• Title/Summary/Keyword: oxygen-18

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Using LNAPL to Enhance in situ Oxygen Transfer: (II) Biotic Condition (LNAPL을 이용한 지중 산소전달 향상: (II) Biotic Condition)

  • Ha, Jeong-Hyub;Kang, Seon-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.3
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    • pp.337-342
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    • 2004
  • Previous experiment was performed under abiotic condition. Steady-state abiotic experiments in the sand-tank reactor with air flowing through the reactor headspace demonstrated that oxygen supply through the water table interface into the saturated zone was enhanced when an LNAPL (dodecane) pool was present at the water table. Biotic condition was considered in this study. Biotic experiments performed after inoculating the reactor with Pseudomonas putida mt-2, which does not grow on dodecane, indicated that the enhanced oxygen supply in the presence of the LNAPL pool also enhanced biodegradation of a solute (glucose) plume passing beneath the LNAPL pool at steady-state.

A Study on the Combustion Characteristics of Diesel Engine by the Change of the Intake Air Composition (흡기조성 변화에 따른 디젤 기관의 연소 특성 변화)

  • 김세원;임재문
    • Journal of Advanced Marine Engineering and Technology
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    • v.18 no.2
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    • pp.91-96
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    • 1994
  • Intake gases other than air, which is composed of oxygen, nitrogen, carbon dioxide, and argon, are used to study their effects on the performance of the diesel engine experimentally. The engine is operated at constant speed and fixed fuel injection timing, and cylinder pressure and heat release rate are measured at various intake gas compositions. The results show that increase of oxygen concentration improves the performance of the engine generally. The adverse effect is observed when the oxygen concentration is increased over the critical oxygen concentration of this test, mainly because of the over-shortened ignition delay. Increase of carbon dioxide concentration degardes the performance of the engine, mainly due to the lower specific heat ratio of carbon dioxide. Adding argon gas to the intake gas improves the overall performance. Finally, it is found that two most influencing factors affecting the performance of the diesel engine in this study are ignition delay and speific heat ratio of the intake gas.

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The Role of Oxygen for Expressing Superconductivity in La-Ca-Cu-O Compounds

  • 정동운
    • Bulletin of the Korean Chemical Society
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    • v.20 no.3
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    • pp.281-284
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    • 1999
  • Two La1.82Ca1.18Cu2O6+δ (2126) compounds exhibited different properties depending upon how they were synthesized. The compound prepared under high oxygen pressure showed superconductivity. But the compound prepared under low oxygen pressure did not exhibit superconductivity, and showed a metal-insulator transition. Our study on these compounds shows that a small amount of additional oxygen intercalated into the superconducting phase plays an important role for superconductivity. The Fermi surface of non-superconducting 2126 compound possesses nesting phenomena, which is the reason for the M-1 transition. On the other hand, the superconducting 2126 compound does not show Fermi surface nesting. This is because the additional oxygen removes some electrons from Cu d-orbitals, thereby bradking the Fermi surface nesting.

Low-Oxygen Atmosphere and its Predictors among Agricultural Shallow Wells in Northern Thailand

  • Wuthichotwanichgij, Gobchok;Geater, Alan F.
    • Safety and Health at Work
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    • v.6 no.1
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    • pp.18-24
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    • 2015
  • Background: In 2006, three farmers died at the bottom of an agricultural shallow well where the atmosphere contained only 6% oxygen. This study aimed to document the variability of levels of oxygen and selected hazardous gases in the atmosphere of wells, and to identify ambient conditions associated with the low-oxygen situation. Methods: A cross-sectional survey, conducted in June 2007 and July 2007, measured the levels of oxygen, carbon monoxide, hydrogen sulfide, and explosive gas (percentage of lower explosive limit) at different depths of the atmosphere inside 253 wells in Kamphaengphet and Phitsanulok provinces. Ambient conditions and well use by farmers were recorded. Carbon dioxide was measured in a subset of wells. Variables independently associated with low-oxygen condition (<19.5%) were identified using multivariate logistic regression. Results: One in five agricultural shallow wells had a low-oxygen status, with oxygen concentration decreasing with increasing depth within the well. The deepest-depth oxygen reading ranged from 0.0% to 20.9%. Low levels of other hazardous gases were detected in a small number of wells. The low-oxygen status was independently associated with the depth of the atmosphere column to the water surface [odds ratio (OR) = 13.5 for 8-11 m vs. <6 m], depth of water (OR = 0.17 for 3-<8 m vs. 0-1 m), well cover (OR = 3.95), time elapsed since the last rainfall (OR = 7.44 for >2 days vs. <1 day), and location of well in sandy soil (OR = 3.72). Among 11 wells tested, carbon dioxide was detected in high concentration (>25,000 ppm) in seven wells with a low oxygen level. Conclusion: Oxygen concentrations in the wells vary widely even within a small area and decrease with increasing depth.

A NUMERICAL STUDY ON THE HEAT AND FLUID FLOW IN A REGENERATIVE OXY-FUEL COMBUSTION SYSTEM (순산소 연소용 축열시스템 내에서의 열 유동 수치해석)

  • Kang, K.;Hong, S.K.;Noh, D.S.;Ryou, H.S.
    • Journal of computational fluids engineering
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    • v.18 no.3
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    • pp.1-7
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    • 2013
  • A pure oxygen combustion technology is crucial in Carbon Capture and Storage (CCS) technology especially in capturing of $CO_2$, where CCS will reduce 9 $GtCO_2$ by 2050, which is 19% of the total $CO_2$ reduction amount. To make pure oxygen combustion feasible, a regenerative system is required to enhance the efficiency of pure oxygen combustion system. However, an existing air combustion technology is not directly applicable due to the absence of nitrogen that occupies the 78% of air. This study, therefore, investigates the heat and fluid flow in a regenerative system for pure oxygen combustion by using commercial CFD software, FLUENT. Our regenerative system is composed of aluminium packed spheres. The effect of the amount of packed spheres in regenerator and the effect of presence or absence of a bypass of exhaust gas are investigated. The more thermal mass in regenerator makes the steady-state time longer and temperature variation between heating and regenerating cycle smaller. In the case of absence of bypass, the regenerator saturates because of enthalpy imbalance between exhaust gas and oxygen. We find that 40% of exhaust gas is to be bypassed to prevent the saturation of regenerator.

Preparation and Permeation Characteristics of Modified Polydimethylsiloxane Membrane for Facilitated Oxygen Transport (Polydimethylsiloxane 계 촉진수송 산소부화막의 제조 및 그 투과 특성)

  • Shim, Jyong-Sup;Kim, Un-Young;Kang, Yong-Soo;Kim, Byung-Gi;Hong, Jae-Min
    • Applied Chemistry for Engineering
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    • v.1 no.2
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    • pp.140-146
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    • 1990
  • Polydimethylsiloxane(PDMS) containing [N, N'-bis (3- (salicylidene amino) propyl) amine Co(II)] (Co(saldpt)) as a fixed oxygen carrier was synthesized. UV-visible spectra of the membrane demonstrated that Co(saldpt) binded molecular oxygen specificaaly and reversibly. From time lag method experiment, it was found that both oxygen permeability and diffusibity increase with decreasing upstream pressure, while solubility maintain nearly constant. The maximum oxygen permeability and oxygen selectivity over nitrogen obtained was 18.6 barrer and 4, respectively, at 25 mmHg and $40^{\circ}C$ from the the PDMS membrane containing 1 wt% of Co(saldpt). Facilitation behavior was explained in terms of the dual sorption model.

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Optical and Structural Properties of TiO2 Thin Films Prepared at Various Oxygen Pressure by Electron-Beam Evaporation (산소 분압에 따라 전자빔 증착법으로 제작된 TiO2 박막의 구조적.광학적 특성)

  • Choi, Won-Seok;Kim, Jang-Seob;Jung, Jong-Min;Hahn, Sung-Hong;Kim, Eui-Jung;Lee, Chung-Woo;Joo, Jong-Hyun
    • Korean Journal of Optics and Photonics
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    • v.18 no.2
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    • pp.171-177
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    • 2007
  • We prepared $TiO_2$ thin films by electron-beam evaporation at various oxygen pressures, and investigated their optical and structural properties as a function of the annealing temperature. The physical properties of the $TiO_2$ thin films depend upon the injection oxygen content. With the increased injection of oxygen, the phase transformation temperature and the transmittance of $TiO_2$ thin films in the range of visible wavelength were increased. For low injection of oxygen, the absorption edges of $TiO_2$ thin films were more red-shifted when annealed at temperatures from $700^{\circ}C$ to $1100^{\circ}C$.

Analysis of the Characteristics of Flue Gas in Infrared Mobile Heaters for Gas Room Heating (가스난방용 적외선 히터의 연소배기가스 특성해석)

  • Kim Young-Gyu;Kwon Jeong-Rock;Kim Chung-Kyun
    • Journal of the Korean Institute of Gas
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    • v.2 no.1
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    • pp.66-73
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    • 1998
  • This paper deals with the combustion characteristics of flue gas in infared mobile heaters. The experimental work has been performed to obtain the concentration levels and combustion characteristics of flue gas with varying chamber size and room temperature. The experimental results showed that oxygen depletion sensor device was operated at the oxygen concentration level of $18.3\%$ for all the chamber size. The combustion characteristics of oxygen and carbon dioxide show a linearity After 10 minutes the combustion property of carbon monoxide occurs at random without a level of oxygen and carbon dioxide in closed space of the heater. In these results, it is very important to prevent incomplete combustion through a sufficient ventilation, and accident prevention with a reduction of the oxygen and diffusion of toxic carbon monoxide.

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Assessment of Conscious Coginition Degree and Survey on Oxyen Generators using the Indoor Environment (실내환경중의 산소발생기 사용에 대한 인식도 평가)

  • 손종렬;조윤수;이규현;황상용
    • Journal of environmental and Sanitary engineering
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    • v.18 no.4
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    • pp.64-69
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    • 2003
  • Recently, Indoor air quality(IAQ) in workplace, residential environments and office has been concern of people, scientists and related the public. The oxygen in air was very important and essential element in every aspect of life. This study was performed on a questionnaire survey of 400 people about their awareness of indoor air quality, oxygen generators and measured of oxygen concentration in indoor environment. The results obtained were as follows; As respondents are having their 90% of daytime indoors a day, and 80% of them can feel indoor air pollutions degrees directly by particle matters. The control of most important problems of IAQ was the poor ventilation. We know that 22% of the respondents was recognized the oxgen generator. And for the installation of indoor pollution control equipment, 20% of all respondents installed oxygen generators because almost respondents was not satified the trust of ability purified indoor air pollutants. In the experimental results, it was found that the oxygen concentration of sampling sites were in the range of 20~23.5%. Therefore, it was recommended that the government related IAQ was suggested the guideline and control of oxygen generators. Finally, it appeared that the oxygen generators using indoor environment can be applied to new technology for cleaning of indoor air.

Analysis of Components and Oxygen Consumption Rate for Zinc Concentrates in a Closed Chamber (아연정광의 성분분석 및 챔버내 산소소모량 평가)

  • Hae Dong Park;Eun Song Hwang
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.33 no.1
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    • pp.6-11
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    • 2023
  • Objective: This study was conducted to identify the cause of suffocation accident. Methods: We analyzed the components of zinc concentrates by ICP-OES (inductively coupled plasma optical emission spectroscopy) and tested the oxygen consumption by zinc concentrates in a 13.2-liter closed chamber. Results: Zinc, sulfur and iron were the main components of the four types of zinc concentrates, and accounted for 76~89% by weight. Zinc concentrates (0.5 or 0.927 kg) depleted the oxygen concentration from 20.9% to 7.4~18.9% during seven days. The rate of oxygen consumption was in the range of 3.0~11.0 mM/day·kg-sample at 21~24℃ and around 95% of free air space within the closed chamber. Conclusion: Since zinc concentrate consumes oxygen in a confined space, measures should be taken to prevent suffocation accident (such as ventilation and monitoring of oxygen concentration).