• Title/Summary/Keyword: p-Si

Search Result 4,598, Processing Time 0.03 seconds

Properties of Hydration and Strength of Sol-gol Derived Fine Particle in the System $CaO-P_2O_5-SiO_2$ (졸겔법에 의한 $CaO-P_2O_5-SiO_2$계 미세분말의 수화 및 강도특성)

  • 이형우;김정환
    • Journal of the Korean Ceramic Society
    • /
    • v.31 no.10
    • /
    • pp.1231-1239
    • /
    • 1994
  • In this study, gel powder which had relatively high hydration reactivity in CaO and P2O5 rich composition of CaO-P2O5-SiO2-H2O system was prepared by sol-gel process and its hydrated specimen was manufactured. The it was investigated to appropriate calcination temperature in sol-gel process which hydrated specimen of gel powder have proven to strength and the effect of factors influenced strength in hydration process. The major product of before and after hydration reaction was hydroxyapatite, and crystalline phase of C-S-H was already formed during gelation process. After hydration reaction of pressed specimen, crystalline phase of C-S-P-H was formed. It was hydrated product of silicocarnotite (5CaO.P2O5.SiO2). Gel phases of C-S-H and C-S-P-H occured as a result of partial substitution of amorphous silica by P2O5 was formed. The strength of hydrated hardened body is developed by strong bonding and bridging between the gel phases of C-S-H or C-S-P-H and the crystalline products such as hydroxyapatite, Ca(OH)2 C-S-H and C-S-P-H. In addition, the ultrafine gel powder have an great effect on increase of hydration reaction.

  • PDF

A Study on the Effects of Addition Elements on the Refinement of Primary Si Particles in Hypereutectic Al-Si alloys (과공정 Al-Si 합금의 초정 Si입자의 미세화에 미치는 첨가원소의 영향에 관한 연구)

  • Kim, Gyeong-Min;Go, Seung-Un;Yun, Ui-Park
    • Korean Journal of Materials Research
    • /
    • v.5 no.4
    • /
    • pp.412-419
    • /
    • 1995
  • 과공정 Al-18wt%Si합금의 초정 Si입자의 미세화에 미치는 첨가원소의 영향에 관하여 조사하였다. 초정 Si입자의 크기는 P량이 증가함에 따라 미세해졌으며 적정 P량은 40ppm이었다. 최적주입온도는 AlCuP, CuP 경우 각각 75$0^{\circ}C$, 80$0^{\circ}C$이었으며 미세화 처리 후 10분 이상 경과되어도 초정 Si입자의 크기는 변화가 없었다. 또한 WDS분석 결과 초정 Si내에 AIP가 핵생성 site로 존재함을 알 수 있었다.

  • PDF

Composite Structures of $SiC_p$/6063 Aluminum Alloy by Rheo-Compocasting. (Rheo-Compocasting에 의한 $SiC_p$/6063 Al합금의 복합조직)

  • Choe, Jeong-Cheol
    • Journal of Korea Foundry Society
    • /
    • v.10 no.4
    • /
    • pp.309-315
    • /
    • 1990
  • Aluminum alloy matrix composites reinforced by SiC particles were prepared by rheocompocasting, a process which consists of the incoporation and distribution of reinforcement by stirring within a semi-solid alloy. When the volume fraction of SiCp and stirring speed were fixed, the dispersion of SiCp in Al-matrix alloy depended on stirring time and solid volume fraction in slurry. The results were as follows : 1) As a dispersed SiCp during stirring at $647^{\circ}C$ in 6063-Al alloy, SiC was better dispersed than that other temperature, where solid volume fraction was 43% in slurry. 2) When increased solid fraction in slurry, rate of dispersing SiC increased during stirring and porosities decreased in matrix alloy after casting. 3) Inspite of stirring with 800rpm, since solid particles of matrix alloy in slurry joined each other and occured joining growth, so that SiC was not dispersed into solid particle.

  • PDF

Effect of SiC Particle Size on Hot Workability of AA2024/$SiC_P$ Composites (AA2024/$SiC_P$ 복합재료의 열간 가공성에 미치는 강화상 크기의 영향)

  • 고병철;홍흥기;유연철
    • Proceedings of the Korean Society for Technology of Plasticity Conference
    • /
    • 1997.03a
    • /
    • pp.81-84
    • /
    • 1997
  • The hot deformation behavior of SiCp/AA2024 composites reinforced with different sizes of SiCp reinforcements (1, 8, 15, 36, and 44${\mu}{\textrm}{m}$) was investigated by hot torsion tests. The hot restoration of the composites depending on the SiCp reinforcements particle size was studied from the effective stress - strain curves. Dynamic recrystallization (DRX) was occurred in the SiCp/AA2024 composites during the hot deformation at 320 - 43$0^{\circ}C$ under a strain rate of 1.0/sec. Also, the critical strain for DRX decreased with decreasing the reinforcement size of SiCp from 44 to 8${\mu}{\textrm}{m}$. The composite reinforced with SiCp of 8${\mu}{\textrm}{m}$ showed the highest flow stress (265 MPa) and the work hardening rate at 32$0^{\circ}C$ under a strain rate of 1.0/sec.

  • PDF

The Thermal Stability and Elevated Temperature Mechanical Properties of Spray-Deposited $SiC_P$/Al-11.7Fe-1.3V-1.7Si Composite

  • Hao, L.;He, Y.Q.;Wang, Na;Chen, Z.H.;Chen, Z.G.;Yan, H.G.;Xu, Z.K.
    • Advanced Composite Materials
    • /
    • v.18 no.4
    • /
    • pp.351-364
    • /
    • 2009
  • The thermal stability and elevated temperature mechanical properties of $SiC_P$/Al-11.7Fe-1.3V-1.7Si (Al-11.7Fe-1.3V-1.7Si reinforced with SiC particulates) composites sheets prepared by spray deposition (SD) $\rightarrow$ hot pressing $\rightarrow$ rolling process were investigated. The experimental results showed that the composite possessed high ${\sigma}_b$ (elevated temperature tensile strength), for instance, ${\sigma}_b$ was 315.8 MPa, which was tested at $315^{\circ}C$, meanwhile the figure was 232.6 MPa tested at $400^{\circ}C$, and the elongations were 2.5% and 1.4%, respectively. Furthermore, the composite sheets exhibited excellent thermal stability: the hardness showed no significant decline after annealing at $550^{\circ}C$ for 200 h or at $600^{\circ}C$ for 10 h. The good elevated temperature mechanical properties and excellent thermal stability should mainly be attributed to the formation of spherical ${\alpha}-Al_{12}(Fe,\;V)_3Si$ dispersed phase particulates in the aluminum matrix. Furthermore, the addition of SiC particles into the alloy is another important factor, which the following properties are responsible for. The resultant Si of the reaction between Al matrix and SiC particles diffused into Al matrix can stabilize ${\alpha}-Al_{12}(Fe,\;V)_3Si$ dispersed phase; in addition, the interface (Si layer) improved the wettability of Al/$SiC_P$, hence, elevated the bonding between them. Furthermore, the fine $Al_4C_3$ phase also strengthened the matrix as a dispersion-strengthened phase. Meanwhile, load is transferred from Al matrix to SiC particles, which increased the cooling rate of the melt droplets and improved the solution strengthening and dispersion strengthening.

Effect of p-type a-SiO:H buffer layer at the interface of TCO and p-type layer in hydrogenated amorphous silicon solar cells

  • Kim, Youngkuk;Iftiquar, S.M.;Park, Jinjoo;Lee, Jeongchul;Yi, Junsin
    • Journal of Ceramic Processing Research
    • /
    • v.13 no.spc2
    • /
    • pp.336-340
    • /
    • 2012
  • Wide band gap p-type hydrogenated amorphous silicon oxide (a-SiO:H) buffer layer has been used at the interface of transparent conductive oxide (TCO) and hydrogenated amorphous silicon (a-Si:H) p-type layer of a p-i-n type a-Si:H solar cell. Introduction of 5 nm thick buffer layer improves in blue response of the cell along with 0.5% enhancement of photovoltaic conversion efficiency (η). The cells with buffer layer show higher open circuit voltage (Voc), fill factor (FF), short circuit current density (Jsc) and improved blue response with respect to the cell without buffer layer.

Effect of Environmental Factors on the Growth of Microcystis aeruginosa (Cyanobacteria) in Agricultural Reservoirs (농업용 저수지에서 환경 요인이 Microcystis aeruginosa (cyanobacteria) 성장에 미치는 영향)

  • Kwon, O-Chang;Park, Jung-Won;Chung, Gyu-Young;Lee, Jong-Eun;Seo, Eul-Won
    • Journal of Life Science
    • /
    • v.21 no.8
    • /
    • pp.1183-1189
    • /
    • 2011
  • The present study is aimed at examining the effects of the physico-chemical environmental factors of water systems on water bloom at Homin and Gagok reservoirs in Pungcheon-Myeon, Andong, Gyeongsangbuk-do. The mean water temperature and the contents of chlorophyll-a, total-nitrogen, total-phosphorus and phosphate-phosphorus were higher at the Gagok reservoir. On the other hand, the pH mean value was higher at the Homin reservoir. The mean value of microelements (Na, K, Mg, Fe, Si) was higher at the Gagok reservoir. The cyanobacteria which was considered to be the cause of water bloom at the two reservoirs was Microcystis aeruginosa. It started to grow in May and showed the highest standing crop in August. Between the increase of standing crop of M. aeruginosa and the water quality, correlation values of $Na^+$ (r=-0.910, p<0.05), $Fe^{2+}$ (r=-0.855, p<0.05) and $Si^{4+}$ (r=0.989, p<0.01) at the Homin reservoir increased amount of standing crop. Meanwhile, at the Gagok reservoir, the contents of $Na^+$ (r=-0.776, p<0.05), $Si^{4+}$ (r=0.899, p<0.05) were highly related to the increase of standing crop. Interestingly, Si, which is the limiting factor for diatoms, has a high correlation with standing crop of cyanobacteria. In conclusion, the water blooming is caused not by a simple factor but a synergistic effect due to complex actions including high concentrations of nitrogen and phosphorus ions and many other environmental factors.

The Revised Version of the Minnesota Multiphasic Personality Inventory in Korean College Students with Symptoms of Temporomandibular Disorders

  • Park, Hye Sook
    • Journal of Oral Medicine and Pain
    • /
    • v.44 no.1
    • /
    • pp.16-24
    • /
    • 2019
  • Purpose: The purpose of this study was to assess the association of personality characteristics with temporomandibular disorders (TMDs). Methods: Four hundred and fifty one college students in Gyeonggi-do completed the revised version of the Minnesota Multiphasic Personality Inventory (MMPI-2) and a questionnaire and collected data were analyzed by IBM SPSS Statistics ver. 25.0 software (IBM Co., Armonk, NY, USA). Results: Mean values of the number of positive answers of TMD symptoms were significantly higher in higher scorers on hypochondriasis (Hs), depression (D), paranoia (Pa) (Hs>60, D>64, Pa>59) (p<0.01). Higher scorers on Hs, hysteria (Hy), schizophrenia (Sc), Pa, psychasthenia (Pt) (Hy>64, Sc>64, Pt>64) exhibited significantly higher mean values of the number of positive answers of contributing factors for TMD (p<0.01, p<0.001). Low scorers on social introversion ($Si{\leq}44$) exhibited significantly lower mean value of the number of positive answers of contributing factors for TMD than high or moderate scorers on Si (Si>64, 45-64) (p<0.01, p<0.05). The percentage of subjects who responded that they had at least one TMD symptom was significantly higher in higher scorers on Hs, Pt, D (p<0.05, p<0.01). The significantly higher percentage of higher scorers on D, Pa reported at least one contributing factor for TMD (p<0.05). The percentage of subjects who responded that they had at least one TMD symptom or one contributing factor for TMD was significantly different among three groups divided by T-score on Si (p<0.01, p<0.05). T-scores of Hs, D, Hy, Pt and Sc showed significant correlation with the numbers of TMD symptoms and contributing factors for TMD, respectively (p<0.001). A correlation was found between T-score of Pd and the number of TMD symptoms (p<0.001). T-score of Si correlated to the number of contributing factors for TMD (p<0.001). Conclusions: Most clinical scales of MMPI-2 were found to be related to TMD. Psychological assessment including MMPI-2 may play a role in predicting treatment outcome and planning treatment of TMD.

Microstructural Changes during Semi-solid State in Hypereutectic Al-Si Alloy (과공정 Al-Si 합금의 반고상 재가열시 미세조직 변화)

  • Kim, In-Joon;Kim, Do-Hyang
    • Journal of Korea Foundry Society
    • /
    • v.18 no.6
    • /
    • pp.541-549
    • /
    • 1998
  • Microstructural characteristics of hypereutectic Al-Si alloys during reheating at semi-solid temperature have been investigated. The size and morphology of primary Si particles in wedge-type mold-cast ingot has been compared with hot-rolled sheet and Si particulate reinforced Al composite. Effects of P and Sr addition on the morphological changes of primary Si particles have been also investigated. Observation of the solidification microstructures of the wedge-type mold-cast ingot at different cooling rates showed that alloying elements such as P and Sr affect the morphology of Si particles, especially in the area solidified at a slow cooling rate. Negligible change in the size of primary crystals was observed after reheating experiment, but ${\alpha}-halo$ formed around the Si particles and fine particles of Si precipitated in the surrounding area of the Si particles. In addition, there seemed to be no coarsening with increasing of holding time and the region of ${\alpha}-halo$ being decreased. Nucleation and recrystallization was accelerated with addition of alloying elements during hot rolling resulting in a decrease of primary Si particle size. In the case of extruded specimens, morphological change of primary Si particles was not observed after reheating. No ${\alpha}-halo$ formation was observed in Si reinforced Al composite because of the oxide film formed on the Si particles which acted as a diffusion barrier between substrate and the primary Si particles.

  • PDF

ON THE SOLAR OSCILLATOR STRENGTH OF SiH+

  • TRIVEDI CHETNA;SINHA K.
    • Journal of The Korean Astronomical Society
    • /
    • v.29 no.spc1
    • /
    • pp.345-346
    • /
    • 1996
  • The contrasting values of the oscillator strengths for the (0,0) band of SiH+ molecules for the $A\;^1II-X\;^1{\sum}+$ transition reported in literature, motivated us to reinvestigate the same with the help of a new set of well accepted solar photospheric models, elemental abundances and dissociation energy.

  • PDF