• Title/Summary/Keyword: oxygen transfer capacity

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N2O Decomposition Characteristics and Efficiency Enhancement of Rh/CeO2 Catalyst (Rh/CeO2 촉매의 N2O 분해반응 특성 및 효율증진 연구)

  • Nam, Ki Bok;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.29 no.5
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    • pp.541-548
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    • 2018
  • In this work, the $N_2O$ decomposition catalyst and reaction characteristics to control the $N_2O$ removal were described. Experiments were carried out by using Rh as an active metal catalyst on various supports and the $Rh/CeO_2$ catalyst with $CeO_2$ support showed the best activity for the $N_2O$ decomposition when it was prepared under the constant heat treatment condition ($500^{\circ}C$-4 hr). $H_2-TPR$ and XPS analyzes were performed to confirm the effect of the physical and chemical properties of the catalyst on $N_2O$ decomposition. As a result, it was found that the increase of the oxygen transfer capacity of the catalyst due to the increase of both the redox property and $Ce^{3+}$ amount affected the decomposition reaction of $N_2O$. In addition, the future work will include a treatment process capable of decomposition $N_2O$ and NO under the condition that $N_2O$ and NO are simultaneously generated and its characteristics of $N_2O$ decomposition reaction.

A Review on SEBS Block Copolymer based Anion Exchange Membranes for Water Electrolysis (SEBS 블록 공중합체를 기반으로 한 수전해용 음이온 교환막에 대한 총설)

  • Kim, Ji Eun;Park, Hyeonjung;Choi, Yong Woo;Lee, Jae Hun
    • Membrane Journal
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    • v.32 no.5
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    • pp.283-291
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    • 2022
  • Hydrogen energy has received much attention as a solution to the supply of renewable energy and to respond to climate change. Hydrogen is the most suitable candidate of storing unused electric power in a large-capacity long cycle. Among the technologies for producing hydrogen, water electrolysis is known as an eco-friendly hydrogen production technology that produces hydrogen without carbon dioxide generation by water splitting reaction. Membranes in water electrolysis system physically separate the anode and the cathode, but also prevent mixing of generated hydrogen and oxygen gases and facilitate ion transfer to complete circuit. In particular, the key to next-generation anion exchange membrane that can compensate for the shortcomings of conventional water electrolysis technologies is to develop high performance anion exchange membrane. Many studies are conducted to have high ion conductivity and excellent durability in an alkaline environment simultaneously, and various materials are being searched. In this review, we will discuss the research trends and points to move forward by looking at the research on anion exchange membranes based on commercial polystyrene-b-poly(ethylene-co-butylene)-b-polystyrene (SEBS) block copolymers.