• 제목/요약/키워드: pH variation

검색결과 1,305건 처리시간 0.027초

물리, 화학적 처리방법에 의한 염색폐수의 색도제거에 관한 연구 (A Study on the Reduction of Color in Dye Wastewaters by Physico-chemical Processes)

  • 이준석;김민호;김영규
    • 한국환경보건학회지
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    • 제19권3호
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    • pp.29-35
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    • 1993
  • This study was performed to obtain optimal conditions for reduction of color in dye wastewaters using coagulation-sedimentation processes with redox reactions. The reduction of color as well as organic matters variation was observed after coagulation-sedimentation processes using FeSO$_4$ $\cdot$ 7H$_2$O and NaOCl. Coagulation-redox reaction was done with the dose of Coagulant and oxidant at various pH values. Redox reaction was done through jar-mixing and aeration. The results of study were as follows: 1. In the coagulation-sedimentation processes using FeSO$_4$ $\cdot$ 7H$_2$O, color reduction was heigher at pH 3. With variance of dosage of FeSO$_4$ $\cdot$ 7H$_2$O, color reduction was higher at 250 mg/l. When coagulation-sedimentation using FeSO$_4$ $\cdot$ 7H$_2$O 250 mg/l was added at pH 3, the reduction of color, COD$_{Mn}$, and COD$_{Cr}$ showed 47.6%, 21.3% and 22.1%, respectively. 2. When NaOCI was added at level of 100 ppm in raw wastewater at pH 3, the reduction of color, COD$_{Mn}$, and COD$_{Cr}$ showed 30.2%, 5.5% and 6.2%, respectively. 3. After coagulation-sedimentation processes by addition of FeSO$_4$ $\cdot$ 7H$_2$O, when NaOCl was added at level of 250 mg/l in supernant, color reduction was 47.8% in aeration and 37.5% in jar-mixing. 4. Color reduction by aeration was higher than that by jar-mixing.

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수산 지역의 규회석과 그 용해 거동 (Wollastonite from and Its Dissolution Behaviors)

  • 김수진;현성필;이성근
    • 한국광물학회지
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    • 제9권1호
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    • pp.1-6
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    • 1996
  • Woolastonite from Susan occurs as intercalations in limestone beds of Lower Paleozoic Joseon Supergroup. It is a thermal metamorphic product of impure limestone. Electron microprobe analysis shows that it is considerably pure wollastonite. It has triclinic cell with a=7.932$\AA$, b=7.328$\AA$, c=7.069$\AA$, $\alpha$=89.995$^{\circ}$, $\beta$=$95.255^{\circ}$, and $ \Upsilon=103.367^{\circ}$.Dissolution behaviors of wollastonite have been studied conducting three different dissolution experiments; two different reactions with HC1 (one batch and one re-initialization experiment) and one traction with distilled water. In the batch type powder wollastonite-HCl reaction, pH of solution rapidly increases in the early stage and then its rate of increase slows down to reach plateau resulting in parabolic relationship with time. It is represented by the early rapid rise and fall in pH giving a sharp pH-edge and succeeding slow rise in the re-initialization experiment. The early rapid rise in pH is due to the rapid sorption of H- in solution to oxygens on the reactive surface of wollastonite and the fall in pH means that all reactive surface sites are occupied by H- ions and no more H- adsorption occurs. The slow rise in pH following the pH- edge is due to the dissolution of wollastonite as evidenced by the correlation of pH variation and cation concentration. Dissolution of powder wollastonite in HCl shows linear trend with time. Si is dissolved predominantly over Ca at a constant rate. Ca is dissolved predominantly in the very early stage. Dissolution rate of coarse-grained wollastonite fragments in distilled water is parabolic with times howing a rapid reaction in the early stage and a slow reaction in the advanced stage. The Ca/Si ratio in solution is high in the case of coarse-grained wollastonite fragment as compared with powder wollastonite. The coarse-grained wollastonite fragment-water (acid) reaction resulted in the solution with an elevated constant pH value (alkaline) giving an important significance on the environmental view point.

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다량의 붕소원소를 함유하는 식물의 중금속 이온 교환반응 (Heavy Metal Son Exchange Reaction in Boron-Rich Containing Plants)

  • 배계선;성대동
    • 한국환경과학회지
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    • 제5권6호
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    • pp.757-762
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    • 1996
  • The removal effectiveness of various heavy metal ions in boron-rich containing plants has been studied by means of spectroscopic and pH methods. Treatment of the boron-rich containing sample which was collected from cherry and root of cabbage to heavy metal ions is resulted in that an excellent removal effect shows in the case of large ionic size of heavy metal. Stability constants are depended on the variation of pH.

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희귀(稀貴) 수종(樹種) 눈향나무 집단(集團)의 동위효소(同位酵素) 분석(分析)에 의한 유전변이(遺傳變異) 연구(硏究) (Genetic Variation in the Endemic Rare Tree Species, Juniperus chinensis var. sargentii HENRY)

  • 양병훈;권해연;한상돈
    • 한국자원식물학회지
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    • 제19권1호
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    • pp.76-82
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    • 2006
  • 우리나라 고산 지역에 제한적으로 자생하는 희귀 유전자원인 눈향나무(Juniperus chinensis var. sargentii HENRY)의 설악산 및 한라산 집단을 대상으로 동위효소 분석에 의한 유전적 다양성을 조사하였다. 총 7개 동위효소에서 11개의 재현성 있는 유전자좌가 분석되었으며, 이중 Mdh-1, Mdh-2, Mdh-3 및 Pig-1 유전자좌를 제외한 7개 유전자좌에서 다형성이 관찰되었다. 분석된 두 집단의 유전변이량은 각각 A=2.2, $A_e=1.61,\;P_{95}=54.5,\;H_{o}=0.179,\;H_e=0.287$(설악산 집단)과 A=2.1, $A_e=1.48,\;P_{95}=63.6,\;H_{o}=0.270,\;H_e=0.250$(한라산 집단)으로 국내 타 침엽수종으로부터 동위효소 분석을 통해 추정된 유전변이량에 비해 다소 높은 경향을 보였으며, 분석 집단간 유전적 분화 정도는 그리 높지 않은 것으로 나타났다($F_{ST}=0.039$). 설악산 집단의 경우 이형접합도의 관찰치가 기대치에 비해 매우 낮았으며 근교계수 값이 매우 높게 나타나(F=0.376), 전반적으로 근친교배 또는 유전적 부동의 영향을 많이 받고 있는 것으로 추정되었다. 이는 설악산 눈향나무 집단의 분포 면적이나 개체수가 한라산 집단에 비해 매우 적기 때문인 것으로 추정되며, 향후 설악산 집단의 보존을 위한 보다 적극적인 노력이 필요한 것으로 사료된다.

Allelic variation of melanocortin-1 receptor locus in Saudi indigenous sheep exhibiting different color coats

  • Mahmoud, Ahmed H.;Mashaly, Ashraf M.;Rady, Ahmed M.;Al-Anazi, Khalid M.;Saleh, Amgad A.
    • Asian-Australasian Journal of Animal Sciences
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    • 제30권2호
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    • pp.154-159
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    • 2017
  • Objective: This study was designed to characterize the DNA polymorphisms of the melanocortin-1 receptor (MC1R) gene in indigenous Saudi Arabian sheep breeds exhibiting different color coats, along with individuals of the Sawaknee breed, an exotic sheep imported from Sudan. Methods: The complete coding region of MC1R gene including parts of 3' and 5' untranslated regions was amplified and sequenced from three the indigenous Saudi sheep; Najdi (generally black, n = 41), Naeimi (generally white with brown faces, n = 36) and Herri (generally white, n = 18), in addition to 13 Sawaknee sheep. Results: Five single nucleotide polymorphisms (SNPs) were detected in the MC1R gene: two led to nonsynonymous mutations (c.218 T>A, p.73 Met>Lys and c.361 G>A, p.121 Asp>Asn) and three led to synonymous mutations (c.429 C>T, p.143 Tyr>Tyr; c.600 T>G, p.200 Leu>Leu, and c.735 C>T, p.245 Ile>Ile). Based on these five SNPs, eight haplotypes representing MC1R $E^d$ and $E^+$ alleles were identified among the studied sheep breeds. The most common haplotype (H3) of the dominant $E^d$ allele was associated with either black or brown coat color in Najdi and Sawaknee sheep, respectively. Two other haplotypes (H6 and H7) of $E^d$ allele, with only the nonsynonymous mutation A218T, were detected for the first time in Saudi indigenous sheep. Conclusion: In addition to investigating the MC1R allelic variation in Saudi indigenous sheep populations, the present study supports the assumption that the two independent nonsynonymous Met73Lys and Asp121Asn mutations in MC1R gene are associated with black or red coat colors in sheep breeds.

베시클을 이용한 단분산 구형 미분체 합성에서 베시클 내 알루미늄 이온의 침전조건과 침전메카니즘 (Condition and Mechanism of Precipitation of Intravesicular Aluminum Ion in Preparation of Monodispersed Spherical Fine Particles With Use of Vesicles)

  • 정종재;김창현;이병교;이창섭;이해욱
    • 대한화학회지
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    • 제40권8호
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    • pp.535-541
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    • 1996
  • 베시클을 이용한 알루미나 미분체 제조에 있어서 베시클 외부 분산계의 pH 변화, 즉 수산화이온의 농도변화가 베시클 내부에서 침전 반응기구 및 침전물의 입자 형태, 분포, 크기등에 미치는 영향을 고찰하고자 하였다. 투과전자현미경(TEM)과 탁도계로 관찰한 결과 분산계의 pH가 11.4 및 11.3에서부터 베시클내부에서 알루미늄 이온과 수산화이온이 반응하여 침전물이 생성되기 시작하였고 pH 12.0 에서 평균입자 크기가 50nm정도의 미세하고 균일한 구형의 침전물이 형성되었다. pH12.3 이상인 영역에서는 시간경과에 따른 베시클간의 응집 및 합체가 일어나 베시클 내부의 침전물이 pH12.0에서 생성된 침전물 크기에 비해 약 두 배 정도 성장함을 알 수 있었다.

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쌍전, 월악, 청양 및 산내 철·망간중석 광산의 유체포유물 온도와 심도에 따른 H/F 값의 변화 (H/F Variation in Wolframites According to Depth and Temperature of Mineralization at Ssangjeon, Weolag, Cheongyang and Sannae Mines, Korea)

  • 박맹언
    • 자원환경지질
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    • 제26권3호
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    • pp.259-265
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    • 1993
  • 본 논문은 심도별 시료 채취가 가능한 국내 주요 함중석 열수석영맥 광상 (쌍전, 월악, 청양, 산내광산)에서 산출되는 철 망간중석과 동일맥 중 공생단계에 있어서 밀접하게 수반되는 같은 광화시기의 석영을 대상으로 유체포유물 온도, 철 망간중석에서의 H/F값 및 광화작용의 섬도와의 상관관계를 밝히기 위해서 시도 되었다. 연구대상 함중석 열수석영맥광상에서 철 망간중석의 H/F값은 생성온도와 광화작용의 심도에 따라 특정적인 상관관계를 보여준다. 윌악, 청양 및 산내광산에서 산출되는 철 망간중석의 H/F값은 광화온도가 높을수록 광화심도가 깊을수록 증가된다. 이는 광화용액의 pH값이 냉각과 모암과의 반응에 따라 감소되었음을 시사한다. 쌍전광산의 경우 생성온도가 높아짐에 따라서 상대적으로 제한된 범위내에서 H/F값이 증가되나 심도에 따라서는 상기 광산과는 상반된 결과를 나타낸다. 이러한 결과는 알카리장석과 견운모등의 침전에 따른 pH값의 증가를 유도한 물리 화학적 환경이 조성되었음을 의미한다. 본 연구에서 밝혀진 함중석-휘수연 열수 석영맥에서 산출되는 철 망간중석의 심도에 따른 생성온도와 H/F값의 특성은 유사한 지질환경의 물리화학적 조선(동일한 공생단계)이 형성되면 지질온도계로서의 활용이 가능하며 H/F값은 열수석영맥에서 산출되는 철 망간중석광의 심도 탐광시 고려되어야 할 요건으로 심도추정 및 탐사지침으로 활용할 수 있을 것으로 사료된다.

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환경적 스트레스에 의한 Helicobacter pylori의 형태 변화

  • 이학성;최태부
    • 한국미생물·생명공학회지
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    • 제25권3호
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    • pp.240-247
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    • 1997
  • Bacillary is the most common form of H. pylori observed during human infection. However, it is known that the morphology change of H. pylori from bacillary to coccoid can be occurred with a response to the environmental stresses such as the nutrient depletion, accumulation of toxic metabolites, pH alteration, and exposure to antimicrobial agents. The coccoid form of H. pylori, which is viable but non-culturable in vitro, seems to be the major cause of antibiotic resistancy and high reinfectability of H. pylori. In this regard, we studied the environmental factors that can induce the morphological change in vitro of H. pylori, and the change of fatty acid composition of plasma membrane. The morphological change from bacillary to coccoid could be observed with the depletion of nutrients, pH variation and reactive oxygen species added in the culture media. This morphologic conversion was paralleled by a dramatic decrease in unsaturated fatty acids and an increase in saturated fattv acids of plasma membrane. The change in composition of membrane fatty acid seems to be a kind of protection mechanism of H. pylori against these environmental stresses.

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Cloning and Expression Analysis of the ${\alpha}$-Subunit of Porcine Prolyl 4-hydroxylase

  • Cho, Eun Seok;Jung, Won Youg;Kwon, Eun Jung;Park, Da Hye;Chung, Ki Hwa;Cho, Kwang Keun;Kim, Chul Wook
    • Asian-Australasian Journal of Animal Sciences
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    • 제20권11호
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    • pp.1655-1661
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    • 2007
  • Prolyl 4-hydroxylase (P4H) plays a central role in collagen synthesis by catalyzing the hydroxylation of the proline residue in the X-Pro-Gly amino acid sequence, and controls the biosynthesis of collagen that influences overall meat quality. In order to verify expression level of the catalytic ${\alpha}$ subunit of P4H, a 2.7 kb clone of the ${\alpha}$ subunit gene for P4H was selected from a cDNA library prepared from the muscular tissue of Sancheong berkshire pigs, and the whole gene sequence was determined. As expression level of the ${\alpha}$ subunit of P4H differed between tissues of pigs, we intended to assess more precisely the level of ${\alpha}$-subunit expression between tissues of Sancheong Berkshire pigs by using RT-PCR. Muscular and adipose tissues were taken from each pig grouped by growth stage (weighing 60, 80, and 110 kg) of Yorkshire and Sancheong Berkshire pigs, and the expression levels of the ${\alpha}$-subunit of P4H were examined. Since there were significant differences in the expression level with respect to variation in growth stage (p<0.01), an attempt was made to identify any influences of pig species and tissue variation. The muscular and adipose tissues of pigs weighing 110 kg showed higher expression levels than pigs weighing 60 kg and 80 kg. In general, significantly higher expression levels were found in muscular than in adipose tissue. The expression levels in Sancheong Berkshire were significantly higher than in Yorkshire pigs (p<0.01 or p<0.05). Since expression level of the ${\alpha}$-subunit of P4H affects the activity of P4H and is connected to the biosynthesis of collagen and increased collagen can improve meat texture, this finding may explain why meat quality of the Sancheong Berkshire pig is acclaimed in Korea. Given the higher expression levels of the ${\alpha}$-subunit gene in adipose than in muscular tissue, and also in the heavier pigs, more intensive studies are required to assess the correlation between expression level of the ${\alpha}$ subunit gene and overall meat quality.

전산해석을 이용한 적층형 증발기 성능특성 연구 (A Study of Laminated Evaporator Performance Characteristics through Numerical Analysis)

  • 시종민;한창섭;김재훈;우승길
    • 설비공학논문집
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    • 제15권3호
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    • pp.210-219
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    • 2003
  • A laminated evaporator performance simulation software has been developed and the performance characteristics have been examined with variation of important design parameters, number of plate ( $P_{N}$), plate inner height ( $P_{h}$), Plate thickness ( $p_{t}$) and plate wetted Perimeter ( $P_{wl}$ ). To confirm the program, performance experiment was carried out for two different evaporators. The simulation results matched with experiments within $\pm$10%. Through the parametric studies, $P_{N}$ was shown to be most influential. The $P_{N}$, $P_{h}$ and $P_{wl}$ had a maximum cooling capacity point in the calculation range. In case of $P_{t}$, the smaller was the better.ter.etter.ter.