• Title/Summary/Keyword: oxidation index

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Fatty Acid Composition as a Predictor for the Oxidation Stability of Korean Vegetable Oils with or without Induced Oxidative Stress

  • Yun, Jung-Mi;Surh, Jeong-Hee
    • Preventive Nutrition and Food Science
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    • v.17 no.2
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    • pp.158-165
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    • 2012
  • This study was designed to investigate whether the fatty acid composition could make a significant contribution to the oxidation stability of vegetable oils marketed in Korea. Ten kinds, 97 items of vegetable oils that were produced in either an industrialized or a traditional way were collected and analyzed for their fatty acid compositions and lipid oxidation products, in the absence or presence of oxidative stress. Peroxidability index (PI) calculations based on the fatty acid composition ranged from 7.10 to 111.87 with the lowest value found in olive oils and the highest in perilla oils. In the absence of induced oxidative stress, malondialdehyde (MDA), the secondary lipid oxidation product, was generated more in the oils with higher PI (r=0.890), while the tendency was not observed when the oils were subjected to an oxidation-accelerating system. In the presence of the oxidative stress, the perilla oils produced in an industrialized manner generated appreciably higher amounts of MDA than those produced in a traditional way, although both types of oils presented similar PIs. The results implicate that the fatty acid compositions could be a predictor for the oxidation stability of the vegetable oils at the early stage of oil oxidation, but not for those at a later stage of oxidation.

The Analysis of the Oxidation Index of Korea Traditional Paper(Hanji) Which Is Used as the Rrestoration Paper of the Waxed Volume in the Annals of Joseon Dynasty (조선왕조실록 밀랍본 복원용지로서 전통한지의 oxidation index 분석)

  • Seo, Jin-Ho;Jeong, So-Young;Jeong, Seon-Hwa
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.1
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    • pp.55-61
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    • 2008
  • The annals of Joseon Dynasty is the most valuable resource containing the record of Korean history and has been known as one of the UNESCO's Memory of the World Register. In some period, wax-treated paper was used in the annals of Joseon Dynasty to prevent the damage from pests. But, wax-treated volumes were discolored to brown, white or black, and partially cracked by the stiffened wax. It means that wax-treated volumes were damaged by the hardening and oxidizing of wax. The wax is considered as the first reason in damages on the wax-treated volume. Therefore, in this study we analysed the oxidation index of Korea traditional paper(Hanji) which is used as the restoration paper of the waxed volume in the annals of Joseon Dynasty by using FT-IR. As the analysis of FT-IR, the traditional two-layed stamping paper (Hanji sample F), which was treated by starch in its surface, was shown the most stable state after the accelerated ageing test.

Determination of Kinetic Parameters in Coal Weathering Processes

  • Yun, Yongseung
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1993.11a
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    • pp.31-36
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    • 1993
  • Three different methods were employed to measure the degree of aerial oxidation in coal and the resulting oxidation/weathering indices were applied to obtain kinetic parameters of aerial oxidation processes, The index (i.e., slurry pH, Free Swelling Index, weight gain) values were subjected to kinetic analysis based on power-law Arrhenius type reaction model. The results show that activation energy of the aerial oxidation in 20-29$0^{\circ}C$ is in the range of 12-16 ㎉/㏖ and the agreement among three techniques is remarkable. The first order kinetic model is suitable in describing low temperature aerial oxidation process, except in the FSI case where the zero order expression is the best one.

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Color Evolution in Anodized Titanium (열산화에 의한 티타늄의 발색효과)

  • 송오성;홍석배;이정임
    • Journal of the Korean institute of surface engineering
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    • v.35 no.5
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    • pp.325-329
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    • 2002
  • We investigated the oxide thickness and color evolution with the oxidation temperatures between $370^{\circ}C$ and $950^{\circ}C$ for 30 minutes in an electric furnace. Oxide thickness and color index were determined by cross sectional field emission scanning electron microscopy (FESEM) images and digital camera images, respectively. We confirmed that thermal oxidation was suitable for the mass production of color-titanium products, while coloring process window was narrow compared with anodizing oxidation process.

Finding interstitial oxygen in an Si substrate during low temperature plasma oxidation

  • Kim, Bo-Hyun;Ahn, Jin-Hyung;Ahn, Byung-Tae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.690-693
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    • 2003
  • An Si substrate (100) was oxidized at $400^{\circ}C$ in inductively coupled oxygen plasma. Interstitial oxygen was found in the Si substrate at the initial stage of oxidation by IR measurements. An x-ray rocking curve of Si substrates showed a lower peak intensity due to lattice distortion by the interstitial oxygen. The refractive index of thin oxides, below which interstitial oxygen existed in the Si substrate, was smaller than the refractive index of thick oxides, below which no interstitial oxygen existed. The interstitial oxygen was found by plasma oxidation using $O_{2}$ gas and $N_{2}O$ gas. The inductively coupled plasma oxidation using $N_{2}O$ gas was performed by atomic oxygen, not by molecular oxygen, indicating that atomic oxygen in plasma is responsible for the incorporation of interstitial oxygen.

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Antioxidant Effect of Soyasaponin on the Liposomal Phospholipid Membrane (인지질 Loposome 에 미치는 대두 Saponin의 항산화효과)

  • 신미옥;배송자;김남홍
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.21 no.4
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    • pp.381-385
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    • 1992
  • The effect of antioxidant activity of soyasaponin on the liposomal phospholipid membrane were investigated by spectrophotometry. The oxidation index and oxidation rate of ${\alpha}-tocopherol$ containing egg phosphatidylcholine (EPC) liposomes were markedly decreased in the presence of soyasaponin relative to those of purephospholipid liposmes. ${\alpha}-tocopherol$ containing liposomes delayed the oxidation of liposomes. Especially soyasaponin stimulated the antioxidant activity of ${\alpha}-tocopheroal$ in liposomes. These results indicates that soyasaponin in liposomes had some additive effect on antioxidant of ${\alpha}-tocopherol$ toward liposomes.

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Synthesis of High Refractive Spiroheterocyclic Derivatives Through Thioacetalization of Multi-Carbonyl Compounds

  • Ye, Ji-Myoung;Maheswara, Muchchintala;Do, Jung-Yun
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2494-2498
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    • 2012
  • Preparation of several new spirocyclic mercapto derivatives is described. Thiol protection on multi-carbonyl compounds allows of high sulfur content necessary to induce high refractive index. Condensation of 1,3-dimercapto-2-propanol and cyclohexanone followed by successive oxidation and thioacetalization affords a dispirocycle with four sulfurs. Selective S,S-protection of cyclohexane-1,4-dione is achieved with 1,3-dimercapto-2-propanol and 2,3-dimercapto-1-propanol to provide dispirocycles with four sulfurs. Olefine-oxidation of norbornene gives a useful dialdehyde intermediate which is transformed to 1,3-dithiolane for a linearly-bound-cyclic molecule. Refractive index of linearly-bound-cycles was below 1.60 and dispirocycles exhibited high refractive index of 1.57-1.69.

Non-Constructive analysis for the cover and inner paper in the Taebaeksan volume of Joseon Dynasty annals (조선왕조실록 태백산사고본 표지 및 내지의 비파괴적 특성 연구)

  • Cho, Jung-Hye;Kim, Kang-Jae;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.42 no.3
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    • pp.28-36
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    • 2010
  • Today We have three full series of the annals of Joseon Dynasty. Taebaeksan volume which is one of them shows comparatively good maintenance but Taebaeksan volume also decomposed in patches. The size of cover and inner paper were increased in late Joseon Dynasty, but the weight, thickness and basis weight bears no relation to each other. The oxidation index of paper in annals of pre-periods of King Sunjo shows very high value. After the annals of King Sunjo, the oxidation index of paper is very similar to today's Hanji. L.a.b values of inner paper in the Taebaeksan volume are similar generally. The average length of fiber using image analysis soft ware is 8.08~9.92 mm, that like immediate value of measurement. The air fraction of fiber's range is 1.20~2.12%. It lower than today's Hanji. After considering the factors of the length of fiber, air fraction and FE-SEM, we reached that no difference between raw material of inner paper in the Taebaeksan volume.

The Effect of Ginseng Extracts on the Photooxidation of Liposome I. The protective effect of the formation of hydroperoxides (Liposome의 광산화반응에 미치는 인삼추출물의 영향 제1보. Hydroperoxide 생성 억제 효과)

  • Baek, Tae-Hong;Kim, Yeong-Ho;Lee, Jun-Hong
    • Journal of Ginseng Research
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    • v.14 no.3
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    • pp.379-384
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    • 1990
  • In order to study the lipid peroxidation caused by light and the protective action it in biological memberane, reverse-phase evaporation liposome (REV) was employed as a model memberance and the effect of several antioxidants and ginseng water extracts were tested. In the presence of photosensitizer, liposome was oxidized easily and the oxidation index dut to the peroxidation was increased. The oxidation index of liposome was increased according to the increase in temperature. When dl-${\alpha}$-tocopherol, ${\beta}$-carotene or L-ascorbic acid was added into the reaction mixture, the photooxidation of liposome was inhibited. Ginseng water extract and crude saponin inhibited the rate of oxidation index of liposome in low concentration but increase in high concentration. On the other hand, when lipid hydroperoxide of liposome was tested by ferrothiocyanate method, ginseng water extract and crude saponin acted as antioxidants.

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Comparing Physicochemical Properties, Fatty Acid Profiles, Amino Acid Composition, and Volatile Compounds in Dry-Cured Loin: The Impact of Different Levels of Proteolysis and Lipid Oxidation

  • Jin-Kyu Seo;Youn Su Lee;Jeong-Uk Eom;Han-Sul Yang
    • Food Science of Animal Resources
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    • v.44 no.1
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    • pp.103-118
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    • 2024
  • The aim of this study is to compare the quality characteristics of dry-cured loins with different levels of proteolysis and lipid oxidation and to investigate the relationship between these factors on quality characteristics. The dry-cured loins were divided into four groups [proteolytic index (PI) and 2-thiobarbituric acid reactive substances (TBARS) of high levels (HH), PI of high level and TBARS of low level (HL), PI of low level and TBARS of high level (LH), and PI and TBARS of low levels (LL)] based on the proteolysis index and TBARS. Moisture, protein, and fat content were all significantly influenced by proteolysis and lipid oxidation (p<0.05). The total fatty acid content in the high proteolysis groups (HH and HL) was significantly lower than that in the low proteolysis groups (LH and LL; p<0.05). For total free amino acid content, HH was the highest, and LL was the lowest (p<0.05). On the other hand, there was no significant difference between HL and LH (p>0.05). In the amount of total volatile compounds, there was no significant difference between HH and HL (p>0.05), but LH and LL significantly differed (p<0.05). In conclusion, proteolysis and lipid oxidation can influence the quality characteristics of dry-cured loin. Additionally, proteolysis might be as influential in generating volatile compounds as lipid oxidation.