Angles between Sand and Artificial Rock Interface by Direct Shear Test (직접전단시험에 의한 모래와 인공암석 경계면의 마찰각 특성 연구)

  • Yang, Hong-Suk;Lee, Byok-Kyu;Jang, Seung-Jin;Lee, Su-Gon
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.8
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    • pp.65-73
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    • 2012
  • Soil-rock interface, mainly founded in Granite region of Korea, is known as one of the important factor of the slope failure at the rainfall due to smaller shear strength than soil itself. However, research of the effect on slope stability by soil-rock interfaces is insufficient. Therefore, a series of direct shear tests were performed in order to investigate the effect of soil-rock interface on slope stability. The method of tests is to get sand itself and sand-artificial rock interface shear strength from different grain size of sands and artificial rock samples. The results of tests show that the friction angle of interface depends primarily on particle size and surface roughness. Interface friction angle ratio ${\mu}(={\delta}/{\Phi})$ is in the range of 0.75 ~ 0.96, this results indicate that interface friction angle is smaller than sand itself.

Application of Superfluid Shock Tube Facility to experiment of High Reynolds number flow (초유동 충격파관 장치의 고레이놀즈수 유동실험에의 응용)

  • ;H. Nagai;Y. Ueta;K. Yanaka;M. Murakami
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2002.02a
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    • pp.27-30
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    • 2002
  • The particle velocity in superfluid helium (He II) induced by a gas dynamic shock wave impingement onto He II free surface were studied experimentally by using Schlieren visualization method with an ultra-high speed video camera. It is found form visualization results that a dark zone in the immediate vicinity of the vapor-He II interface region is formed because of the high compressibility of He II and is developed toward bulk He II with the flowing-down speed of the vapor-He II interface. The mass velocity behind a transmitted compression shock wave that is equal to the contraction speed of He II amounts to 10 m/sec, the Reynolds number of which reaches $10^{7}$. This fact suggests that the superfluid shock tube facility can be applied to an experimental facility for high Reynols number flow as an alternative to the superfluid wind tunnel.

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The Present Status of Development of Inductively Coupled Plasma Simulator based on Fluid Model (유체 모델을 기반으로 하는 유도 결합 플라즈마 시뮬레이터 개발 현황)

  • Kwon, D.C.;Yoon, N.S.
    • Journal of the Korean Vacuum Society
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    • v.18 no.3
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    • pp.151-163
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    • 2009
  • The domestic development status of Inductively Coupled Plasma (ICP) simulator which is based on fluid model is explained. As each part which composes the unified simulator, electron heating module, charged and neutral particle transport module, surface reaction module including a sheath model, and GUI (Graphic User Interface) with pre- and post-processors are described in order. Also, we present data base status of chemical reaction and physical collision, which has been applied to the recently developed simulator until now. Lastly, some future plans of development are suggested.

Micro-shear bond strengths of resin-matrix ceramics subjected to different surface conditioning strategies with or without coupling agent application

  • Gunal-Abduljalil, Burcu;Onoral, Ozay;Ongun, Salim
    • The Journal of Advanced Prosthodontics
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    • v.13 no.3
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    • pp.180-190
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    • 2021
  • Purpose. This study aimed to assess the influence of various micromechanical surface conditioning (MSC) strategies with or without coupling agent (silane) application on the micro-shear bond strength (µSBS) of resin- matrix ceramics (RMCs). Materials and Methods. GC Cerasmart (GC), Lava Ultimate (LU), Vita Enamic (VE), Voco Grandio (VG), and Brilliant Crios (BC) were cut into 1.0-mm-thick slices (n = 32 per RMC) and separated into four groups according to the MSC strategy applied: control-no conditioning (C), air-borne particle abrasion with aluminum oxide particles (APA), 2W- and 3W-Er,Cr:YSGG group coding is missing. The specimens in each group were further separated into silane-applied and silane-free subgroups. Each specimen received two resin cement microtubules (n = 8 per subgroup). A shear force was applied to the adhesive interface through a universal test machine and µSBS values were measured. Data were statistically analyzed by using 3-way ANOVA and Tukey HSD test. Failure patterns were scrutinized under stereomicroscope. Results. RMC material type, MSC strategy, and silanization influenced the µSBS values (P<.05). In comparison to the control group, µSBS values increased after all other MSC strategies (P<.05) while the differences among these strategies were insignificant (P>.05). For control and APA, there were insignificant differences between RMCs (P>.05). The silanization decreased µSBS values of RMCs except for VE. Considerable declines were observed in GC and BC (P<.05). Conclusion. MSC strategies can enhance bond strength values at the RMC - cement interface. However, the choice of MSC strategy is dependent on RMC material type and each RMC can require a dedicated way of conditioning.