• Title/Summary/Keyword: ozone depletion

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The Changes of UV-B Radiation at the Surface due to Stratospheric Aerosols (성층권 에어로졸에 의한 지표면 UV-B 복사량 변동)

  • Jai-Ho Oh;Joon-Hee Jung;Jeong-Woo Kim
    • International Union of Geodesy and Geophysics Korean Journal of Geophysical Research
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    • v.21 no.1
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    • pp.31-46
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    • 1993
  • A radiative transfer model with two-stream/delta-Eddington approximation has been developed to calculate the vertical distributions of atmospheric heating rates and radiative fluxes. The performance of the model has been evaluated by comparison with the results of ICRCCM (Intercomparison of radiative codes in climate models). It has been demonstrated that the presented model has a capability to calculate the solar radiation not only accurately but also economically. The characteristics of ultraviolet-B radiation (UV-B; 280-320nm) are examined by comparison of relation between the flux at the top of atmosphere and that at the surface. The relation of UV-B is quadratic due to the strong ozone absorption in this band. Also, the dependence of the UV-B radiation on the stratospheric ozone depletion and stratospheric aerosol haze due to volcanic eruption on the stratospheric ozone depletion and stratospheric aerosol haze due to volcanic eruption has been tested with various solar zenith angles. The surface UV-B increases as the solar zenith angle increases. The existence of stratospheric aerosols causes an increase in the planetary albedo due to the aerosols' backscattering. The planetary albedo with aerosol's effect has been increases as the solar zenith angle is not sensitive. It may be caused by the fact that the aerosols' scattering effect becomes saturated with the relatively long path length in a large solar zenith angle. Finally, the regional impact of stratospheric aerosols due to volcanic eruption on the intensity of UV-B radiation at the surface has been estimated. A direct effect is that the flux is diminished at the low latitudes, while it is enhanced in the high latitudes by the aerosols' photon trap or twilight effect. In the high latitudes, both aerosols' scattering and ozone absorption have strong and opposite impacts to the surface UV-B radiation is located at the mid-latitudes during spring season in both hemispheres.

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Life Cycle Assessment of Greenhouse Gas Emissions from Livestock and Food Wastes Co-digestive Biogas Production System (전과정평가 방법을 이용한 가축분뇨/음식폐기물 통합 소화형 바이오가스 시설의 온실가스 배출량 평가)

  • Nam, Jae-Jak;Yoon, Young-Man;Lee, Young-Haeng;So, Kyu-Ho;Kim, Chang-Hyun
    • Korean Journal of Environmental Agriculture
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    • v.27 no.4
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    • pp.406-412
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    • 2008
  • Biogas plant with anaerobic digestion is receiving high attention as a facility for both livestock waste treatment and electric power generation. Objective of this study was to perform life cycle assessment (LCA) of a biogas plant which incorporates swine and food waste (7:3) as source materials for biogas production. In addition, the biogas production process was compared with the prevalent composting method as a reference in the aspects of green house gas (GHG) reduction potential and environmental impact. The biogas method was capable of reducing 52 kg $CO_2$ eq. emission per ton of swine/food waste, but the composting process was estimated to emit 268 kg $CO_2$ eq. into air. The biogas method was evaluated as more beneficial to the environment by mitigating the impact on abiotic depletion potential (ADP), global warming potential (GWP), ozone depletion potential (ODP), eutrophication potential (EP), and photochemical ozone creation potential (POCP), but not to acidification potential (AP).

Life Cycle Assessment on the Reuse of Glass Bottles (유리병 재사용에 대한 전과정평가)

  • Kim, Hyung-Jin;Kwon, Young-Shik;Choi, Yoon-Geun;Chung, Chan-Kyo;Baek, Seung-Hyuk;Kim, Young-Woo
    • Clean Technology
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    • v.15 no.3
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    • pp.224-230
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    • 2009
  • Life Cycle Assessment (LCA) has been studied on the reuse of glass bottles. The system boundary in this study encompassed from gate to gate such as production and transportation. A 360 mL volume of a glass bottle was selected as the functional unit. The environmental impact assessments was studied on 6 categories including abiotic resource depletion, acidification, eutrophication, global warming, ozone depletion, and photochemical oxidant creation. The results showed that the most significant impact categories were abiotic resource depletion (48.63%) and global warming (46.27%), and the rest categories revealed insignificant impacts. In the whole system, the chemicals used for the new bottle production revealed the major contribution to the environmental impacts (71.24%), followed by the use of electricity (16.74%) and transportation (11.8%). In addition, the environmental impact of sodium silicate to be put into the stage of the new bottle production was found to be 45.68%, causing severe influence on abiotic resource depletion and global warming.

A Study on Development of Alternative Non-aqueous Cleaning Agents to Ozone Depletion Substances and its Field Application (오존파괴물질 대체 비수계세정제 개발 및 현장 적용 연구)

  • Park, Yong-Bae;Bae, Jae-Heum;Lee, Min-Jae;Lee, Jong-Gi;Lee, Ho-Yeoul;Bae, Soo-Jung;Lee, Dong-Kee
    • Clean Technology
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    • v.17 no.4
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    • pp.306-313
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    • 2011
  • Flux or solder is used in soldering process for manufacturing electronic parts such as printed circuit boards (PCB). After soldering process, residual flux and solder paste on the parts should be removed since their residuals could cause performance degradation or failure of parts due to their corrosion and electric leakage. Ozone depletion substances such as 1,1,1- trichloroethane (TCE) and HCFC-141b have widely been using for removal of residual flux and solder paste after soldering process In manufacturing of electronic parts until now. In this study, non-aqueous cleaning agents without flash point were developed and applied to industrial field for replacement of cleaning agents with ozone depletion. In order to develop non-aqueous cleaning agents without ethers, esters, fluoride- type solvents. And their physical properties and cleaning abilities were evaluated, and they were applied to industrial fields for cleaning of flux and solder on the PCB. And vacuum distillation apparatus were operated to determine their operating conditions and recycling yields for recycling of used cleaning agents formulated in this study. As a result of physical properties measurement of our formulated cleaning agents, they were expected to have good wetting and penetrating power since their surface tensions were relatively low as 18.0~20.4 dyne/$cm^2$ and their wetting indices are relatively large. And some cleaning agents holding fluoride-type solvents as their components did not have any flash point and they seemed to be safe in their handling and storage. The cleaning experimental results showed that some cleaning agents were better in their cleaning of flux and solder paste than 1,1,1-TCE and HCFC-141b. And industrial application results of the formulated cleaning agents for cleaning PCB indicated that they can be applicable to industry due to their good cleaning capability in comparison with HCFC-141b. The recycling experiments of the used formulated cleaning agents through a vacuum distillation apparatus also showed that their 91.9~97.5% could be recycled with its proper operating conditions.

Condensation Heat Transfer Characteristics of HCFC - 123 inside Horizontal Smooth Tube (HCFC-123의 수평 평활관내 응축 전열 특성에 관한 연구)

  • 권옥배;오후규;오종택;김성규
    • Journal of Advanced Marine Engineering and Technology
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    • v.17 no.3
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    • pp.24-32
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    • 1993
  • Experimental data on the heat transfer characteristics of HCFC-123 and CFC-11 during condensation in horizontal smooth tube are presented. The experimental apparatus consisted of a closed working fluid loop, coolant loop, and measuring system. The major components of the working fluid loop made of a refrigerant pump, boiler, superheater, refrigerant flow meter, receiver and test section. The tube-in-tube type test section was made of smooth tube which were constructed form 9.52 mm outer diameter of smooth copper tube with 50 mm outside diameter of PVC tube duct. The ranges of parameter, such as refrigerant mass velocity, coolant flow rate, and quality were 90-325kg/($m^2$.s), 60-360kg/h, 5-95% respectively. Data were obtained under steady state condition for annular flow. As a result of these, the condensation heat transfer coefficients for HCFC-123 were slightly lower than those of CFC-11 from 8% to 15% inside horizontal smooth tube. Furthermore, a new generalized correlation for the heat transfer coefficients of HCFC-123 and CFC-11 during condensation inside horizontal smooth tube is proposed.

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Environmental Impact Evaluation of Virgin Pulp Using Life Cycle Assessment Methodology (LCA기법을 이용한 천연펄프의 환경 영향 평가)

  • 김형진;조병묵;황용우;박광호
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.1
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    • pp.49-60
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    • 2004
  • Life Cycle Assessment for the pulp, which is mainly used as the raw material of fine paper, base paper for food packaging and paper cup, has been carried out in this study to consider environmental aspects by quantifying the environmental emission and to evaluate its environmental impact potential. The system boundary was selected from cradle to gate stage(raw material acquisition, transportation of raw material and product manufacturing) of the product. Environmental impact was divided into 8 categories considering Korean situation: abiotic resource depletion, global warming, ozone depletion, acidification, eutrophication, photochemical oxidant creation, ecotoxicity and human toxicity. In Life Cycle Impact Assessment(LCIA) methodology phase, Ecopoint, Eco-indicator 95 and Korean eco-indicator were used and the results carried out by each methodology were compared. The results from this study were also compared with those of foreign study to verify the reliability of the results. The results of the study could be utilized as the basic data for Environmental Management System(EMS), Design for Environment(DfE) and Type III eco-labeling in the paper and paper-related industry.

Parameterization Model for Damaging Ultraviolet-B Irradiance

  • Kim, Yoo-Keun;Lee, Hwa-Woon;Moon, Yun-Seob
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.3 no.1
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    • pp.41-56
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    • 1999
  • Since UV-B radiation measuring networks have not been established, numerical models which calculate the flux from other readily available meteorological measurements may play an important role. That is, such a problem can be solved by using parameterization models such as two stream approximation, the delta-Eddington method, doubling method, and discrete ordinate method. However, most UV-B radiative transfer models have not been validated with measurements, because such models are not intended as practical computational schemes for providing surface estimates of UV-B radiation. The main concern so far has been to demonstrate model sensitivity for cloudless skies. In particular, few have been concerned with real cloud information. Clouds and aerosols have generally been incorporated as constituents of particular atmospheric layers with specified optical depths and scattering properties. The parameterization model presented here is a combination of a detailed radiative transfer algorithm for a coludless sky radiative process and a more approximate scheme to handle cloud effects. The model input data requires a daily measurement of the total ozone amount plus a daily record of the amount and type of cloud in the atmosphere. Measurements for an examination of the models at the Department of Atmospheric Sciences, Pusan National University have been takenfrom February, 1995. These models can be used to calculate present and future fluxes where measurements have not been taken, and construct climatologies for the period before ozone depletion began.

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The Performance Analysis of Sea Water Heat Pump applied Low GWP Refrigerants (Low GWP 냉매를 적용한 해수열 히트펌프의 성능해석)

  • Lim, Seung-Taek;Kim, Hyeon-Ju;Lee, Ho-Saeng
    • Journal of Power System Engineering
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    • v.20 no.5
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    • pp.92-97
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    • 2016
  • In this study, the seawater Heat Pump System using seawater with temperature of annual domestic conditions ($0^{\circ}C$ to $25^{\circ}C$) is designed in order to compare its performance against the Heat Pump using unused heat of seawater. As a potential replacement for current refrigerants that exacerbate global warming and ozone delpetion, a Low GWP refrigerant's performance is analyzed. The basic water to water Heat Pump system is chosen and three commercial refrigerants - R134a, R410a, R32 - are used to compare against new Low GWP refrigerant R1234ze. When seawater with temperature of $25^{\circ}C$ is used, the performance change showed maximal increase in COP, 38.3%. low GWP refrigerant R1234ze, showed great performance characteristics reach to 5.242 and Existing commercial refrigerant, R134a showed only less than 0.03 performance difference against R1234ze. The study confirms notable performance of R1234ze refrigerant through simulation as environmentally friendly refrigerant for domestic seawater Heat Pump.

Multi Analysis of Fumigants in Soil and Water (물과 토양에서 훈증제의 동시분석법 확립)

  • Kim, Jung-Ho
    • Environmental Analysis Health and Toxicology
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    • v.21 no.4 s.55
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    • pp.365-373
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    • 2006
  • Emission of methyl bromide (MeBr) from soil was implicated in stratospheric ozone depletion. To determine multi analysis of alternatives fumigants for MeBr, this paper describes the methods of analysis in water and soil. The MeBr, methyl iodide (Mel), propargyl bromide (PBr), cis 1,3-dichloropropene (cis 1,3-D), trans 1,3-dichloropropene (trans 1,3-D) and chloropicrin(CP) are separated on the base line on GC-ECD at three column of AT+DB+DB (90m) with temperature programing of $35^{\circ}C{\rightarrow}110^{\circ}C$ on GC-ECD. The relative retention time for MeBr, Mel, PBr, cis 1,3-D, trans 1,3-D and CP is 1.0, 1.4, 2.3, 3.2, 3.6 and 3.7, respertively. The detection limit for MeBr, Mel, PBr, cis 1,3-D, trans 1,3-D and CP is 469 pg, 5 pg, 21 pg, 79 pg, 101 PE and 5pg, respectively. Recovery of MeBr Mel, PBr, cis 1,3-D, trans 1,3-D and CP in water added 150 ppm fumigants were 81%, 96%, 95%, 97%, 98% and 99%, respectively. Recovery of MeBr, MeI, PBr, cis 1, 3-D, trans 1,3-D and CP in soil added 150ppm fumigants were 56%, 84%), 85%, 81%, 87% and 88%, respectively.

Overview of UV-B Effects on Marine Algae (자외선이 해조류에 미치는 영향에 관한 고찰)

  • 한태준
    • Korean Journal of Environmental Biology
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    • v.17 no.1
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    • pp.1-9
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    • 1999
  • Numerous observations revealed strong evidence of increased middle ultraviolet radiation or UV-B (280 ~ 320 nm) at the earth's surface resulting from stratospheric ozone depletion. UV is the waveband of electromagnetic radiation which is strongly absorbed by nucleic acids and proteins, thus causing damage to living systems. It has been recorded in the East Sea, Korea that solar UV-B impinging on the ocean surface penetrates seawater to significant depths. Recent researches showed that exposure to UV-B for as short as 2h at the ambient level (2.0 Wm$^{-2}$) decreased macroalgal growth and photosynthesis and destroyed photosynthetic pigments. These may suggest that UV-B could be an important environmental factor to determine algal survival and distribution. Some adaptive mechanisms to protect macroalgae from UV-damage have been found, which include photoreactivation and formation of UV-absorbing pigments. Post-illumination of visible light mitigated UV-induced damage in laminarian young sporophytes with blue the most effective waveband. The existence of UV-B absorbing pigments has been recognized in the green alga, Ulva pertusa and the red alga, Pachymeniopsis sp., which is likely to exert protective function for photosynthetic pigments inside the thalli from UV-damage. Further studies are however needed to confirm that these mechanisms are of general occurrence in seaweeds. Macroalgae together with phytoplankton are the primary producers to incorporate about 100 Gt of carbons per year, and provide half of the total biomass on the earth. UV-driven reduction in macroalgal biomass, if any, would therefore cause deleterious effects on marine ecosystem. The ultimate impacts of increasing UV-B flux due to ozone destruction are still unknown, but the impression from UV studies made so far seems to highlight the importance of setting up long-term monitoring system for us to be able to predict and detect the onset of large -scale deterioration in aquatic ecosystem.

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