• Title/Summary/Keyword: oxygen gas

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Curing Properties of UV-LED Curable Color Coating (UV-LED 경화형 칼라 코팅의 경화특성 연구)

  • Ho, Shin-Chan;Kim, Jong-Gu;Hong, Jin-Who;Ahn, Tae-Jung;Kim, Hyun-Kyoung
    • Journal of Adhesion and Interface
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    • v.13 no.1
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    • pp.31-37
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    • 2012
  • In this study, we investigated the curing properties of UV-LED curable color coating. Specially, the effects of UV-LED wavelength (365, 395, and 405 nm), inert gas, the concentration of photosensitizer, and dual curing on the curing behavior of UV-LED coating systems were studied. The photopolymerization behaviors and the unreacted acrylate groups at Film-air (FA) interface and Film-substrate (FS) interface were investigated by photo differential scanning calorimetry (Photo-DSC) and Fourier-transform infrared spectroscopy with attenuated total reflection (FT-IR/ATR), respectively. Photo-DSC results showed that the heat flow and the ultimate conversion for coating system cured by 405 nm UV-LED were higher than the corresponding values for coating systems cured by 395 and 365 nm UV-LED. FT-IR/ATR results showed that the UV-LED curing systems improved interior and through curing of the coating film, but significantly are affected by oxygen inhibition at FA-interface. The inert environment such as nitrogen purging and the dual curing improved the surface and interior curing of the coating films.

Effects of Heat Pretreatment on the Quality under Storage of Fresh Ginger Rhizomes (저장 전 열처리가 생강의 이화학적 및 관능적 특성에 미치는 영향)

  • Chung, Hun-Sik;Lee, Hyeon-Jeong;Seong, Jong-Hwan;Moon, Kwang-Deog
    • Food Science and Preservation
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    • v.16 no.5
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    • pp.623-628
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    • 2009
  • Fresh ginger rhizomes were heat-treated for 10 min, 30 min, or 60 min using hot air ($40^{\circ}C$, $50^{\circ}C$, or $60^{\circ}C$), and stored in low-density polyethylene (0.04 mm thickness) bags for 2 months at $12{\pm}1^{\circ}C$. We studied the effects of heat pretreatment on changes in gas levels after packaging, and quality characteristics of the rhizomes. Oxygen and carbon dioxide levels progressively fell and rose, respectively, as the temperature of heat treatment rose and the duration of such treatment was extended. The sprouting rate of ginger rhizomes treated at $40^{\circ}C$ was higher than that of other samples. Rotting, softening, and increasing pH of rhizomes were accelerated by treatment at higher temperature for a longer time. Weight loss and soluble solid levels were not affected by heat treatment. Sensory qualities such as appearance, odor, and overall acceptability of rhizomes fell with treatment at a higher temperature for a longer time. These results suggest that heat pretreatment has a detrimental effect on the quality of fresh ginger rhizomes.

Design and Evaluation of a Lung Assist Device for Patients with Acute Respiratory Syndrome using Hollow Fiber Membranes (중공사 막을 이용한 급성호흡곤란증후군 환자용 폐 보조 장치의 설계와 평가)

  • Lee, Sam-Cheol;Kwon, O-Sung;Kim, Ho-Cheol;Hwang, Young-Sil;Lee, Hyun-Cheol
    • Membrane Journal
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    • v.15 no.3
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    • pp.224-232
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    • 2005
  • The use of the lung assist device (LAD) would be well suited for acute respiratory failure (ARF) patients, combining the simplicity of mechanical ventilation with the ability of extracoporeal membrane oxygenators (ECMO) to provide temporary relief for the natural lungs. This study's specific attention was focused on the effect of membrane vibration in the LAD. Quantitative experimental measurements were performed to evaluate the performance of the device, and to identify membrane vibration dependence on blood hemolysis. We tried to decide upon excited frequency band of limit hemolysis when blood hemolysis came to through a membrane vibration action. The excited frequency of the module type 5, consisted of 675 hollow fiber membranes, showed the maximum gas transfer rate. We concluded that the maximum oxygen transfer rate seemed to be caused by the occurrence of maximum amplitude and the transfer of vibration to hollow fiber membranes. It was excited up to $25{\pm}5$ Hz at each blood flow rate of module type 5. We found that this frequency became the 2nd mode resonance riequency of the flexible in blood flow. Blood hemolysis was low at the excited frequency of $25{\pm}5$ Hz. Therefore, we decided that limit hemolysis frequency of this LAD was $25{\pm}5$ Hz.

Changes of Physico-Characteristics in Green Pumpkin during Storage by Packaging Material and Method (포장재질 및 방법에 따른 애호박의 저장 중 품질변화)

  • Lee, Jin-Won;Shin, Hye-Seoung;Lee, Kyung-Hee;Park, Jang-Woo
    • Korean Journal of Food Science and Technology
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    • v.41 no.4
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    • pp.374-379
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    • 2009
  • In this study, we investigated effects of different packaging materials and methods on physico-characteristics of green pumpkin during storage at $10^{\circ}C$. Whole green pumpkin samples were packaged with polyvinyl chloride film (PVCF), orange coating film (OCF), paraffin film (PF), or paper with paraffin film (PWPF) and stored at $10^{\circ}C$. Weight loss, pH, firmness, browning, and gas composition ($O_2$ and $CO_2$) inside the film packages were evaluated. All characteristics of the unpackaged group (control group, CON) changed rapidly and lost marketability as compared with the packed pumpkin group. The pH values in all of the green pumpkin samples were between 6.38 and 6.67, and decreased with increased storage time. Over the storage time, all packaged pumpkin groups evidenced prevented or retarded deterioration of the green pumpkin samples in terms of appearance, texture, and discoloration. Firmness decreased slightly with increased storage time. Brown color difference were much higher in the controls than in the film-packaged green pumpkin samples, and increased rapidly in the early stages of storage. These results were attributed to reduce respiration rates as a result of elevated carbon dioxide and reduced oxygen levels in the packages. The results of this study demonstrated that the green pumpkin packaged with PWPF and PVCF showed retarded deterioration as compared to the CON, OCF and PF samples in a controlled atmosphere, and thus significant differences were noted according to the packaging material and methods used.

Treatment of Liquid Waste Containing Highly Concentrated Ethylenediaminetetraaceticacid by Using Underwater Electrical Discharge (수중 전기방전을 이용한 에틸렌디아민테트라아세트산 폐액의 처리)

  • Jo, Jin-Oh;Mok, Young-Sun;Kang, Duk-Won
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.5
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    • pp.564-570
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    • 2007
  • This study investigated the treatment of liquid waste containing highly concentrated iron(III)-ethylenediaminetetraaceticacid (Fe(III)-EDTA) of 70,000 mg/L by an underwater electrical discharge process using low voltage and high current. When AC voltage is applied to the discharging electrode with the other electrode grounded, the temperature of the liquid waste around the discharging electrode rapidly increases, and at the same time, hydrogen and oxygen gases are formed at the electrode as a result of electrochemical reactions. Ultimately, gases formed by vaporization of water and electrochemical reactions cover the electrode. Since the liquid waste is electrically conductive, it elongates the ground electrode up to the border of the gas layer, where electrical discharge occurs. Without hydrogen peroxide, electrical discharge was able to remove about 50% of Fe(III)-EDTA. As the concentration of hydrogen peroxide added increased, the removal efficiency of Fe(III)-EDTA increased. When the molar ratio of hydrogen peroxide to the initial Fe(III)-EDTA was higher than 24.7, more than 80 g of Fe(III)-EDTA was removed with an energy of 1 kWh. A comparison between tungsten and steel electrodes showed that electrode material did not affect the Fe(III)-EDTA removal. In the present underwater electrical discharge process, the removal of Fe(III)-EDTA was completed within 30 min at molar ratios of hydrogen peroxide to the initial Fe(III)-EDTA higher than 24.7.

Surface Modification of Polytetrafluoroethylene by Using Low Energy Hydrogen Ion Beam (저에너지 수소 이온빔을 이용한 polytetrafluoroethylene 표면 개질)

  • Lee, Jung-Hwan;Kim, Dong-Hwan;Yeo, Woon-Jung;Han, Young-Gun;Cho, Jun-Sik;Kim, Hyun-Joo;Koh, Seok-Jeun
    • Journal of the Korean Vacuum Society
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    • v.15 no.6
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    • pp.612-618
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    • 2006
  • Surface modification of PTFE by ion irradiation was performed to improve its surface properties, In the case where argon was used to irradiate the PTFE films, an increase in the adhesion strength was observed when the ion fluence was over $1\times10^{15}\;ions/cm^2$, but the surface morphology dramatically changed to a needle-shaped one. However, when we used hydrogen ions under $O_2$ environmental gas, the adhesion strength increased at an ion fluence of $5\times10^{16}\;ions/cm^2$ and the surface morphology by the hydrogen irradiation was not needle-shaped. The surface morphology and adhesion strength of the hydrogen modified PTFE was influenced by the oxygen flow rate. It was confirmed by reflectance measurements that the surface properties of the hydrogen ion irradiated PTFE were superior to those of the argon ion irradiated PTFE.

Formation of MOCVD TiN from a New Precursor (새로운 증착원으로 형성된 MOCVD TiN에 관한 연구)

  • Choe, Jeong-Hwan;Lee, Jae-Gap;Kim, Ji-Yong;Lee, Eun-Gu;Hong, Hae-Nam;Sin, Hyeon-Guk
    • Korean Journal of Materials Research
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    • v.9 no.3
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    • pp.244-250
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    • 1999
  • MOCVD TiN films were prepared from a new TiN precursor, tetrakis(etylmethylamino)titanium (TEMAT) and ammonia. Deposition of TiN films from a single precursor, TEMA T yielded the growth rates of $70 to 1050\AA$/min, depending on the deposition temperature. Furthermore, the excellent bottom coverage of -90% over $0.35\mu\textrm{m}$ contacts was obtained at $275^{\circ}C$. The addition of ammonia to TEMA T lowered the resistivity of as- deposited TiN film to ~ $800\mu\omega-cm$ from $3500~6000\mu\omega-cm$ and improved the stability of TiN film in air. Examination of the films by Auger electron spectroscopy(AES) showed that the oxygen and carbon contents decreased with the addition of ammonia. However, increasing ammonia flow rate decreased the bottom coverage of TiN films over $0.5\mu\textrm{m}$ contacts, probably due to the high sticking coefficient of intermediate species produced from the gas phase reaction of TEMA T and ammonia. Based on the byproduct gases detected by the quadrupole mass spectrometer (QMS), the transammination reaction was proposed to be responsible for TiN deposition. In addition, XPS analysis revealed that the carbon in the films made from TEMA T and ammonia was metallic carbon, suggesting that $\beta$-hydrogen activation process occurs competitively with the transammination reaction.

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Quality Characteristics of Retorted Chicken Breast Products Packaged in a Multilayer Barrier Tray During Chilled Storage (차단성 다층 트레이에 포장된 레토르트 닭 가슴살제품의 냉장 중 품질 특성)

  • Jang, Dong-Hyun;Lee, Keun-Taik
    • Food Science of Animal Resources
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    • v.32 no.4
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    • pp.483-490
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    • 2012
  • Ready-to-eat chicken breasts were packaged in a multilayer, gas-tight tray with top film and various quality changes were investigated during the 24 wk of storage at $10^{\circ}C$. Over the storage period, total aerobes, mesophilic aerobic and anaerobic spore formers, and Clostridium spp. were not detected above 1.0 log CFU/g (detection limit). The residual oxygen ratio in the head space of tray and pH values tended to decrease with storage time, namely from initial values of 5.7% and 6.56 to 3.3% and 6.34 at week 24, respectively. Thiobarbituric acid reactive substances and volatile basic nitrogen values increased from 0.52 mg malonaldehyde (MA)/kg and 2.1 mg/100 g initially, to 3.70 mg MA/kg and 39.9 mg/100 g at week 24, respectively. In terms of the change in meat color during storage, the samples showed a slight increasing trend of CIE $a^*$, $b^*$, and ${\Delta}E$ values over the storage period until week 24 (p<0.05). The change in brine color showed a similar trend with meat of which Hunter $b^*$ and ${\Delta}E$ values increased slightly during storage during 24 wk (p<0.05). The values for the transmittance degree of brine in the samples tended to decrease. Moreover, values for the absorbance degree tended to increase with storage time until week 24. The sensory scores for color, texture, odour, and flavour were evaluated below 5.0 (marketability level) after 24 wk of storage. Based on this sensory evaluation, it could be concluded that retorted RTE chicken breast could remain marketable for at least 20 wk at $10^{\circ}C$.

Comparison of Anesthetic Responses Induced by MZT and XZT Combinations at General Anesthesia for Laparoscopic Salpingectomy in Rearing Female Asiatic Black Bears (Ursus thibetanus)

  • Kang, Tae Ku;Kim, Ill-Hwa;Lee, Jun-Am;Park, So-Young;Hwang, Dae-Youn;Kang, Hyun-Gu
    • Journal of Veterinary Clinics
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    • v.36 no.6
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    • pp.306-313
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    • 2019
  • It is important to identify the most suitable anesthetic agent that has minimal side effects to be able to control and perform surgeries on bears. In this study, we examined and compared the induction and recovery times as well as the physiological changes occurring during anesthesia induced by medetomidine-zolazepam/tiletamine (MZT) and xylazine-zolazepam/tiletamine (XZT) at general anesthesia for laparoscopic salpingectomy in 326 female Asiatic black bears. The body temperature, heart rate, respiratory rate, and levels of PaO2 and EtCO2 were the physiological changes measured during surgical procedures in female bears after anesthesia. In addition, the levels of pO2, pCO2, and sO2 were measured using a portable blood gas analyzer. To induce recovery from anesthesia, bears anesthetized with MZT were intravenously administered atipamezole and bears anesthetized with XZT were intravenously administered yohimbine. The combination MZT, at dosages of 0.019 ± 0.001 mg/kg for medetomidine and 1.4 ± 0.1 mg/kg for ZT, or the combination XZT, at dosages of 2.0 ± 0.1 mg/kg for xylazine and 3.0 ± 0.1 mg/kg for ZT, proved to be reliable and effective in anesthetizing Asiatic black bears for a 40-min handling period for routine clinical procedures. The average anesthesia induction times were 16.5 ± 0.95 min for the bears in the MZT group and 12.0 ± 0.44 min for those in the XZT group. A significant difference was noted between the two drugs (P < 0.001) in terms of the average anesthesia induction time. The anesthesia induction time was shorter for bears with lower body weights than those with higher body weights (P < 0.05). The recovery time of MZT was significantly faster than that of XZT (11.3 ± 0.45 min vs. 18.5 ± 0.83 min) (P < .001). The bears anesthetized with MZT exhibited lower cardiopulmonary suppression than those anesthetized with XZT (P < 0.05). The body temperatures and EtCO2 of bears in the M ZT group were significantly lower than those in the XZT group as time progressed after anesthesia (P < 0.05). The average pO2 before the bears were supplied with oxygen was 64.8 ± 3.7 mmHg, but it increased to 211.5 ± 42.5 mmHg afterwards (P < 0.001). In conclusion, our results indicate that bears anesthetized with MZT have longer anesthesia induction time, shorter recovery time, slower heart and respiratory rates, and lower body temperatures and EtCO2 than those anesthetized with XZT. These findings suggest that XZT is preferable to MZT, warranting further research on its uses and clinical responses in bears.

The Characteristics of Groundwater and a Field Test for Thermal Insulation of Landfarming of Petroleum Contaminated Soil in Winter Season (유류오염지역의 지하수 수질특성 및 동절기 토양경작법의 온도보전을 위한 현장사례 연구)

  • Cho, Chang-Hwan;Kim, Soon-Heum;An, Jong-Ik;Lee, Yoon-Oh;Choi, Sang-Il
    • Journal of Soil and Groundwater Environment
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    • v.18 no.5
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    • pp.7-14
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    • 2013
  • The objectives of this study were to identify the characteristics of groundwater in the petroleum contaminated site and to evaluate the applicability of house-type landfarm facilities heated with briquette stoves in winter season. The six monitoring wells were installed at the site where pH, dissolved oxygen, and temperature were all measured. Also groundwater contaminants, benzene, toluene, ethylbenzene, xylene and total petroleum hydrocarbon, were analyzed twice. House-type two landfarm facilities ($12m{\times}40m{\times}4.8m$) each installed with four briquette stoves were constructed. During four rounds treatment process, VOCs, moisture, temperature were monitored and soil contaminants were analyzed. The pH was 6.37 and considered subacid and DO was measured to be 3.12 mg/L. The temperature of groundwater was measured to be $9.48^{\circ}C$. The groundwater contaminants were detected only in the monitoring wells within the contaminated area or close to it showing that the groundwater contaminated area was similar to the soil contaminated area. During the landfarm process, 73.3% of VOCs concentration in interior gas was decreased and moisture was lowered from 17.7% to 13.4%. In the morning, at 8:00 am, the temperature was decreased showing soil ($5.5^{\circ}C$) > interior ($4.8^{\circ}C$) > exterior ($3.5^{\circ}C$). In the afternoon, at 2:00 pm, the temperature was soil ($8.6^{\circ}C$) < interior ($9.9^{\circ}C$) < exterior ($11.5^{\circ}C$) with solar radiation. The temperature difference between interior and exterior was $0.7^{\circ}C$ in the morning, but it was $1.6^{\circ}C$ in the afternoon. A total of 130 days were taken for four round landfarm processes. Each process was completed within 33 days showing 80% of cleanup efficiency ($1^{st}$ order dissipation rate(k) = 0.1771).