• 제목/요약/키워드: oxidative characteristics

검색결과 328건 처리시간 0.025초

방사선 조사선량에 따른 유지의 이화학적 성질변화 (I) (Changes of the phsico-Chemical Characteristics of oils treated by the ${\gamma}$-ray irradiation (I) -The Extracted soybean oil-)

  • 임국이
    • 대한가정학회지
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    • 제30권4호
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    • pp.77-88
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    • 1992
  • To investigate the oxidative stabilities of the ${\gamma}$-ray irradiated soybean during storage and heating and some physico-chemical characteristics of soybean and the extracted soybean oil (SBO) with/without the ${\gamma}$-ray irradiation were determined. The ${\gamma}$-ray level use in irradiation for soybean were 2.5, 5.0 and 10.0 KGY respectively and Acid Value, Peroxide Value, Conjugated Diene Value, Composed Fatty Acids amounts, and Trans Fatty Acid occurrence were determined for all samples, which were incubated at 45$\pm$1$^{\circ}C$ for 25 days heated at 180$\pm$1$^{\circ}C$ for 30 hours. And these values of the ${\gamma}$-ray treated samples were compared to those of nontreated samples. The results were obtained as follows : 1. According to the increased level of the ${\gamma}$-ray irradiation, there was little difference in Dielectric Constant, Viscosity, and the Induction Period by Rancimat. But, in case of 5.0 KGY, oxidative stability was increased more twice than that of non-irradiation. In the quantity of fatty Acids composition of the extracted soybean oil irradiated with 10.0 KGY, palmitic, oleic and linoleic acids were less increased thanb those of non-irradiation, while stearic, linolenic acids were decreased. In the case of 2.5 KGY irradiation, stearic and oleic acids were increased. 2. The Acid Value of SBO according to the ${\gamma}$-ray irradiation level was almost not change, but was 0.1 lower than that of non-irradiation during incubation (45$\pm$1$^{\circ}C$). The Peroxide Value of SBO with the ${\gamma}$-ray irradiation, was very lower than that of non-irradiation, but its effect on oxidative stability was better of SBO treated with 5.0 KGY and 10.0 KGY. In the Fatty Acids composition of SBO, palmitic, stearic, oleic acids were increased, while linoleic, linolenic acids were decreased during incubation(45$\pm$1$^{\circ}C$). This tendency was more obvious due to the ${\gamma}$-ray level. While heating(180$\pm$1$^{\circ}C$), the Acid Value of SBO treated with the ${\gamma}$-ray irradiation was decreased, the Acid Value of SBO irradiated with 2.5 KGY was the lowest. Also the peroxide Values of SBO treated with 5.0 KGY, 10.0 KGY were very lower than that of non-irradiation. Conjugated Diene Value of SBO was almost unchanged according to the ${\gamma}$-level and heating time. 3. When the methyl linoleate was irradiated with the ${\gamma}$-ray, the Trans Fatty Acid was little produced. In case of SBO with non-irradiation, the trans C18:1 was occured about 6.5~7.9%, but trans C18:2 and C18:3 were not shown, while SBO irradiated with the ${\gamma}$-ray 2.5, 5.0, 10.0 KGY, trans C18:3 and C18:2 amount in SBO were increased according to heating time, but trans C18:3 was little occured. As these results, the effects of the ${\gamma}$-ray irradiation to oil containing food were to cut down the energy for food storage and to increase oxdative stability during storge. And also it was shown to be the best that 10.0 KGY of the ${\gamma}$-ray irradiation would be applied to soybean.

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Surface Characterization of Carbon Fibers as Anode Materials for Li Secondary Batteries

  • Takamura, Tsutomu;Awano, Hidekazu;Ura, Tetsuya;Ikezawa, Yasunari
    • 분석과학
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    • 제8권4호
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    • pp.583-590
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    • 1995
  • Pitch-based mesophase carbon fibers prepared at different temperatures were heat-treated at temperatures lower than those of the preparation and the electrochemical Li doping/undoping characteristics were evaluated in relation to the data of IR, mass, etc. Presence of surface hydroxyls were confirmed by FTIR for lower temperature sample which showed poor anode characteristics. Upon oxidative heating, removal of surface hydroxyls took place, resulting in a remarkable improvement of the electrode characteristics. At the same time, surface roughening took place, which was confirmed by SEM and double layer capacity measurements. In situ mass spectra obesrved during the heat-treatments showed gas evolution of $H_2O$, CO, $CO_2$, $C_2H_4$, and/or $H_2$ depending on the conditions. These data together with those of weight loss and conductivity provided us a valuable information in regard to the evaluation of the electrochemical characteristics.

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Effect on quanti-quality milk and mozzarella cheese characteristics with further increasing the level of dried stoned olive pomace in diet for lactating buffalo

  • Taticchi, A.;Bartocci, S.;Servili, M.;Di Giovanni, S.;Pauselli, M.;Mourvaki, E.;Zilio, D. Meo;Terramoccia, S.
    • Asian-Australasian Journal of Animal Sciences
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    • 제30권11호
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    • pp.1605-1611
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    • 2017
  • Objective: Following a previous report, an experiment was conducted to determine the effect of increasing level of dried stoned olives pomaces (DSOP) in the diet of lactating buffaloes on milk and mozzarella cheese yield and characteristics. Methods: Sixteen pluriparous buffaloes distributed into two groups were fed an isoenergetic (0.9 milk forage unit/kg) and isoprotein (149 g/kg dry matter [DM] of crude protein) diet, with or without DSOP. Each animal received 17 kg DM/d. Samples of forages and concentrates were weekly collected and used for duplicate chemical analyses. Individual milk samples from each control were analyzed for chemical and coagulating parameters and daily production of mozzarella cheese was estimated. At the end of the trial, bulk milk of each group was processed to produce mozzarella cheese and chemical (fat, protein, ash, pH) composition, fatty acids composition, carotenoids and tocopherols content were determined. A sensory test was also performed. The oxidative stability was measured on mozzarella cheese and on governing liquid. Results: No significant differences were observed, neither for milk yield and body condition score, nor for milk characteristics. The fat was higher (p<0.05) in mozzarella of DSOP fed group but, saturated fatty acids were lower and unsaturated higher (p<0.01). Furthermore, lower atherogenic (p<0.01), and thrombogenic (p<0.05) indices were found in mozzarella cheese of DSOP fed group. In addition, the administration of DSOP did not affect the mozzarella cheese oxidative stability and no negative effect was found in the sensory properties. Conclusion: No contraindications appeared for the inclusion of DSOP in the diet of lactating buffaloes. Besides, important effects on mozzarella cheese quality were obtained, such as a modification of fat content and attributes with an increment in the mono-unsaturated. Additionally, a lower saturated/unsaturated ratio and atherogenic and thrombogenic indices suggest an improvement of dietetic and nutritional characteristics of mozzarella cheese.

골판지 포장재에 알루미늄 코팅이 파프리카의 저장 중 품질특성에 미치는 영향 (The effect of aluminum coating to corrugated packaging on quality characteristics of paprika during storage)

  • 김아나;하명화;이교연;샤피어라만;김남섭;최성길
    • 한국식품저장유통학회지
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    • 제24권7호
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    • pp.934-941
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    • 2017
  • 파프리카는 우리나라의 대표적인 수출작물로 알려져 있지만 장거리 유통 중 일어나는 품질열화로 인해 상품적 가치가 감소되는 문제가 있다. 따라서 본 연구는 농산물 유통 시 주로 사용되는 골판지상자의 내부에 알루미늄을 코팅하여 기능성을 부여한 포장용기를 개발하였으며, 이를 이용하여 파프리카를 포장하여 저장 중 선도유지 및 품질특성에 미치는 영향을 알아보았다. 골판지상자 내부에 알루미늄을 코팅함으로써 방습성을 향상시키고 기체투과도를 저하시킴으로써 포장된 파프리카의 펙틴분해효소 활성이 저하됨에 따라 파프리카의 중량변화율과 조직연화 현상이 저해되었고, 산화효소 활성이 감소함으로써 총 페놀 함량 및 항산화 활성이 향상되는 것으로 나타났다. 결과적으로 알루미늄 코팅한 골판지상자는 파프리카의 상품성 및 저장성을 향상시키는 포장용기로 이용될 수 있을 것으로 생각되며, 알루미늄박의 내수성, 내한성, 보향성, 내오염성 등의 특성을 활용한 추가연구를 통해 국내 농산물의 장거리 유통 및 수출 활성화에 이바지할 수 있을 것이라 생각된다.

Relationships between Myosin Light Chain Isoforms, Muscle Fiber Characteristics, and Meat Quality Traits in Porcine Longissimus Muscle

  • Choi, Young-Min;Ryu, Youn-Chul;Lee, Sang-Hoon;Kim, Byoung-Chul
    • Food Science and Biotechnology
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    • 제14권5호
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    • pp.639-644
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    • 2005
  • The aim of this study was to investigate the effect of the myosin light chain (MLC) isoforms on the muscle fiber characteristics and meat quality traits in porcine longissimus muscle. Pale, soft, exudative (PSE) samples had a lower content of essential light chain (ELC) 1S isoforms and a higher proportion of the fiber type IIB than the reddish-pink, firm, non-exudative (RFN) samples. These compositions suggest that the PSE pork has a higher glycolytic and a lower oxidative capacity than the RFN pork. Therefore, these characteristics of PSE pork might affect the metabolic rate and meat quality traits, including protein solubility. In addition, the indicator traits of the postmortem metabolic rate were related to the ELC 1F/3F ratio ($pH_{45\;min}$: r = -0.43, P < 0.001; R-value: r = 0.53, P < 0.001). These results suggest that the MLC isoform composition can affect the postmortem metabolic rate and meat quality traits.

열매마(Dioscorea bulbifera) 분말을 첨가한 스펀지케이크의 품질특성 (Quality Characteristics of Sponge Cakes made with Air Potato (Dioscorea bulbifera) Powder)

  • 김명현
    • 한국식생활문화학회지
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    • 제37권4호
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    • pp.354-362
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    • 2022
  • The purpose of this study was to investigate the possibility of using air potato (Dioscorea bulbifera) powder to make sponge cakes. The sponge cake batter was made by adding 0, 10, 20, 30, and 40% of air potato powder, and the resultant anti-oxidative properties and quality characteristics were analyzed. The study showed that the height, batter yield, and loss rate of sponge cakes decreased as increasing amounts of air potato powder were added, but the weight, viscosity, moisture content, and specific gravity increased. An evaluation of the color showed that the L and b values were highest in the control group but the a value was highest in the 40% group. There was no significant difference between samples in terms of cohesiveness, although the study showed a significant increase in the hardness, chewiness, and gumminess as the quantity of air potato powder in the sponge cakes increased. The total polyphenol content and DPPH radical scavenging activity increased noticeably as more air potato powder was added to the sponge cakes. The results thus showed that the study groups with the addition of air potato powder showed higher antioxidant activity than the control group.

Rapid Discoloration of Aged Beef Muscles after Short-Term/Extreme Temperature Abuse during Retail Display

  • Kim, Hyun-Wook;Setyabrata, Derico;Choi, Yun-Sang;Kim, Yuan H. Brad
    • 한국축산식품학회지
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    • 제36권3호
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    • pp.343-351
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    • 2016
  • The objective of this study was to evaluate the effects of a short-term/extreme temperature abuse (STA) on color characteristics and oxidative stability of aged beef muscles during simulated retail display. Two beef muscles (longissimus lumborum, LL and semitendinosus, ST) were aged for 7 (A7), 14 (A14), 21 (A21), and 28 d (A28), and further displayed at 2℃ for 7 d. The STA was induced by placing steak samples at 20℃ for 1 h on the 4th d of display. Instrumental and visual color evaluations, ferric ion reducing capacity (FRC) and 2-thiobarbituric acid reactive substances (TBARS) assay were performed. Initially, redness, yellowness and hue angle of all beef muscles were similar, regardless of aging time before display (p>0.05). An increase in postmortem aging time increased lipid oxidation and caused a rapid discoloration after STA during display (p<0.05). ST muscle was more sharply discolored and oxidized after STA, when compared to LL muscle (p<0.05). The FRC value of beef muscles was decreased after 7 d of display (p<0.05). The results from the current study indicate adverse impacts of postmortem aging on color and oxidative stabilities of beef muscles, particularly under temperature abusing conditions during retail display. Thus, developing a specific post-harvest strategy to control quality attributes in retail levels for different muscle types and aging conditions would be required.

천연망간산화물에 의한 클로로페놀의 산화결합생성물을 매개로 한 다환방향족화합물(PAH) 오염물의 고정화 효과 (Enhancement of Phenanthrene Sorption Rate on Natural Manganese Oxide Using the Oxidative Coupling Reaction of Phenanthrene)

  • 전선영;박재우;신원식;고석오
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제10권5호
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    • pp.45-51
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    • 2005
  • 본 연구에서는 다환방형족화합물의 하나인 phenanthrene를 이용하여 천연망간산화물에 흡착/탈착되는 특성을 평가하였다. 토양, 퇴적물이나 수체에 다양한 오염물이 동시에 존재하는 경우를 고려하여 페놀계 오염물이 있는 경우, 다환 방형족화합물의 흡탈착에 미치는 영향을 조사하였다. 망간산화물에 의하여 4-클로로페놀은 효과적으로 산화되었으며 반응산물은 고분자화(휴믹화) 되는 경향을 나타내었다. 4-클로로페놀이 분해됨에 따라 망간산화물 표면에 흡착되는 phenanthrene의 양은 급격히 증가하였다. 또한, 4-클로로페놀이 존재하는 경우 흡착된 phenanthrene의 탈착에 대한 저항성은 4-클로로페놀 농도가 증가할수록 강하게 나타남으로써 고분자화된 4-클로로페놀 반응산물에 phenanthrene이 강하게 흡착되어 있다는 결과를 도출하였다. 결과적으로 망간산화물은 페놀계 오염물과 다환방향족화합물을 동시에 처리하는데 효과적으로 사용될 수 있음을 보여주었다.

Isoprostane Characteristics in Sick House Syndrome, Atopy and Asthma Patient

  • Choi, Dal-Woong;Sohn, Jong-Ryeul;Moon, Kyung-Hwan;Byeon, Sang-Hoon;Lee, Jang-Hi;Kim, Hi-Choi;Kim, Young-Hwan
    • 한국환경보건학회:학술대회논문집
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    • 한국환경보건학회 2005년도 국제학술대회
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    • pp.289-292
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    • 2005
  • An imbalance between oxidants and antioxidants, in favor of oxidants leading to oxidative stress, is known to play an important role in the pathogenesis of various diseases. Isoprostanes are structurally stable isomers of the conventional enzymatically derived prostaglandins, which are produced in vivo primarily by a free radical catalyzed peroxidation of polyunsaturated fatty acids. In asthmatics, disease severity can occur from environmental exposure to air pollution. Some surveys suggested that air pollutants, especially diesel-exhaust particulates, could trigger allergic sensitization and development of atopic diseases. Sick house syndrome (SHS) presents healthy damage owing to the indoor environment of a building. The aim of this study was to examine isoprostane as a parameter fur oxidative stress in environments related diseases such as sick house syndrome, atopy and asthma. We measured plasma and urinary levels of isoprostane from health volunteers, sick house syndrome, atopy and asthma patients. Plasma isoprostane concentrations in asthma and sick house syndrome group were significantly higher than in control. Urinary isoprostane levels were significantly higher in volunteers with sick house syndrome and asthma compared with health volunteers. These findings suggest that plasma and urinary isoprostane measurement may have useful clinical implications for investigating sick house syndrome and asthma. The interventions that decrease exposure to environmental reactive oxygen species might be beneficial in these diseases.

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산소-플라즈마 공정에서 산화제의 생성에 대한 연구 (A Study for Oxidants Generation on Oxygen-plasma Discharging Process Discharging System)

  • 김동석;박영식
    • 한국환경과학회지
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    • 제22권12호
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    • pp.1561-1569
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    • 2013
  • This study carried out a laboratory scale plasma reactor about the characteristics of chemically oxidative species (${\cdot}OH$, $H_2O_2$ and $O_3$) produced in dielectric barrier discharge plasma. It was studied the influence of various parameters such as gas type, $1^{st}$ voltage, oxygen flow rate, electric conductivity and pH of solution for the generation of the oxidant. $H_2O_2$ and $O_3$.) $H_2O_2$ and $O_3$ was measured by direct assay using absorption spectrophotometry. OH radical was measured indirectly by measuring the degradation of the RNO (N-Dimethyl-4-nitrosoaniline, indicator of the generation of OH radical). The experimental results showed that the effect of influent gases on RNO degradation was ranked in the following order: oxygen > air >> argon. The optimum $1^{st}$ voltage for RNO degradation were 90 V. As the increased of $1^{st}$ voltage, generated $H_2O_2$ and $O_3$ concentration were increased. The intensity of the UV light emitted from oxygen-plasma discharge was lower than that of the sun light. The generated hydrogen peroxide concentration and ozone concentration was not high. Therefore it is suggested that the main mechanism of oxidation of the oxygen-plasma process is OH radical. The conductivity of the solution did not affected the generation of oxidative species. The higher pH, the lower $H_2O_2$ and $O_3$ generation were observed. However, RNO degradation was not varied with the change of the solution pH.