• Title/Summary/Keyword: ozone monitoring

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Application of a Gas Chromatography/Luminol Detection System for Peroxyacetyl Nitrate Airborne Measurement

  • Khang, Bumju;Ahn, Joon Young;Song, Dasol;Lee, Gangwoong
    • Asian Journal of Atmospheric Environment
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    • v.7 no.2
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    • pp.105-113
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    • 2013
  • We constructed and tested an airborne peroxyacetyl nitrate (PAN) monitoring system based on luminol chemiluminescence detection with fast gas chromatography. This system allowed for simultaneous measurement of PAN and nitrogen dioxide ($NO_2$) with a time resolution of <2 min. Actual sample masses within the fixed volume sample loop at various altitudes and temperatures were adjusted to standard atmosphere, using measured pressures and temperatures. The airborne PAN measurement system was evaluated during two field studies above the southern Korean Peninsula in August and October 2009. The detection limit based on the ISO approach was 0.035 ppbv PAN, well below the observed concentrations of 0.185-1.49 ppbv during these studies. Under these conditions, the PAN mixing ratios were positively correlated with $O_x$ ($O_x=O_3+NO_2$), with slopes varying between 0.014 and 0.033 and intercepts between 22.6 and 55.1 ppbv $O_x$. The intercepts corresponded roughly to background $O_x$ mixing ratios in central Europe; however, the slopes were above the range of slopes reported in other studies. We also enhanced the durability, safety, and ease of maintenance of the PAN monitoring system by redesigning the structure of the conventional luminol cell.

An Assessment Study for the Urban Air Monitoring Network in Seoul (서울지역 도시대기측정망 평가 연구)

  • Ghim, Young Sung;Choi, Yongjoo;Park, Ji Soo;Kim, Chan Hyuk
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.5
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    • pp.504-509
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    • 2014
  • Twenty-five stations of the urban monitoring network in Seoul were assessed with a focus on surveillance function of the exceedances of 8-hour ozone and 24-hour $PM_{10}$ standards. The two standards were selected because their attainment rates were particularly low. Two hierarchical cluster analyses were performed to group stations with similar atmospheric environments-one using daily highest 8-hour [$O_3+NO_2$], 8-hour $O_3$ concentrations plus corresponding 8-hour $NO_2$ concentrations considering the interconversion of $O_3$ and $NO_2$, and the other using 24-hour $PM_{10}$ concentrations. An index to measure higher concentration and exceedances of the standards was introduced. Within a cluster, sufficiently high score was assigned to the trends station or the station with higher index. Scores for $O_3+NO_2$ and $PM_{10}$ of a given station were added and ranked in the descending order to determine the relative importance.

Correlation Analysis of Atmospheric Pollutants and Meteorological Factors Based on Environmental Big Data

  • Chao, Chen;Min, Byung-Won
    • International Journal of Contents
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    • v.18 no.1
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    • pp.17-26
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    • 2022
  • With the acceleration of urbanization and industrialization, air pollution has become increasingly serious, and the pollution control situation is not optimistic. Climate change has become a major global challenge faced by mankind. To actively respond to climate change, China has proposed carbon peak and carbon neutral goals. However, atmospheric pollutants and meteorological factors that affect air quality are complex and changeable, and the complex relationship and correlation between them must be further clarified. This paper uses China's 2013-2018 high-resolution air pollution reanalysis open data set, as well as statistical methods of the Pearson Correlation Coefficient (PCC) to calculate and visualize the design and analysis of environmental monitoring big data, which is intuitive and it quickly demonstrated the correlation between pollutants and meteorological factors in the temporal and spatial sequence, and provided convenience for environmental management departments to use air quality routine monitoring data to enable dynamic decision-making, and promote global climate governance. The experimental results show that, apart from ozone, which is negatively correlated, the other pollutants are positively correlated; meteorological factors have a greater impact on pollutants, temperature and pollutants are negatively correlated, air pressure is positively correlated, and the correlation between humidity is insignificant. The wind speed has a significant negative correlation with the six pollutants, which has a greater impact on the diffusion of pollutants.

Air Quality Management in the Industrial Estate, HAP or VOC\ulcorner (산업단지 대기질 관리, HAP인가 VOC인가\ulcorner)

  • 김영성
    • Journal of Korean Society for Atmospheric Environment
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    • v.15 no.4
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    • pp.513-517
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    • 1999
  • Problems of secondary pollution and hazardous pollutants have rapidly come to the front in our society during the past few years. More attention should be paid to monitoring and assessment in order to identify the nature of complicated problems, but our air-quality policy is hurriedly seeking for management strategies. A typical example is air quality management in the industrial estates such as those located in Yochon and Ulsan. Yochon Industrial Estate was designated as a special air-quality management area of volatile organic compounds(VOCs) in 1996. And VOCs in the air of Ulsan Industrial Estate has been specially controlled since 1997. In this paper, however, it is suggested that hazardous air pollutants(HAPs) rather than VOCs should have been managed in the industrial estates. History of studies on organic compounds in the air of the industrial estates is reviewed. A stepwise approach for air quality management in the industrial estates is recommended.

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ANALYSIS OF TROPOSPHERIC $NO_2$ BASED ON SATELLITE MEASUREMENTS

  • Kwon Eun-Han;Lim Hyo-Suk
    • Proceedings of the KSRS Conference
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    • 2005.10a
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    • pp.374-377
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    • 2005
  • The distribution and changes of tropospheric nitrogen dioxide ($NO_2$) are analyzed using the satellite measurements data from GOME (Global Ozone Monitoring Experiment) and SCIMACHY (SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY). We produced global maps of tropospheric $NO_2$ for 4 seasons using GOME measurements from January 1997 to June 2003. The global distribution shows high values in regions with dense population and high industrialization. Tropospheric $NO_2$ shows obvious seasonal changes depending on its emission and lifetime. Based on the good agreement between two instruments in the time period of overlapping measurements (January 2003-June2003), we linked SClAMACHY data to the GOME time series. The combined time series over the past decade indicate that $NO_2$ 1evels over China are rapidly increasing while those over Europe are decreasing. We also discussed potential application of spaceborne instruments in detecting and characterizing long-distance transport of $NO_2$.

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Focal Plane Damage Analysis by the Space Radiation Environment in Aura Satellite Orbit

  • Ko, Dai-Ho;Yeon, Jeoung-Heum;Kim, Seong-Hui;Yong, Sang-Soon;Lee, Seung-Hoon;Sim, Enu-Sup;Lee, Cheol-Woo;De Vries, Johan
    • Bulletin of the Korean Space Science Society
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    • 2011.04a
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    • pp.28.1-28.1
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    • 2011
  • Radiation-induced displacement damage which has caused the increase of the dark current in the focal plane adopted in the Ozone Monitoring Instrument (OMI) was studied in regards of the primary protons and the secondaries generated by the protons in the orbit. By using the Monte Carlo N-Particle Transport Code System (MCNPX) version 2.4.0 along with the Stopping and Range of Ions in Matter version 2010 (SRIM2010), effects of the primary protons as well as secondary particles including neutron, electron, and photon were investigated. After their doses and fluxes that reached onto the charge-coupled device (CCD) were examined, displacement damage induced by major sources was presented.

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Analysis of PM10 Concentration using Auto-Regressive Error Model at Pyeongtaek City in Korea (자기회귀오차모형을 이용한 평택시 PM10 농도 분석)

  • Lee, Hoon-Ja
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.3
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    • pp.358-366
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    • 2011
  • The purpose of this study was to analyze the monthly and seasonal PM10 data using the Autoregressive Error (ARE) model at the southern part of the Gyeonggi-Do, Pyeongtaek monitoring site in Korea. In the ARE model, six meteorological variables and four pollution variables are used as the explanatory variables. The six meteorological variables are daily maximum temperature, wind speed, amount of cloud, relative humidity, rainfall, and global radiation. The four air pollution variables are sulfur dioxide ($SO_2$), nitrogen dioxide ($NO_2$), carbon monoxide (CO), and ozone ($O_3$). The result shows that monthly ARE models explained about 17~49% of the PM10 concentration. However, the ARE model could be improved if we add the more explanatory variables in the model.

Comparison of Analytical Methods for Ozone Precursors Using GC-MS and GC-FID (오존전구물질 VOC 분석의 분석방법(GC-MS, GC-FID) 간 비교연구)

  • 황승만;허귀석;이재환
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2001.11a
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    • pp.249-250
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    • 2001
  • 최근 대도시 지역에서의 오존농도가 환경기준을 초과하는 빈도가 날로 증가하고 있는 실정이며, 이에 국내의 경우 오존농도 증가에 대비하여 대기 중 오존농도가 일정기준(시간당 0.12 ppm)보다 높게 나타났을 때 신속하게 경보를 발령, 시민들의 건강과 생활환경상의 피해를 최소화하기 위해 오존경보제를 시행해오고 있다. 한편 전세계적으로 대도시 지역에서의 지표면 오존농도가 환경기준을 초과함에 따라 오존생성과 관련된 전구물질(precursor)에 대한 제어과정이 지표면 오존농도의 저감을 실현하기 위한 가장 시급한 과제로 대두되고 있으며, 특히 미국의 경우 1993년부터 광화학평가측정망(Photochemical Assessment Monitoring Stations;PAMS)을 설치하여 이들 물질에 대한 보다 집중적인 모니터링을 실시하고 있는 것으로 알려져 있다. (중략)

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Studies on the Quality Control of the Ozone Precursors Monitoring System (On-line 오존 Precursor Analyzer의 정도관리 연구)

  • 조석주;이민환;김민영;김명희;김신도
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.11a
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    • pp.241-242
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    • 2002
  • 오늘날 전 세계적으로 대도시 지역에서 지표면 오존농도가 환경기준을 초과하는 빈도가 증가함에 따라 오존의 생성과 관련 있는 전구물질(precursor)인 질소산화물과 휘발성유기화합물에 대한 제어과정이 지표면 오존농도의 저감을 실현하기 위하여 가장 중요한 과제로 대두하고 있다1). 이러한 오존농도의 증가 원인 파악을 위하여 환경부는 서울을 중심으로 한 수도권지역 뿐만 아니라 전국의 대도시의 주변지역에 대한 광화학 측정망을 확충하고 고농도 오존 발생기간에 대하여 집중측정 등을 수행하며, 대책수립에 필요한 기초자료를 마련할 수 있도록 하는 방안을 모색하고 있다. (중략)

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Implementation of Differential Absorption LIDAR (DIAL) for Molecular Iodine Measurements Using Injection-Seeded Laser

  • Choi, Sungchul;Baik, Sunghoon;Park, Seungkyu;Park, Nakgyu;Kim, Dukhyeon
    • Journal of the Optical Society of Korea
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    • v.16 no.4
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    • pp.325-330
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    • 2012
  • Differential absorption LIDAR (DIAL) is frequently used for atmospheric gas monitoring to detect impurities such as nitrogen dioxide, sulfur dioxide, iodine, and ozone. However, large differences in the on- and off-line laser wavelengths can cause serious errors owing to differential aerosol scattering. To resolve this problem, we have developed a new DIAL system for iodine vapor measurements in particular. The suggested DIAL system uses only one laser under seeded and unseeded conditions. To check the detection-sensitivity and error effects, we compared the results from a system using two seeded lasers with those from a system using a seeded and an unseeded laser. We demonstrate that the iodine concentration sensitivity of our system is improved in comparison to the conventional two seeded or two unseeded laser combinations.