• Title/Summary/Keyword: pH adjustment

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Corrosion Control in Water Distribution System using Lime and Carbon Dioxide(II) - Evaluation on the Characteristics of Corrosion as a Function of Pipe Material (소석회와 CO2를 이용한 상수관로의 부식제어(II) - 관종별 부식특성 평가)

  • Lee, Doo-Jin;Kim, Young-Il;Song, Young-Il;Park, Hyun-A
    • Journal of Korean Society of Water and Wastewater
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    • v.22 no.3
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    • pp.379-387
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    • 2008
  • The pH & alkalinity adjustment method by lime and carbon dioxide($CO_2$) for corrosion control in water distribution system was investigated to evaluate the corrosion characteristics of metal pipes, such as galvanized iron, copper, stainless steel, and carbon steel. When the pH in sand filtered and ozone+GAC treated water was increased with lime and $CO_2$ from 7.5 to 8.0, the concentration of residual chlorine decreased at higher pH and longer reaction time; the concentration of trihalomethane increased. The corrosion rate of coupons with corrosion control using lime and carbon dioxide was showed much smaller than those without corrosion control using pilot-scale simulated distribution system. The galvanized iron was corroded much faster than carbon steel, copper, and stainless steel. Especially, copper and stainless steel coupons were hardly corroded. The galvanized iron and carbon steel coupons with corrosion control were produced the corrosion products less than those without corrosion control by the results of environmental scanning electron microscope(ESEM) and energy dispersive x-ray spectroscopy(EDS) analyses. The galvanized iron coupon with pH and alkalinity adjustment by lime and carbon dioxide was detected about 30 percent of zinc, when the carbon steel was detected about 30 percent of calcium by calcium carbonate products formation. For the results of X-ray diffraction(XRD) analyses, the goethite(${\alpha}$-FeOOH) was identified as primary corrosion product of galvanized iron without corrosion control, while the Zinc oxide(ZnO) was found on corrosion products of galvanized iron coupon with corrosion control as the results of EDS analyses. However, the carbon steel corrosion products regardless of corrosion control were composed predominantly of maghemite(${\gamma}-Fe_2O_3$) and hematite(${\alpha}-Fe_2O_3$).

Preparation of Monodisperse Melamine-Formaldehyde Microspheres via Dispersed Polycondensation

  • Cheong, In-Woo;Shin, Jin-Sup;Kim, Jung-Hyun;Lee, Seung-Jun
    • Macromolecular Research
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    • v.12 no.2
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    • pp.225-232
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    • 2004
  • We have successfully synthesized relatively monodisperse and cross-linked melamine-formaldehyde (M-F) microspheres by dispersed polycondensation and subsequent pH adjustment with serum replacement cleaning. The average particle sizes (equation omitted): weight-average and (equation omitted) : number-average), the polydispersity index (equation omitted), the number of particles N$\_$p/ and the gel content of the M-F microspheres were observed by varying the pH, the surfactant concentration, and the polymerization temperature. We observed that both the pH and the polymerization temperature were predominant factors in determining (equation omitted) and N$\_$p/, but the effect that the temperature and pH had on the gel content ( > 94% for all samples) was negligible. The exponents of the slopes of plots of N$\_$p/ versus pH and surfactant concentration were -10 and 0.6, respectively. Particle nucleation and growth were achieved within short periods; the incessant coagulation occurred even in the presence of surfactants.

Effect of Cryoprotectants on the Quality Characteristics of Chicken Breast Surimi Manufactured by pH Adjustment during Freezing Storage (pH 조절법으로 제조한 닭가슴살 수리미의 저장 중 품질특성에 미치는 냉동변성방지제 첨가 효과)

  • Jin, Sang-Keun;Kim, Il-Suk;Choi, Yeung-Joon;Yang, Han-Sul;Park, Gu-Boo
    • Food Science of Animal Resources
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    • v.27 no.3
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    • pp.320-328
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    • 2007
  • This study was conducted to determine the effect of pH adjustment and the addition of cryoprotectants on the quality characteristics of chicken breast surimi. We prepared surimi from Alaska pollack, as a the control, by two time washing times and the addition of cryoprotectants. Different preparations of surimi were manufactured by adjusting to pH 11.0 and the addition of different addition cryoprotectants during frozen storage (T1 : 5% sorbitol and 0.3% polyphosphate, T2: 4% sugar, 5% sorbitol and 0.3% polyphosphate, and T3: 2% salt, 4% sugar, 5% sorbitol and 0.3% polyphosphate). The moisture content was significantly lower in the control and T3 samples. The crude protein content was increased with storage times. The crude protein was higher in the control. The water-holding capacity, myofibrillar protein and shear force were significantly higher in T3 than other surimi samples. All gel characteristics were significantly higher in the control and T3 than other surimi samples. pH 11.0 adjusted chicken breast surimi had greater lightness than the control, and T3 samples had the highest lightness and whiteness. Sensory evaluations were significantly higher in the control and T3 than the other samples. The gel, and physical characteristics and sensory evaluation of T3 were similar to the control. T3 samples had superior color and pH than the control Alaska pollack surimi.

Effects of Diatomearth Application on the Nursery Soil pH in the Tray and on the Growth of Rice Seedling (규조사(珪藻士) 시용(施用)이 수도용(水稻用) 상자(箱子) 육묘(育苗) 상토(床土)의 pH 조절(調節) 및 묘(苗) 생육(生育)에 미치는 영향(影響))

  • Kim, Sun-Kwan;Jung, Pil-Kyun
    • Korean Journal of Soil Science and Fertilizer
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    • v.23 no.4
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    • pp.297-301
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    • 1990
  • The study was conducted to investigate the effects of diatomearth(pH 3 and CEC 20me/100g) on the adjustment of nursery soil pH and on the growth of rice seedling in the tray. The results are as follows ; 1. The soil pH and damping-off of rice seedling were decreased with increase in diatomearth application. 2. Ten to fifteen percent of diatomearth was required to adjuse the optimum soil pH range of 4.5-5.5. 3. Changes in nursery soil pH adjusted by diatomearth were less than those by sulfuric acid during the incubation period. 4. Diatomearth application increased dry weight and height of rice seedling.

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Effects of pH-Shift Processing and Microbial Transglutaminase on the Gel and Emulsion Characteristics of Porcine Myofibrillar System

  • Hong, Geun-Pyo;Chun, Ji-Yeon;Jo, Yeon-Ji;Choi, Mi-Jung
    • Food Science of Animal Resources
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    • v.34 no.2
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    • pp.207-213
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    • 2014
  • This study investigated the effects of microbial transglutaminase (MTGase) and pH-shift processing on the functional properties of porcine myofibrillar proteins (MP). The pH-shift processing was carried out by decreasing the pH of MP suspension to 3.0, followed by re-adjustment to pH 6.2. The native (CM) and pH-shifted MP (PM) was reacted with and without MTGase, and the gelling and emulsion characteristics were compared. To compare the pH-shifted MTGase-treated MP (PT), deamidation (DM) was conducted by reacting MTGase with MP at pH 3.0. Rigid thermal gel was produced by MTGase-treated native MP (CT) and PT. PM and DM showed the lowest storage modulus (G') at the end of thermal scanning. Both MTGase and pH-shifting produced harder MP gel, and the highest gel strength was obtained in PT. All treatments yielded lower than CM, and CT showed significantly higher yield than PM and DM treatments. For emulsion characteristics, pH-shifting improved the emulsifying ability of MP-stabilized emulsion, while the treatments had lower emulsion stability. PM-stabilized emulsion exhibited the lowest creaming stability among all treatments. The emulsion stability could be improved by the usage of MTGase. The results indicated that pH-shifting combined with MTGase had a potential application to modify or improve functional properties of MP in manufacturing of meat products.

Clarification of the Juice Extracted from Stored Apples by pH Adjustment (저장 사과로부터 착즙한 쥬스의 pH 조절에 의한 청징)

  • Kim, Dong-Man;Lee, Sei-En;Kim, Kil-Hwan
    • Korean Journal of Food Science and Technology
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    • v.21 no.2
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    • pp.180-184
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    • 1989
  • Clarification of the juice extracted from stored Fuji apples was studied with pectolytic enzyme and pH control, separately and in combinations. In the separated treatment, the clarity of the juice was increased with the treated enzyme amount. The juice adjusted pH to 3.5 with malic acid had the highest clarity in pH range from 3.5 to 5.0, but this juice was not acceptable because of high acidity. In combination of the two treatment, the clarity of the juice treated with the enzyme at pH 4.0 was higher than that of the juice without the enzyme, and the juice with ligh trasmittance of about 92% could be obtained at the pH by addition with one-third amount of enzyme which was used for clarification of the juice extracted from the fresh apples at harvesting season.

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Effect of Cryoprotectants on the Physico-chemical Characteristics of Chicken Breast Surimi Manufactured by pH Adjustment during Freezing Storage (냉동변성 방지제가 pH 조절법으로 제조한 닭가슴살 수리미의 냉동저장 중 이화학적 특성에 미치는 영향)

  • Jin, Sang-Keun;Kim, Il-Suk;Kim, Su-Jung;Jeong, Ki-Jong;Lee, Jae-Ryong;Choi, Yeung-Joon
    • Food Science of Animal Resources
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    • v.27 no.3
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    • pp.267-276
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    • 2007
  • This study was conducted to determine the effect of cryoprotectants (sugar, sorbitol, polyphosphate) on the physico-chemical characteristics of chicken breast surimi manufactured by pH adjustment (pH 11.0) during freezing storage. The final surimi was divided into experimental units to which the following treatments were randomly assigned: C (Alaska pollack surimi: two washings, 4% sugar +5% sorbitol ${\pounds}'$ 0.3% polyphosphate additive): T1 (chicken breast surimi: pH 11.0 adjusted, 0.3% polyphosphate additive): T2 (chicken breast surimi pH 11.0 adjusted, 5% sorbitol +0.3% polyphosphate additive); T3 (chicken breast surimi: pH 11.0 adjusted, 4% sugar +5% sorbitol +0.3% polyphosphate additive). The crude protein content of the control was higher than all treated samples, however the moisture, crude fat and crude ash of T3 were higher than the control (p<0.05). The pH, WHC and collagen content of the control were higher than all of the treated samples, and these values decreased with storage time for all treatments and the control (p<0.05). The cholesterol content of the control was lower than all treated samples, but the myofibrillar protein contents of all treated samples were higher than the control (p<0.05). The cooking loss of T2 was lower than the control and the other two treatments (p<0.05). The $L^*,\;a^*\;and\;b^*$ values of all treated samples were higher than those of the control during freezing storage (p<0.05). The W value of T3 at 1.5 and 3 months of freezing storage was higher than the control and T1 (p<0.05). The myoglobin and met-Mb contents of the control were similar to all treated samples, and the met-Mb content of the control and all treated samples increased with storage time (p<0.05). Immediately after freezing, the hardness of the control was higher than all treated samples, however it was lower after 1.5 and 3 months of frozen storage (p<0.05). The cohesiveness and gumminess of the control were higher than all treated samples immediately after freezing, however the values for T3 were higher than those of the control and the other two treatments during frozen storage for 1.5 and 3 months (p<0.05).

Growth and N, P removal efficiency of Chlorella vulgaris according to the nitrogen sources and pH condition (질소원 및 pH 조절빈도에 따른 Chlorella vulgaris의 성장특성 및 하수고도처리능 평가)

  • Han, Su-Hyun;Kim, Sun-Jin;Kim, Tae-Hyeong;Cho, Ki-Ju;Lee, Yunhee;Hwang, Sun-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.6
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    • pp.833-840
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    • 2012
  • This study aimed to investigate growth rate and nutrient removal efficiency of Chlorella vulgaris according to nitrogen sources and frequency of pH adjustment. Nitrogen and phosphorus removal efficiencies were evaluated in the three different conditions using $NO_3{^-}$, $NH_4{^+}$ as a sole nitrogen source and mixed condition. Initial nutrient concentrations in artificial wastewater were 30 mg-N/L and 3 mg-P/L similar to secondary wastewater effluent. When nitrogen source was $NO_3{^-}$, there was no inhibition on the growth of C. vulgaris with adjusting pH every 24 hr while growth inhibition occurred with $NH_4{^+}$ caused by pH drop. N, P removal efficiencies were no significant depending on the nitrogen sources. As pH was adjusted to 7 by pH-stat, growth rate and nutrient removal efficiencies were increased compared to adjusting pH every 24 hr, however, growth rate and nutrient removal efficiencies were no significant depending on the nitrogen sources.

A Basic Study on the Removal of Iron Ion in Waste Water by the Precipitation Flotation Method (부선법에 의한 폐수중 철이온의 제거에 관한 기돌 연구)

  • 김형석;조동성;오재현
    • Resources Recycling
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    • v.2 no.2
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    • pp.1-8
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    • 1993
  • This study was carried out in order to define the effective collectors and the opitimum conditions for the removal of iron ion in waste water by flotation method. The results obtained in this study are summarized as follows. Fe(II) and Fe(III) were removed effectively at pH7 and 6 respectively by using sodium lauryl sulfate, an anionic collector. The anionic collector, aeropromotor 845, removed both Fe(II) and Fe(III) effectively in pH ranges of from 5 to 9. The cationic collector, trimetyl dodecyl ammonium chloride, removed both Fe(II) and Fe(III) effectively in pH ranges from 10 to 11 and from 4 to 10, respectively. Therefore, Fe(II) and Fe(III) could be effectively removed by forming the iron hydroxide precipitates by simple pH adjustment of the solutions above precipitation point of ferrous and ferric ion by flotation method. Then, the effective pH regulator and collector were NaOH and $Na_2CO_3$,aeropromotor 845 and trimetyl dodecyl ammonium chloride, respectively.

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Minimizing of Residual Aluminum in Water Treatment Process (정수처리공정에서 잔류 알루미늄 최소화 방안)

  • 이미영;조덕희;박종현
    • Proceedings of the Korean Sanitation Conference
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    • 2004.11a
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    • pp.54-65
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    • 2004
  • Use of aluminum salts as coagulants In water treatment may lead to increased concentrations of aluminum in finished water. Aluminum is a suspected causative agent of neurological disorders such as Alzheimer's disease. The objective of this study was to examine variation and minimizing in residual aluminum concentration during water treatment process. The aluminum sources at Bokjeong Water Plant were present naturally aluminum in the raw water and derived due to use of PACS as a coagulant. Much of the raw water total aluminum were in particulate and suspended aluminum. In this study was compared the optimize condition to minimize the concentration of residual aluminum using Jar-test with the various coagulants such as alum, PAC, PACS. The results indicated that PACS was more effective than alum, PAC and insufficient or excessive alum, PAC, PACS addition led to increase residual aluminum. Adjustment raw water pH $6.5\~7.0$ before coagulation using PACS was capable of minimizing total and dissolved aluminum. Thus it is important that the optimal dosage of coagulant and the optimal pH adjustment before coagulation can decided to minimize the concentration of residual aluminum in treated water.

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