• Bulletin of the Korean Chemical Society
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• v.31 no.9
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• pp.2565-2570
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• 2010

The orthorhombic $MgB_2C_2$ structure contains well-separated parallel graphite-like $B_2C_2^{2-}$ layers which extend infinitely in two dimensions. Three possible ways to distribute B and C atoms in the hexagonal sublattice sites are adopted. Band structures for the hypothetical distribution patterns are examined to assess the electronic stability of these phases and to account for the observed arrangement by means of extended Huckel tight-binding calculations. The preferred choice is the layer with B and C alternating strictly so that B is nearest neighbor to C and vice versa. A rationale for this is given. Due to the alternation of B and C within the honeycomb layers, $MgB_2C_2$ is a band insulator, which through partial substitution of Mg with Li, is predicted to turn metallic with holes in the $\sigma$ bands at the Fermi level.

• The Korean Journal of Ceramics
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• v.4 no.2
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• pp.103-113
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• 1998

By using a gas-tight electrochemical cell, we can perform high-temperature coulometric titration and measure electronic transport properties to determine the elecronic defect structure of metal oxides. This technique reduces the time and expense required for conventional thermogravimetric measurements. The components of the gas-tight coulometric titration cell are an oxygen sensor, Pt/yttria stabilitized zirconia(YSZ)/Pt, and an encapsulated metal oxide sample. Based on cell design, both transport and thermodynamic measurements can be performed over a wide range of oxygen partial pressure ($pO_2=10^{-35}$ to 1 atm). This paper describes the high-temperature gas-tight electrochemical cells used to determine electronic defect structures and transport properties for pure and doped-oxide systems, such as YSZ, doped and pure ceria $(Ca-CeO_2 \;and\; CeO_2)$, copper oxides and copper-oxide-based ceramic superconductors, transition metal oxides, $SrFeCo_{0.5}O_x,\; and \;BaTiO_2$.

• Journal of the Korean Institute of Gas
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• v.25 no.6
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• pp.22-28
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• 2021

Combustion characteristics were examined experimentally for a swirl-stabilized double cone premixed burner nozzle used for industrial gas turbines for power generation. An original model and a variant with a different fuel injection pattern are tested to compare their combustion characteristics such as NOx, CO and stability in pressurized conditions with single burner-flame and in an ambient multi-flame conditions with multi-burners. Test results show that NOx emissions are smaller for the variant, whose number of fuel holes is reduced with the same total area of fuel holes, in ambient and pressurized single-flame conditions with single burner, which results from enhanced fuel/air mixing due to a higher penetration of fuel into the air stream. The multi-burnerflame test results show that NOx emissions are smaller for the variant due to reduced flame interactions, which, on the contrary, slightly reduces the stability margin. On-site test results fromin an actual power plants also show that NOx emissions are reduced for the variant, compared with the original one, which is in agreement with the lab test results stated above.

• Animal cells and systems
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• v.5 no.1
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• pp.45-50
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• 2001

Rana ovarian follicles consist of oocyte, vitelline envelope, granulosa cells, and theca/epithelial layer. Using scanning electron microscopy, the surface structure of each follicular component was investigated. Changes in oocyte surface during oocyte maturation were also examined. Theca/epithelial layer was almost transparent and some blood vessels and granulosa cells were observed underneath in intact follicle. The number of granulosa cells was estimated to be 6700-7200 per oocyte. The granulosa cells partially overlapped each other and their microvilli penetrated the vitelline membrane via holes present in the vitelline envelope and seemed to be linked to oocyte microvilli. After removal of the vitelline envelope by microforcep, oocyte microvilli were observed on the surface of the devitellined oocyte. The oocyte microvilli formed partial clusters on the surface of white spot area which appears iust before germinal vesicle breakdown (GVBD), whereas they were evenly distributed in other areas. The microvilli became shorter and less dense with oocyte maturation. The lengths of oocyte microvilli in the immature and mature oocyte were 1.5 $\mu$m and 0.6 $\mu$m, respectively. The present study suggests a fundamental structural change occurring on the oocyte surface during maturation.

• Journal of Welding and Joining
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• v.33 no.2
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• pp.78-84
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• 2015

Self-piercing rivet(SPR) is mechanical joining methods and which can be joining dissimilar materials. Unlike conventional riveting, SPR also needs no pre-drilled holes. During plastically deformation, SPR pierces upper sheet and joins it to under sheet. SPR has been mainly applied to the joining the automobile body and some materials, such as glass fiber reinforced polymer and aluminum alloy, which represent the sheet-formed materials for lightweight automobile. Glass fiber reinforced plastic(GFRP) has been considered as a partial application of the automobile body which is lighter than steels and stronger than aluminium alloys. It is needed SPR to join Al alloy sheets and GFRP ones. In this paper, in order to design the rivet and anvil, which are suitable for GFRP, the joinability was examined through simulations of SPR joining between GFRP and Al alloy sheets. For this study, AutoCAD was used for the modeling and the simulated using commercial FEM code DEFORM-2D. The simulated results for SPR process joining between GFRP and Al alloys were confirmed by the same conditions as experimental trials.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.32 no.1
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• pp.39-46
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• 2008

The loss coefficient of the butterfly valve which allows partial opening of the valve at closed position and is applicable to the small-sized pipe system with the diameter of 1 inch was measured for the variation of the valve disk blockage ratio. Two different types of the valve disk configuration to adjust the blockage ratio were considered. One was the solid type valve disk of which the diameter was changed into the smaller size rather than the pipe diameter, and the other was the perforate type valve disk on which some holes were perforated. The results from two types of valve disk were compared to identify their characteristics in the loss coefficient distributions. The loss coefficient and the controllable angle of the valve disk were decreased exponentially with the decrease of the blockage ratio. In addition, the perforate valve disk had the effect on the higher loss coefficient rather than the solid type valve disk.

• Journal of The Korean Astronomical Society
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• v.29 no.spc1
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• pp.119-122
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• 1996

The case for a massive black hole in the center of the Galaxy is reassessed using improved modeling techniques and observational data. A dark mass of ${\~}{\times} 10^6$ Mo is present within 0.2 pc of the Galactic center. However, the available data can be modeled, without appealing to a massive black hole, using an extended distribution of dark stellar remnants (neutron stars and stellar mass black holes) provided that the stellar initial mass function in the central parsec is deficient in stars less massive than $\~$1 Mo. Such a situation may be a natural consequence of repeated gas build-up followed by starbursts in the central region. A clear distinction between this and the massive central black hole model cannot be made using red giant tracers outside 0.2 pc due to uncertainties in the radial velocity dispersion distribution. The cluster of massive early-type emission-line stars in the central parcsec more effectively probe the mass distribution close to Sgr A $\ast$, but their small number and partial rotational support complicate mass determinations. Proper motion determinations for stars within 0.5' of Sgr A$\ast$ may be the most effective means of unambiguously determining the mass distribution in the immediate vicinity of the Galactic center.

• Korean Journal of Materials Research
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• v.13 no.8
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• pp.519-523
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• 2003

We report the synthesis of cubic spinel $ZnCo_2$$O_4$thin films and the tunability of the conduction type by control of the oxygen partial pressure ratio. Zinc cobalt oxide films were grown on$ SiO_2$(200 nm)/Si substrates by reactive magnetron sputtering method using Zn and Co metal targets in a mixed Ar/$O_2$atmosphere. We found from X-ray diffraction measurements that the crystal structure of the zinc cobalt oxide films grown under an oxygen-rich condition (the $O_2$/Ar partial pressure ratio of 9/1) changes from wurtzite-type $Zn_{1-x}$ $Co_{X}$O to spinel-type $ZnCo_2$$O_4$with the increase of the Co/Zn sputtering ratio,$ D_{co}$ $D_{zn}$ . We noted that the above structural change accompanied by the variation of the majority electrical conduction type from n-type (electrons) to p-type (holes). For a fixed $D_{co}$ $D_{zn}$ / of 2.0 yielding homogeneous spinel-type $_2$O$ZnCo_4$films, the type of the majority carriers also varied, depending on the$ O_2$/Ar partial pressure ratio: p-type for an $O_2$-rich and n-type for an Ar-rich atmosphere. The maximum electron and hole concentrations for the Zn $Co_2$ $O_4$films were found to be 1.37${\times}$10$^{20}$ c $m^{-3}$ and 2.41${\times}$10$^{20}$ c $m^{-3}$ , respectively, with a mobility of about 0.2 $\textrm{cm}^2$/Vs and a high conductivity of about 1.8 Ω/$cm^{-1}$ /.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.35 no.7
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• pp.601-611
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• 2007

Most of mechanically jointed aircraft structures are always encountered the fretting damages on the contact surfaces between two jointed structural members or at the edges of fastener holes. The partial slip and contact stresses associated with fretting contact can lead to severe reduction in service lifetime of aircraft structures. Thus a critical need exists for predicting fretting crack initiation in mechanically jointed aircraft structures, which requires characterizing both the near-surface mechanics and intimate relationship with fretting parameters. In this point of view, a series of fretting fatigue specimen tests for 2024-T351 Al-alloy, have been conducted to validate a mechanics-based model for predicting fretting fatigue life. And included in this investigaion were elasto-plastic contact stress analyses using commercial FEA code to quantify the stress and strain fields in subsurface to evaluate the fretting fatigue crack initiation.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.27 no.6
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• pp.663-672
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• 2014

Recently, modular structural systems have been applicable to building construction since they can significantly reduce building construction time. They consists of several unit modular frames of which each beam-column joint employs an access hole for connecting unit modular frames. Their structural design is usually carried out under the assumption that their load-carrying mechanism is similar to that of a traditional steel moment-resisting system. In order to obtain the validation of this assumption, the cyclic characteristics of beam-column joints in a unit modular frame should be investigate. This study carried out finite element analyses(FEM) of unit modular frames to investigate the cyclic behavior of beam-column joints with the structural influence of access holes. Analysis results show that the unit modular frames present stable cyclic response with large deformation capacities and their joints are classified into partial moment connections. Also, this study develops a simple spring model for earthquake nonlinear analyses and suggests the Ramberg-Osgood hysteretic rule to capture the cyclic response of unit modular frames.