• Bulletin of the Korean Chemical Society
• /
• v.23 no.6
• /
• pp.799-803
• /
• 2002

Partial oxidation of methane has been conducted over $CeO_2$and it has been found that $CeO_2$has an extraordinary catalytic activity in the reaction. Its activity was strongly dependent on the $CH_4/CO_2$ ratio. Total combustion was dominant with stoichiometric feed ratio$(CH_4/O_2=$ 2.0) but partial oxidation was achieved between the $CH_4/O_2$ ration of 3.8 4.3 and the period depended upon the feed composition. The proposed raaction mechanism it that oxygen vacancies in raduced deria are supplied with oxygen molecules from the reactant, and then activate adsorbed oxygen, followed by releasing activated axygen species reacting with methane to produce $H_2$ and CO.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.17 no.4
• /
• pp.422-425
• /
• 2004

In this study, the AZO thin films were prepared as a function of oxygen gas flow ratio at room temperature by FTS(Facing Targets Sputtering) apparatus using Zn:Al(metal)-Zn:Al(metal) or Zn(metal)-ZnO:Al(ceramic). The film thickness, crystalline and electric properties of AZO thin film was evaluated by $\alpha$-step, XRD and 4-point probe. In the results, the resistivity of AZO thin film was shown the lowest value about 8${\times}$10$^{-2}$ $\Omega$-cm(Zn:Al-Zn:Al), 3${\times}$10$^{-1}$ $\Omega$-cm(Zn-ZnO:Al) at the oxygen gas flow ratio 0.3. And the AZO thin film has good crystalline at oxygen gas flow ration 0.4, using Zn:Al-Zn:Al targets.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2003.05c
• /
• pp.131-135
• /
• 2003

Zinc Oxide(ZnO) thin films on Si (100) substrate were deposited by RF magnetron sputter with changing sputtering conditions such as argon/oxygen gas ratios, RF power, and substrate temperature, chamber pressure and target-substrate distance. To analyze a crystallographic properties of the films, $\theta/2\theta$ mode X-ray diffraction, SEM, and AFM analyses. C-axis preferred orientation, resistivity, and surface roughness highly depended on $Ar/O_2$ gas ratios. The resistivity of ZnO thin films rapidly increased with increasing oxygen ratio and the resistivity value of $9{\times}10^7{\Omega}cm$ was obtained at a working pressure of 10 mTorr with $Ar/O_2$=50/50. The surface roughness was also improved with increasing oxygen ratio and the ZnO films deposited with $Ar/O_2$=50/50 showed the excellent roughness value of $28.7{\AA}$.

• Korean Journal of Food Science and Technology
• /
• v.30 no.2
• /
• pp.434-438
• /
• 1998

The antioxidant effects of 700 ppm ginseng extract, 100ppm caffeic acid, ferulic acid, vanillic acid, or ${\alpha}-topherol$ on the 1% linoleic acid aqueous buffer system was studied by measuring malondialdehyde (MDA) and headspace oxygen. The compounds showed antioxidant activities in the following order: $caffeic\;acid{\geq}ferulic\;acid\;>\;{\alpha}-tocopherol$>ginseng extract>vanillic acid, with the oxidation inhibition ratio of 63.5, 62.9, 52.3, 51.2 and 5.6% of the control according to MDA results. The mixture of 100 ppm caffeic acid, 100 ppm ${\alpha}-tocopherol$ and 700 ppm ginseng extract had a high oxidation inhibition ratio of 91.2%. Headspace oxygen results had a similar trend with the MDA results. Headspace oxygen results showed that the antioxidant activities were in order of ferulic acid>caffeic acid>${\alpha}-tocopherol$>ginseng extract>vanillic acid and headspace oxygen contents were 18.56, 17.78, 17.17, 16.65 and 15.95%, respectively.

• Journal of Photoscience
• /
• v.2 no.2
• /
• pp.77-81
• /
• 1995

Photoreactions of pseudosaccharin ethers have been investigated. Pseudosaccharin 3-allyl ether undergoes a facile photoreaction via reaction pathways involving homolysis of bond between pseudosaccharyl oxygen and 3-allyl carbon, and excited nucleophilic substitution of allyloxy group by solvent which are not quenched by oxygen present in the reaction. Product yield demonstrates that the homolysis pathway predominates over the nucleophilic substitution in ca. 7:1 ratio. In contrast, pseudosaccharin alkyl ethers follow different reaction routes to produce two products, solvent-substituted pseudosaccharin alkyl ethers and reduction products, 3-alkoxy-1, 2-benzisothiazoles. The formations of reduction products, 3-alkoxy-1, 2-benzisothiazoles are completely quenched by oxygen.

• 수도
• /
• s.50
• /
• pp.20-25
• /
• 1989

Water quality of river is greatly influenced by sediments of planktons, suspended solids and organic matters being transported by efflenced. The water quality is also affected by their release at the place of sediments with slow flow of water. This paper deals with the Characteristics of Oxygen consumption of sediments in small river which is greatly vary with time. Some typical samples of sediment were taken from both aerobic and anaerobic condition reserved for several months. and, the samples of sediment were checked on the relative ratio of oxygen consumption by nitrification.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.2 no.2
• /
• pp.49-58
• /
• 1994

A study on the performance of a Diesel engine with various intake gas compositions other than that of air are performed experimentally. In this study, the concentrations of each of oxygen, nitorgen, carbon dioxide, and argon are changed and their effects on the performance of the engine are investigated parametrically. The experiments are performed at constant engine speed condition, and main measured parameters are cylinder pressure, intake gas compositions, fuel consumption rate. Increase of oxygen concentration up to 24% improved the performance of the engine generally. The adverse effect was observed when the oxygen concentration was increased over 24%. Increase of carbon dioxide concentration degraded the performance of the engine, mainly due to the lower specific heat ratio of carbon dioxide. Adding argon gas to the intake gas improved the overall performance. Finally, it is found that two most influencing factors affecting the performance of the Diesel engine in this study of intake gas composition variation are ignition delay and specific heat ratio of the intake gas.

• Journal of the Korean Ceramic Society
• /
• v.41 no.2
• /
• pp.106-110
• /
• 2004

Nickel oxide (NiO) thin films were prepared on Si(100) substrates at room temperature by RF magnetron sputtering using a NiO target. The effects of oxygen flow ratio for the plasma gas on the preferred orientation and surface morphology of the NiO films were investigated. Highly crystalline NiO film with (100) orientation was obtained when it was deposited in pure Ar gas. For NiO film deposited in pure O$_2$ gas, on the other hand, the orientation of the film changed from (100) to (111) and its deposition rate decreased. The origin of the preferred orientation of the films was discussed. NiO films also showed different surface morphologies and roughnesses with the oxygen flow ratio.

• Transactions of the Korean hydrogen and new energy society
• /
• v.21 no.1
• /
• pp.42-49
• /
• 2010

Increasing environmental concerns regarding the use of fossil fuels and global wanning have prompted researcher to investigate alternative fuels. The purpose of this study is to investigate the syngas production by biogas reforming using a compression spark ignition engine. The parametric screening studies were carried out according to the variations of oxygen enrichment rate, biogas $CO_2$ ratio, intake gas temperature, and engine revolution. When the oxygen enrichment rate and input gas temperature increased, hydrogen and carbon monoxide were increased. But the biogas $CO_2$ ratio and engine revolution increased, the syngas were reduced. For the reforming of methane 100% only, generation of hydrogen and carbon monoxide was 58% and 17%, respectively. However when the biogas $CO_2$ ratio was 40%, hydrogen and carbon monoxide concentration were about 20% each.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2017.05a
• /
• pp.803-810
• /
• 2017

the liquid oxygen transitions to a supercritical state, causing rapid changes in properties and pseudo boiling in supercritical combustion. the combustion reaction operating in a supercritical state depends on the turbulence diffusion caused by difference of density, therefore, a study of the diffusion flow and pseudo boiling is required. Many researchers have studied these phenomena in the supercritical combustion, but A case study by various variables is inadequate. In this study, the flow field and flame structure were investigated numerically by changing the recirculation flow and liquid oxygen core length through oxygen-fuel ratio(O/F), combustor diameter and recess ratio at supercritical pressure condition.