• 대한가정학회지
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• 제46권6호
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• pp.13-19
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• 2008

In this paper, the dyeing ability of the volcanic ash dyeing on cotton knitted fabrics were investigated. Acrylic copolymer was used to improve the depth of fabric color in the dyeing process. K/S values of dyed fabrics were measured to examine the dyeing properties. Two different classes of dyeing process were tested; (1) volcanic ash dyeing after pretreatment and (2) simultaneous co-treatment with volcanic ash and acrylic copolymer. In the first process, the effects of parameters such as the concentration of volcanic ash, concentration of Na2S04, dyeing time, dyeing temperature and pH of dyebath were noted. In the second process, the effects of parameters such as concentration of acrylic copolymer, dyeing time and temperature, and drying temperature were noted. Experimental results showed that the co-treatment of acrylic copolymer improved the dyeing properties of cotton knitted fabrics with volcanic ash. For the first dyeing experiment, concentration of dispersing agent was 0.1%, concentration of volcanic ash was 4%, treatment time was 20minutes, concentration of $Na_2SO_4$ was 2%, treatment temperature was $60^{\circ}C$ and treatment pH of dyebath was neutral. In the second dyeing experiment, concentration of acrylic copolymer was 2%, treatment temperature was $80^{\circ}C$, treatment time was 40 minutes, and treatment drying temperature was $150^{\circ}C$.

• 한국의류학회지
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• 제42권2호
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• pp.342-359
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• 2018

This research investigated the relationship between the amount of fixed pigment and the color of silk dyed with three types of fermented indigo powder dye under different temperatures and pH, by reduction or nonreduction method. Amount of fixed pigment was analyzed using the Ultimate 3000 HPLC-DAD instrument and the color of dyed silk was measured using the X-rite spectrocolorimeter. All silk samples dyed by reduction method showed PB color. The amount of indigotin fixation was dependent on the dyeing temperature and pH regardless of the indigotin composition in the dye. Indirubin was less dependent upon the dyeing condition in the reduction dyeing and its fixation was minimum level. Dyeing conditions which can maximize the indigotin fixation were $50^{\circ}C/pH$ 11 and $70^{\circ}C/pH$ 7 conditions in reduction dyeing. Color of silk showed more redness ($a^*$) thus higher PB color when the indigotin fixation was low and indirubin fixation was relatively high. Indirubin fixation was very low with slightly better fixation by nonreduction method. More reddish color was obtained by nonreduction dyeing, and by more alkaline dyebath.

• 한국염색가공학회지
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• 제12권4호
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• pp.239-247
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• 2000

The coloring matter was extracted from the heartwood of Amur cork tree by distilled water. Change of UV-Visible spectra of coloring matter solution by extraction condition and stability for irradiation were determined, and the effect of repeated dyeing with condition of dyebath and mordanting method on shade depth and lightfastness were also investigated. The results are as follows : 1) Absorbance of Amur cork tree extract increased with the lapse of extraction time. λmax of color solution extracted from Amur cork tree was found at 420, 333, and 262nm. 2) Absorbance of Amur cork tree extract decreased remarkably after 2hr irradiation. 3) The K/S of silk fabrics increased with the increase of dyeing temperature, time, amounts of Amur cork tree for extraction, and pH of color solution. 4) K/S of silk fabrics dyed by repeated dyeing method was affected by pH and concentration of color solution. 5) Lightfastness of silk twice dyed with Amur cork tree extract after pre-mordanted by 8%(o.w.f) chromium acetate was moderately improved.

• 한국의류학회지
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• 제15권3호
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• pp.281-288
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• 1991

Optical behaviors and dyeing properties of color solution extracted from arrowroot leaves were investigated. The wavelength of maximum absorption of the color solution appeared at 268 and 320 nm, respectively. The amount of colors extracted was increased with extracting temperature and time. Spectra of color solution are shifted to longer wavelength at higher pH values, and shifted to shorter wavelength by irradiation for 2 hrs. Remaining ratio of colors by irradiation decreased with increasing alkalinity of color solution. Degree of exhaustion on the silk fabrics was related to the concentration and pH of dyebath. Surface color of dyed fabrics, lightfastness and wash-fastness were variously according to mordant used. Hot water resistance and drycleaning fastness of dyed silk fabrics by treatment of mordants were all within commercially acceptable limits.

• 한국염색가공학회지
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• 제13권4호
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• pp.241-248
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• 2001

Natural indigo dyeing has been used mainly on cellulosic fibers and silk during the course of history in Korea. In order to extend the usage of this one of the most important natural dyes, its dyeability on wool fabrics has been studied to find out the optimum dyeing condition for wool fiber which is susceptible to alkaline medium. The dyeing method used was hydrosulphite vat of extracted dye. K/S values of dyed fabrics were investigated to analyze the dyeability of natural indigo on wool fibers and colors were measured through $L^*,\;a^*,\;b^*$ and Munsell Values. Highest K/S values were obtained at the temperature of 60(C and pH 7 to 8. The Munsell Values for hue of wool fabrics dyed with extracted indigo powder using hydrosulphite vat fell mostly in PB range. As the dyebath pH increased, blueness increased. Different dyeing conditions resulted in change of colors of dyed fabrics due to the difference in amounts of indigotin and indirubin contents within the dyed fiber as shown by HPLC.

• 한국염색가공학회지
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• 제16권1호
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• pp.26-33
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• 2004

Two reactive disperse dyes having $\alpha$-bromoacrylamide or acrylamide group were synthesized and their dyeing properties were compared with a disperse dye. Dyeing properties of reactive disperse dyes were strongly influenced by the chemical structure of reactive group. The amount of absorbed reactive disperse dye containing $\alpha$-bromoacrylamide group on polyester fiber was less than the disperse dye, and that on nylon fiber was much higher. When polyester and nylon fiber were simultaneously dyed in a dye pot, nylon fiber absorbed the reactive disperse dye more than polyester fiber. The reactive disperse dye having acrylamide group could reduces difference in color depth to a large extent, but the application of carrier or variation of dyebath pH were not sufficient for giving the same color depth to both fibers. The N/P union fabric could be dyed with the reactive disperse dye and its wash fastness were good to excellent.

• 한국의류산업학회지
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• 제11권6호
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• pp.968-973
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• 2009

To get a variety of colors on silk fabrics with natural dyes, mordanting and combination dyeing were carried out. Gromwell, sappan wood, safflower were used as the three primary colors for combination dyeing. Metal compounds containing alum and iron were used as mordanting agents. In combination dyeing of safflower and sappan wood, safflower and gromwell, gromwell and sappan wood, various colors were obtained according to the content of dyes used. Safflower/sappan wood dyeing showed different colors between yellow red and red purple of Munsell color circle such a YR, R and RP. And safflower/gromwell dyeing showed R, RP, P and PB Munsell color circle and then gromwell/sappan wood showed R, RP and P. As the result of these experiments, wide range of colors (YR-R-RP-P-PB-B) were obtained according to various mixing portion of safflower, gromwell, sappan wood, dyebath pH and repetition dyeing.

• 한국잠사곤충학회지
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• 제37권2호
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• pp.154-160
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• 1995

Silk/CDP 혼합사의 염색거동을 살펴보기 위하여 pH, 염색온도, 조제 등 염색조건을 변화시켜가면서 고찰한 결과 다음과 같은 결론을 얻었다. 1. 견섬유는 염욕의 pH가 증가함에 따라 일계 pH까지 염착량이 증가하는 경향을 나타냈으나 CDP 섬유는 pH에 따른 염착량의 변화가 거의 나타나지 않았다. 염색온도의 염착거동에 대한 영향은 염색온도가 증가하면 초기염착속도는 증가하는 반면 최종 염착량은 줄어드는 일반적인 경향을 나타내었다. 특히 CDP섬유의 경우 유리전이온도 이하에서도 염착속도가 상당히 느린 결과를 보였다. 2. Carrier를 사용하여 silk/CDP 혼합사를 염색하는 경우 염욕의 pH 및 염색온도에 따라 각 component에의 염료 흡착 및 탈착거동, 염착량 변화 등이 차이가 나는 것으로 나타났다. 또한 carrier가 없는 경우에는 CDP component에는 거의 염착이 이루어지지 않았다. 3. Silk/CDP 혼합사의 염색시에 나타나는 이염현상은 carrier의 존재하에서 CDP component의 구조 이완에 따라 염착능력이 증대되고 염욕의 평형이 깨어지면서 silk component의 탈착과 동시에 친화력이 큰 CDP component,쪽으로 염료이동이 일어나는 것으로 나타났다.

• 패션비즈니스
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• 제22권4호
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• pp.106-117
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• 2018

The present study was conducted to investigate dyeing properties and functionality of silk fabrics dyed with extracts from buckwheat skin. Comparative results of color strength(K/S) values of dyed silk fabrics were studied to quantify the effects of dye concentrations, dyeing temperatures, dyeing time and the pH; the effect of mordants; and color changes. And also evaluated the fastness, antimicrobial property, ultraviolet protection properties of the dyed and mordanted silk fabrics. The color strength(K/S) values of silk generally increased depending on the increasing dye concentration, dyeing temperature, and dyeing time. And the highest color strength values were obtained at a dye concentration of 100%(v/v), a dyeing temperature of $90^{\circ}C$, a dyeing of time 80 minutes, and a dyebath of pH 2. The color fastness to light of dyed and mordanted silk fabrics were found to be good, and the drycleaning and rubbing fastness were excellent. The fade of washing fastness was not good, however, the stain of washing fastness and perspiration fastness showed relatively good grade. The Al, Cu, Fe mordanted silk fabrics(except Fe for Klebsiella pneumoniae) showed 99.9% reduction rate. The ultraviolet protection properties of the mordanted fabrics were generally improved. Moreover, the Cu and Fe mordnared fabrics showed very exceptional ultraviolet protection factors.

• Journal of Electrochemical Science and Technology
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• 제12권1호
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• pp.82-91
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• 2021

This study was conducted to investigate the effect of initial pH, current density, and electrolysis time on process performance in terms of decolorization and chemical oxygen demand (COD) removal from disperse dyebath wastewater (DDW) by mono-polar parallel laboratory scale electrocoagulation (EC) process. COD reduction of 51.3% and decolorization of 92.8% were obtained with operating cost of 0.19 €/㎥ treated wastewater for Al-Al electrode pair, while 90.5% of decolorization and 49.2% of COD reduction were obtained with operating cost of 0.20 €/㎥ treated wastewater for an Fe-Fe electrode pair. The amount of sludge production were highly related to type of the electrode materials. At the optimum conditions, the amount of sludge produced were 0.18 kg/㎥ and 0.28 kg/㎥ for Al-Al and Fe-Fe electrode pairs, respectively. High decolorization can be explained by the hydrophobic nature of the disperse dye, while limited COD removal was observed due to the high dissolved organic matter of the DDW based on auxiliary chemicals. Energy, electrode, and chemical consumptions and sludge handling were considered as major cost items to find a cost-effective and sustainable solution for EC. The contribution of each cost items on operating cost were determined as 10.0%, 51.1%, 30.5% and 8.4% for Al-Al, and they were also determined as 9.0%, 38.0%, 40.5% and 12.5% for Fe-Fe, respectively. COD reduction and decolorization were fitted to first-order kinetic rule.