• 제목/요약/키워드: ozone$PM_{10}$

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반도체 웨이퍼 제조공정 클린룸 구조, 공기조화 및 오염제어시스템 (Clean Room Structure, Air Conditioning and Contamination Control Systems in the Semiconductor Fabrication Process)

  • 최광민;이지은;조귀영;김관식;조수헌
    • 한국산업보건학회지
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    • 제25권2호
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    • pp.202-210
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    • 2015
  • Objectives: The purpose of this study was to examine clean room(C/R) structure, air conditioning and contamination control systems and to provide basic information for identifying a correlation between the semiconductor work environment and workers' disease. Methods: This study was conducted at 200 mm and 300 mm semiconductor wafer fabrication facilities. The C/R structure and air conditioning method were investigated using basic engineering data from documentation for C/R construction. Furthermore, contamination parameters such as airborne particles, temperature, humidity, acids, ammonia, organic compounds, and vibration in the C/R were based on the International Technology Roadmap for Semiconductors(ITRS). The properties of contamination control systems and the current status of monitoring of various contaminants in the C/R were investigated. Results: 200 mm and 300 mm wafer fabrication facilities were divided into fab(C/R) and sub fab(Plenum), and fab, clean sub fab and facility sub fab, respectively. Fresh air(FA) is supplied in the plenum or clean sub fab by the outdoor air handling unit system which purifies outdoor air. FA supply or contaminated indoor air ventilation rates in the 200 mm and 300 mm wafer fabrication facilities are approximately 10-25%. Furthermore, semiconductor clean rooms strictly controlled airborne particles(${\leq}1,000{\sharp}/ft^3$), temperature($23{\pm}0.5^{\circ}C$), humidity($45{\pm}5%$), air velocity(0.4 m/s), air change(60-80 cycles/hr), vibration(${\leq}1cm/s^2$), and differential pressure(atmospheric pressure$+1.0-2.5mmH_2O$) through air handling and contamination control systems. In addition, acids, alkali and ozone are managed at less than internal criteria by chemical filters. Conclusions: Semiconductor clean rooms can be a pleasant environment for workers as well as semiconductor devices. However, based on the precautionary principle, it may be necessary to continuously improve semiconductor processes and the work environment.

Optimization of aircraft fuel consumption and reduction of pollutant emissions: Environmental impact assessment

  • Khardi, Salah
    • Advances in aircraft and spacecraft science
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    • 제1권3호
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    • pp.311-330
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    • 2014
  • Environmental impact of aircraft emissions can be addressed in two ways. Air quality impact occurs during landings and takeoffs while in-flight impact during climbs and cruises influences climate change, ozone and UV-radiation. The aim of this paper is to investigate airports related local emissions and fuel consumption (FC). It gives flight path optimization model linked to a dispersion model as well as numerical methods. Operational factors are considered and the cost function integrates objectives taking into account FC and induced pollutant concentrations. We have compared pollutants emitted and their reduction during LTO cycles, optimized flight path and with analysis by Dopelheuer. Pollutants appearing from incomplete and complete combustion processes have been discussed. Because of calculation difficulties, no assessment has been made for the soot, $H_2O$ and $PM_{2.5}$. In addition, because of the low reliability of models quantifying pollutant emissions of the APU, an empirical evaluation has been done. This is based on Benson's fuel flow method. A new model, giving FC and predicting the in-flight emissions, has been developed. It fits with the Boeing FC model. We confirm that FC can be reduced by 3% for takeoffs and 27% for landings. This contributes to analyze the intelligent fuel gauge computing the in-flight fuel flow. Further research is needed to define the role of $NO_x$ which is emitted during the combustion process derived from the ambient air, not the fuel. Models are needed for analyzing the effects of fleet composition and engine combinations on emission factors and fuel flow assessment.

XAD 수지에 의한 친수성 및 소수성 수용성 유기탄소의 특성조사 (Study on Characterization of Hydrophilic and Hydrophobic Fractions of Water-soluble Organic Carbon with a XAD Resin)

  • 정재욱;김자현;박승식;문광주;이석조
    • 한국대기환경학회지
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    • 제27권3호
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    • pp.337-346
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    • 2011
  • 24-hr integrated measurements of water-soluble organic carbon (WSOC) in PM2.5 were made between May 5 and September 25, 2010, on a six-day interval basis, at the Metropolitan Area Air Pollution Monitoring Supersite. A macro-porous XAD7HP resin was used to separate hydrophilic and hydrophobic WSOC. Compounds that penetrate the XAD7HP column are referred to hydrophilic WSOC, while those retained by the column are defined as hydrophobic WSOC. Laboratory calibrations using organic standards suggest that hydrophilic WSOC includes lowmolecular aliphatic dicarboxylic acids and carbonyls with less than 4 or 5 carbons, amines, and saccharides. While the hydrophobic WSOC is composed of compounds of aliphatic dicarboxylic acids with carbon numbers larger than 4~5, phenols, aromatic acids, cyclic acid, and humic-like Suwannee River fulvic acid. Over the entire study period, total WSOC accounted for on average 48% of OC, ranging from 32 to 65%, and hydrophilic WSOC accounted for on average 30.5% (9.3~66.7%) of the total WSOC. Based on the previous results, our measurement result suggests that significant amounts of hydrophobic WSOC during the study period were probably from primary combustion sources. However, on June 9 when 1-hr highest ozone concentration of 130 ppb was observed, WSOC to OC was 0.61, driven by increases in the hydrophilic WSOC. This result also suggests that processes, such as secondary organic aerosol formation, produce significant levels of hydrophilic WSOC compounds that add substantially to the fine particle fraction of the organic aerosol.

서울 도심대기의 NO, NO2와 O3 사이의 대기화학적 특성 연구 (Characteristics in Atmospheric Chemistry between NO, NO2 and O3 at an Urban Site during MAPS (Megacity Air Pollution Study)-Seoul, Korea)

  • 김득수;정진상;안준영
    • 한국대기환경학회지
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    • 제32권4호
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    • pp.422-434
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    • 2016
  • This study was conducted to understand roles of $NO_x(=NO+NO_2)$ on high $O_3$ episodes at an urban monitoring station in Seoul. Concentrations of NO, $NO_2$, $NO_y$ and $O_3$ were measured intensively at KIST monitoring station which located at urban center in Seoul metropolitan area during May 18~June 13, 2015. Sampling period was planed because high $O_3$ and PM occurred frequently during from late spring to early summer months in Seoul. The experimental site locates in NW from center of Seoul and is surrounded by residential area. Belt highway of the city runs from north to west side nearby experimental site. Vehicle exhaust emissions due to heavy traffic influenced $NO_x$ concentration at the site during northwesterly wind. Specific $NO_2$ concentration was measured by Blue Light photolytic converter, and it was compared to $NO_2$ concentration measured by molybedenum converter. $[NO_2]_{phtolysis}$ was usually lower than $[NO_2]_{molybedenum}$ during the experiment period; however their diurnal variations were very similar. The linear relationship between these $NO_2$ concentrations was found to be $[NO_2]_{phtolysis}$=0.64 $[NO_2]_{molybedenum}$ - 2.6, $r^2$=0.83 during May 16~8, 2015. The difference between $NO_2$ by molybdenum converter and by photolytic converter (${\Delta}NO_2=[NO_2]_{molybedenum}-[NO_2]_{phtolysis}$) accounted for residual $NO_y$ which can represent $NO_z$ (=$NO_y-NO_x$). $O_3$ concentration showed typical daily trend which has maximum at late afternoon and minimum during the night. $O_3$ increased at a rate of 7 ppb/hr since 8 am. and reached the maximum concentration (~80 ppb) at 3 pm.. The diurnal pattern of $O_3$ was inversely related with that of $NO_2$, suggesting that the formation of $O_3$ was the result of photochemical activity of $NO_2$.

강화지역의 기후특성 분석을 통한 '강화약쑥'의 생육 환경 연구 (Study on the Growth Environment of 'Gangwha-mugwort' Through the Climatological Characteristic Analysis of Gangwha Region)

  • 안중배;허지나;정해곤;박종호
    • 한국농림기상학회지
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    • 제14권2호
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    • pp.71-78
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    • 2012
  • 본 연구에서는 Eupatilin이 고함유된 약쑥의 생육환경을 구명하고자 하였다. 이를 위해서 먼저 선행연구를 통해 Eupatilin이 고함유된다고 알려진 강화지역의 기상학적 특성을 살펴보고, 재배지역별, 수확시기별 Eupatilin 함유량과 기상요소와의 관계를 분석 하였다. 또한 강화지역의 해양, 대기질, 토양 그리고 약쑥 생육지 분포 자료를 이용하여 환경학적 조건도 분석 하였다. 결과적으로 일조시간이 길고 일교차가 큰 지역이 유효 성분이 많이 함유된 약쑥 생산에 유리한 환경이며, 강화도는 주변 지역에 비해서 일조시간이 길며 일교차가 크기 때문에 Eupatilin 함량이 많은 약쑥의 재배 및 서식처로써 적합한 지역으로 사료되었다. 또한 강화는 약한 해풍과 주변 해역의 낮은 염분도에 의해 유입되는 염분의 양이 다른 해안지방에 비하여 낮으며 다른 지역과 비교해볼 때 청정한 대기환경을 가지고 있는 것으로 분석되었다. 이와 더불어, 강화지역은 산지 주변으로 배수가 양호한 사양 질 내지 식양 질이 많이 분포하는데 이러한 토양 분포는 약쑥 생육지 분포와 일치하였다. 즉, 적절한 염분의 유입과 청정한 대기 그리고 배수가 양호한 토양이 Eupatilin 함유에 유리한 환경이 되었을 것으로 사료되었다.

국내휘발유 승용차량으로부터의 N2O배출인자 특성연구 (Characteristics of N2O Emission Factor and Measurements from Gasoline-Powered Passenger Vehicles)

  • 김득수;류정호;유영숙;정성운;김대욱
    • 한국환경과학회지
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    • 제16권2호
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    • pp.179-185
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    • 2007
  • Nitrous oxide ($N_2O$) is an important trace gas in the atmosphere not only because of its large global warming potential (GWP) but also because of the role in the ozone depletion in the stratosphere. It has been known that soil is the largest natural source of $N_2O$ in global emission. However, anthropogenic sources contributing from industrial section is likely to increase with rising the energy consumption, and transportation as well. In this study, a total of 32 gasoline-powered passenger vehicles (ranging from small to large engine's displacement and also ranging from aged catalyst to new catalyst) were tested on the chassis dynamometer system in order to elucidate the characteristics of $N_2O$ emission from automobiles under different driving modes. Ten different driving modes developed by NIER were adapted for the test. The results show that the $N_2O$ emission decreases logarithmically with increase of vehicle speed over the all test vehicles ($N_2O$) emission = -0.062 Ln (vehicle speed) + $0.289,\;r^2=0.97$). It revealed that the larger engine's displacement, the more $N_2O$ emission were recorded. The correlation between $N_2O$ emission and catalyst aging was examined. It found that the vehicles with aged catalyst (odometer record more than 8,0000km) emit more $N_2O$ than those with new catalyst. Average $N_2O$ emission was $0.086{\pm}0.095\;N_2O-g/km$ (number of samples=210) for the all test vehicles over the test driving modes.

레드비트를 함유하는 화장품의 담배 연기에 의한 피부 지질 산화 방지 효과 (Protective Effect of Cosmetics Containing Red Beet against Cigarette Smoke-induced Oxidative Damage in Human Skin)

  • 서초롱;하태현;문지영;김정미;박병권;이지원;박진오;신진희
    • 대한화장품학회지
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    • 제44권2호
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    • pp.111-116
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    • 2018
  • 최근 화장품 시장에서 안티폴루션 효능이 있는 화장품은 새로운 피부 건강을 위한 해결책으로 나타나고 있다. 외부(대기) 오염물질에 의해 피부의 산화 기전을 매개하는 주요 원인 인자들로 오존, UV, 미세먼지 및 담배연기 등을 꼽을 수 있다. 담배 연기의 노출은 직 간접적으로 피부 표피 내 지질의 산화를 야기한다. 피부의 지질 산화에 의해 squalene과 squalene monohydroperoxide의 비율 변화가 발생하고, malondialdehyde (MDA)가 지질산화 산물로 생성된다. 따라서, 본 연구에서는 담배연기 노출 시 발생하는 피부 산화에 대하여 레드비트를 함유하는 화장품이 방지할 수 있는 효능이 있는지에 대하여 MDA의 생성량으로 관찰하였다. 시험대상자 전박부를 세 영역(음성대조, 양성대조, 시험제품)으로 나누어 각 지름 3.3 cm의 원으로 구획하고, 15분간 담배연기에 노출 후 피부 표면으로부터 지질막을 걷어낸 후 TBARS assay를 통하여 MDA를 정량 하였다. 음성대조(무도포, 미노출)에 비해 양성대조(무도포, 담배연기 노출)의 MDA 생성량이 3.7배 증가된 결과로, 오염물질인 담배연기에 의한 피부의 산화적 손상을 확인하였다. 반면에 레드비트를 함유하는 화장품을 미리 도포한 영역은 양성대조에 비해 MDA 생성량이 25% 감소하는 결과를 나타내었다. 결론적으로, 담배연기 노출은 피부표피 내 지질 산화를 야기하며, 레드비트를 함유하는 화장품이 이러한 대기환경오염으로부터 방어적 효과(안티폴루션 효과)를 보이는 것을 확인하였다.

대기오염물질 농도에 따른 천식 응급환자 수 예측 연구 (A prediction study on the number of emergency patients with ASTHMA according to the concentration of air pollutants)

  • 이한주;지민규;김청원
    • 서비스연구
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    • 제13권1호
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    • pp.63-75
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    • 2023
  • 산업이 발전하면서 대기오염물질에 대한 관심도는 높아졌다. 대기오염물질은 환경오염, 지구 온난화 등 다양한 분야에 영향을 미쳤다. 그 중 환경성 질환은 대기오염물질에 의해 영향을 받은 분야 중 하나이다. 대기오염물질은 분자의 크기가 작아 인체의 피부나 호흡기를 통해 영향을 미칠 수 있다. 이러한 점 때문에 대기오염물질과 환경성 질환에 대한 연구가 다양하게 진행됐다. 환경성 질환의 일환인 천식은 증상이 심해져 천식발작을 일으킬 경우 생명에 위협을 줄 수 있고 성인 천식의 경우 한번 발병을 하면 완치가 어렵다. 천식을 악화시키는 요인에는 황사, 대기오염이 포함된다. 전 세계적으로 천식은 유병률이 증가하고 있는 추세이다. 본 논문에서는 대기오염물질이 천식 환자의 응급실 입원 건수와 어떤 상관관계를 가지는지 연구하고 상관관계가 높은 대기오염물질을 이용하여 미래의 천식 환자 수를 예측했다. 대기오염물질은 아황산가스(SO2), 일산화탄소(CO2), 오존(O3), 이산화질소(NO2)와 미세먼지(PM10) 5가지 대기오염물질의 농도를 이용하고 환경성 질환은 천식 환자의 응급실 입원 건수 데이터를 이용하였다. 대기오염물질과 천식의 응급환자 수에 대한 데이터는 2013년 1월1일 부터 2017년 12월 31일 까지 총 5년 치의 데이터를 이용하였다. 모델은 Informer와 LTSF-Linear의 두 가지 모델을 이용하여 예측을 진행하였고 모델의 성능을 측정하기 위해 MAE, MAPE, RMSE 의 성능지표를 이용했다. 천식의 응급환자 수 예측은 응급환자 수를 포함하여 예측을 진행한 경우와 포함하지 않고 진행한 두 가지 경우 모두 진행하여 결과를 비교했다. 본 논문은 Informer와 LTSF-Linear 모델을 이용한 천식 응급환자 수의 예측에 모델의 성능을 향상 시키는 대기 오염물질을 제시한다.