• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2003.11a
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• pp.51-55
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• 2003

The thermal behavior of NiFe$_2$O$_4$ prepared by a solid-state reaction was investigated for H$_2$ generation by the thermochemical cycle. The reduction of NiFe$_2$O$_4$ started from 800 $^{\circ}C$, and the weight loss was 0.2-0.3 wt％ up to 1000 $^{\circ}C$. At this reaction, NiFe$_2$O$_4$ was reduced by release of oxygen bonded with the Fe$^3$ion in the B site of NiFe$_2$O$_4$. In the $H_2O$ decomposition reaction, H$_2$ was generated by oxidation of reduced NiFe$_2$O$_4$. The crystal structure of NiFe$_2$O$_4$ for redox reaction maintained spinel structure. Then, NiFe$_2$O$_4$ is excellent material in the thermochemical cyclic reaction due to release oxygen at low temperature for the reduction reaction and produce H$_2$ maintaining crystal structure for redox reaction.

• Korean Journal of Metals and Materials
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• v.50 no.11
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• pp.823-828
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• 2012

Direct reduction of $Ta_2O_5$ using liquid calcium was investigated. The experiment was conducted in a closed stainless steel chamber in an Ar atmosphere for 5-120 minutes. Most of $Ta_2O_5$ was reduced to ${\alpha}-Ta$ in 30 minutes above 1173 K and at a molar ratio of Ca and $Ta_2O_5$ above 10. The particles size increased with the reaction temperature, but it did not change much above 1223 K. The oxygen content of metal Ta was about 1 wt%.

• 한국신재생에너지학회:학술대회논문집
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• 2009.11a
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• pp.252-252
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• 2009

• Korean Chemical Engineering Research
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• v.50 no.5
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• pp.843-849
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• 2012

When we use NiO based particle as an oxygen carrier in a chemical looping combustion system, the fuel conversion and the $CO_2$ selectivity decreased with increasing reaction temperature within high temperature range (> $900^{\circ}C$) due to the increment of exhaust CO concentration from reduction reactor. To improve reduction reactivity at high temperature, the applicable metal oxide component was selected by calculation of the equilibrium CO concentration of metal oxide components. After that, feasibility of reduction reactivity improvement at high temperature was checked by using solid mixture of the selected metal oxide particle and NiO based oxygen carrier. The reactivity was measured and investigated using batch type fluidized bed. The solid mixture of $Co_3O_4/CoAl_2O_4$(10%) and OCN706-1100(90%) showed higher fuel conversion, higher $CO_2$ selectivity and lower CO concentration than OCN706-1100(100%) cases. Consequently, we could conclude that improvement of reduction reactivity at high temperature range by adding some $Co_3O_4$ based oxygen carrier was feasible.

• Proceedings of the Korean Vacuum Society Conference
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• 2013.08a
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• pp.128.2-128.2
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• 2013

Crucially, effective catalysts must be capable of efficiently catalyzing the protonation of adsorbed CO to adsorbed CHO or COH. One of the strategies is alloying with metals with higher oxygen affinity and Au-Zn alloy is one of the best candidates. At first, we made Au-Zn alloy using vacuum evaporating method. Zn was deposited on the Au(211) surface and the amount was estimated by X-ray photoelectron spectroscopy (XPS) using the relative sensitivity of Au 4f and Zn 3d. We investigated CO adsorption on a clean Au(211) and Au-Zn alloy using temperature-programmed desorption (TPD) and XPS. From the TPD results, we can conclude that the presence of the particular step sites at the Au(211) surface imparts stronger CO bonding and Zn atoms are sitting on the step sites at the Au(211) when Zn is deposited. The XPS results show the oxygen atoms of CO bond Zn atoms on Au-Zn surface. It should be an evidence that alloying Zn atoms that has high oxygen affinity into an electrocatalyst may allow CHO* to bind to the surface through both the carbon and oxygen atoms.

• Korean Chemical Engineering Research
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• v.60 no.3
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• pp.459-467
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• 2022

Redispersion of Pt-Sn particles in Pt, PtSn catalyst which have been sintered by high temperature hydrogen reduction was investigated using oxygen treatment with various temperatures. The aim of this study was to understand the relationship between the catalytic activity for propane dehydrogenation reaction and the change in the physicochemical properties of the catalyst. X-ray diffraction analysis (XRD), CO pulse chemisorption, and H₂ temperature programmed reduction (H₂-TPR) were performed to investigate the state of active metal and interactions between particles of redispersed catalyst. It was confirmed that the dispersion and particle size of platinum, the crystal phase of the catalyst, and the reduction behavior were changed according to the oxygen treatment. As for the catalytic activity in propane dehydrogeantion, sintered PtSn catalyst treated with oxygen at 500 ℃ showed best activity and recovery of initial activity. It was confirm that catalyst after oxygen treatment at 500 ℃ showed high dispersion of Pt and decreased particle size as the results of CO pulse chemisorption and XRD of catalyst, and thus the redispersion of PtSn particles in sintered catalyst was occurred. Catalytic activity was recovered due to redispersion using oxygen treatment, and the activity recovery of the PtSn catalyst was higher than that of Pt catalyst.

• Proceedings of the Korean Society of Food Hygiene and Safety Conference
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• 2002.05a
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• pp.138-138
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• 2002

Oxidative stress has been associated with a number of diseases in human. Among the sources that can generate oxidative stress, it has been reported that iron can generate reactive oxygen species (ROS)with thiol. In iron overload state, increased thiol levels in plasma appeared to be associated with human mortality. In this study we examined whether iron could interact with thiols in plasma, generating ROS. In human plasma, unlike with Fe(III), Fe(II) increased lucigenin-enhanced chemiluminescence in concentration-dependent manner, and this was inhibited by SOD. Boiling of plasma did not affect chemiluminescence induced by Fe(II). Hovever, thiol depletion in plasma by pretreatment with N-ethylmaleimide (NEM)decreased Fe(II)-induced chemiluminescence significantly, suggesting that Fe(II) generated superoxide anion by the nonenzymatic reaction with plasma thiol. Consistent with this findings, albumin, the major thiol contributor in plasma, also generated ROS with Fe(II) and this generation was inhibited by pretreatment with NEM. Treatment with Fe(II) to plasma resulted un significant reduction of oxygen radical absorbance capacity (ORAC) value, suggest that total antioxidant capacity could diminished in iron overload state. In conclusion, In iron overload state, plasma may be affected by oxidative stress mediated by nonenzymatic reaction of Fe (II)with plasma thiol.

• Food Engineering Progress
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• v.14 no.3
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• pp.202-207
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• 2010

Low-pressure plasmas (LPPs) were generated with different gases such as air, oxygen and nitrogen, and their inactivation effects against Escherichia coli were compared in order to evaluate the potential as a non-thermal microbial disinfection technology. Homogeneous plasmas were generated under low pressure below 1 Torr at gas flow rate of 350 mL/min regardless the types of gases. Temperature increases by LPPs were not detrimental showing less than ${10^{\circ}C}$ and ${25^{\circ}C}$ increases after 5 and 10 min treatments, respectively. The smallest temperature increase was observed with air LPP, and followed by oxygen and nitrogen LPPs. More than 5 log reduction in E. coli was achieved by 5 min LPP treatment but the destruction effect was retarded afterward. The LPP inactivation was represented by a iphasic first order reaction kinetics. The highest inactivation rate constant was achieved in air LPP and followed by oxygen and nitrogen LPPs. The small D-values of the LPP also supported its potentialities as a non-thermal food surface disinfection technology in addition to the substantial microbial reduction of more than 5 logs.

• Clean Technology
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• v.24 no.4
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• pp.307-314
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• 2018

In this study, NMO (Natural Manganese Ore), $MnO_2$, and $Mn_2O_3$ catalysts were used in the selective catalytic reduction process to remove nitrogen oxides (NOx) using $NH_3$ as a reducing agent at low temperatures in the presence of oxygen. In the case of the NMO (Natural Manganese Ore), it was confirmed that the conversion of nitrogen oxides in the stability test did not change even after 100 hours at 423 K. The Kinetics experiments were carried out within the range where heat and mass transfer were not factors. From a steady-state Kinetics study, it was found that the low-temperature SCR reaction was zero order with the respect to $NH_3$ and 0.41 ~ 0.57 order with the respect to NO and 0.13 ~ 0.26 order with the respect to $O_2$. As temperature increases, the reaction order decreases as a result of $NH_3$ and oxygen concentration. It was confirmed that the reaction between the $NH_3$ dissociated and adsorbedon the catalyst surface and the gaseous nitrogen monoxide (E-R model) and the reaction with the adsorbed nitrogen monoxide (L-H model) occur.

• Corrosion Science and Technology
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• v.6 no.6
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• pp.304-307
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• 2007

As to the reflection electrode of LCD (liquid crystal displays), silver-copper-gold alloy (hereafter, it is called as ACA (Ag98%, Cu1%, Au1%)) is an effective material of which weathering resistance can be improved more compared with pure silver. However, there is a problem that gold remains on the substrate as residues when ACA is etched in cerium ammonium nitrate solution or phosphoric acid. Gold can not be etched in these etchants as readily as the other two alloying elements. Gold residue has actually been removed physically by brushing etc. This procedure causes damage to the display elements. Another etchant of iodine/potassium iodide generally known as one of the gold etchants can not give precise etch pattern because of remarkable difference in etching rates among silver, copper and gold. The purpose of this research is to obtain a practical etchant for ACA alloy. The results are as follows. The cyanogen complex salt of gold generates when cyanide is used as the etchant, in which gold dissolves considerably. Oxygen reduction is important as the cathodic reaction in the dissolution of gold. A new etchant of sodium cyanide / potassium ferricyanide whose cathodic reduction is stronger than oxygen, can give precise etch patterns in ACA alloy swiftly at room temperature.