• Title/Summary/Keyword: ozone-water

Search Result 583, Processing Time 0.026 seconds

Removal of Tetrachloroethylene using Advanced Oxidation Processes (고급산화법을 이용한 Tetrachloroethylene의 처리)

  • Shin, Hang-Sik;Lim, Jae-Lim
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.10 no.4
    • /
    • pp.64-72
    • /
    • 1996
  • The effect of $O_3$, $O_3/pH$, and $O_3/H_2O_2$, $O_3/UV$, and $H_2O_2/UV$ advanced oxidation process(AOP) were investigated for the treatment of tetrachloroethylen(PCE) at various condition. The removal efficiency of 10, 20, and 30ppm PCE by ozonation were almost same, only about 60%. And pseudo first-order rate constants, ko for overall oxidation was about 0.097($min^{-1}$). In the $O_3/pH$ AOP experiment for the 20ppm PCE, the removal rate of PCE increased with the increase of pH. However, mineralization rate of PCE at pH 7 was higher than at pH 10. In the $O_3/H_2O_2$ AOP, the removal rate of PCE was the highest at peroxide-to-ozone dosage ratio of about 0.9, which PCE was removed over 99.95%. Despite 42% of PCE was directly photolyzed by the UV irradiation, the removal efficiency of PCE by $O_3/UV$ AOP was only about 70%. In $H_2O_2/UV$ AOP, the removal efficiency of PCE increased to about 98% in proportion to the $H_2O_2$ injection concentration at constant UV intensity of 5W/l.

  • PDF

Piggery Waste Treatment using Improved MLE Process in Full-Scale (수정된 MLE 공정을 이용한 Full-Scale에서의 돈사분뇨처리)

  • Hwang, In-Su;Min, Kyung-Sok
    • Journal of Korean Society on Water Environment
    • /
    • v.22 no.5
    • /
    • pp.895-904
    • /
    • 2006
  • The improved MLE (modified Ludzack-Ettinger) process was operated for piggery waste treatment in full-scale public livestock waste treatment plant. The treated waste from bioreactor was suitable for the strict effluent standard of 200 mgCOD/L and 60 mgTN/L as it was dewatered chemically without settling tank and passed through filtration process. Though this treatment method produced a great deal of sludge ($6.4m^3\;per\;m^3$ dewatered piggery waste) it was able to accomplish predominant effluent quality by removing non-biodegradable COD and color without advanced oxidation process as ozone, fenton and etc.. The nitrogen removal efficiency of bioreactor was rapidly declined from March to May (from 0.016 to 0.005 kgN/kgVSS-day) when disinfection is in earnest as well as from warm season when reactor temperature rises higher than $35^{\circ}C$(from 0.016 to 0.008 kgN/kgVSS-day). This study proves that counterplanes for infection residuals, bioreactor temperature and dewatering sludge reduction are necessary for piggery waste treatment.

Performances of a Sludge Reduction Process Using High Concentration Membrane Bioreactor with Sludge Pretreatment (슬러지 전처리와 고농도 MBR을 이용한 슬러지 감량화 공정연구)

  • Han, Kyu-Chul;Yeom, Ik-Tae;Jung, Woo-Jin;Kim, Hyung-Soo
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.17 no.4
    • /
    • pp.559-566
    • /
    • 2003
  • From this research, the performances of a sludge reduction in the sewage sludge aerobic digestion was experimented by using a sludge pretreatment and membrane bioreactor. The submerged plate membrane was used as the solid-liquid separation membrane. After drawing small amounts of sludge in a bioreactor and then doing the alkaline treatment and ozone treatment, the sludge was sent to back to the reactor. The HRT in the reactor was set as 5 days and the operation in the reactor was carried out at the DO of 1mg/L on average. After 100 days of operation in the reactor, it was shown that the reduction efficiency of total solids was more than 83%. Most of volatile solids were removed through mineralization, and the considerable portion of the non-volatile solids was dissolved and then flowed out with the effluent. Only about 16.3% of total solids in the sludge was accmulated in the reactor even without the loss of volatile fraction. Also, by deriving nitrification and denitrification in one reactor simultaneously, more than 90% of nitrogen removal effect was realized and the experiment was run smoothly without fouling of membrane, even in the high concentration of MLSS. Based on this experiment, sludge can be reduced considerably at a low HRT by these two newly suggested approach.

A Study of Ocean Thermal Energy Conversion Systems Using Kalina cycle and Regenerative Rankine cycle (Kalina 사이클과 재생 Rankine 사이클을 이용한 해양 온도차 발진 시스템)

  • Shin, S.H.;Jung, D.S.;Kim, C.B.;Seo, T.B.
    • Solar Energy
    • /
    • v.19 no.3
    • /
    • pp.101-113
    • /
    • 1999
  • Thermodynamic performance of a simple Rankine cycle, regenerative Rankine cycle, and Kalina cycle for Ocean thermal Energy Conversion(OTEC) is evaluated under the same condition with various working fluids. The evaporator and condenser are modeled by a UA and LMTD method while the turbine and pump are modeled by considering isentropic efficiencies. As for the working fluids, R22, R134a, R32, propylene, ammonia are used for the Rankine cycles while ammonia/water and R32/R134a mixtures are used for Kalina cycle. Calculated results show that newly developed fluids such non-ozone depleting refrigerants as R134a and R32 perform as well as R22 and ammonia. The regenerative Rankine cycle showed a 1.2 to 2.8% increase in energy efficiency as compared to the simple Rankine cycle while the Kalina cycle with ammonia/water mixture showed a 1.8% increase in energy efficiency. The efficiency of the Kalina cycle with R32/R134a mixtures is the same as that of a simple Rankine cycle using R22. Therefore, the regenerative Rankine cycle turns out to be best choice for OTEC applications.

  • PDF

인공위성 원격탐사에 의한 지구 수계환경 감시

  • 박경윤
    • Water for future
    • /
    • v.24 no.3
    • /
    • pp.36-41
    • /
    • 1991
  • 1960년대 초부터 미 국립항공우주국(NASA)에서 기상위성을 지구궤도에 올리면서 시작되고 우주개발 선도국들에 의해 수 없이 발사되어 지구상공을 선회하고 있는 각종 실험위성, 자원탐사위성들로부터 이전까지만해도 지엽적이고 단편적인으로 알려지던 지구환경현황들이 이제는 지구전체에 대한 시시각각의 정보로 확대되고 있다. 기상위성들에 장착된 Sensor들로는 구름과 기상현상의 분포는 물론이고 각 대양의 해수면 온도 분포들이 파악되고 있으며 식물지수에 의한 지상의 식물분포의 계절적 변화양상에서 열대림의 사막화 추세들까지도 분석된다. 특히 위성탐사에 의한 남극 오존홀 (Ozone Hole)의 확인은 최근악화 되고 있느 swlrnchs 환경문제에 대한 커다란 주의를 환기시켜 주었다. 대양의 Phytoplankton 분포가 계절에 따라 위성자료에 의해 분석되므로서 해양의 생산능력(Productivity)의 변화도 알게되고 있다. 해양수면의 높이를 측정했던 초단파(microwave)영역의 SAR 자료는 구름을 투과하여 지구표면을 전천후 Monitoring할 수 있는 다음 세대의 Sensor로 각광을 받고 있으며 앞으로 유럽과 일본, 카나다, 소련 등에서 이들 새로운 Sensor들이 탑재 될 자원탐사 위성(ERS)과 RADASAT 등의 위성이 계속해서 개발되고 있어 이들에 의한 지구환경상태 진단은 크게 각광받게 될 것이다. 그외에도 해면풍 운량, 총강우량 분포, 대기 투명도, 대기의 열수지등의 계절적 변화에 대한 인공위성자료 해석을 통하여 지구의 온난화nas제가 본격적으로 ud가되고 있다. 또한 자원탐사위성인 Landsat 과 SPOT 등의 위성에 의해서는 각대륙의 토지 이용도 변화, 토사의 이도, 지질도 작성, 입체도 제착등과 농산물수확량의 예측있어서 괄목할 만한 발전이 계속되고 있다. 더욱이 NASA와 일본, 유럽등에서 지구관측을 위해서 준비하고 있는 각종 지구관측위성(EOS)들이 실용화 될 2000년 대에는 일반 지구환경감시는 물론 수계환경 감시 체계구축에 획기적인 진전이 있을 것으로 기대된다.

  • PDF

Photosynthetic Inhibition in Leaves of Ailanthus altissima under O3 Fumigation

  • Lee, Jae-Cheon;Oh, Chang-Young;Han, Sim-Hee;Kim, Pan-Gi
    • Journal of Ecology and Environment
    • /
    • v.29 no.1
    • /
    • pp.41-47
    • /
    • 2006
  • We investigated the enect of $O_3$ on the photosynthetic characteristics of tree of heaven (Ailanthus altissima) that is naturalized plant and used as restoration plant for contaminated area. Two-year-old seedlings were planted to pots and transferred into closed $O_3$ chamber. Photosynthetic pigments contents and photosynthetic characteristics were measured every three weeks under 100 pub $O_3$ fumigation. There was no visible foliar injury by $O_3$ exposure and contents of photosynthetic pigments did not show significant differences between control and $O_3$-treated seedlings. Also there were no significant differences in stomatal conductance, and water use efficiency. But photosynthetic rate and apparent quantum yield (AQY) of $O_3$ treated seedlings were reduced after nine weeks of ozone fumigation. In addition, the reduction of carboxylation efficiency and photorespiration were observed in the leave of $O_3$ treated seedlings after six weeks. In accordance with our result, carbon fixation system of A. altissima was most sensitive to $O_3$ stress to evaluate physiological damage induced by $O_3$.

Analysis of efficient ozonizer character using high-frequency Inverter (고주파 인버터를 이용한 고농도 오존발생기 특성 해석)

  • Kim, Y.H.;Hwang, Y.M.;Noh, I.B.;Kim, Y.B.;Woo, S.H.;Woo, J.I.
    • Proceedings of the KIEE Conference
    • /
    • 2002.07b
    • /
    • pp.1006-1008
    • /
    • 2002
  • Recently deep interests and attractions have been paid on the generation of ozone with environment polisy. Especially, which is widely used to remove bad smell and to clear water. This paper presents control and performance of a voltage source IGBT inverter developed for silent corona discharge type ozonizer. And proposed addition circuit for maintain discharge the center of in the airgap. In this paper, schemed equivalent electric circuit of the discharge electrode for simulation. Finally, the effectiveness of this discharge tube character of ozonizer is investigated in the simulation and experimental results.

  • PDF

An Integrated Emission Model of Greenhouse Gases to Assess Regional Climate Change

  • Moon, Yun-Seob;Oh, Sung-Nam;Hyun, Myung-Suk
    • Proceedings of the Korea Air Pollution Research Association Conference
    • /
    • 2003.05b
    • /
    • pp.421-422
    • /
    • 2003
  • Greenhouse gases (GHGs) such as carbon dioxide ($CO_2$), methane (CH$_4$), nitrous oxide ($N_2$O), chlorofluorocarbons (CFCs), sulphur hexafluoride (SF$_{6}$), together with water vapour ($H_2O$) and ozone play an important role in determining the earth's climate. The primary cause of the enhancement of GHGs is the global use of fossil fuels to generate heat, power, and electricity for a growing world population, as well as the changes in the land use, especially for agriculture. In addition, biomass buring and biofuel emissions play major roles in the GHG emissions in the Asian region because they produce large amounts of carbon monoxide (CO), nonmethane volatile organic compounds(NMVOC), black carbon(BC) and other gases. (omitted)d)

  • PDF

Dyeing of Natural Fibers with Extract of Ginkgo biloba Bark(I) - Pigments Analysis and Dyeability - (은행나무 수피 추출액에 의한 천연섬유의 염색( I ) -색소분석 및 염착성-)

  • 최순화;조용석
    • Textile Coloration and Finishing
    • /
    • v.13 no.5
    • /
    • pp.306-311
    • /
    • 2001
  • Natural colorants haute attracted much attention all over the world because of their non-hazardous nature. The world is becoming increasingly aware of environmental Issues, such as ozone layer depletion, water pollution and waste disposal problems. The use of synthetic dyestuffs for their synthesis and application in the dyeing industries has been criticized due to introduction of contaminants into the environment. This has led to the desire to turn to the traditional, and more natural way of life. In this study, the colorants of extract of Ginkgo biloba bark were analysed and their dyeing properties on silk, wool and cotton were studied. It was found that uv-visible absorption spectra of extract of Ginkgo biloba bark showed two strong absorption Peaks in the range of 240 ∼400 In. From the result of IR spectra, the major ingredient of extract of Gikgo biloba bark seems to be the flavon which is one of the flavonoid derivatives. Silk, wool, and cotton dyed with the extract of Ginkgo biloba bark showed a reddish yellow color. Their color differences were increased drastically with repetition of dyeing by three times.

  • PDF

The effect of surface treatment on interface formation between pentacene and polymer dielectrics

  • Han, Seung-Jin;Kim, Jae-Hoon;Park, Yong-Sup;Back, Kyu-Ha;Kim, Gi-Heon;Hong, Sa-Hwan;Kim, Dal-Hyun;Kim, Jeong-Won
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2007.08b
    • /
    • pp.1415-1418
    • /
    • 2007
  • Electronic and structural properties of the interfaces formed by pentacene deposited on a polymer-based dielectrics are investigated by electron spectroscopy, atomic force microscopy, and water contact angle measurement. There is strong influence of surface treatment of the polymer dielectrics on the energy level alignment and the surface topography upon the pentacene deposition.

  • PDF