• 전기화학회지
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• 제8권2호
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• pp.106-114
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• 2005

This article covers the theoretical ac-impedance models for the analysis of oxygen reduction on the porous cathode electrode f3r solid oxide fuel cell (SOFC). Firstly, ac-impedance models were explained on the basis of the mechanism of oxygen reduction, which were classified into the rate-determining steps; (i) adsorption of oxygen atom on the electrode surface, (ii) diffusion of adsorbed oxygen atom along the electrode surface towards the three-phase (electrode/electrolyte/gas) boundaries, (iii) surface diffusion of adsorbed oxygen atom m ixed with the adsorption reaction of oxygen atom on the electrode surface and (iv) diffusion of oxygen vacancy through the electrode coupled with the charge transfer reaction at the electrode/gas interface. In each section for ac-impedance model, the representative impedance plots and the interpretation of important parameters attributed to the oxygen reduction reaction were explained. Finally, we discussed in detail the applications of the proposed theoretical ac-impedance models to the real electrode of SOFC system.

• 한국진공학회지
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• 제8권2호
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• pp.165-171
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• 1999

Diamond-like carbon(DLC) films were synthesized using the rf-plasma CVD technique with the addition of small amounts of nitrogen and oxygen to a gas mixture of $CH_4$ and $H_2$. The gas flow ratio of $CH_4$ to $H_2$ was 2.4:1, and 3% , 13.6% of nitrogen were added to the gas mixture of $CH_4$ and $H_2$ for the deposition of DLC films. The film stress tended to decrease as the nitrogen concentration increased from 3% to 13.6%, probably due to the decrease of the number of the interlink between carbon atoms. The residual stress tended to slightly decrease when 3% of oxygen was added. Scratch tests were performed to investigate the adhesion between the DLC films and the Ti intelayer after pretreating the TiN surface with direct hydrogen plasma. The adhesion was enhanced by adding nitrogen and oxygen to the $CH_4$ and $H_2$ gas mixture. The adhesion for the 3% nitrogen addition was better than that for the 13.6% nitrogen addition. The Vicker's hardness of the DLC films was measured to be 1100Hv.

• 한국재료학회지
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• 제9권3호
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• pp.269-273
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• 1999

일반적으로 LPCVD 방법에 의한 다결정 실리콘 박막은 $SiH_4$가스를 열분해하여 증착한다. 본 실험에서는 다결정 실리콘 박막속에 포함된 산소농도를 낮추기 위하여 실리콘 웨이퍼를 반응로 안으로 장착할 때, 20slm의 $N_2$가스를 반응로의 위에서부터 아래로 flow하였으며 박막의 산소농도를 측정하기 위하여 두께가 $1000\AA$인 박막을 증착한 다음 SIMS로 분석한 결과 반응로의 hatch에 있는 짧은 injector를 통하여 20slm의 $N_2$가스를 flow한 경우보다 박막의 산소농도가 ~30배 정도 낮아짐을 알 수 있었다. 긴 injector를 사용하여 증착된 박막의 두께 균일도, particle 및 Rs를 측정하여 박막증착의 재현성이 있음을 평가하였다.

• 한국수소및신에너지학회논문집
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• 제7권2호
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• pp.129-135
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• 1996

전해질로써 $Nafion^{(R)}$과 같은 고체고분자막과 수소/산소 가스가 계면을 형성할 경우의 전압전류특성을 측정하였다. 사용된 가스는 수소와 산소의 조성비를 달리하여 혼합한후 공급하였다. 사용된 전극은 상업용 탄소 기체 확산 전극을 이용하였으며 전극의 분산된 촉매와 전해질과의 접촉을 용이하게 하기위해 5% $Nafion^{(R)}$을 발라주었다. 직류전원 공급장치를 이용하여 산화 전극과 환원 전극에 걸어주는 전압을 조정하였다. 전압전류의 분석결과로부터 에너지효율은 수소/산소혼합물의 수소농도에 예민하게 의존함을 알 수 있었다.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 1999년도 추계종합학술대회 논문집
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• pp.1067-1070
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• 1999

Anesthesia gas to pour to patients affects the flow and volume as the pressure difference of an oxygen and an anesthesia gas. An anesthesia gas, being injurious and polluting an environment, must control the pressure of an oxygen gas because of being used by closing up tight. But a pressure sensor to use for measuring an oxygen gas appears other pressure as the characteristic and the error difference of elements to use for implementing an system. A medical machine such as an anesthesia ventilator must be accurate because of using for the person's body. So we intend to implement an system for a sensor pressure measurement not to be change regardless of an environment. This papers is the target that a sensor pressrue measurement to be changed in environment is equal to actual sensor pressure measurement. So an implemented system is using analog filter and digital filter to reduce a noise. And we are using auto-zeroing and calibration to correct a sensor pressure which is changed in environment. Through such a process we increase the accuracy and the confidence of an anesthesia ventilator by controlling the flow of an anesthesia gas.

• 한국가스학회지
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• 제27권3호
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• pp.84-90
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• 2023

연소의 3요소 중 대기 중에 상시 존재하는 산소는 고압산소 조건에서는 극미량의 가연물만으로도 화재·폭발이 발생할 수 있으며. 연소속도 역시 상당하여 순식간에 공정 설비 및 배관을 녹이는 등 직접적인 영향을 줄 수 있는 온도까지 상승할 수 있다. 따라서 고압산소 상태에서 발생한 사고는 기타 사고에 비해 큰 피해가 발생하는 경우가 많다. 최근 산소공급 배관에 설치되어 있는 밸브를 조작하던 도중 내부에서 급격한 연소와 함께 파열이 발생하여 폭발로 인한 인명피해가 발생하였는데, 오래된 탄소강 배관인 경우 운전 중 발생한 Particle이 가연물이 되어 사고가 발생할 수 있다. 특히나 산소설비는 고압가스안전관리법에 따라 허가된 시설이고, 산업안전보건법에 의한 제한규정이 없는 상태이기 때문에 이러한 기준 적립이 무엇보다 중요하다. 따라서 본 연구에서는 사고사례 및 해외기준을 바탕으로 고압 산소 취급 시 안정성 향상을 위한 방법에 대해 검토하고자 한다.

• 유체기계공업학회:학술대회논문집
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• 유체기계공업학회 2006년 제4회 한국유체공학학술대회 논문집
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• pp.551-554
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• 2006

Inhibition of propellant temperature rising in liquid propulsion rocket using cryogenic fluid as a propellant is very important. Especially propellant temperature rising during stand-by after filling and pre-pressurization can bring into cavitation in turbo-pump. One of the method preventing propellant temperature rising in cryogenic feeding system is recirculating propellant through the loop composed of propellant tank, feed pipe, and recirculation pipe. The circulation of propellant is promoted through gas-lift effect by gas injection to lower position of recirculation pipe. In this experiment liquid oxygen and gas helium is used as propellant and injection gas. Under atmospheric and pressurized tank ullage condition, helium injection flow-rate is varied to observe the variation of recirculating flow-rate and propellant temperature in the feed pipe. There is appropriate helium injection flow-rate for gas-lift recirculation system.

• 한국표면공학회지
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• 제53권5호
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• pp.201-206
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• 2020

A SiOxCy(-H) thin film was synthesized by atmospheric pressure dielectric barrier discharge(APDBD), and a SiO₂-like layer was formed on the surface of the film by oxidation treatment using oxygen plasma. Hexamethylcyclotrisiloxane was used as a precursor for the SiOxCy(-H) synthesis, and He gas was used for stabilizing APDBD. Oxygen permeability was evaluated by forming an oxidized SiOxCy(-H) thin film on a PET film. When the single-layer oxidized SiOxCy(-H) film was coated on the PET, the oxygen gas permeability decreased by 46% compared with bare PET. In case of three-layer oxidized SiOxCy(-H) film, the oxygen gas permeability decreased by 73%. The oxygen permeability was affected by the thickness of the SiO₂-like layer formed by oxidation treatment rather than the thickness of the SiOxCy(-H) film. The excellent corrosion resistance was demonstrated by coating an oxidized SiOxCy(-H) thin film on the silver-coated aluminum PCB for light emitting diode (LED).

• 청정기술
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• 제20권3호
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• pp.212-217
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• 2014

재생공정에서 황화 된 탈황흡수제의 재생을 위하여 산소는 산화제로 사용되었다. 재생공정에서 미량의 미 반응 산소는 직접 황 회수 공정으로 유입된다. 그러나, $SO_2$ 환원을 위한 반응성은 미 반응 산소의 다양한 이유에 의해서 저하된다. $SO_2$ 환원을 위한 반응성 실험을 위해 Sn-Zr계 촉매가 사용되었으며, $SO_2$와 $O_2$는 각각 5.0 vol%와 4.0 vol%로 고정하였고 $300-450^{\circ}C$와 1-20 atm에서 수행되었다. 본 연구에서는 고온건식 탈황공정의 직접 황 회수공정에 유입되는 미 반응산소에 의한 촉매반응성 저하에 미치는 영향을 조사하였다. $SO_2$ 환원으로 생성된 원소 황은 미 반응산소에 의해서 재산화되고, redox반응기구에서 Sn-Zr계 촉매의 빈 격자 산소자리가 미 반응산소에 의해서 재산화되므로 $SO_2$ 전화율은 감소되는 것으로 판단된다. 한편 환원제로써 공급된 CO는 미 반응산소에 의해서 산화되어 연소열에 의해 촉매 충전 층 온도가 상승되기도 한다. 결과적으로 충전 층의 빠른 온도상승은 활성 물질을 소결시켜 촉매의 비활성화를 초래하게 된다.

• 대한기계학회논문집B
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• 제24권9호
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• pp.1247-1254
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• 2000

The effects of recirculated exhaust gas on the characteristics of $NO_x$ and soot emissions under a wide range of engine load have been experimentally investigated by a water-cooled, four-cylinder, indirect injection, four cycle and marine diesel engine operating at two kinds of engine speeds. The simultaneous control of $NO_x$ and soot emissions in diesel engines is targeted in this study. The EGR system is used to reduce $NO_x$ emissions, and a novel diesel soot removal device with a cylinder-type scrubber for the experiment system which has 6 water injectors(A water injector has 144 nozzles in 1.0 mm diameter) is specially designed and manufactured to reduce the soot contents in the recirculated exhaust gas to intake system of the engines. The intake oxygen concentration and the mean equivalence ratio calculated by the intake air flow and fuel consumption rate, and the exhaust oxygen concentration measured are used to analyse and discuss the influences of EGR rate on $NO_x$ and soot emissions. The experiments are performed at the fixed fuel injection timing of $15.3^{\circ}$ BTDC regardless of experimental conditions. It is found that $NO_x$ emissions are decreased and soot emissions are increased owing to the drop of intake oxygen concentration and exhaust oxygen concentration, and the rise of equivalence ratio as the EGR rate rises.