• Title/Summary/Keyword: pH variation

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Treatment of Cu-EDTA by using Photocatalytic Oxidation Process - Comparison between UV Lamp and Solar Light - (광산화 공정을 이용한 Cu-EDTA 처리 - 인공 자외선램프와 태양광의 처리경향 비교 -)

  • Shin, In-Soo;Choi, Bong-Jong;Lee, Seung-Mok;Yang, Jae-Kyu
    • Journal of Korean Society on Water Environment
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    • v.21 no.1
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    • pp.66-72
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    • 2005
  • Effect of the pH, molar ratio of Cu(II)/EDTA, concentration of Cu(II)-EDTA and ionic strength on the photocatalytic oxidation(PCO) of Cu(II)-EDTA in solar light was studied in this work. Experimental results in this work were compared with previous results obtained with UV-lamp. In the kinetics, Cu(II)-EDTA decomposition was favorable below neutral pH. The removal of Cu(II) and DOC was favorable as $TiO_2$ dosage increased. The initial rate for the decomplexation of Cu(II)-EDTA linearly increased as the concentration of Cu(II)-EDTA increased. The removal of Cu(II) and DOC was not much affected by variation of ionic strength with $NaClO_4$ as a background ion while much reduction was observed in the presence of background ions having higher formal charges. The removal trend of Cu(II) and DOC with variation of ionic strength and concentration of Cu(II)-EDTA in solar light was similar with that in UV light. Variation of the molar ratio of Cu(II)/EDTA showed a negligible effect on the removal of both Cu(II) and DOC. However, removal of both Cu(II) and DOC was two-times greater than that previous results obtained with UV light.

Maximum number of total born piglets in a parity and individual ranges in litter size expressed as specific characteristics of sows

  • Freyer, Gertraude
    • Journal of Animal Science and Technology
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    • v.60 no.5
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    • pp.13.1-13.7
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    • 2018
  • Background: The objective of this study was to underline that litter size as a key trait of sows needs new parameters to be evaluated and to target an individual optimum. Large individual variation in litter size affects both production and piglet's survival and health negatively. Therefore, two new traits were suggested and analyzed. Two data sets on 5509 purebred German Landrace sows and 3926 Large White and crossing sows including at least two parental generations and at least five parities were subjected to variance components analysis. Results: The new traits for evaluating litter size were derived from the individual numbers of total born piglets (TBP) per parity: In most cases, sows reach their maximum litter size in their fourth parity. Therefore, data from at least five parities were included. The first observable maximum and minimum of TBP, and the individual variation expressed by the range were targeted. Maximum of TBP being an observable trait in pig breeding and management yielded clearly higher heritability estimates ($h^2{\sim}0.3$) than those estimates predominantly reported so far. Maximum TBP gets closer to the genetic capacity for litter size than other litter traits. Minimum of TBP is positively correlated with the range of TBP ($r_p=0.48$, $r_g$ > 0.6). The correlation between maximum of TBP and its individually reached frequency was negative in both data sets ($r_p=-0.28$ and - 0.22, respectively). Estimated heritability coefficients for the range of TBP comprised a span of $h^2=0.06$ to 0.10. Conclusion: An optimum both for maximum and range of total born piglets in selecting sows is a way contributing to homogenous litters in order to improving the animal-related conditions both for piglets' welfare and economic management in pig.

Evaluation of electrical energy consumption in UV/H2O2 advanced oxidation process for simultaneous removal of NO and SO2

  • Shahrestani, Masoumeh Moheb;Rahimi, Amir
    • Environmental Engineering Research
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    • v.24 no.3
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    • pp.389-396
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    • 2019
  • The electrical energy consumption (EEC) in removal of NO by a $UV/H_2O_2$ oxidation process was introduced and related to removal efficiency of this gas. The absorption-reaction of NO was conducted in a bubble column reactor in the presence of $SO_2$. The variation in NO removal efficiency was investigated for various process parameters including NO and $SO_2$ inlet concentrations, initial concentration of $H_2O_2$ solution and gas flow rate. EEC values were obtained in these different conditions. The removal efficiency was increased from about 22% to 54.7% when $H_2O_2$ concentration increased from 0.1 to 1.5 M, while EEC decreased by about 70%. However, further increase in $H_2O_2$ concentration, from 1.5 to 2, had no significant effect on NO absorption and EEC. An increase in NO inlet concentration, from 200 to 500 ppm, decreased its removal efficiency by about 10%. However, EEC increased from $2.9{\times}10^{-2}$ to $3.9{\times}10^{-2}kWh/m^3$. Results also revealed that the presence of $SO_2$ had negative effect on NO removal percentage and EEC values. Some experiments were conducted to investigate the effect of $H_2O_2$ solution pH. The changing of pH of oxidation-absorption medium in the ranges between 3 to 10, had positive and negative effects on removal efficiency depending on pH value.

Volume-Weighted Ion Cocentration of Rainwater in Taean Area (태안지역 강우의 화학성분 특성)

  • Lee, Jong-Sik;Jung, Goo-Bok;Kim, Jin-Ho;Kim, Won-Il;Yun, Sun-Gang;Im, Jae-Cheal
    • Korean Journal of Environmental Agriculture
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    • v.20 no.4
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    • pp.284-288
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    • 2001
  • This study was carried out to investigate the chemical properties of rainwater in Taean area. Rainwater was collected during seven months from April to October in 2000, and analyzed for its chemical composition. The pH of rainwater at April and May were higher than those from June to September. Occurrence rate of rain above pH 5.6 was 42.1%, which showed the highest ratio from rainwater samples during investigation periods. Those of pH $5.0{\sim}5.6$ and $4.5{\sim}5.0$ range were 21.1 and 31.6%, respectively. The major cation in rainwater were $Ca^{2+}$ and $NH_4\;^+$, and $SO_4\;^{2-}$ was more than 50% of total anion composition. Monthly variation of acidity neutralization capacity by $Ca^{2+}$ and $NH_4\;^+$ was decreased during rainy season. The $nss-SO_4\;^{2-}/NO_3\;^-$, ratio was 2.0 which means $SO_4\;^{2-}$ contributed to acidity of rainwater two times more than $NO_3\;^-$.

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Study on Heat Generation of a Bulk HTS for Application to a 100 kWh SFES Superconductor Bearing

  • Jung, S.Y.;Lee, J.P.;Han, Y.H.;Han, S.C.;Jeong, N.H.;Ko, J.S.;Jeong, S.K.;Sung, T.H.
    • Progress in Superconductivity
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    • v.8 no.1
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    • pp.122-126
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    • 2006
  • This paper presents experimental and numerical investigation on heat generation of a bulk HTS for application to a 100 kWh Superconductor Flywheel Energy Storage System(SFES) bearing. An experimental device is manufactured to reproduce varying magnetic field conditions that a bulk HTS may experience during the operation of the 100 kWh SFES. The bulk HTS is directly cooled by a cryocooler while the heat is generated by the eddy currents created by varying magnetic fields induced by a coil. In order to design the cryocooling system for the 100 kWh SFES project, a preliminary experiment to investigate the actual cooling load variation under AC magnetic field has been carried out. In the experiment, two different copper holders were designed and tested. Several temperature sensors were installed on each component of the assembly and the temperatures were measured for several operating conditions of the 100 kWh SFES. The experimental investigation on the thermal response of the bulk HTS and its holder is considered to be a valuable step fur the successful materialization of a large-scale SFES.

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Do universal adhesives promote bonding to dentin? A systematic review and meta-analysis

  • Elkaffas, Ali. A.;Hamama, Hamdi H.H.;Mahmoud, Salah H.
    • Restorative Dentistry and Endodontics
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    • v.43 no.3
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    • pp.29.1-29.13
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    • 2018
  • Objectives: The aims of this study were to conduct a systematic review of the microtensile bond strength (${\mu}TBS$) of multi-mode adhesives to dentin and to perform a meta-analysis to assess the significance of differences in the ${\mu}TBS$ of one of the most commonly used universal adhesives (Scotchbond Universal, 3M ESPE) depending on whether the etch-and-rinse or self-etch mode was used. Materials and Methods: An electronic search was performed of MEDLINE/PubMed, ScienceDirect, and EBSCOhost. Laboratory studies that evaluated the ${\mu}TBS$ of multi-mode adhesives to dentin using either the etch-and-rinse or self-etch mode were selected. A meta-analysis was conducted of the reviewed studies to quantify the differences in the ${\mu}TBS$ of Scotchbond Universal adhesive. Results: Only 10 studies fulfilled the inclusion criteria for the systematic review. Extensive variation was found in the restorative materials, testing methodologies, and failure mode in the reviewed articles. Furthermore, variation was also observed in the dimensions of the microtensile testing beams. The meta-analysis showed no statistically significant difference between the etch-and-rinse and self-etch modes for Scotchbond Universal adhesive (p > 0.05). Conclusions: Multi-mode 'universal' adhesives can achieve substantial bonding to dentin, regardless of the used modes (either etch-and-rinse or self-etch).

The influences of extraction time and pressure on the chemical characteristics of Gyejibokryeong-hwan decoctions

  • Kim, Jung-Hoon;Lee, Nari;Shin, Hyeun-Kyoo;Seo, Chang-Seob
    • The Korea Journal of Herbology
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    • v.29 no.6
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    • pp.1-6
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    • 2014
  • Objectives : This study was aimed to compare Gyejibokryeong-hwan (GBH) decoctions produced using different pressure levels for various extraction times to find the optimal extraction conditions through extraction yield, total soluble solids content (TSSC), hydrogen ion concentration (pH), and the contents of chemical compounds. Methods : Decoctions of GBH were prepared under the pressure levels of 0 or $1kgf/cm^2$ for 30-180 min using water as extraction solvent. The extraction yield, TSSC, and pH were measured, and the amounts of the chemical compounds were determined using high performance liquid chromatography-photodiode array detector. Results : The higher pressure and longer extraction time increased the values of TSSC and extraction yield, while decreased the pH value. The decoctions produced in 180 min by pressurized method and produced in 150 min by non-pressurized method showed maximum values of extraction yield and TSSC with minimum value of pH. The amounts of chemical compounds showed variations in pressurized and non-pressurized decoction during overall extraction times. The influences of pressure and extraction time on extraction yield, TSSC, pH, and the contents of chemical compounds were confirmed by regression analysis, which showed that all extraction values were significantly affected by at least one of two extraction factors, pressure and extraction time. Conclusions : This study suggests that the pressure and extraction time can significantly affect the extraction efficiency of components from GBH decoctions. However, optimal extraction conditions could not be chosen due to the variation of the amounts of chemical compounds.

Studies on Cultural Characteristics for High Density Fermentation of Phellinus linteus WI-001 (Phellinus linteus WI-001 균사체의 고밀도 배양을 위한 배양학적 특성 연구)

  • 김종래;권호균;전계택;김규중;이계관
    • Microbiology and Biotechnology Letters
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    • v.28 no.2
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    • pp.105-110
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    • 2000
  • Various environmental factors such as pH, temperature and initial glucose concentration were investigated for enhancing cell growth in fermentations of Phellinus linteus WI-OOl, a producer of polysaccarides with potent anticancer activities. Optimal pH and temperature were around 5.5 and $28^{\circ}C$, respectively. Relatively little variation of pH was observed ranging between 5.5 and 6.5 during the whole fermentation period. Maximum cell concentration and specific growth rate were investigated in the media containing initial glucose concentrations of 0.5%, 1 %, 2%, 3% and 4%. High initial glucose concentration enhanced biomass production but showed negative effect on specific growth rate. In bioreactor experiments with various feeding strategies, increases of 28% and 42% in final cell concentration were obtaind as compared to conventional batch process, by adopting pulse and continuous supplement of 2% glucose solution, respectively.

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Effect of Lignin Addition on Characteristics of Cement Pastes (리그닌 첨가가 시멘트 페이스트 특성에 미치는 영향)

  • Sim, Jae-Hong;Park, Joon-Seok
    • Applied Chemistry for Engineering
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    • v.18 no.2
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    • pp.178-182
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    • 2007
  • This research was conducted to evaluate the effect of lignin addition on the characteristics of portland cement pastes. Lignin was added to cement at the ratio of 0.5 to 2.0% on dry weight basis. The specimens were cured for 3, 7, 14, and 28 days. Distilled water and sea water were used as leaching solutions. pH and concentration of Ca, Na, and K ions in the leaching solutions were analyzed. Lignin addition of 0.5~2.0% to cement pastes decreased the leached concentration of Ca, Na, and K ions for distilled water, compared to the case without lignin addition. However, a significant pH variation of the leached solutions was not observed with the lignin addition. Lignin addition significantly improved the compressive strength of cement pastes, approximately 30~60% for curing in distilled water and 3~20% for that in sea water.

Removal of Hazardous Heavy Metals (Cd, Cr, and Pb) from Laver Pyropia sp. with Acid Treatment (산 처리에 의한 김(Pyropia sp.)의 유해 중금속(Cd, Cr, Pb) 제거 효과)

  • Mok, Jong Soo;Son, Kwang Tae;Lee, Tae Seek;Lee, Ka Jeong;Jung, Yeoun Joong;Kim, Ji Hoe
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.49 no.5
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    • pp.556-563
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    • 2016
  • We examined the removal of hazardous heavy metals (Cd, Cr, and Pb) from laver Pyropia sp. using citric, hydrochloric, and nitric acids. Under the same conditions, the quality of the laver samples was also evaluated using the variation in absorbance and major mineral levels. The heavy metals that accumulated in raw laver samples after 3 days in seawater included Pb (117.79 μg/g), Cr (33.53 μg/g), and Cd (10.54 μg/g) in descending order. The rate of heavy metal removal from laver was higher at lower pH for all acids used. However, its color changed unsatisfactorily at pH 2.0. After 10 min in seawater at pH 2.5, the heavy metals in laver were eliminated in the order Cd (68.7–81.6%), Pb (57.7–67.0%), and Cr (31.9–49.4%) using the three acids. The differences in heavy metal removal among acid types were not significant. The laver quality was not affected after 20 min at the pH range of 2.5–4.0. The maximum removal of heavy metals was from laver soaked for 10 min in seawater at pH 2.5 using the organic acid, citric acid.