• Title/Summary/Keyword: ozone-water

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A Study on the Change in Forest Community by Air Pollution at Yocheon District (大氣汚染에 依한 麗川地域의 森林群集變化에 關한 硏究)

  • Kim, Joon-Seon;Kim, Tae-Wook
    • Journal of Korean Society for Atmospheric Environment
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    • v.2 no.3
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    • pp.1-10
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    • 1986
  • Nowadays, air pollution by increasing consumption of fossil fuels resulting from rapidly growing population and industrialization has caused the adverse effects on terrestrial ecosystems and become one of the most serious problems causing environmental discriptions. Air pollution such as $SO_2, HF, NO_X,$ fly ash, ozone and PAN might influence plant growth, reproduction, nutrient cycling, photosynthesis and predisposition to entomological and pathological stresses on plants. Furthermore, accumulation of those toxic substances in forests might cause subtle or serious changes in the structure and function of forest ecosystems. Since 1970s, a number of large industrial complexes had been constructed as a part of industrialization plan in Korea. Accordingly, the forest exosystems around them has been under chronic influences of air pollution and effects of air pollution on plants became a matter of concern. In Yocheon Industrial Complex which consisted of lots of petrochemical plants and a phosphatic fertilizer manufacturing plant, forests has been exposed to chronic air pollution, mainly HF and $SO_2$ gas, Various reports were available to investigate the potential effects of air pollution on crops and forest trees in Yocheon. Kim and Kim surveyed vegetation by naked eye method and reported 71 families, 150 genera and 158 species were growing within a 2 km from air pollution sources in 1981. Needle injuries on Pinus spp. in the polluted area water reported by Kim, et al. and Kim, et al. Kim, et al. investigated the primary production of Pinus thunbergii forests in the polluted area and verified that growth inhibition of Pinus thunbergii was attributable to air pollution. Thus, previous reports suggested that forest ecosystems around Yocheon Industrial Complex were influenced adversely by air pollution. The objective of this study was to investigate the subtle ecological changes in forest community exposed to chronic air pollution in Yocheon.

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A Study on Volume Reduction of Waste Sludge by Aerobic Thermophilic Bacteria (호기성 호열미생물에 의한 하수슬러지 감량화 효율에 관한 연구)

  • Bae, Yoon-Sun;Kim, Soon-Young;Nam, Duck-Hyun;Park, Chul-Hwi;Kim, Jin-Su;Takada, Kazu
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.4
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    • pp.497-505
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    • 2005
  • Domestic Sewage Treatment Plants are mostly based on biological treatment, in which large amounts of excess sludge are generated and occupy about 40 ~ 60% of the total sewage treatment costs. Several methods for sludge treatment has been so far reported as upgrading biodegradation of sludge; heat treatment, chemical treatment, including thermo-alkali and ozone, mechanical treatment including ultrasonic pulverization. But, it has a limitation in case of reducing the amount of excess sludge which are already producted. In this study, application of excess sludge reduction process using thermophilic aerobic bacteria for activated sludge was examined. The research was carried out two different stage. one for a biological wastewater treatment and the other for a thermophilic aerobic solubilization of the waste sludge. A portion of excess sludge from the wastewater treatment step was into the thermophilic aerobic sludge solubilization reactor, in which the injected sludge was solubilized by thermophilic aerobic bacteria. The solubilized sludge was returned to the aeration tank in the wastewater treatment step for its further degradation. Sludge solubilization reactor was operated at $63{\pm}2^{\circ}C$ with hydraulic retention time(HRT) of 1.5 ~ 1.7 day. Control group was operated with activated sludge process(AS) and experiment group was operated with three conditions(RUN 1, RUN 2, RUN3). RUN 1 was operated with AS without sludge solubilization reactor. RUN 2 were operated with AS with sludge solubilization reactor to examine correlation between sludge circulation ratio and sludge reduction ratio by setting up sludge circulation ratio to 3. RUN 3 was operated with sludge circulation ratio of 3 and MLSS concentration of 1,700~2,000mg/L to examine optimum operation condition. The quantity of excess sludge production was reduced sharply and in operation of RUN 3, sludge The quantity of excess sludge production was reduced sharply and in operation of RUN 3, sludge solubilization ratio and sludge reduction ratio were 53. 7%, 95.2% respectively. After steady state operation, average concentration of TBOD, SBOD, $TCOD_{Cr}$, $SCOD_{Cr}$, TSS, VSS, T-N, T-P of effluent were 4.5, 1.7, 27 .8, 13.8, 8.1, 6.2, 15.1, 1.8mg/L in the control group and were 5.6, 2.0, 28.6, 19.1, 9.7, 7.2, 16.1, 2.0mg/L in the experimental group respectively. They were appropriate to effluent standard of Sewage Treatment Plants.

Wet Chemical Process for Improving Air Quality in Semiconductor Manufacturing Process (반도체 생산공정의 대기질 개선을 위한 복합 대기오염물의 습식화학 제거공정)

  • Jun, Chang-Sung;Kim, Hak-Ju;Park, Young-Moo;Lee, Dae-Won;Ham, Dong-Suk;Jeon, Sang-Moon;Lee, Kwan-Young
    • Clean Technology
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    • v.13 no.2
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    • pp.109-114
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    • 2007
  • In this study, we performed basic researches to develop wet purification system for improving air qualities of ventilation in semiconductor manufacturing process. Using 0.5 M aqueous solution of $KMnO_4$, 50 ppm of $NH_3$, SOx and NOx were reduced to 99% successfully. However, the removal of $O_3$ was limited to $22{\sim}30%$ for all the tested chemical solutionsincluding $KMnO_4$. Therefore, adoption of a dry ozone filter is necessary to reduce $O_3$ below a satisfactory level. For all the chemical solutions tested, NOx removal efficiency increased as NOx was mixed with $O_3$. As chemical solution was sprayed using water spraying system equipped with air atomizing type nozzle, the removal efficiencies of gaseous pollutants increased due to the increase of gas-liquid interfacial area.

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A Study on the Retrieval of River Turbidity Based on KOMPSAT-3/3A Images (KOMPSAT-3/3A 영상 기반 하천의 탁도 산출 연구)

  • Kim, Dahui;Won, You Jun;Han, Sangmyung;Han, Hyangsun
    • Korean Journal of Remote Sensing
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    • v.38 no.6_1
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    • pp.1285-1300
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    • 2022
  • Turbidity, the measure of the cloudiness of water, is used as an important index for water quality management. The turbidity can vary greatly in small river systems, which affects water quality in national rivers. Therefore, the generation of high-resolution spatial information on turbidity is very important. In this study, a turbidity retrieval model using the Korea Multi-Purpose Satellite-3 and -3A (KOMPSAT-3/3A) images was developed for high-resolution turbidity mapping of Han River system based on eXtreme Gradient Boosting (XGBoost) algorithm. To this end, the top of atmosphere (TOA) spectral reflectance was calculated from a total of 24 KOMPSAT-3/3A images and 150 Landsat-8 images. The Landsat-8 TOA spectral reflectance was cross-calibrated to the KOMPSAT-3/3A bands. The turbidity measured by the National Water Quality Monitoring Network was used as a reference dataset, and as input variables, the TOA spectral reflectance at the locations of in situ turbidity measurement, the spectral indices (the normalized difference vegetation index, normalized difference water index, and normalized difference turbidity index), and the Moderate Resolution Imaging Spectroradiometer (MODIS)-derived atmospheric products(the atmospheric optical thickness, water vapor, and ozone) were used. Furthermore, by analyzing the KOMPSAT-3/3A TOA spectral reflectance of different turbidities, a new spectral index, new normalized difference turbidity index (nNDTI), was proposed, and it was added as an input variable to the turbidity retrieval model. The XGBoost model showed excellent performance for the retrieval of turbidity with a root mean square error (RMSE) of 2.70 NTU and a normalized RMSE (NRMSE) of 14.70% compared to in situ turbidity, in which the nNDTI proposed in this study was used as the most important variable. The developed turbidity retrieval model was applied to the KOMPSAT-3/3A images to map high-resolution river turbidity, and it was possible to analyze the spatiotemporal variations of turbidity. Through this study, we could confirm that the KOMPSAT-3/3A images are very useful for retrieving high-resolution and accurate spatial information on the river turbidity.

CHLOROFORM IN THE AIR OF INDOOR SWIMMING POOLS AND THE OUTDOOR AIR NEAR THE SWIMMING POOLS IN A CITY OF KOREA (국내 한 도시의 실내 수영장 공기 및 수영장 인근의 실외 공기에서의 클로로포름)

  • 조완근;황영미
    • Journal of Environmental Science International
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    • v.3 no.3
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    • pp.253-261
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    • 1994
  • Chloroform present in the swimming water disinfected with sodium hypochlorite is released to the air of swimming pools. The air chloroform concentrations were measured in two swimming pools A and B which applied both sodium hypochlorite a:d ozone. Thew mean concentrations are 28.0 $\mu\textrm{g}$/m3 and 33.6 $\mu\textrm{g}$/m3in the swimming pools A and B, respectively. On the other hand, the mean water chloroform concentrations in the swimming pools A and B were 23.9 $\mu\textrm{g}$/l and 19.5 $\mu\textrm{g}$/l, respectively. The air chloroform concentrations were lower in the swimming Bools A and B than those reported by previous studies abroad employed the swimming pools which applied sodium hypochlorite only for water disinfection. The water chloroform concentrations were also lower in this study than in the previous studies. The relationship between the air and water chloroform concentrations measured in this study was significant with p=0.002 and Rz=0.42. At similar time to the indoor air sampling, outdoor air samples were collected at two sites near each of the swimming Pools A and B. The mean outdoor air chloroform concentrations near the swiminE Pools A and B were 0.41 $\mu\textrm{g}$/m3 and 0.16 $\mu\textrm{g}$/m3, respectively. The outdoor air chloroform concentrations measured in this study were equal to or lower than those reported by previous studies abroad. 'rho chloroform dose inhaled for a typical one-hour swim was estimated to be 25.9 $\mu\textrm{g}$ per person, corresponding to a specific 0.37 $\mu\textrm{g}$/kg body weight for a reference 70 Kg male adult, while the inhalation dose of chloroform from the outdoor air was estimated to be 5.6 $\mu\textrm{g}$ per person per day, corresponding to a specific 0.08 $\mu\textrm{g}$/Kg/day for the same reference male adult.

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Quality Characteristics of Sliced Raw-fish Washed by Different Methods during Storage (세척방법에 따른 생선회의 저장 중 품질특성)

  • Oh, Seung-Hee;Jung, Yoo-Kyung;Kim, Su-Hyun;Kim, Soon-Dong
    • Food Science and Preservation
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    • v.14 no.6
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    • pp.571-577
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    • 2007
  • Storage characteristics of fresh and thawed sliced raw fish (flounder and rockfish) washed in different solutions (tap water, A; jade water, B; 0.2% chitosan-ascorbate (CA), C; 0.03 ppm ozone water, D; 1.5% vinegar containing jade water, E; 1.5% vinegar and 0.2% CA containing jade water, F) at $10^{\circ}C$ were investigated. Changes in pH and acidity of thawed sliced raw fish (TS) during storage were lower than for fresh sliced raw fish (DS). The total microbial content (log cfu/g) of A stored for 3 days in DS was 6.7 (which represented an increase of 1 log cycle compared with day zero), but was 5.50 in B, 3.23 in C, 4.90 in D, 2.40 in E and 1.77 in F, the latter similar to counts at day zero. The degree of microbial contamination of DS and TS followed the order F > E > D > C > B > A in flounder, and F > E > C > D > B > A in rockfish. In general the hardness and chewiness of TS was less than for DS. While the effect of CA on TS texture was not significant in flounder, the effect showed in rockfish. For DS, the appearance in B, C and D was relatively good, as was freshness. Fishiness of flavor was in the order A > B > F > E > D > C. Overall acceptability of flounder and rockfish treated with C was better than treatment with the other washing agents. For TS the appearance of flounder and rockfish were good in B and C. The freshness of flounder and rockfish were in the order of D > C > B > A > E > F and D > C > B > A > E > F, respectively. Fishiness of the flavor of sliced raw fish was lowest in D, which also provided the best overall acceptability.

A Study of Molecular Size Distributions of Humic Acid by Photo-Oxidation and Ozonation (부식질의 광산화 및 오존산화에 있어서의 분자량 크기분포 변화 특성에 관한 연구)

  • Kim, Jong-Boo;Kim, Kei-Woul;Rhee, Dong Seok
    • Analytical Science and Technology
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    • v.16 no.4
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    • pp.292-298
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    • 2003
  • In this study, the photooxidation and ozonation of humic acid (HA) in aqueous solution were conducted and the treated HA samples at different reaction time were analyzed using ultrafiltration techniques to evaluate the change of their molecular size distributions with its DOC removal. Molecular size distribution of untreated HA showed 41.5% in higher molecular size fractions (>30,000 daltons) and 15.2% in much smaller molecular size fraction (<500 daltons). As UV irradiation time was increased, it was observed that the degradation of the large molecules of the fraction of >30,000 daltons into much smaller molecules was increased. In UV system, the HA molecules of the fraction of <500 daltons became significantly more and its percentage was increased from 35.3% (UV only irradiation) to 58.9% ($UV/TiO_2$) and 87.8% ($UV/H_2O_2$) in the presence of the photocatalysis. Otherwise, ozonation of HA produced mainly the fraction of medium molecular size ranging from 3,000 to 30,000 daltons with much lower portion (<~7%) in the fraction of <500 daltons. In ozone only system, the fraction of 30,000~10,000 daltons occupied in 41.5% at 60 min of ozonation time. In $O_3/H_2O_2$ system, the fraction of 30,000~10,000 daltons and 10,000~3,000 daltons occupied in 38.9% and 36.2% respectively. Based on these results, we suggested applicable treatment process which could be combined with $UV/H_2O_2$, $UV/TiO_2$ and $O_3$, $O_3/H_2O_2$ system for more effective removal of humic acid in water treatment.

Growth Inhibition against Contaminants in Aseptic Chocolate Milk Using Physicochemical Methods (물리.화학적 처리에 의한 멸균 초콜릿 우유 오염균의 생육억제 효과)

  • Choi, Moon-Kyoung;Yoon, So-Young;Lee, So-Young;Kim, Koth-Bong-Woo-Ri;Lee, Chung-Jo;Jung, Ji-Yeon;Kwak, Ji-Hee;Kim, Min-Ji;Kim, Dong-Hyun;SunWoo, Chan;Lee, Ju-Woon;Byun, Myung-Woo;Ahn, Dong-Hyun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.40 no.8
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    • pp.1157-1163
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    • 2011
  • This study was conducted to investigate the cause of microbiological contaminants in aseptic chocolate milk and evaluate the effect of a physicochemical treatment on the growth inhibition of isolated bacterial strains. The bacterium isolated from aseptic chocolate milk was identified as Bacillus lentus and was named B. lentus M1. In the heat and pH treatment, the growth of B. lentus was inhibited at 110$^{\circ}C$ for >15 min and at pH's <5 and >10. An electrolyzed water treatment against B. lentus M1, revealed 5 mm growth past the inhibition zone. The effect of ozone gas on B. lentus M1 growth was evaluated using viable cell counts. When the initial number of B. lentus M1 was $10^2$ and $10^3$ CFU, the bacteria were completely suppressed by ozone gas treatment for 10 and 30 min, respectively. In a microwave treatment, B. lentus M1 was sterilized following microwave treatment for 1 min. As the result of ${\gamma}$-irradiation against B. lentus M1, numbers decreased as the ${\gamma}$-irradiation dosage increased. These results show the growth inhibition effects against contaminants in aseptic chocolate milk using physicochemical treatments.

Evaluation of Sensitivity and Retrieval Possibility of Land Surface Temperature in the Mid-infrared Wavelength through Radiative Transfer Simulation (복사전달모의를 통한 중적외 파장역의 민감도 분석 및 지표면온도 산출 가능성 평가)

  • Choi, Youn-Young;Suh, Myoung-Seok;Cha, DongHwan;Seo, DooChun
    • Korean Journal of Remote Sensing
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    • v.38 no.6_1
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    • pp.1423-1444
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    • 2022
  • In this study, the sensitivity of the mid-infrared radiance to atmospheric and surface factors was analyzed using the radiative transfer model, MODerate resolution atmospheric TRANsmission (MODTRAN6)'s simulation data. The possibility of retrieving the land surface temperature (LST) using only the mid-infrared bands at night was evaluated. Based on the sensitivity results, the LST retrieval algorithm that reflects various factors for night was developed, and the level of the LST retrieval algorithm was evaluated using reference LST and observed LST. Sensitivity experiments were conducted on the atmospheric profiles, carbon dioxide, ozone, diurnal variation of LST, land surface emissivity (LSE), and satellite viewing zenith angle (VZA), which mainly affect satellite remote sensing. To evaluate the possibility of using split-window method, the mid-infrared wavelength was divided into two bands based on the transmissivity. Regardless of the band, the top of atmosphere (TOA) temperature is most affected by atmospheric profile, and is affected in order of LSE, diurnal variation of LST, and satellite VZA. In all experiments, band 1, which corresponds to the atmospheric window, has lower sensitivity, whereas band 2, which includes ozone and water vapor absorption, has higher sensitivity. The evaluation results for the LST retrieval algorithm using prescribed LST showed that the correlation coefficient (CC), the bias and the root mean squared error (RMSE) is 0.999, 0.023K and 0.437K, respectively. Also, the validation with 26 in-situ observation data in 2021 showed that the CC, bias and RMSE is 0.993, 1.875K and 2.079K, respectively. The results of this study suggest that the LST can be retrieved using different characteristics of the two bands of mid-infrared to the atmospheric and surface conditions at night. Therefore, it is necessary to retrieve the LST using satellite data equipped with sensors in the mid-infrared bands.

Inhibition of Urea Hydrolysis and Nitrification in Upland Soils by Artemisia asiatica Extracts (쑥 추출물(抽出物)의 밭토양중(土壤中) 요소분해(尿素分解), 질산화(窒酸化) 작용(作用) 억제효과(抑制效果))

  • Lim, Sun-Uk;Shin, Myonug-Ho;Park, Hyun-Jun;Kim, Min-Kyun
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.4
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    • pp.392-399
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    • 1998
  • Nitrogen fertilizers such as urea are readily hydrolyzed in soils to produce ammonium ions which pass through nitrification and denitrification processes. These serial processes have drawn attention due to nitrogen losses, eutrophication, blue baby syndrome, and ozone depletion problems. The purpose of this study was to test the inhibitory effects of hot-water extract and organic solvent fractions of Artemisia asiatica leaves on soil urea hydrolysis and nitrification. In addition, the effects of organic solvent fractions on urease activity and ureolytic bacterial population were also investigated. First, hot-water extract of Artemisia asiatica leaves inhibited soil nitrification substantially with a marginal stimulatory effect on soil urea hydrolysis. Soils treated with hot-water extract of Artemisia asiatica leaves showed significant decreases in the accumulation of soil $NO_3-N$ (~68% decrease) compared with the control soil without the treatment of hot-water extract. In contrast, $CHCl_3$/MeOH fraction and basic aqueous layer of Artemisia asiatica leaves inhibited soil urea hydrolysis very strongly, causing 5.8 and 4.3-fold higher accumulation in amounts of remaining urea-N compared with the non-treated soil. Meanwhile, non of the organic solvent fractions showed any significant effects on soil nitrification inhibition. The inhibition of ureolytic bacterial activity by $CHCl_3$/MeOH fraction and aqueous basic layer of Artemisia asiatica leaves without any effects on urease activity itself led us to conclude that the inhibitions of soil urea hydrolysis were caused by the antagonistic effects on ureolytic bacterial activity.

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