• Title/Summary/Keyword: pH variation

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A Study on the Chemical Characteristics of Acid Rain in Taejon City (대전지역 산성강우의 화학적 특성에 관한 연구)

  • 구자공;박경렬
    • Journal of Korean Society for Atmospheric Environment
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    • v.9 no.2
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    • pp.147-153
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    • 1993
  • From March 1990 to August 1991, every each 5mm bulk precipitation samples were collected at one residental area in Taejon City to investigate chemical characteristics of acid rain. Major ion concentrations of rain samples $(pH, SO_4^{2-}, NO_3^-, CL^-, NH_4^+, Na^+, K^+, Ca^{2+}, Mg^{2+})$ were analysed and compared with the concentration of air pollutants (T. S. P, $SO_2, NO_x$) that were measured by Ministry of Environment. The results of statistical analysis are as followings. Rain pH was relatively high on October and January and relatively low on August, November and February. Major anion is sulfate, and it's concentration is 2.36 times higher than nitrate's, and major cations are ammonium, sodium and calcium ion. Monthly variation of sulfate and calcium concentrations are higher than the others. Ion concentration and rain pH were correlated negatively with rainfall amount. Major ions in rain samples were $SO_4^{2-}, NO_3^-, NH_4^+, Ca^{2+}$ and regression equations are proposed by multiple regression of measured data. Also, regression equation between air pollutants(T. S. P, $SO_2$) and $SO_4^{2-}, Na^+, K^+, Ca^{2+}, Mg^{2+} ions in rain samples were made. From this wer can predict rain pH.

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A Study on the Oxidation Characteristics of p-Cresol on Pt Anode (백금전극(白金電極)에 의한 파라크레졸의 양극전해(陽極電解) 산화특성(酸化特性))

  • Kim, Hong-Soo;Nam, Jeong-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.7 no.2
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    • pp.47-53
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    • 1990
  • The electrochemical oxidation behavior of p-cresol on platinum anode had been investigated by cyclic voltammetric method for the variation of concentration, scan rate of potential, temperature and pH of electrolyte. The oxidation potential of p-cresol was dependent on the electrolyte until the pH=11.5, but in basic solution over its, it was held at o.40V(vs. SCE). A diffusion was rate determining step of oxidation as irreversible reaction by the transfer atone electron. The current of peak was proportional to concentration of p-cresol until the 0.1N and optimum concentration was found to be about 0.1N. The activation energy was calculated for 5.8kcal/mol from the plot of log $I_l$ vs. 1/T.

Chemical Characteristics of Precipitation in Pusan I. Temporal and spatial variation of pH and major ions (부산지역 강우의 화학적 특성 I. pH 및 주요이온의 시ㆍ공간적 변화)

  • Jeon, Eun-Ju;Yang, Han-Sub;Ok, Gon;Kim, Young-Sub
    • Journal of Environmental Science International
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    • v.7 no.5
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    • pp.707-716
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    • 1998
  • The chemical characteristics of precipitation was investigated in Pusan area. Samples were collected from January to November in 1996 at 4 sites, and analyzed pH, major soluble ionic components(C $l^{[-10]}$ , N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$, N $a^{+}$, $K^{+}$, N $H_4$$^{+}$, $Mg^{2+}$, $Ca^{2+}$). The order of anion and cation concentrations for the initial precipitation were C $l^{[-10]}$ > S $O_4$$^{2-}$ > N $O_3$$^{[-10]}$ , and $Ca^{2+}$ > N $a^{+}$ > N $H_4$$^{+}$$Mg^{2+}$$K^{+}$, respectively. At coastal sites(P1 and P2) C $l^{[-10]}$ and N $a^{+}$ of maritime sources (seasalt) were high, but at inland sites(P3 and P4) nss-C $a^{2+}$ and nss-S $O_4$$^{2-}$ were high. Calcium ion for the initial precipitation showed high value of enrichement factor(EF) relative to seawater composition. The contribution of seasalt to the composition of precipitation was higher at bite P1 (53.5%) than those of the other sites. Throughout the year the concentrations of major ions for the initial precipitation were low in the heavy rain season. The mean pH for the initial precipitation was 5.4 and showed the negative relationship with the precipitaion amount. The S $O_4$$^{2-}$ and N $O_3$$^{[-10]}$ do not play an important role in rain acidification due to the high(97%) neutralizing effect of amonia and calcium species.and calcium species.

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Analysis of the Stress Characteristics of Double Layered Tube at Elevated Temperature (고온에서 이중튜브의 열응력특성해석)

  • Kim, E.H.;Jang, J.H.;Park, S.P.;Moon, Y.H.
    • Transactions of Materials Processing
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    • v.19 no.7
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    • pp.405-410
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    • 2010
  • Double layered tube that has been used for transportation and oil piping system is occasionally exposed to elevated temperature. The change in stress state at elevated temperature is important for the safe design of double layered tube. In this study, the variation of stress state for hydroformed double layered tube of which inner tube is stainless steel and outer tube is mild steel has been analytically analyzed. To characterize the thermal stress at elevated temperature, analytical model to provide thermal stresses between outer tube and inner tube was developed by using theories of elasticity and Lame equation. The feasibility of analytical model is verified by finite element analysis using ANSYS $CLASSIC^{TM}$, commercially available code. The variation of thermal stress at various thickness combination of inner and outer tube has also been investigated by proposed analytical model.

Variations of Properties and Microbial Community during Fermentation of Makgeollies by Isolated Yeasts from Traditional Makgeollies (전통막걸리에서 분리한 효모균주를 이용한 막걸리 발효과정 중의 물성 및 미생물 군집의 변화)

  • Jeon, Myong Je;Jang, Min Kyung;Lee, Sol Jee;Park, Sung Hwan;Kim, Mihyang;Sohn, Jae Hak;Lee, Han-Seung;Lee, Dong-Geun;Lee, Sang-Hyeon
    • Journal of Life Science
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    • v.23 no.6
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    • pp.796-803
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    • 2013
  • Property changes and bacterial characterizations by polymerase chain reaction-denaturing gradient gel electrophoresis (PCR-DGGE) were investigated during the fermentation of Makgeollies by 5 isolated yeast strains. Changes of pH were large between day 0 (pH 6) and day 2 (pH 3) and showed less variation after then. ANOVA analyses revealed that pHs were statistically different with fermentation times (p<0.001), while strains (p=0.60) did not. Acidities were changed from 0.19 to 1.04% and showed rather high increase from day 2, and fermentation times (p<0.001) and strains (p=0.006) represented statistical differences. All strains showed less than 0.150% at amino-type nitrogen contents except S strain showed 0.442% at day 8, and there were no statistical differences with fermentation times (p=0.4558) and strains (p=0.3513). Saccharinities of C strain were higher from day 4, and fermentation times (p<0.0001) and strains (p=0.007) showed statistical differences. Large variation of alcohol concentrations (%) were observed between day 0 (0%) and day 2 (10%) and showed less variation after day 2, and there was no statistical difference with strains. Dominant prokaryotes were Lactobacillus fermentum and Pediococcus pentosaceus, which producing acids and functional materials. Dominant eukaryote was Saccharomyces cerevisiae, which might be resulted from addition of yeasts.

Mineralogical Study of the Granite Weathering in the Seoul Area: Water-Rock Interaction in the Namsan Granite (남산 화강암의 풍화 및 광물-물 반응에 관한 연구)

  • Lee, Soo-Jae;Kim, Soo-Jin
    • Journal of the Mineralogical Society of Korea
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    • v.7 no.1
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    • pp.40-48
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    • 1994
  • The weathering of the Namsan granite was studied in terms of sorption process. The Namsan granite consists mainly of quartz, alkali feldspar, plagioclase (${Ab_{85}An_{15}}-Ab_{100}$ and biotite with small amounts of sericite, magnetite and ilmenite. The kinetic factors for altering the granite body are the proton and hydroxyl ions derived from the reaction of water and mineral. There are two different types of pH variation curves for rocks of different mineral assemblages. when powdered granite was dispersed in distilled water under ambient condition. The sorption-process proceeds by three steps for fresh granite; (1) the initial rapid pH-rise to 10 by the uptake of proton by negatively charged mineral surfaces, (2) the gradual pH-down, and (3) the stable pH tail between 7.1-7.5. For somewhat weathered granites, the sorption proceeds; (1) the initial rapid pH-down to 4.8, (2) the slight pH-rise and slow ph-down, and (3) the stable pH tail between 5.0-5.3. The reaction rate is controlled by the density of adsorbable sites, the solubility of the mineral, pH of the system and formation of amorphous gel and gibbsite. Amorphous gel floates on the surface of the solution while stirring the powdered granite and then is transformed into gibbsite in an hour or so. The pH saturation values for -325 mesh fresh granite from 5 m depth is about pH 10 when rock/water ratio is over 10g/200 ml.

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The characteristics of chloramine formation and decay with pH variation (pH 변화에 따른 클로라민 생성과 분해 특성)

  • 조관형;김평청;우달식;조영태
    • Journal of Environmental Science International
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    • v.11 no.4
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    • pp.347-353
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    • 2002
  • This study was conducted to investigate the characteristics of chloramination as a secondary disinfection in a drinking water distribution system. At the range from pH 6 to pH 8, monochloramine was predominant with a trace of dichloramine, and the free chlorine was detected after breakpoint. At $25^{\circ}C$, the breakpoints of pH 6, 7 and 8 appeared when the weight ratios of chlorine to ammonia nitrogen were 11:1, 9:1 and 10:1 respectively, and the peak points on the breakpoint curves at pH 6, 7 and 8 were in the Cl$_2$ / NH$_3$-N ratio of 9:1, 6:1 and 5:1 respectively. As pH increased from 6 to 8, maximum point of monochloramine on the breakpoint curve was moved from 7:1 to 5:1 in the weight ratio of chlorine to ammonia nitrogen. The maximum concentration of monochloramine was formed at the pH values of 7~8 and in the Cl$_2$ / NH$_3$-N ratio below 5:1. As the Cl$_2$/NH$_3$-N ratio increased and the pH lowered, chloramines decay proceeded at an increased rate, and residual chloramines lasted longer than the residual free chlorine. The monochloramine and the dichloramine were formed at pH 6, and then the dichloramine continued increasing with contact time.

Application of Disinfection Models on the Plasma Process (플라즈마 공정에 대한 소독 모델 적용)

  • Back, Sang-Eun;Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Science International
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    • v.21 no.6
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    • pp.695-704
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    • 2012
  • The application of disinfection models on the plasma process was investigated. Nine empirical models were used to find an optimum model. The variation of parameters in model according to the operating conditions (first voltage, second voltage, air flow rate, pH) were investigated in order to explain the disinfection model. In this experiment, the DBD (dielectric barrier discharge) plasma reactor was used to inactivate Ralstonia Solanacearum which cause wilt in tomato plantation. Optimum disinfection models were chosen among the nine models by the application of statistical SSE (sum of squared error), RMSE (root mean sum of squared error), $r^2$ values on the experimental data using the GInaFiT software in Microsoft Excel. The optimum model was shown as Weibull+talil model followed by Log-linear+ Shoulder+Tail model. Two models were applied to the experimental data according to the variation of the operating conditions. In Weibull+talil model, Log10($N_o$), Log10($N_{res}$), ${\delta}$ and p values were examined. And in Log-linear+Shoulder+Tail model, the Log10($N_o$), Log10($N_{res}$), $k_{max}$, Sl values were calculated and examined.

Variation in Tree Growth Characteristics, Pilodyn Penetration, and Stress-wave Velocity in 65 Families of Acacia mangium Trees Planted in Indonesia

  • HIDAYATI, Fanny;LUKMANDARU, Ganis;INDRIOKO, Sapto;SUNARTI, Sri;NIRSATMANTO, Arif
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.5
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    • pp.633-643
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    • 2019
  • Growth characteristics [stem diameter (D), tree height (H)] and wood properties [Pilodyn penetration (P) and stress-wave velocity (SWV)] were measured for 65 families of 6-year-old Acacia mangium trees planted in Indonesia, in order to characterize their variation in D, H, P, and SWV. Therefore, the correlations between the measured characteristics were also determined, and their significant differences observed. Furthermore, their low to moderate values of narrow-sense heritability was obtained, and the results indicated the characteristics to be genetically controlled in A. mangium. In addition, highly significant positive correlations were observed among the growth characteristics, suggesting a close relationship, while there was no significant association between the growth characteristics and P, as well as SWV, indicating their independent. Therefore, these results demonstrate a potential for the improvement of both growth and wood properties of A. mangium trees, using the appropriate breeding programs. In addition, 18 families showed good performance in D and SWV, signifying their positive prospect of being considered as plus trees for the next generation breeding cycles.

Fleece Phenotype Influences Susceptibility to Cortisol-induced Follicle Shutdown in Merino Sheep

  • Ansari-Renani, H.R.;Hynd, P.I.;Aghajanzadeh, A.
    • Asian-Australasian Journal of Animal Sciences
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    • v.20 no.11
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    • pp.1761-1769
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    • 2007
  • This experiment was conducted to determine the extent to which susceptibility to cortisol-induced follicle shutdown is influenced by fleece phentotype. Twenty Finewool (10 sheep low fibre diameter, low coefficient of fibre diameter-LL and 10 low fibre diameter, high coefficient of variation of fibre diameter-LH) and twenty Strongwool (10 low fibre diameter, low coefficient of variation of fibre diameter-HL and 10 high fibre diameter and high coefficient of variation of fibre diameter-HH) sheep of 9 months of age were individually penned in an animal house and were injected intramuscularly with an aqueous suspension of hydrocortisone acetate at a rate of 1.42 mg/kg body weight for a period of two weeks. Fibre diameter was measured from clipped tattooed patch wool samples. Follicle activity was measured by histological changes in skin biopsies taken weekly. Blood samples were collected at two-week intervals and plasma cortisol measured. Increased plasma cortisol concentration significantly (p<0.05) reduced clean wool production and mean fibre diameter dropped to its lowest level four weeks after commencement and two weeks after the cessation of cortisol injection. Elevation of plasma cortisol concentration significantly (p<0.0001) increased the percentage of inactive follicles two weeks after injection started. High fibre diameter groups (Strongwool sheep; i.e. HL+HH) had significantly (p<0.0001) higher percentage of follicle shutdown than low fibre diameter groups (Finewool sheep; i.e. LL+LH). Average percentage of shutdown follicles for Finewool (LL+LH) and Strongwool (HL+HH) Merino sheep was $9.8{\pm}0.9$ and $13.5{\pm}0.9$ respectively. Shutdown of primary follicles was more pronounced in Finewool than Strongwool sheep. There was no significant effect of coefficient of variation of fibre diameter on propensity to follicle shutdown induced by exogenous cortisol. It is concluded that elevation in plasma cortisol concentration is inhibitory to the normal activity of follicles in Strongwool sheep but that variation in fibre diameter has little or no effect.