• Title/Summary/Keyword: pH influence

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Influence of pH on Sensitivity of $WO_3$ NO gas sensor fabricated by Sol-Coprecipitation method (Sol-Coprecipitation 법에 의한 NO 감지용 $WO_3$ 센서 제조시 pH의 영향)

  • Kim, Suk-Bong;Lee, Dae-Sik;Lee, Duk-Dong;Huh, Jeung-Soo
    • Journal of Sensor Science and Technology
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    • v.10 no.2
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    • pp.118-124
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    • 2001
  • When particles are dissolved in solution, they have different zeta-potentials depending on pH. Zeta-potential has an influence on particle separation, which can control particle size. And the size of $WO_3$ particle affects the sensitivity of $WO_3$ sensor for detecting NO gas. Therefore we study influence of pH on NO-sensing $WO_3$ gas sensor fabricated by Sol-Coprecipitation method. As pH increases from 2 to 7, dynamic mobility of $WO_3$ precursor was increased. When pH was 7, it showed the largest distribution separation. It means when pH is 7, we can make $WO_3$ powder which has smaller particle size. And it is confirmed by particle size analysis of $WO_3$ powder, X-ray diffration result of $WO_3$ sensing layer and surface morphology. It also affect NO sensing characteristics of $WO_3$ gas sensor. The sensing film synthesized at pH 7 showed the largest sensitivity.

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Influence of Osmolality and Acidity on Fertilized Eggs and Larvae of Olive Flounder (Paralichthys olivaceus)

  • Kim, Ki-Hyuk;Moon, Hye-Na;Noh, Yun-Hye;Yeo, In-Kyu
    • Development and Reproduction
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    • v.24 no.1
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    • pp.19-30
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    • 2020
  • The pH of water is one of the main environmental factors exerting selective pressure on marine and freshwater organisms. Here, we focus on the influence of pH on an organism's ability to maintain homeostasis and investigate the effects of acidification on immunity-related genes and osmotic pressure during early development of the olive flounder, Paralichthys olivaceus. The aim of our study was to determine the influence of various pH levels on the fertilized eggs and larvae of P. olivaceus. Gametes of P. olivaceus were artificially introduced and the resulting fertilized eggs were incubated at pH 4.0 (low), 6.0, and 8.0 (equivalent to natural sea water; control). We found that all eggs sank from the water column at pH 4.0. After 38 h, these eggs showed slow development. Hatching occurred more slowly at pH 4.0 and 6.0 and did not occur at all at pH 4.0. Result of gene expression, caspase and galectin-1 were expressed from the blastula to pre-hatch stages, with the exception of the two-cell stage. HSP 70 was also steadily expressed at all pH levels over the five days. The osmolality of fertilized eggs differed marginally at each stage and across pH levels. So, this results demonstrates that low pH level is detrimental to P. olivaceus fertilized eggs.

For the chlorophyll decrease and formation of Chlorolla variegata by Glucose-Culture (II) Influence of temperature and pH (Chlorella Variegata Beijerinck 의 Glucose 배양에 있어서의 Chlorophyll 증감관계에 관한연구 (제 2 ) .pH 의 영향에 대한)

  • 이현순
    • Korean Journal of Microbiology
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    • v.5 no.1
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    • pp.20-23
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    • 1967
  • I studied about temperature and pH concentration having influence upon chlorophyll decrease on the Glucose culture of Chlorella variegata Beijerinck(211/10a). I cultured under $25^{\circ}C$(standard), $15^{\circ}C$ and $35^{\circ}C$ and compared with each other. The culture of $15^{\circ}C$ didn't have any large difference with the standard culture($25^{\circ}C$) but the culture of $35^{\circ}C$ had a large amount of chlorophyll decrease without carbohydrate accumulation, stimulation of cell division and nitrogen-deficiency. Chlorella variegata had optimum pH 6.5-7 and was a little weak in all phenomenon under pH 8 rather than under pH 6.5-7. Under pH 5 they had deep chlorophyll decrease without phephytin.

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Study on the Antithiamin Activities of Synthetic Antioxidants (합성항산화제 항Thiamin성에 대한 연구)

  • 한명규
    • Journal of Food Hygiene and Safety
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    • v.12 no.4
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    • pp.310-314
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    • 1997
  • Antithiamin activities of BHA, BHT, PG and TBHQ of synthetic antioxidants on the effect of temperature and pH was determined by means of HPLC. The influence of synthetic antioxidants on the degration of thiamin was found to be dependent on temperature and pH. The degradation of thiamin was considerably more rapid at pH 7 than pH 4. The influence on the heat of synthetic antioxidants at pH 4 and 38* was extremely slight, but the degradation of thiamin at pH 7 was much more rapid at 60* than at 38*. After 24 hours of incubation both PG and TBHQ at pH 7 and 60* nearly completely destroyed thiamin. Tests of antithiamin activities showed that TBHQ, which was decomposed completely in 72 hours, was more effective than PG at pH 7 and 38* but BHA and BHT hardly had antithiamin activities which was evaluated under various reactions of pH and temperature. Thiamin degradation, at pH 7 and 6$0^{\circ}C$, was proportional to the concentration of PG. When the ratio of PG to thiamin was increased from 0.15:1 to 2:1, the degradation rate also increased. However, the change between ratio of 1:1 and 2:1 was negligible.

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A Study of Optimization a-Si:H(p) for n-type c-Si Heterojunction Solar Cell (N-Type c-Si 이종접합 태양전지 제작을 위한 a-Si:H(p) 가변 최적화)

  • Heo, Jong-Kyu;Yoon, Ki-Chan;Choi, Hyung-Wook;Lee, Young-Suk;Dao, Vinh Ai;Kim, Young-Kuk;Yi, Jun-Sin
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.77-79
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    • 2009
  • Amorphous/crystalline silicon heterojunction solar cells, TCO/a-Si:H (p)/c-Si(n)/a-Si:H(n)/Al, are investigated. The influence of various parameters for the front structures was studied. We used thin (10 nm) a-Si:H(p) layers of amorphous hydrogenated silicon are deposited on top of a thick ($500{\mu}m$) crystalline c-Si wafer. This work deals with the influence of the a-Si:H(p) doping concentration on the solar cell performance is studied.

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Influence of Different Operational pH Conditions and Granulation on Enhanced Biological Sequencing Batch Phosphorus Removal (생물학적 회분식 인 제거 공정에서 pH의 영향과 그래뉼 생성)

  • Ahn, Johwan;Seviour, Robert
    • Journal of Korean Society on Water Environment
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    • v.27 no.6
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    • pp.754-759
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    • 2011
  • A sequencing batch reactor (SBR) was operated under different pH conditions to better understand the influence of pH to granulation in enhanced biological phosphorus removal systems. Granules from the SBR were also investigated using scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). Considerable decreases in the amount of phosphorus released per substrate provided under anaerobic conditions and the content of biomass polyphosphate under aerobic conditions were observed when pH was changed from 7.5 to 7.0, followed by 6.5. Aerobic granulation was also observed at pH 7.0. A number of bacteria with the typical morphological traits of tetrad-forming organisms (TFOs) were observed at pH 7.0, including large members of cluster. Filamentous bacteria were also there in large numbers. The occurrence and growth of granules were further enhanced at pH 6.5. A SEM analysis showed that the aerobic granules had a compact microbial structure with shaperical shape and morphologically consisted of aggregates of small coccoid bacteria and filamentous bacteria encapsulated by extracellular polymeric substance. The main material ions identified by EDX moreover revealed that the structural materials for polyphosphate in the granules include phosphorus, potassium and calcium. Therefore, these results strongly suggested that PAOs are a dominant population in the microbial community of the aerobic granules.

Influence of pH on the Antioxidant Activity of Melanoidins Formed from Different Model Systems of Sugar/Lysine Enantiomers

  • Kim, Ji-Sang;Lee, Young-Soon
    • Food Science and Biotechnology
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    • v.17 no.6
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    • pp.1310-1315
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    • 2008
  • This study was to investigate the influence of pH on the antioxidant activity of melanoidins formed from glucose (Glc) and fructose (Fru) with lysine enantiomers in the Maillard reaction. Melanoidins formed from D-isomers were found to be effective antioxidants in different in vitro assays with regard to the ferrous ion chelating activity, 1, l-diphenyl-2-picryl-hydrazil (DPPH) radical scavenging activities, ferric reducing/antioxidant power (FRAP), and 2,2'-azinobis(3-ethylbenothiazoline-6-sulfonic acid) diammonium salt (ABTS) radical scavenging activity. In particular, the chelating activity of these melanoidins at a pH of 7.0 was greater than those with pH of 4.0 and 10.0. The chelating activity and DPPH radical scavenging activity of the melanoidins formed from the Glc systems were higher than those of the melanoidins formed from the Fru systems. However, the FRAP and ABTS radical scavenging activity of these melanoidins were not different according to pH level, with exceptions being the Fru systems.

A Study on the Influence of Fermented Milk on Oral Ecology - The influence of fermented milk on salivary S. mutans, lactobacilli, pH, and viscosity (유산균 발효유가 구강 생태에 미치는 영향에 관한 연구 - 유산균 발효유가 타약내의 Streptococcus mutans와 lactobacilli 수, 타액 점조도 및 pH에 미치는 영향)

  • Sung-Woo Lee
    • Journal of Oral Medicine and Pain
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    • v.18 no.1
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    • pp.83-96
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    • 1993
  • Even though the increasing interest in fermented milk, the information on the influence of fermented milk on oral health in literature is sparce. We have investigated the effect of fermented milk on saliva. Thirty-three healthy unmedicated subjects at the age of their twenties were included in this study and divided into control, fermented milk, and milk groups. And, the experiment period was 70 days. The authors examined the number of salivary S.mutans, Lactobacilli, pH, and viscosity at the beginning of the experiment. And, we investigated the changes of the these factors at 10,40, and 70 days after. The authors came to the following conclusions The obtined results were as follows : 1. There were no significant changes in the numbers of saliary S. mutans in the control, fermented milk, andmilk groups through the experimental period. 2. There was no significant change in the number of salivary lactobacilli in the fermented milk group throiugh the experimental period. 3. There was a decrease in salivary pH after 40 and 70 days in fermented milk group. 4. There were no significant changes in the values of salivary viscosity at a low shear rate in all groups, but there were increases in these values at a high shear rate in the fermented milk and milk groups through the experimental period.

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Effect of pH in 3.5% NaCl aqueous solution and ferrite grain size on corrosion fatigue fracture of dual phase steel (複合組織鋼의 부식피로파괴에 미치는 3.5% NaCl水溶液의 pH와 母相粒徑의 效果)

  • 오세욱;강호민
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.11 no.6
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    • pp.867-876
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    • 1987
  • Corrosion fatigue fracture with change in the grain size of M.E.F. dual phase steel is investigated in 3.5% NaCI aqueous solution at pH 2, 4, 6, 9, and 11. Generally speaking, decrease in corrosion fatigue life is strongly dependent on decrease in pH and slightly on the grain size. For the B material with the big grain size, the fatigue life is small due to its large reduction ratio of corrosion fatigue life. The influence of grain size on the reduction ratio of corrosion fatigue life is large at pH 11-6. Whi9le at pH 4-2 the reduction ratio of corrosion fatigue life only depends on the corrosion effect. The larger grain size and the lass pH result in the greater influence on corrosion fatigue crack propagation rate. As pH decreases, the plateau portion in the crack propagation rate curves of the B material are distinct. Crack propagation rate curves become slow down at high .DELTA.K range because crack closure effect by minute corrosion products inside crack causes the oxidation corrosion action less effective for a certain period of time. In A material with small grain size, fatigue life is increased in proportion with increase of martensite intergranular which brings forth restraining the crack propagation decreases crack propagation rate. Corrosion pit which is created in the surface of specimen is found at pH 6,4 and 2 which is noticeable and the unevenness of the surface of the specimen becomes severe as pH decreases. The unevenness of corrosion fatigue fracture surface is severe as the effect of pH increases i.e. as pH decreases. In proportion with increase in the grain size and decrease in pH, the aspect of brittle fracture becomes evident.

Influence of Site-Directed Mutagenesis on Protein Assembly and Solubility of Tadpole H-chain Ferritin

  • Kim, Kyung-Suk
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.3 no.2
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    • pp.67-70
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    • 1998
  • In order to understand the influence of ferroxidase center on the protein assembly and solubility of tadpole ferrin, three mutant plasmids, pTH58K, pTH61G, and pTHKG were constructed with the aid of site-directed mutagenesis and mutant proteins were produced in Eshcerichia coli. Mutant ferritin H-subunits produced by the cells carrying plasmids pTH58K and pTHKG were active soluble proteins, whereas the mutant obtained from the plasmid pTH61G was soluble only under osmotic stress in the presence obtained from the plasmid pTH61G was soluble only under osmotic stress in the presence of sorbitol and betaine. Especially, the cells carrying pTH61G together with the plasmid pGroESL harboring the molecular chaperone genes produced soluble ferritin. The mutant ferritin H-subunits were all assembled into ferritin-like holoproteins. These mutant ferritns were capable of forming stable iron cores, which means the mutants are able to accumulate iron with such modified ferroxidase sites. Further functional analysis was also made on the individual amino acid residues of ferroxidase center.

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