• Title/Summary/Keyword: ozone monitoring

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ON-line System을 이용한 오존 Precursor의 거동에 대한 연구 (Studies on the Variation of the Ozone Precursors using On-Line Air Monitoring System)

  • 조석주;윤중섭;여인학;이민환;김민영;김신도
    • 한국대기환경학회:학술대회논문집
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    • 한국대기환경학회 2002년도 춘계학술대회 논문집
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    • pp.251-252
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    • 2002
  • 최근 서울시보건환경연구원에서는 국내 최초로 미국의 PAMS(Photochemical Assessment Monitoring Systems) 측정망을 응용한 VOCs 측정망을 구축하여 대기 중 탄화수소를 포함하는 휘발성유기화합물를 측정 운영 중에 있다. VOCs는 그 종류와 발생원이 복잡 다양할 뿐만 아니라 시료의 채집과 분석방법에 여러 가지 기술적인 어려움이 내재한다. (중략)

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휘발성유기화합물과 질소산화물의 오존생성 기여도 평가에 관한 연구 (Estimation on the Contribution of VOCs and Nitric Oxides in Creating Photochemical Ozone)

  • 정장표;유숙진
    • 대한환경공학회지
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    • 제32권2호
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    • pp.209-218
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    • 2010
  • 감전동 측정소에서 측정한 일반대기의 휘발성유기화합물 중 방향족화합물이 전체의 51.3%로 가장 높은 농도를 나타내었고 다음이 paraffin류(44.2%), olefin류(2.7%), alkyne류(1.8%)의 순이었으며 대연동 측정소는 paraffin류가 전체의 56.7%를 나타내어 가장 높았으며 다음이 aromatic류(35.9%), olefin류(6.1%), alkyne류(1.3%)순으로 조사되었다. POCP를 고려한 오존생성 기여도는 toluene이 30.6%로 가장 높았으며 그 다음으로 propane, m/p-xylene, ethylbenzene, 1,2,4-trimethylbenzene이 각각 10.2%, 9.4%, 7.4%, 5.2%로 높았다 상위 5가지 물질의 기여도가 전체의 62.8%로 다른 물질들의 기여도 보다 비교적 높은 것으로 나타났다. 한편 상위 32종의 VOCs가 전체 VOCs중 97.6%로 조사되어 나머지 14개 VOCs물질의 오존생성 기여율은 미미한 것으로 조사되었다. 고농도 오존이 발생한 시점과 $NO_2$/NO의 비의 시간 변화율이 바뀌는 시점은 대체적으로 아주 유사한 현상을 보였다. 이것은 고농도 오존과 광화학적 현상이 밀접한 관계를 보인다는 것을 간접적으로 시사한다. NO의 $NO_2$로의 전환이 오존의 고농도 현상에 중요한 역할을 하고 있다는 것을 알 수 있다.

TOVS로 부터 도출한 한반도 부근의 전오존량 분포 및 그 특성 비교 (The Distribution of Total Ozone Amounts and Intercomparison of their characteristics Derived from the TOVS Observations over the Korean Peninsula)

  • 정효상;주상원
    • 대한원격탐사학회지
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    • 제11권3호
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    • pp.23-31
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    • 1995
  • 기상청에서는 1990년부터 Smith등(1984,1986)이 개발한 ITPP-VI(International TOVS Program Package)를 사용하여 직접 물리 해법을 이용한 연직온도분포 및 총오존량을 산출하여 예보현업에 이용하고 있다. 그러나 현재의 초기입력자료로 사용되는 기후값은 너무 오래되었고, 국지효과나 한반도 부근의 특성이 제외되었으므로 도출된 전오존량의 분포를 직접 사용하기에는 그 정확성이나 신빙성이 희박하다. 따라서 ITPP-VI로부터 오존량 산출자료의 질적 개선을 위해 초기 입력자료중 지표값을 기후자료 대신에 GPV(Gridded Point Values) 자료를 입력하여 오존량 도출을 수행하였다. GPV자료의 입력을 통한 TOVS 오존량 자료(TOVS-GPV)가 정량적으로 어느 정도 개선되었는 지 알아보기 위하여 두경우의 총오존분포도를 비교하였다. GPV 지표자료의 입력으로 도출한 총 오존량은 기후값으로 도출한 총오존량(TOVS-CLIMA)에 비해 한반도 부근에서의 오존량 변화를 더 자세하게 표현하였다. 정량적으로 질적 개선을 알아보기 위해 1994년 2월 한달동안 지상 관측 자료로써 연세대학교의 오존분광기(Dobsometer)로 관측한 오존량(Uy), TOVS-GPV(Ug), TOVS- CLIMAT(Uc), 그리고 TOMS(Total Ozone Monitoring System) 관측값(Um)을 이용하여 나타낸 결과, 월변화의 경향은 연세대학교 총오존량값의 변화에 대해 TOVS-GPV(Ug), TOVS-CLIMAT (Uc)와 TOMS(Um) 값들의 변화는 크지만, 새로운 TOVS-GPV 오존량은 TOVS-CLIMAT 오존 량에 비해 TOMS 오존량과 연세대학교 관측치와 유사한 경향을 보였다.

Monitoring of Climate Change of Northeast Asia and Background Atmosphere in Korea

  • Oh, Sung-Nam;Chung, Hyo-Sang;Choi, Jae-Cheon;Bang, So-Young;Hyun, Myung-Suk
    • 한국환경과학회:학술대회논문집
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    • 한국환경과학회 2003년도 International Symposium on Clean Environment
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    • pp.232-235
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    • 2003
  • In general, the parameters of climate change include aerosol chemical compounds, aerosol optical depth, greenhouse gases(carbon dioxide, CFCs, methane, nitrous oxide, tropospheric ozone), ozone distribution, precipitation acidity and chemical compounds, persistent organic pollutants and heavy metals, radioactivity, solar radiation including ultra-violet and standard meteorological parameters. Over the last ten years, the monitoring activities of Korea regarding to the climate change have been progressed within the WMO GAW and ACE-Asia IOP programs centered at the observation sites of Anmyeon and Jeju Gosan islands respectively. The Greenhouse gases were pointed out that standard air quality monitoring techniques are required to enhance data comparability and that data presentation formats need to be harmonized and easily understood. Especially, the impact of atmospheric aerosols on climate depends on their optical properties, which, in turn, are a function of aerosol size distribution and the spectral reflective indices. Aerosol optical depth and single scattering albedo in the visible are used as the two basic parameters in the atmospheric temperature variation studies. The former parameter is an indicator of the attenuation power of aerosols, while the latter represents the relative strength of scattering and absorption by aerosols. For aerosols with weak absorption, surface temperature decreases as the optical depth increases because of the domination of backscattering. For aerosols with strong absorption, however, warming could occur as the optical depth increases. The objective of the study is to characterize the means, variability, and trends of Greenhouse gases and aerosol properties on a regional basis using data from its baseline observatories in Korea peninsula. A further goal is to understand the factors that control radiative forcing of the greenhouse and aerosol.

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통계분석을 이용한 광주지역 대기오염도 (An Assessment of Air Quality Using Statistical Analysis in Gwangju Area)

  • 서광엽;백계진;신대윤
    • 한국환경보건학회지
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    • 제30권5호
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    • pp.417-426
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    • 2004
  • We investigate changing characteristics and concentration distribution of ambient air quality using data from which obtained local ambient air monitoring network and local meterological measuring sites in Gwangju area from January to December in 2003. Sulfur dioxide ($SO_2$) showed that increase from 8 AM and decrease in 6 PM but, it was not drastically changed concentration. it also 0.010 ppm in 1995 from at this time it's decrease step by step and than some constant in year 2001 to 2003. Nitrogen dioxide ($NO_2$) concentration was showed highest peak in 10 AM and increase again at 6 PM. And also it showed peak concentration (0.026 ppm) in 2001 and decreased from after that times. Ozone was showed peak concentration in 1 PM and Nitrogen dioxide was ditto in 10 AM from this data, we can conclude that this two article ws showed chemical reaction by 3 to 5 hours. There was no case of Ozone alarm in Gwangju area since 1995, but it showed highest ozone concentration (over 0.070 ppm) in May and June of the year and 2 to 4 PM of the day and sometimes it showed increase at the dawn. Ozone product optimum condition was that air temperature is over $25^{\circ}C$, no rain and increase solar radiation (over $20MJ/m^2$) and no wind or below 2.0 m/s wind speed.

우리나라의 오존도 변화 추이와 주요 인자 (Trends and Factors of Ozone Concentration Variations in Korea)

  • 김영성
    • 한국대기환경학회지
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    • 제16권6호
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    • pp.607-623
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    • 2000
  • Major trends of ozone concentration variations in Korea were investigated by using observation data from around 100 stations for the period of 1991∼1997. In addition, important regulating those variations were inferred. Three measures such as the number of days exceeding 80ppb, the 95th percentile of daily maxima, and the annual average concentration were used for the analysis of multi-scale ozone concentration variations. Three areas in the southwest (Sosan, Mokpo, and Cheju) of which monitoring has been operated since 1995 showed the highest annual average concentrations over; this was noted because of the high annual average in the Yosu area in the early 1990s. Large increases in annual average concentrations were observed along the relatively cleaner areas connecting Kangnung and Kwangju(northeast to southwest), in contrast to polluted areas connecting Seoul and Pusan(northeast to southeast). Both the number of exceedance days and the daily maximum concentration were nearly constant in the Greater Seoul Area in spite of interannual flucturations associated with year-to-year changes in air temperature. Within the Greater Seoul Area, all three measures usually showed the same trend; they decreased in the middle and west and increased in the east and northeast. All three measures including the number of exceedance days increased largely at Sillim where the average concentration was high but no exceedance days were recorded in the early 1999s, Nationwide ozone concentration variations appear to be determined by the competitive influence of long-range transport and local urban emissions, Within the city including the Greater Seoul Area, changes in emission which accompany changes in population and in the number if vehicles ( in the process of urban development) were found to be important components of ozone concentration variations.

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반순환여과양식시스템에서 오존 유래 잔류산화물이 넙치(Paralichthys olivaceus) 사육수의 수질과 미생물에 미치는 영향 (Ozone-produced Oxidants Improve Water Quality Parameters and Microbial Colony Counts in the Semi-Recirculating Aquaculture System for Olive Flounder Paralichthys olivaceus)

  • 정상명;박우근;박성덕;박정환;김재원;김병기
    • 한국수산과학회지
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    • 제54권5호
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    • pp.751-760
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    • 2021
  • This study investigated the changes in water quality parameters and microbial colonies when ozone was applied to a semi-recirculating aquaculture system (semi-RAS) for the olive flounder Paralichthys olivaceus (500 g in average weight). Concentrations of ozone-produced oxidants (OPO) in rearing tanks were maintained at 0, 0.014, 0.025 mg/L as Cl2 for 26 days. Except total ammonia nitrogen, nitrite nitrogen, nitrate nitrogen, phosphate phosphorus, chemical oxygen demand, and total suspended solids decreased significantly with increasing OPO concentration in daily and weekly monitoring (P<0.05). Colony forming unit (CFU) counts of heterotrophic marine bacteria decreased in an OPO concentration-dependent manner. Overall reduction rates of microbial colonies in the treatments were 80% higher than those of the control (P<0.05). During the experiment, the OPO concentration-driven ozonation was reliably practiced without any adverse effects on the animals cultured in semi-RAS. Considering the biohazard, operating cost, and stability of ozonation, an OPO concentration of 0.014 mg/L would be sufficient to control water quality parameters and microbial colonies in a semi-RAS.

PBL Scheme에 대한 WRF-CMAQ 민감도 분석 (Sensibility Study for PBL Scheme of WRF-CMAQ)

  • 문난경;김순태;서지현
    • 한국대기환경학회지
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    • 제27권6호
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    • pp.791-804
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    • 2011
  • Numerical simulations were carried out to investigate the impact of PBL (Planetary boundary layer) scheme implemented in WRF on the result of meteorological fields and CMAQ modeling. 25-day period, representing high ozone concentration, was selected for the simulations. The three WRF domains covered East Asia region, Korean Peninsula and Seoul metropolitan area. The sensitivity of WRF-CMAQ modeling to the various PBL schemes was assessed and quantified by comparing model output and against observation from the meteorological and the air quality monitoring network within the domain. The meteorological variables evaluated included temperature, wind speed and direction over surface sites and upper air sounding sites. The CMAQ variables included gaseous species $O_3$ and $NO_x$ over monitoring stations. Although difference of PBL schemes implemented in WRF, they did not appreciably affect the WRF and CMAQ performance. There are partially differences between non-local and local mixing scheme, but are not distinct differences for the results of weather and air quality. It is suggested that impact of parameterization of vertical eddy diffusivity scheme in CMAQ also need to be researched in the future study.

대조코호트 연구를 위한 충주의 대기오염현황 조사와 산단지역과의 비교 (The Investigation and Comparison of Characteristics of Air Pollution for Cohort Study in Chungju with Industrial Cities)

  • 김재훈;위성승;남상훈;안정선;김대선
    • 한국환경보건학회지
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    • 제34권1호
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    • pp.1-11
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    • 2008
  • The purpose of this study was to investigate air quality in Chungju, Korea, using data obtained with a local air quality monitoring system. We have utilised cohort studies to investigate the relations between environmental pollution and the health of residents near large industrial complexes since 2004. This study analyzes the $O_3,\;NO_2,\;SO_2,\;CO\;and\;PM_{10}$ concentration in Chungju from 2002 to 2006. Air pollutants are closely related to the number of manufacturing facilities and cars, energy utilization and weather conditions. Generally, the diurnal concentration of air pollutants in Chungju reached the highest level in the morning (about$08:00{\sim}$) and early evening (about$19:00{\sim}$). On the other hand, the diurnal concentration of ozone as recorded gives the highest amount in late afternoon (about$16:00{\sim}$) and lowest in early morning (about$08:00{\sim}$). The concentration of air pollutants in Chungju was highest from winter to spring and lowest during the summer season. On the other hand, the monthly variation of ozone concentration was greatest in June and smallest in December. Also the, $PM_{10}$ concentration posted the highest record in April and the lowest during September. In general, this study analyzed air pollution changes in Chungju as well as in large scale industrial complex regions within Korea such as Ulsan, Pohang, Kwangyang, Sihwa Panwol and Gangneung in Korea. We compared the air quality of Chungju with those of these cites and found that air pollutants except for CO in Chungju was generally lower than large industrial complex regions.