• KSBB Journal
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• 제23권6호
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• pp.546-550
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• 2008

본 연구에서는 아스타잔틴의 각종 유기용매와 물에 대한 용해도와 산화, 빛, 온도 및 pH에 의한 아스타잔틴의 안정성을 검토하였다. 아스타잔틴은 유기용매인 아세톤과 아세트산에 비교적 용해도가 높았으며 물에는 거의 용해되지 않았다. 아스타잔틴의 용해도에 미치는 pH의 영향을 검토한 결과, 산성 조건 (pH 2)에서는 중성이나 염기성 조건에 비하여 용해도가 10-20배 증가하였다. 아스타잔틴은 산화와 빛에 대한 안정성이 매우 낮았으며, pH 3에서도 안정성이 급격히 떨어지는 것으로 조사되었다. 온도에 대한 영향을 조사한 결과, 상온 보관시에도 아스타잔틴이 쉽게 분해되었으며, 특히 $100^{\circ}C$에서 5초 동안 가열할 경우 아스타잔틴이 90% 이상 분해되었다. 결론적으로 아스타잔틴을 식품이나 화장품 등의 산업적 활용을 위해서는 안정성과 용해도 개선이 요구되는 것으로 판단되었다.

• Macromolecular Research
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• 제12권6호
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• pp.598-603
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• 2004

Cellulose nitrate (CN) composite membranes, containing cobalt porphyrin (CoP) complexes self-assembled within nanometer-sized rhenium clusters (ReCoP), have been prepared and their oxygen and nitrogen gas perme­abilities were analyzed. The solubility of ReCoP and the characteristics of the corresponding composite membranes were analyzed using a Cahn microbalance, FT-IR spectroscopy, wide-angle X-ray scattering, and differential scanning calorimetry. The nitrogen permeability through the CN composite membranes decreased upon addition of ReCoP and CoP, which implies that the presence of these oxygen carrier complexes affects the structure of the polymer matrix. The oxygen permeability through the composite membranes containing small quantities of ReCoP decreased, but it increased upon increasing the concentration. The oxygen gas transport was affected by the matrix at low ReCoP concentrations, but higher concentrations of ReCoP increased the oxygen permeability as a result of its reversible and specific interactions with oxygen, effectively realizing ReCoP carrier-mediated oxygen transport.

• 한국염색가공학회지
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• 제20권2호
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• pp.29-37
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• 2008

Polar amino groups of the waste SS(silk-sericin) were modified by two isocyanate compounds of MOI[2-(methacryloyloxy)ethyl isocyanate] and AOI [2-(acryloyloxy)ethyl isocyanate]. When the MOISS (MOI-modified silk sericin) or AOISS(AOI-modified silk sericin) was pressed hot, vinyl groups in the MOI or AOI were polymerized and then the flexible and transparent films were obtained. Tensile moduli and strengths of the MOISS films were significantly improved as the MOI contents increased. By the addition of the isocyanate compounds, silk sericin films exhibited lower solubility to the distilled water($80^{\circ}C$) and also lower swell ratio to the distilled water(room temperature). In the effect of tensile properties and restraining the water swelling, MOI was better than AOI. BOD(biochemical oxygen demand)/TOD(theoretical oxygen demand) of the pure sericin film was almost 100% perfect level after 10 days immersion into the activated sludge. With increasing isocyanate content reacted with polar amino groups, BOD/TOD decreased. When more than 50 mol% of polar amino groups remained unreacted, sericin films could retain more biodegradability. Comparing with MOI from the viewpoint of biodegradability, AOI was more effective.

• 자원리싸이클링
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• 제23권1호
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• pp.33-39
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• 2014

본 연구에서는 폐 PCB의 주성분인 Cu와 $CaO-SiO_2-Al_2O_3-MgO$계 슬래그의 평형실험에 의해 Cu의 용해도에 대하여 조사하였다. 1673 K~1825 K 범위에서 일정한 비율로 미리 용융된 4원계 슬래그와 Cu를 흑연 도가니에 각각 20 g 장입한 후, 10시간동안 평형 을 유지하였다. 분위기 중의 산소분압은 CO가스와 Ar가스의 비율을 조절하여 $10^{-17.23}{\sim}10^{-15.83}$ atm 범위로 제어하였다. 평형산소 분압과 염기도 및 MgO 농도가 증가할수록 슬래그 중 Cu의 농도는 증가하였다. 그리고 반응 온도가 높을수록 슬래그 중의 Cu의 농도는 감소하였다. 슬래그 중으로 용해되는 Cu의 반응은 발열반응이다.

• Journal of Pharmaceutical Investigation
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• 제28권2호
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• pp.121-126
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• 1998

The solubility and physicochemical stability of caroverine hydrochloride (CRV), an antispasmodic, in buffered aqueous solutions were studied using a reverse phase high performance liquid chromatography. The solubilty of the drug at pH 2.76-5.40 was similar at the range 31.9-36.2 mg/ml $(34^{circ}C)$, but, at the pH higher than 6.0, markedly decreased. The use of polyethylene glycol 400 as a cosolvent did not increase the solubility at any compositions examined. Moreover. increasing molar concentration of aqueous phosphate buffer from 0 to 0.5 M remarkably decreased the solubility. The degradation of CRY followed the apparent first-order kinetics. The degradation was accelerated with decreasing pH and increasing storage temperature. The half-lives for the degradation of CRY (1.0 mg/ml) at pH 1.28. 4.01 and 5.93 $(45^{\circ}C)$ were 2.8, 31.4 and 124 hr. respectively. The pHs of incubated solutions were to some extent lowered perhaps due to the formation of acidic degradation products. The addition of disodium edetate (0.01%) to the CRY solution (pH 4.95) retarded 2.5 times the degradation rate at $45^{\circ}C$, but the use of sodium bisulfite (0.1%) accelerated 2.9 times the rate. The activation energy for the CRY solution (20 mg/ml. pH 5.4) containing 0.01% EDTA was calculated to be 5.98 kcal/mole. When the solution was stored under nitrogen displacement in ampoule, there was no significant degradation even after 3 months at $40^{\circ}C$, indicating that protection from oxidation by air (oxygen) is essential for the complete stabilization of CRY solution.

• Journal of Electrochemical Science and Technology
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• 제4권2호
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• pp.71-80
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• 2013

The study of methyl viologen ($MV^{2+}$) mediated oxygen reduction in electrolytic ethanol media possesses potential application in the electrochemical synthesis of hydrogen peroxide mainly due to the advantages of the much increased solubility of molecular oxygen ($O_2$) and high degree of reversibility of $MV^{2+/{\bullet}+}$ redox couple. The diffusion coefficients of both $MV^{2+}$ and $O_2$ were investigated via electrochemical techniques. For the first time, $MV^{2+}$ mediated $O_2$ reduction in electrolytic ethanol solution has been proved to be feasible on both boron-doped diamond and micro-carbon disc electrodes. The electrocatalytic response is demonstrated to be due to the radical cation, $MV^{{\bullet}+}$. The homogeneous electron transfer step is suggested to be the rate determining step with a rate constant of $(1{\pm}0.1){\times}10^5M^{-1}s^{-1}$. With the aid of a simulation program describing the EC' mechanism, by increasing the concentration ratio of $MV^{2+}$ to $O_2$ electrochemical catalysis can be switched from a partial to a 'total catalysis' regime.

• Korean Chemical Engineering Research
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• 제55권4호
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• pp.530-534
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• 2017

Chitosan is a promising flocculant for microalgae harvesting, but its scale-up application is not economically supported yet. Low solubility of chitosan in microalgae suspension demands high dosage (as a flocculant) to destabilize the cells, and thus, increases the cost of microalgae harvesting. This study identifies efficient solvents for the chitosan, and optimizes the concentration of solvents and chitosan dose to improve the harvesting efficiency. Chitosan was dissolved in different acids, and subsequently used as a flocculant. The flocculant efficacy was measured in terms of harvesting efficiency and reduction in chemical oxygen demand (COD) of the microalgae suspension. It was found that chitosan dissolved in 0.05 M HCl showed the highest harvesting efficiency ($89{\pm}0.87%$) at only 30 mg/L of dosage. In comparison, 270 mg/L of $FeCl_3{\cdot}6H_2O$ was required to attain $86{\pm}0.083%$ of the harvesting efficiency. $H_2SO_4$ dissolved chitosan required high flocculant dose (150 mg/L) and resulted in relatively low harvesting efficiency ($77{\pm}0.11%$). It was concluded that the efficacy of chitosan is solvent dependent, and the selection of proper solvent can decrease the dosage requirement for microalgae harvesting.

• 한국재료학회지
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• 제24권2호
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• pp.81-86
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• 2014

The nitrogen solubility and nitride capacity of $CaO-SiO_2-Al_2O_3-MgO-CaF_2$ slag systems were measured by using gas-liquid equilibration at 1773K. The nitrogen solubility of this slag system decreased with increasing CO partial pressure, with the linear relationship between nitrogen contents and oxygen partial pressure being -3/4. This system was expected to show two types of nitride solution behavior. First, the nitrogen solubility decreased to a minimum value and then increased with the increase of CaO contents. These mechanisms were explained by considering that nitrogen can dissolve into slags as "free nitride" at high basicities and as "incorporated nitride" within the network at low basicities. Also, the basicity of slag and nitride capacity were explained by using optical basicity. The nitrogen contents exhibited temperature dependence, showing an increase in nitrogen contents with increasing temperature.

• 대한가정학회지
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• 제25권1호
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• pp.43-50
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• 1987

Non-durable flame retardant finish, borax/boric acid mixed solution, was applied to cotton fabric with pad-dry method. The LOI(limited oxygen index) was measured as the measare of the flame retardant effect. The TGA was investigated to know the thermal behavior of the samples. In addition, the solubility of the solutions was investigated. The results were as follows: 1) There was a synergism of flame retardant effect in the borax/boric acid mixed solution treatment and the maximum synergism was shown around the ratio of 7 : 3 2) After the borax/boric acid solution treatment, the degradation temperature was lowered and degraded at the larger temp range with slower rate. The residual char length also increased. 3) The solubility of borax/boric acid become higher when the ratio of borax/boric acid became similar. Compositions from 80/20 to 40/60 borax/boric acid mixtures were solubilized well in room temperatuare or warmwater therefor there was no problem for home use.

• 한국세라믹학회지
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• 제51권4호
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• pp.312-316
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• 2014

The joining behavior of forsterite ceramics to SUS304 alloy using $8PbO-78Bi_2O_3-8B_2O_3-4ZnO-2SiO_2$ (wt%) system glass frit was investigated. The contact angle was smaller than $90^{\circ}$ at a temperature of $460^{\circ}C$. Redox reaction at the interface between forsterite and SUS304 was found to appear when the electrons in the metal part moved toward the glass part and the oxygen ions in glass moved to the metal side. The decrease of the surface tension due to the PbO solubility on the forsterite side contributed to the better wetting behavior at low temperature.