• Title/Summary/Keyword: pH paper

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Design of Pretreatment Process in Cellulosic Ethanol Production (목질계 셀룰로오스 에탄올 생산공정에서 전처리과정의 설계)

  • Kim, Hyungjin;Lee, Seung Bum
    • Applied Chemistry for Engineering
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    • v.26 no.4
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    • pp.511-514
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    • 2015
  • A pretreatment process of cellulose decomposition to a monosaccharide plays an important role in the cellulosic ethanol production using the lignocellulosic biomass. In this study, a cellulosic ethanol was produced by using acidic hydrolysis and enzymatic saccharification process from the lignocellulosic biomass such as rice straw, sawdust, copying paper and newspaper. Three different pretreatment processes were compared; the acidic hydrolysis ($100^{\circ}C$, 1 h) using 10~30 wt% of sulfuric acid, the enzymatic saccharification (30 min) using celluclast ($55^{\circ}C$, pH = 5.0), AMG ($60^{\circ}C$, pH = 4.5), and spirizyme ($60^{\circ}C$, pH = 4.2) and also the hybrid process (enzymatic saccharification after acidic hydrolysis). The yield of cellulosic ethanol conversion with those pretreatment processes were obtained as the following order : hybrid process > acidic hydrolysis > enzymatic saccharification. The optimum fermentation time was proven to be two days in this work. The yield of cellulosic ethanol conversion using celluclast after the acidic hydrolysis with 20 wt% sulfuric acid were obtained as the following order : sawdust > rice straw > copying paper > newspaper when conducting enzymatic saccharification.

Modification of KOCC with Ultrasonic Wave Treatment (초음파처리에 의한 KOCC의 개질)

  • Ming, He;Lee, Yong-Kyu;Won, Jong Myoung
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.5
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    • pp.44-48
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    • 2013
  • Ultrasonic treatment of KOCC was tried to explore the possibility for improvement of KOCC quality as a raw material for making industrial packaging paper and paperboard. The effect of pH, stock consistencies and treatment times on the ultrasonic response of KOCC were investigated. WRV, apparent density, tensile index and burst index were improved as pH of KOCC slurry is increased. However highest tear index and stiffness were obtained at pH 8. It was also found that the highest WRV and strength properties could be obtained at 0.5% of KOCC consistency during ultrasonic treatment. WRV and most strength properties were improved with ultrasonic treatment time. It was found that ultrasonic treatment can be used as a useful mean for KOCC modificaton.

A Study on the Stress Corrosion Cracking Behaviors for Weld Joint of Steel with Various pH Values in Synthetic Sea Water (인공해수의 pH에 따른 강 용접부의 응력 부식균열거동에 관한 연구)

  • 유효선;나의균;정세희
    • Journal of Welding and Joining
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    • v.13 no.1
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    • pp.78-88
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    • 1995
  • This paper was performed to study the utility of the SP(small punch) test and the AE(acoustic emission) test in the evaluation of SCC(stress corrosion cracking) susceptibility for parent metal and bond line of HT80 steel-weld joint by SAW(submerged arc welding) with the various pH values. The loading rate used was 3*10$^{-4}$ mm/min and the corrosive environment used was synthetic sea water during the SP test and the AE test. According to the test results, the SCC susceptibility of the parent metal was increased in the order of pH6.0, pH8.2 and pH10.0. On the other hand, the bond line showed almost the same high SCC susceptibility in all pH concentrations. Synthetically, from the results of the SCC susceptibility, the macro- and micro-SEM observation, the microfracture behaviors by AE test and the relationship between SCC susceptibility and displacement at incipient failure, .delta.$_{i.f-AE}$, it can be concluded that the SP test and the AE test are the good test methods to evaluate the SCC susceptibility for parent metal and bond line of the weld joint with the change of environmental factors.

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The Effect on the Wear-Corrosion Behavior of Ductile Cast Iron in the Various pH Environments (구상흑연주철재의 마멸-부식특성에 미치는 pH의 영향)

  • 임우조;박동기
    • Tribology and Lubricants
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    • v.19 no.1
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    • pp.31-35
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    • 2003
  • This paper reports the studies on the wear-corrosion behavior of ductile cast iron in the various pH environments. In the variety of pH solutions, corrosion and wear-corrosion loss of GCD 600 were investigated. Also, the anodic polarization test of GCD 600 using potentiostat/galvanostat was carried out. And rubbed surface of GCD 60 using scanning electron micrographs after immersion and wear-corrosion test was examined in the environment of various pH values. The main results are as following In alkali zone, the wear-corrosion loss of GCD 600 increases, but corrosion loss decreases. The unevenness and crack of wear-corrosion surface in neutral zone becomes duller than that in alkali zone. As the corrosive environment is acidified, wear-corrosion behavior of GCD 600 with passing immersion time becomes sensitive.

Adaptive Nonlinear Constrained Predictive Control of pH Neutralization in Fed-batch Bio-reactor

  • Zhe, Xu;Kim, Hak-Kyeong;Kim, Sang-Bong
    • 제어로봇시스템학회:학술대회논문집
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    • 2003.10a
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    • pp.90-95
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    • 2003
  • In this paper, an Adaptive Nonlinear Constrained Model Predictive Control (ANCMPC) is presented for a pH control in a fed-batch bio-reactor. The pH model is represented with Hammerstein Model. The static nonlinear part of Hammerstein model is described with the static pH model, and the dynamic linear part of the Hammerstein model is described with the CARIMA model. The parameters of the CARIMA model is estimated on-line with the input and output measurements of the system using a recursive least squares type of identi�cation algorithm. The e�ectiveness of the proposed controller is shown through simulations.

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An Experimental Study on the Lens Surface Temperature Distribution of P/C Headlamp Using the Three Category of H4 Halogen Bulbs (PIC 렌즈 전조등 렌즈면의 온도분포에 관한 실험적 연구)

  • 박경석;강병도
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.4
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    • pp.158-165
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    • 2002
  • This Paper deals with the headlamp lens surface temperature distribution of p/c headlamp using the three categories of H4 halogen bulbs. Glass is gradually replaced by P/C for the lens material off vehicle headlamp due to the weight reduction and stream lined body of a vehicle. With this trend, the newly established standards for a headlamp with a P/C lens in Europe requires that the heat generated by a bulb should not distort the lens surface. Also the requirements fur the bulb of a headlamp are being enforced in U.S.A & Europe. However, such requirements are not established yet in Korea. By using three kinds (60/55w, 100/90w, 130/90w) of H4 halogen bulbs in this experiment, the surface temperature distribution and Max. temperature on the lens were measured. The results of this study implies the necessity of requirement fur the bulb off headlamp.

Fabrication of Disposable pH Sensor with Micro-volume Type (Micro-volume형 일회용 pH 센서 제작)

  • Jung, Ho;Kim, Heung-Rak;Kim, Young-Duk;Jung, Woo-Chul;Kim, Dong-Su;Nam, Hyo-Duk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.950-952
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    • 2003
  • This paper have been studied fabrication and characteristics of disposable pH sensor using MEMS technology. The sensor has two open-well structure, the container for the internal electrolyte and electrode were formed by anisotropically etching a silicon substrate. unlike currently used KCI saturated solution, the structure was introduced hydrogel which take an advantage of miniaturization, bulk product, a low price. PU and CA/TP used to measurement ion detection, one is reference membrane and the other is pH. fabricated sensor is encapsulated entirely with epoxy, finally sensor was estimated various ion sorts and pH ranges.

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Hydrophilic Interaction Liquid Chromatography (HILIC 분석법 개발을 위한 지능형 솔루션)

  • Matt James;Colin Pipe;Mark Fever;Jen Field;Seungho Chae
    • FOCUS: LIFE SCIENCE
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    • no.1
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    • pp.6.1-6.9
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    • 2024
  • The document is a white paper on Hydrophilic Interaction Liquid Chromatography (HILIC) analysis method development. HILIC is a type of chromatography that uses an organic/aqueous mobile phase and a polar stationary phase. In HILIC, water is a strong solvent, and unlike in Reversed Phase Liquid Chromatography (RPLC), increasing the proportion of water in the mobile phase reduces the retention time of the analyte. The paper discusses when to consider HILIC analysis methods, the advantages of HILIC, and the challenges often encountered due to the lack of understanding of HILIC mechanisms compared to RPLC. It also provides a systematic flowchart for intelligent solutions for HILIC analysis method development, which includes a three-step approach for chromatography analysis method development. The first step involves gathering as much information as possible about the analyte (e.g., pKa, log P, log D). The second step involves analyzing the sample under different pH conditions using three HILIC columns in either isocratic or gradient mode to identify the suitable column/pH combination for the analyte. The third step involves optimizing the separation by investigating other parameters such as temperature and ionic strength, and assessing the robustness of the method. The paper emphasizes that the selection of the appropriate stationary/mobile phase combination, based on the differences between the HILIC stationary phases and the mobile phase pH, can provide high selectivity in the analysis. This step-by-step approach can help users develop an efficient analysis method.

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ON THE SUPERSTABILITY OF SOME FUNCTIONAL INEQUALITIES WITH THE UNBOUNDED CAUCHY DIFFERENCE (x+y)-f(x)f(y)

  • Jung, Soon-Mo
    • Communications of the Korean Mathematical Society
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    • v.12 no.2
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    • pp.287-291
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    • 1997
  • Assume $H_i : R_+ \times R_+ \to R_+ (i = 1, 2)$ are monotonically increasing (in both variables), homogeneous mapping for which $H_1(tu, tv) = t^p(H_1(u, v) (p > 0)$ and $H_2(u, v)^{t^q} (q \leq 1)$ hold for $t, u, v \geq 0$. Using an idea from the paper of Baker, Lawrence and Zorzitto [2], the superstability problems of the functional inequalities $\Vert f(x+y) - f(x)f(y) \Vert \leq H_i (\Vert x \Vert, \Vert y \Vert)$ shall be investigated.

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Analytical Breakdown Voltage for 4H-SiC ${p^+}$ Junction (4H-SiC ${p^+}$접합의 해석적 항복 전압)

  • Jeong, Yong-Seong
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.39 no.1
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    • pp.12-17
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    • 2002
  • In this paper, an effective ionization coefficient for 4H-SiC is extracted in the form of c .E$^{m}$ from ionization coefficients of electron and hole. Analytical expressions for critical electric field and breakdown voltage of 4H-SiC p$^{+}$n junction are derived by employing the effective ionization coefficient. The analytic results agree well with the experimental ones reported within 10% in error for the doping concentration in the range of 10$^{15}$ cm$^{-3}$ ~10$^{18}$ cm$^{-3}$ . .