• Journal of Sensor Science and Technology
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• v.6 no.6
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• pp.451-457
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• 1997

The thick films of oxide semiconductors such as $WO_{3}$, $SnO_{2}$ and ZnO for the $NO_{2}$ detection of sub-ppm range have been prepared and their characteristics were investigated. It is showed that the optimum operating temperatures of the sensors are $300^{\circ}C$ and $220{\sim}260^{\circ}C$ for $WO_{3}$-based and $SnO_{2}$-based thick films, and ZnO-based thick films, respectively. Since the resistance of ZnO-based thick films are extremely high($>10^{6}{\Omega}$), the signal to noise ratio was comparatively low. In order to determine the selectivity, the films are exposed to the interfering gases such as ozone, ammonia, methane and the mixture of carbon monoxide and propane. $WO_{3}$-ZnO(3 wt.%) and $SnO_{2}-WO_{3}$(3 wt.%) thick film sensors show high sensitivity, good selectivity, excellent reproducibility and the linearity of $NO_{2}$ concentration versus sensor resistance. The preliminary results clearly demonstrated that the sensor can be successfully applied for the detection of $NO_{2}$ in sub-ppm range.

• Korean Chemical Engineering Research
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• v.45 no.6
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• pp.648-655
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• 2007

UV/H_2O_2$, $O_3$, $O_3/H_2O_2$, $UV/H_2O_2/O_3$ processes were tested for the removal of COD and color from terephthalic acid wastewater. COD removal efficiencies were 10, 48, 56, 63% in the $UV/H_2O_2$, $O_3$, $O_3/H_2O_2$, $UV/H_2O_2/O_3$ process respectively. Color removal efficiency of $UV/H_2O_2$ process was 80% and $O_3$, $O_3/H_2O_2$, $UV/H_2O_2/O_3$ processes were almost more than 99%. Terephthalic acid, isophthalic acid and benzoic acid were completely destructed in terephthalic wastewater within 120 min by $UV/H_2O_2/O_3$ process and shows high COD and color removal efficiencies. The optimum concentration of $H_2O_2$ dosage was found to be 0.5 M, 25 mM and 5 mM for $UV/H_2O_2$, $O_3/H_2O_2$ and $UV/H_2O_2/O_3$ processes respectively, Organic destruction efficiency was enhanced and also reducing the consumption of $H_2O_2$ dosage by combining UV, $H_2O_2$ and $O_3$ process.

• Journal of Korean Society of Environmental Engineers
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• v.22 no.1
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• pp.103-111
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• 2000

Ozonation and advanced oxidation($H_2O_2/O_3$) process were investigated under various experimental conditions to improve the efficiency of biological filter used for the treatment of recycled wastewater from aquaculture. Ammonia removal followed the first-order reaction whose reaction rate constant(k) was $2.0{\times}10^{-2}min^{-1}$ in ozonation. The ammonia removal rate increased according as the bicarbonate alkalinity is increased. About 46% $NH_3$ was oxidized by ozone at 200 mg/L as $CaCO_3$. When alkalinity existed in wastewater, ammonia removal rate by advanced oxidation was very low due to the inhibition effect of bicarbonate. However, when initial pH was adjusted to about 8.2 by 0.1 N KOH, ammonia removal rate was improved higher than that by ozonation. Especially. ammonia removal rate was the highest at $H_2O_2/O_3$ of 0.25 and about 90% of ammonia was removed in 30 min at this ratio as pH was maintained over 9. In the case of wastewater containing ammonia and organic constituents, ammonia removal efficiency by both ozonation and advanced oxidation decreased seriously because organic constituents consumed the oxidant faster than ammonia. In addition the optimal $H_2O_2/O_3$ ratio was changed. Like ammonia removal, DOC(dissolved organic carbon) increased for first 10 min and then decreased slowly because the particulate organic constituents were oxidized rapidly and then produce DOC. Even when the ammonia concentration by twice, oxidation of DOC was not retarded.

• Korean Journal of Agricultural and Forest Meteorology
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• v.14 no.2
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• pp.71-78
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• 2012

Eupatilin, one of representative medical components of mugwort, can be efficiently extracted from the 'Gangwha Sajabalssuk'. The Eupatilin content may depend on environmental factors such as soil and regional climate in addition to a genetic factor and Gangwha region has a profitable environmental condition for the mugwort growth. In this study, the climatological characteristics of Gangwha was analyzed in order to find the environmental condition of mugwort containing high Eupatilin in term of atmospheric, oceanographic and land variables. The climate of Gangwha is characterized by the relatively low daily temperature and large diurnal variation with plenty of solar radiation, long sunshine duration and less cloudiness. According to our correlation analysis, the long sunshine duration and the large diurnal temperature variation are highly correlated with the Eupatilin contents. The result implies that Gangwha has the favorable conditions for the cultivation and the habitat of the high-Eupatilin concentrated mugwort. Because of the sea surrounding Gangwha Island with low salinity and moderate wind, the salt contained in sea breeze is relatively low compared to other regions. Furthermore, Gangwha has clean atmospheric environment compared to other regions because the concentrations of toxic gases harmful to crop growth such as nitrogen dioxide ($NO_2$), sulfite gas ($SO_2$) and fine dust (PM-10) are lower in the air. The ozone ($O_3$) concentration is moderate and within the level of natural production. It is also found that moderately coarse texture or fine loamy soils known as good for water drainage and for the growth and cultivation of the 'Gangwha-mugwort' are distributed throughout the areas around mountainous districts in Gangwha, coinciding with those of mugwort habitat.

• Journal of Animal Environmental Science
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• v.16 no.3
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• pp.175-180
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• 2010

Many greenhouse gases occur naturally, such as water vapor, carbon dioxide, methane, nitrous oxide, and ozone. Others such as hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), and sulfur hexafluoride ($SF_6$) result exclusively from human industrial processes. Current global warming has been linked to anthropogenic greenhouse gas concentration increases. Methods to quantify greenhouse gas emissions during animal agriculture and the possibility to apply those to circumstance in the world were studied. Various chamber methods with trace gas analyzer (TGA) were used to quantify greenhouse gas emissions from stored manure. Methane fluxes from pails storing liquid swine manure were measured. Methane emissions increased a little with time and mean was 393.2 ${\mu}g\;m^{-2}\;s{-1}$ (standard error : 4 ${\mu}g\;m^{-2}\;s{-1}$).

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.9
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• pp.196-205
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• 2016

The exhaust gas discharged by cars not only threatens the health of the human body, but also contributes to global warming, due to the resulting increase in the concentrations of ozone, fine dust and carbon dioxide. Therefore, the government has steadily implemented careful inspection systems for exhaust emissions, in order to efficiently regulate the exhaust gas of cars. Studies on reducing the exhaust emissions of automobiles have been conducted in various fields, including ones designed to reduce the generation of HC, NOx, and $CO_2$ in the exhaust emission of vehicles. However, there have been insufficient studies on the reduction of the exhaust emission for old diesel vehicles. To develop careful inspection systems for the exhaust emissions of old diesel vehicles, studies on the reduction of the exhaust emissions and improvement of power are necessary by cleaning the carbon sediment in both the intake manifold and injector. Therefore, in this study, we analyzed and compared the amounts of gas emitted when simultaneously cleaning or not cleaning the intake manifold and injector of diesel automobiles with mileages over 80,000 km and operating periods over 5 years. The experimental results showed that in the case where the intake manifold and injector were simultaneously cleaned, there was a decline of 75.2% in the gas emission compared to the cases where only the manifold or injector is cleaned. Also, it was found that simultaneously cleansing the intake manifold and injector enabled the exhaust standard to be satisfied for less than 30% within 8.5 sec.

• Journal of the Institute of Convergence Signal Processing
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• v.22 no.1
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• pp.14-19
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• 2021

This study has attempted to use ozone for the treatment of skin diseases as research results that ozonated olive oil has an excellent therapeutic effect on skin diseases are known. However, there is hardly any accurate data in Korea. Usually, animal tests related to cosmetics are not performed, but toxicity tests were conducted because they were absolutely necessary. In general, there are not many cases of measuring actual data through animal tests for the purpose of confirming the performance of cosmetics, but in the case of toxicity tests, it is recommended to accurately measure skin reactions, so this experiment was conducted. In this experiment, in order to evaluate the skin irritation of ozonated oil (high concentration) on the rabbit, the test substance was applied to the back of the rabbit for 24 hours, and then mortality, general symptoms and skin irritation were evaluated. Experimental Results As a result of evaluating the treatment site of the test substance after a certain period of time, no skin irritation was observed in all animals.

• Journal of Environmental Health Sciences
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• v.50 no.3
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• pp.191-200
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• 2024

Background: Busan is a rapidly industrializing city with many mixed residential and industrial areas. Fine dust emissions from mobile pollution sources such as ships and vehicles are particularly high in Busan. Objectives: This study analyzed the spatial distribution of air pollutants over the past three years and identified the impact of air pollutants through mobile source data in Busan. Methods: We obtained air pollutant data on fine particulate matter (PM₁₀), ultrafine particulate matter (PM_2.5), nitrogen dioxide (NO₂), sulfurous acid gas (SO₂), and ozone (O₃) for the last three years (source: airkorea.or.kr) and analyzed the spatial distribution using SAS 9.4 and Surfer 23. For the mobile pollutant data, we used CCTV data from major intersections in Busan to identify truck and car traffic, and visualized traffic density with QGIS. Results: The analysis of the concentration of air pollutants over three years (2020~2022) showed that all were lower than the annual environmental standards with the exception of PM_2.5. PM₁₀ and PM_2.5 were found to be highly concentrated in the western part of the area, while NO₂ was high in the port area of Busan and SO₂ was high in the western part of the area and near the new port of Busan. In the case of O₃, it was high in the eastern part of the city. The traffic volume of freight vehicles by intersection was concentrated in the West Busan area, and the traffic volume for all cars was also confirmed to be concentrated at "Mandeok Intersection" located in the West Busan area. Conclusions: This study was conducted to determine the relationship between air pollutants emitted from motor vehicles and the distribution of air pollutants in Busan. The spatial distribution of PM₁₀ and PM_2.5 correlates with traffic volume, while high concentrations of SO₂ and NO₂ near the port are associated with ship emissions.

• Analytical Science and Technology
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• v.29 no.3
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• pp.114-125
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• 2016

In this study, 165 wastewater discharge facilities in 10 business types were investigated with regard to 24 specific hazardous substances that included heavy metals, VOCs, CN, and phenol in the Gwangju city. Cu in the range from from 0.008 to 35.420 mg/L was detected in all business types and the detection rate was 46.8 %. Other heavy metals, such as Cd, As, Hg, Pb, and Cr⁺⁶ were detected as well. However, their detection rates ranged between 0.6 and 1.8 %. CN and phenol were detected in one and five facilities, respectively. 12 species of VOCs were detected: chloroform 80.6 % (0.42 to 81.60 μg/L), benzene 16.4 % (1.49 to 3.31 μg/L), trichloroethylene 11.5 % (1.78 to 6.02 μg/L), 1,1-dichloroethylene 10.3 % (1.23 to 5.89 μg/L), and dichloromethane 8.5 % (0.28 to 968.86 μg/L) in the detection rate order. The concentration of VOCs was detected in trace amounts, except for dichloromethane that exceeded the effluent quality standard in three business types, namely, metal manufacturing, food industry, and car washing facility. Chloroform was detected in all business types, where 24.88 μg/L were detected in the laundry business and 53.41 μg/L in the water supply business; the mean concentration of chloroform in these two business types was higher than elsewhere. Therefore, for the disposal of non-degradable specific hazardous substances in industrial wastewater, it is necessary to introduce physical and chemical processes, such as activated carbon adsorption, fenton oxidation, ozone treatment, as well as photocatalyst and the UV radiation.

• Korean Chemical Engineering Research
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• v.40 no.6
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• pp.746-751
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• 2002

Fluidized bed combustion is a coal combustion technology that can reduce both SOx and NOx emission; SOx is removed by limestone that is fed into the combustion chamber and the NOx is reduced by low temperature combustion in a fluidized bed combustor and air stepping, but $N_2O$ generation is quite high. $N_2O$ is not only a greenhouse gas but also an agent of ozone destruction in the stratosphere. The calcium oxide(CaO) is known to be a catalyst of $N_2O$ decomposition. This study of $N_2O$ decomposition reaction in fixed bed reactor packed over CaO bed has been conducted. Effects of parameters such as concentration of inlet $N_2O$ gas, reaction temperature, CaO bed height and effect of $CO_2$, NO, $O_2$ gas on the decomposition reaction have been investigated. As a result of the experiment, it has been shown that $N_2O$ decomposition reaction increased with the increasing fixed bed temperature. While conversion of the reaction was decreased with increasing $CO_2$ concentration. Also, under the present of NO, the conversion of $N_2O$ decomposition is decreased. From the result of kinetic study gained the heterogeneous reaction rate on $N_2O$ decomposition. In the case of $N_2O$ decomposition over CaO, heterogeneous reaction rate is. $\frac{d[N_2O]}{dt}=\frac{3.86{\times}10^9{\exp}(-15841/R)K_{N_2O}[N_2O]}{(1+K_{N_2O}[N_2O]+K_{CO_2}[CO_2])}$. In this study, it is found that the calcium oxide is a good catalyst of $N_2O$ decomposition.