• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2009년 추계학술대회논문집
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• pp.93-96
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• 2009

In the cathode channel of a PEM fuel cell, the local concentration of oxygen near the gas diffusion layer (GDL) decreases in streamwise direction due to chemical reactions, which degrades the efficiency of the oxygen consumption and overall fuel cell efficiency. We numerically studied the influence of the swirling flow generated by a slanted groove mixer (SGM) on the concentration distribution of oxygen. We found that the swirling flow can increase the concentration of oxygen near the GDL, and subsequently improves the oxygen consumption rate.

• 한국초전도학회:학술대회논문집
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• 한국초전도학회 2009년도 Korea Superconductivity Society Meeting 2009
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• pp.52-52
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• 2009

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 추계학술대회논문집B
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• pp.177-184
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• 2001

Combustion using oxygen enriched air is an energy saving technology that can increase thermal efficiency by the improvement of burning rate and high temperature flame. But information about it is not so enough yet. Flame figure, temperature distribution and emission concentration were measured with oxygen enriched concentration and swirl number in a turbulent diffusion flame to investigate the combustion characteristics. The results showed that flame figure became different as long as oxygen enriched concentration varied and that concentration of NO increased suddenly around $O_2$ 60%.

• 한국가스학회지
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• 제8권1호
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• pp.37-47
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• 2004

탄소분자체(CMS)를 사용하여 산소를 정제하기 위한 압력순환식 흡착 공정(PSA)을 연구하였다. 본 연구에서는 zeolite를 사용하는 일반적인 평형 분리 PSA 공정의 생산제품으로 가정된 2성분 혼합가스 ($O_2$/Ar- 95:5 vol.$\%$)와 두 개의 서로 다른 3성분 혼합가스를 ($O_2/Ar/N_2$- 95:4:1, 90:4:6 vol.$\%$) 공급기체로서 사용하였고, $99\%$ 이상의 고순도를 얻기 위한 공정이 개발되었다. 두번의 연속 감압 단계를 포함하는 개발공정의 결과로서 산소 $93\%$를 포함한 공급류의 경우 약 $99.8\%$의 고순도와 함께 $56\%$정도의 회수율을 얻을 수 있었으며, 산소 $90\%$를 포함한 공급류에 대하여도 $97\%$이상의 고순도 산소를 생산해 낼 수 있었다. 본 연구에서 개발된 공정의 경우 흡착제에 대한 흡탈착속도 차이를 이용하여 분리 정제가 진행되며, 공정을 정확히 모사하기 위하여 Langmuir isotherm이 결합된 modified structural diffusion model을 적용하였다.

• 청정기술
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• 제27권1호
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• pp.93-103
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• 2021

기후변화 대응과 탄소배출 저감에 대한 심각성 및 필요성이 중요시 되면서 세계 각국은 온실가스를 감축하고자 하는 노력을 지속하고 있다. 다양한 노력들 중 탄소기반 연료 사용 시 발생되는 이산화탄소를 포집하여 활용하는 CCUS에 대한 연구가 활발히 진행되고 있으며, 이러한 관점에서 CCUS와 함께 활용될 수 있는 가압 순산소 연소에 대한 연구도 여러 연구자들에 의해 진행되고 있다. 본 연구는 가압 순산소 연소의 화염 구조와 오염물질 배출과 관련된 기초적인 정보를 분석하는데 목적이 있다. 이를 위해 대향류 확산 화염 모델을 이용하여 압력 및 산소분율에 따른 연소의 특성을 분석한 결과, 압력이 높을수록 화학 반응의 활성화로 인한 반응율의 증가로 연소 온도가 증가하고 화염두께는 감소한 반면, 산소분율이 높을수록 반응율 증가 및 산화제 운동량 변화에 따른 확산의 영향으로 연소 온도 및 화염두께 모두 증가하였다. 이와 관련된 열방출 반응을 3가지 구간으로 구분하여 분석한 결과, 특히 산소분율이 증가할수록 산화제 측면에서 나타나는 화학 반응이 혼합분율에 따라 크게 두 개의 영역으로 세분화되는 특성이 나타났다. 또한, NO의 생성 메커니즘에 따라 구분된 배출지수(EINO)를 분석하였고, 각 해석 조건에 따른 NO의 생성 경향을 제시하였다.

• 한국세라믹학회지
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• 제34권12호
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• pp.1221-1226
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• 1997

The effects of sintering atmosphere and dopant addition on the behavior of densification and grain growth of SnO2 ceramics were investigated with consideration of defect chemistry. CoO and Nb2O5 were chosen as dopants, and oxygen and nitrogen were used for controlling of sintering atmospheres. With the decrease of oxygen partial pressure, densification was depressed due to evaporation of SnO2 ceramics. In the case of SnO2 sintering, the addition of CoO, which produced oxygen vacancy in SnO2 ceramics, led to acceleration of densification and grain growth. On the contrary, when Nb2O5 as a dopant producing Sn vacancy was added to SnO2 ceramics, densification and grain growth were simultaneously retarded. As results, it was conformed that diffusion of oxygen ions was rate determinant in densification and grain growth of SnO2 ceramics.

• 대한기계학회논문집B
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• 제28권2호
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• pp.160-166
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• 2004

Combustion using oxygen enriched air is known as a technology which can increase flame stability as well as thermal efficiency due to improving the burning rate. Lift-off, blowout limit and flame length were examined as a function of jet velocity, coflow velocity and OEC(Oxygen Enriched Concentration). Blowout limit of the flame below OEC 25% decreased with increase of coflow velocity, but the limit above OEC 25% increased inversely. Lift-off height decreased with increase of OEC. In particular, lift-off hardly occurred in the condition above OEC 40%. Flame length of the flames above OEC 40% was increased until the blowout occurred. Great flame stability was obtained since lift-off and blowout limit significantly increased with increase of OEC.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.326-331
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• 2003

Combustion using oxygen enriched air is known as a technology which can increase flame stability as well as thermal efficiency due to improvement of the burning rate. Lift-off, blowout limit and flame length were examined as a function of jet velocity, coflow velocity and OEC(Oxygen Enriched Concentration). Blowout limit of the flame below OEC 25% decreased with coflow velocity, but the limit above OEC 25% increased inversely. Lift-off height decreased with increase of OEC. Especially lift-off hardly occurred in the condition above OEC 40%. Flame length of the flames above OEC 40% was increased until the blowout occurred. Flame stability became improved since lift-off and blowout limit increased much with increase of OEC.

• 상하수도학회지
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• 제9권4호
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• pp.73-86
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• 1995

The propriety of the numerical model application was examined on Paldang resevoir and its inflow tributaries located in the center of the Korean peninsula and the long term water quality forecast of the oxygen profile was carried out in this syduy. The input data of the model was the capacity of the reservoir, catchment area, percolation, diffusion rate, vertical mixing rate, dissolution rate from the bottom of the reservoir, outflow of the resevoir, water quality measurement and meteorology data of the drainage basin, and the output result was the annual estimation value of the dissolved oxygen concentration and the biochemical oxygen demand. The modeling method is based on the measured or calculated boundary condition dividing the water area into several blocks from the macorscopic aspect and considering the mass balance in these blocks. As the result of the water quality forecast, it was expected that the water quality in Northern Han River and Paldang reservoir would maintain the recent level, but that the water quality in the Southern Han River and its inflow tributary would worsen below the grade 4 of the life environmental standard from around 2000 owing to the decrease of DO concentration and the increase of BOD concentration.

• The Korean Journal of Ceramics
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• 제6권2호
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• pp.177-182
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• 2000

At the porous $La_{0.6}Ca_{0.4}MnO_{3-{\delta}}$(LCM)/YSZ electrodes of solid oxide fuel cells (SOFC), the electrochemical redox reaction of oxygen proceeds via the triple boundary (TPB) of gas/LCM/YSZ. The surface diffusion of adsorbed oxygen on LCM has been proposed as the rate determining process, assuming the gradient of oxygen chemical potential from the outer surface of porous layer to TPB. Along with the formation of this gradient, oxygen nonstoichiometry in the bulk of LCM may varies. In this paper, an electrochemical technique was described precisely to determine the variation of oxygen content in LCM of porous LCM/YSZ under polarization. It was shown that the oxygen potential in LCM layer under large cathodic polarization is much lower than that in the gas phase, being determined from the electrode potential and Nernst equation.