• 한국환경과학회지
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• 제13권1호
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• pp.55-59
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• 2004

The effect of ozone on the formation and the removal of disinfection byproducts(DBPs) of chlorination process was studied to elucidate the performance of water treatment process. The samples of raw water, prechlorination process, and preozonation process were analyzed quantitatively according to the Standard Methods for the Examination of drinking water. As a result, most of total trihalomethanes(THMs) which were formed in prechlorine treatment process was not removed in the preozonation process. Most of haloacetic acids(HAAs), haloacetonitriles(HANs), and chloral hydrate(CH) was removed in sedimentation and biological activated carbon(BAC) filtration processes. However, DBPs were increased more or less by postchlorine step. In particular, the formation of THMs and HAAs depends on ozone more than chlorine, but, the formation of HANs and CH depends on chlorine more than ozone. The seasonal variation of DBPs concentration for the year needs to be investigated to study the temperature effect because DBPs strongly depend on temperature among various efficient factors.

• 한국식품영양학회지
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• 제36권4호
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• pp.236-243
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• 2023

The purpose of this study was to investigate the effects of sterilization, storage period and washing yuzu, according to the washing method, during the storage period. The results showed that the fungus size increased as the storage period increased, and no mold occurred in the yuzu washed with ozone water until 20 days. After 30 days of storage, a mold of 124.1±13.9 mm² was observed. The no-treatment sample had a fungus of 814.5±72.8 mm² in size on day 0 and the fungus the largest fungus was 6,362±636.7 mm² on day 30. In the case of water treatment, the fungus was 286.4±31.5~4,836.4±484.6 mm² in size. The results of the study confirmed that washing yuzu with ozone water has a sterilizing effect.

• 한국막학회:학술대회논문집
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• 한국막학회 2001년도 국제 Workshop:상수원의 현황과 분리막 상수처리(Water Resource and Menbrane Water Treatment)
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• pp.73-94
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• 2001

• 대한환경공학회지
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• 제28권12호
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• pp.1274-1279
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• 2006

본 연구에서는 낙동강 하류 매리원수, 부산시 회동수원지 원수 및 매리원수를 정수처리하는 pilot-plant의 급속 모래여과 처리수를 이용하여 오존 투입농도별로 $BDOC_{rapid}$4와 $BDOC_{slow}$의 생성특성에 대하여 조사하였다. $BDOC_{total}$ 농도가 최대가 되는 오존 투입 농도는 매리원수, 회동원수 및 모래여과 처리수에서 각각 0.9, 1.1 및 1.4 $mgO_3/mgDOC$로 조사되어 실험에 사용된 시료수의 특성에 따라 $BDOC_{total}$이 최대로 생성되는 오존 투입농도는 다르게 나타났다. $BDOC_{rapid}$를 최대로 생성시키는 오존 투입농도는 $BDOC_{total}$을 최대로 생성시키는 오존 투입농도 보다 낮은 $0.9{\sim}1.1\;mgO_3$/mgDOC로 나타났으며, 1 $mgO_3$/mgDOC 이상의 오존 투입농도에서는 $BDOC_{rapid}$의 농도가 오하려 낮아지는 것으로 나타났다. 또한. 오존 처리에 따른 $BDOC_{slow}$의 생성특성 조사에서 $BDOC_{slow}$는 $BDOC_{total}$과 $BDOC_{rapid}$를 최대로 생성시키는 오존 투입농도 보다 더 높은 오존 투입농도에서도 지속적으로 생성되었다. Biofiltration 공정의 전처리로 사용되는 오존의 최적 투입량을 결정할 수 있는 $BDOC_{rapid}/BDOC_{total}$비를 실험에 사용된 시료수별로 조사한 결과 $0.6{\sim}1.0\;mgO_3$/mgDOC로 조사되어 $BDOC_{total}$이 최대로 생성되는 오존 투입농도 $0.9{\sim}1.4\;mgO_3$/mgDOC보다 낮은 것으로 나타났다. 따라서 최적의 오존 투입율 결정시 BDOC 분류를 통한 접근법이 경제성 측면이나 biofiltration 공정의 효율면에서도 훨씬 효율적인 것으로 조사되었다.

• 조명전기설비학회논문지
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• 제18권2호
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• pp.44-48
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• 2004

수표면을 전극으로 사용한 무성방전형 오존발생기를 제안하고 수중의 전도도 변화가 수표면 방전에 미치는 영향을 실험적으로 조사하였다. 수표면 방전에 중요한 영향을 줄 수 있는 요소로 방전공간내의 이온과 수중의 이온 및 극성분자등이 있다. 본 연구에서는 전도도를 변화시켜 수중에 존재하는 이온의 수를 조절함으로써 방전특성을 변화시키고자 하였다. 이를 위해 증류수내에 각각 다른양의 NaCl을 투입함으로써 전도도를 변화시켰고 이때의 전류-전압특성과 오존발생특성을 비교 조사하였다. 결과적으로 순수한 증류수를 사용한 경우보다 NaCl을 투입한 경우 안정된 방전을 발생시킬 수 있었고 투입하는 NaCl의 양을 늘여감에 따라 방전개시전압을 낮출 수 있었다.

• 한국항해항만학회지
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• 제34권3호
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• pp.205-211
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• 2010

밸러스트수 처리를 위한 Plasma Gun의 전기적 특성과 오존 생성에 미치는 주요 운전변수들의 영향에 관해 실험실 규모 연구를 수행하였다. 방전개시전압보다 높은 전압이 인가되면 방전이 시작되고 오존이 생성되었으며 전압이 증가함에 따라 기체로 전달되는 에너지 및 오존 농도가 거의 선형적으로 증가하였다. 오존 생성 측면에서 최적의 에너지 효율성을 얻을 수 있는 전극간 거리가 존재하였으며 실험된 장치에서는 1.95 mm의 전극간 거리에서 최적 효율이 얻어졌다. 전기에너지 특성에 미치는 내부전극 재질의 영향은 무시할만한 수준이었으나 내부전극의 전기전도도와 열전도도 차이가 오존 생성에 큰 영향을 미치는 것으로 나타났다. 일정한 Plasma Gun 구조에서 오존 생성은 기체로 전달되는 에너지밀도에 의해 중요한 영향을 받는 것으로 나타났으며 유입되는 기체의 산소함량이 증가할수록 오존 생성이 증가하는 것으로 나타났다.

• 한국지하수토양환경학회지:지하수토양환경
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• 제17권4호
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• pp.44-50
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• 2012

A new type of chemical oxidation technology utilizing micro bubble ozone oxidizer and a pneumatic fracturing equipment was developed to enhance field applicability of a traditional chemical oxidation technology using hydrogen peroxide as an oxidizer for in-situ soil remediation. To find an efficient way to dissolve gaseous ozone into hydrogen peroxide, ozone was injected into water as micro bubble form then dissolved ozone concentration and its duration time were measured compared to those of simple aeration of gaseous ozone. As a result, dissolved ozone concentration in water increased by 31% (1.6 ppm ${\rightarrow}$ 2.1 ppm) and elapsed time for which maximum ozone concentration decreased by half lengthened from 9 min to 33 min. When the developed pneumatic fracturing technology was applied in sandy loam, cracks were developed and grown in soil for 5~30 seconds so that the radius of influence got longer by 71% from 392 cm to 671 cm. The remediation system using the micro bubble ozone oxidizer and the pneumatic fracturing equipment for field application was made and demonstrated its remediation efficiency at petroleum contaminated site. The system showed enhanced remediation capacity than the traditional chemical oxidation technology using hydrogen peroxide with reduced remediation time by about 33%.

• 환경위생공학
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• 제15권1호
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• pp.14-24
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• 2000

The water treatment by ozone was performed to remove VOC and organic substances in the multistage ozone contactor. This paper is secondary paper about the theme of ozone treatment since the first paper (Kor. Sanitary J., 15, 1(2000)) publicized, it was compared experimental results with theoretical those which were derived from the mathematical model associated with chemical reactions and mass transfer. Basic designing factors were determined as an optimal conditions for the removal rate of VOCs as follows: ozone input concentration in the contactor was 2mg/L, ozone contact time was 7 min and number of contactor was three-layered.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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• pp.908-911
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• 2002

Recently deep interests and attraction have been paid on the generation of ozone, which is widely used to remove bed smell and to clear water. In this paper the silent discharge and ozone generation characteristics of various typed discharge chambers were investigated experimentally. Dielectric of $Al_2O_3$ was embedded in the cylindrical type of discharge chamber to improve the ozone generation rate and to stabilize the silent discharge mode of operation. Discharge current and ozone concentration depend strongly on the applied voltage and frequency.

• 한국의류산업학회지
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• 제6권4호
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• pp.511-514
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• 2004

We studied on the bleaching properties of silk fabric by vapor type ozone processing using ozone's strong oxidation instead of 28% $H_2O_2$ chemical treatment. When vapor type ozone processing was directly treated to fabrics retaining water to 50~70% pick up ratio, high concentration ozone was generated 14,000ppm(168 mg/h) approximately and finally its bleaching improved. The fabric's bleaching effect was improved because vapor type ozone generated the highest decomposition to oxidation of surface and inter molecules. The experiment revealed that fabric's bleaching was improved by change of the pick-up ratio of vapor type ozone processing. However, tensile strength and elongation were reduced by increase of time, and the time that was assumed as the most optimized time to minimize the reduction of fabric's tensile strength and elongation as well as maximizing the fabric's bleaching was 30 minutes.