• 제목/요약/키워드: oxygen gas

검색결과 2,287건 처리시간 0.032초

고온 배기가스의 산소농도가 비예혼합화염의 NOx 발생에 미치는 영향 (Effects of Oxygen Concentration on the NOx Emission of Non-premixed Flame in Hot Exhaust Gas)

  • 손화승;김호영
    • 대한기계학회논문집B
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    • 제26권6호
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    • pp.833-841
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    • 2002
  • The present study examined the possibility of NOx reduction in the high temperature industrial furnaces, duct burner of gas turbine cogeneration and two-stage gas turbine combustor. The experimental study was carried out for the non-premixed flame of second stage combustor with the variations of oxygen concentration in the hot exhaust gas of first stage combustor. It also examined the flammability range, temperature and NOx, $CO_2$, $O_2$formation in the combustor with respect to oxygen concentration in which the fuel(natural gas) is supplying into the hot exhaust gas. The results show that the inner temperature of flame reaches 1,20$0^{\circ}C$ at EGR $O_2$23% and that 15ppm of NOx at EGR $O_2$15.5% increases up to 60ppm at EGR $O_2$23%. It is believed that Fenimore's prompt NOx mechanism is more influential on the NOx formation than Zeldovich's thermal NOx mechanism does.

FGR 시스템 보일러의 배기 배출물에 미치는 재순환 배기의 영향 (Effect of Recirculated Exhaust Gas on Exhaust Emissions of Boiler with FGR System)

  • 배명환;김정민;김이석;조용수;최승철
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.390-395
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    • 2003
  • The effect of recirculated exhaust gas on exhaust emissions under four kinds of nozzle tip with the different fuel consumption rate are experimentally investigated by using an once-through boiler with FGR system. The purpose of this study is to develop the FGR control system for reducing NOx in a boiler. Intake and exhaust oxygen concentrations, and equivalence ratio are applied to discuss the effect of FGR rate on exhaust emissions at various fuel consumption rates. It is found that NOx emissions are decreased, while soot emissions are increased owing to the drop of intake and exhaust oxygen concentrations, and the rise of equivalence ratio as FGR rates are elevated.

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DC Electrical Current Behavior of Calcia Doped Zirconia Under Various Oxygen Containing Gases

  • Lee, Joo-Sin;Park, Tae-Woon
    • The Korean Journal of Ceramics
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    • 제3권1호
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    • pp.37-42
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    • 1997
  • The DC current variation of calcia doped zirconia single crystal was measured under various oxygen containing gases at high temperatures. The DC current was influenced by the gas species for oxygen activity establishment. Also, strong non-ohmic characteristics were observed in the $CO/CO_2/N_2$ gas mixtures. Based on the experimental data obtained by introducing the non-buffering gas $N_2$ into the $CO/CO_2$ mixtures, the processes occurring at the gas/solid interface during a defect relaxation process are discussed.

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산소중독시 가토의 [A-a] gas Gradient 의 변화 (Changes of [A-a] gas Gradient in Rabbits with Oxygen Toxicity)

  • 이두연
    • Journal of Chest Surgery
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    • 제20권1호
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    • pp.1-12
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    • 1987
  • Respiratory care with oxygen inhalation is often a necessity to maintain life, and it is one of the important therapeutic adjuncts in respiratory disease and in intensive care after surgery. However, it has been reported that oxygen toxicity occurs after prolonged exposure to 100% 0, [Smith, 1899; Kistler et al. 1967; Schaffner et al. 1967; Rowland and Newman, 1969. Subjective symptoms of oxygen toxicity include tracheal irritation, frequent cough, some burning sensation in the trachea, tachypnea, severe dyspnea, etc. [Welch, 1963; Fisher et al, 1968; Milier et al, 1970; Clark and Lambertsen, 1971; Sackner, 1975]. Pathologic findings are atelectasis, injuries to the pulmonary capillaries and hemorrhage in the alveoli in gross specimens. There can be inflammation, proliferation of fibrin, thickening of alveolar membranes, degeneration of collagen fibers and interstitial edema in the microscopic findings. [Penrod, 1956; Cedergren, 1959; Bean, 1965; Schaffner, 1967]. Dubois and colleagues [1961] found that the amount of pulmonary surfactant was decreased in oxygen toxicity and atelectasis followed by the decreased pulmonary surfactant. Many authors reported that vital capacity, inspiratory force, pulmonary compliance, pulmonary capillary blood flow and pulmonary elasticity were deceased and arteriovenous shunting increased. [Comroe et al, 1945; Fuson et al, 1965; Kistler et al, 1966; Knowles and Blenner-hassett, 1967; Barber et al, 1978]. Many human volunteers were examined after prolonged exposure in a high oxygenated chamber and there were a few reports on animals with oxygen toxicity, subjects including rabbits. Gas partial pressures of alveoli and arteries were measured in rabbits exposed to 100% $O_2$ and the alveolar-arterial gas gradients were analyzed, which is the basis for the study of oxygen toxicity. These rabbits were divided into two groups; rabbits under natural respiration, and second group under artificial respiration with a respirator. The alveolar $PO_2$ [$P]AO_2$] and $PCO_2$ [$PACO_2$], and the arterial $PO_2$ [$PaO_2$] were measured under varying $O_2$ pressures; 15% $O_2$, 21% $O_2$ and 100% $O_2$.

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친환경 소재에 대한 플라즈마 가공과 효소가공이 감량률에 미치는 영향 (The Effect of the Enzyme Treatment and the Plasma Pre- Treatment on Environment Friendly Fabrics)

  • 김지현
    • 한국의상디자인학회지
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    • 제11권1호
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    • pp.43-51
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    • 2009
  • The cotton, wool, cotton/wool blended(80:20) and tencel fabrics were treated with low temperature oxygen or argon plasma, enzymes(cellulase or protease), or oxygen plasma-enzyme and examined for their weight loss and conditions for treatment for the environment friendly finishing. In the plasma treatment argon gas had better effect on the weight loss than oxygen gas did and the weight loss of all the fabrics was increased as increasing discharge power and discharge time. The weight loss of cotton, wool, cotton/wool blended(80:20) fabrics decreased in a large measure after 1 hr but that of tencel didn't decrease after 1 hr. In case of cellulose fibers oxygen gas plasma induced chemical functional groups on the surface of substrate more than argon gas plasma did so the weight loss of wool was larger than that of cotton, tencel fabrics in oxygen plasma-enzyme treatment. The weight loss of cotton and tencel fabrics decreased the initial stage because oxygen plasma pre-treatment caused cross linking as well as etching effect but argon plasma pre-treatment didn't. The plasma pre-treatment cleared the way for enzyme treatment on the whole but oxygen plasma pre-treatment bear in hand the increase of weight loss more or less because of the cross linking on the surface of cellulose fibers. The appropriate conditions for plasma treatment was 10-1Torr, 40W for 30minutes and for cellulase treatment were enzyme concentration of $3g/{\ell}$, pH 5, $60^{\circ}C$ for 1hr and for protease treatment were enzyme concentration of $4g/{\ell}$ pH 8, $60^{\circ}C$ for 1hr.

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The Fate of Aspen Extractives in Kraft Pulping and Oxygen Delignification

  • Shin, Soo-Jeong;Lai, Yuan-Zong
    • 펄프종이기술
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    • 제37권3호
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    • pp.74-80
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    • 2005
  • The compositions of residual extractives in woodmeal, unbleached and oxygen-delignified aspen kraft pulps were investigated with gas chromatography(GC) and gas chromatography-mass spectrometry (GC-MS) with focus on fate of extractives in kraft pulping and oxygen delignification. Steryl esters and shorter retention time (shorter than palmitic acid) extractives were main extractives in aspen woodmeal. Shorter retention time extractives were well removed in kraft pulping. Sterol esters were hydrolyzed to sterols and fatty acids. Sterols and fatty acids were two major extractives classes in unbleached kraft pulps. Linoleic acid was main fatty acids in unbleached pulps compared with palmitic acid which is generally found in aspen woodmeal. Sterolsand fatty acids were also two major extractives classes in oxygen-delignified kraft pulps. However, linoleic acid was well removed in oxygen delignification.

산소부화화염의 희석방법에 따른 화염특성 변화 (Variation of oxygen-enriched flame characteristics with dilution method)

  • 한지웅;이창언
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.332-337
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    • 2003
  • Oxygen-enriched non-premixed flame characteristics was investigated numerically with variation of dilution methods, which are Flue gas recirculation(FGR) and fuel injection recirculation(FIR). In order to compare flamelets in various oxygen-enrichment conditions reasonably, the adiabatic flame temperature and Damkoller number was held fixed by modulating amount of diluents to fuel and oxidizer stream and by varying global strain rate of flame respectively. Also modified GRI 3.0 reaction mechanism was utilized, which was able to predict oxygen-enriched methane flame correctly. Fundamental flame characteristics such as structure, heat release rate and extinction with FGR and FIR were compared in various oxygen enrichment conditions.

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선회 확산버너에서 산소부화가 연소장에 미치는 영향 (Effect of Oxygen Enrichment in a Swirling Diffusion Gas Burner)

  • 이용후;이진석;이우섭;이도형
    • 한국연소학회지
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    • 제7권2호
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    • pp.34-41
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    • 2002
  • To investigate the combustion characteristics of a swirling diffusion gas burner with oxygen enrichment, mean temperature, CO, $CO_2$, and HC concentrations were measured at various oxygen enrichment conditions. According to the results, the flame temperature increased and the region of high temperature was expanded with increasing oxygen concentration. The $CO_2$ concentrations increased, while the CO concentrations decreased in proportion to the increase of oxygen concentration. On the other hand, the HC concentrations were decreased and this tendency was very strong at the downstream of the combustor.

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Role of oxygen in plasma induced chemical reactions in solution

  • Ki, Se Hoon;Uhm, Han Sup;Kim, Minsu;Baik, Ku Youn;Choi, Eun Ha
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.208.2-208.2
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    • 2016
  • Many researchers have paid attention to the studies on the interaction between non-thermal plasma and aqueous solutions for biomedical applications. The gas composition in the plasma is very important. Oxygen and nitrogen are the main gases of interest in biological applications. Especially, we focus on the oxygen concentration. In this experiment, we studied the role of oxygen concentration in plasma induced chemical reactions in solution. At first, the amount of ions are measured according to changing the oxygen concentration. And we checked the relationship between these ions and pH value. Secondly, when the oxygen concentration is changed, it identified the type and amount of radical generated by the plasma. In order to confirm the effect of these chemical property change to biological material, hemoglobin and RBCs are chosen. RBCs are one of the common basic biological cells. Thirdly, when plasma treated according to oxygen concentration in nitrogen feeding gas, oxidation of hemoglobin and RBC is checked. Finally, membrane oxidation of RBC is measured to examine the relation between hemoglobin oxidation and membrane damage through relative hemolysis and Young's modulus. Our results suggest that reactive species generated by the plasma differsdepending on the oxygen concentration changes. The pH values are decreased when oxygen concentration increased. OH decrease and NO increase are also observed. These reactive species makes change of chemical properties of solution. We also able to confirm that the difference in these reactive species to affect the oxidation of the Hb and RBCs. The Hb and RBCs are more oxidized with the high oxygen concentration conditions. But membrane is damaged more by plasma treatment with only nitrogen gas. It is shown that red blood cells membrane damage and oxidation of hemoglobin are not directly related.

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Off-gas Column Test를 이용한 하수처리장 심층포기시스템의 산소전달 매개변수(α와 F)의 산정 (Evaluation of the Oxygen Transfer Parameters (α and F) of a Coarse Bubble Aeration System by Off-gas Column Test)

  • 김철웅;임세호;신동록;이지영;박재한;안윤희;고광백
    • 한국물환경학회지
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    • 제22권6호
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    • pp.1119-1122
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    • 2006
  • Aeration by using diffusers usually requires approximately 50~90% of the total electricity needed to operate WWTP (WasteWater Treatment Plant)s. Accurate evaluation of the oxygen transfer efficiency for an aeration system, and recommendation of a better alternative may help saving WWTP operational costs. Appropriate techniques and methods to achieve this purpose have not been introduced in Korea. In this study, in-process analysis was performed for a coarse bubble aeration system by the off-gas method to evaluate its applicability in Korea. To accomplish this analysis, an off-gas test, unsteady-state clean water test and steady-state off-gas column test was conducted and comparisons to other aeration systems were made. The ${\alpha}$ and the F estimated from the results of the unsteady-state clean water test and the steady-state off-gas column test were 0.61 and 0.90 respectively in a coarse bubble aeration system. The comparison of P.E tube diffusers laid out single spiral roll and ceramic dome diffusers laid out full floor coverage showed that the oxygen transfer efficiency of the coarse bubble aeration system was less than or similar to other aeration systems. But, airflow rates per unit area were 4~5 times greater than other aeration systems. In regards to the oxygen transfer efficiency for airflow rates per unit area, a retrofit to higher efficiency diffusers was urgently needed. This study showed proved that off-gas methods can apply to evaluate diffuser performances to estimate operating factors and to compare other aeration systems in Korea.