• Title/Summary/Keyword: over-potential

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천연 물질을 이용한 이산화탄소 하이드레이트 형성 억제 (Natural Inhibitors for $CO_2$ Hydrate Formation)

  • 사정훈;이보람;박다혜;한건우;전희동;이건홍
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
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    • pp.122.1-122.1
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    • 2011
  • The motivation for this work was the potential of hydrophobic amino acids such as glycine, L-alanine, and L-valine to be applied as thermodynamic hydrate inhibitors (THIs). To confirm their capabilities in inhibiting the formation of gas hydrates, three-phase (liquid-hydrate-vapor) equilibrium conditions for carbon dioxide hydrate formation in the presence of 0.1 to 3.0 mol% amino acid solutions were determined in the range of 273.05 to 281.45 K and 14.1 to 35.2 bar. From quantitative analyses, the inhibiting effects of the amino acids (on a mole concentration basis) decreased in the following order: L-valine > L-alanine > glycine. The application of amino acids as THIs has several potential advantages over conventional methods. First, the environmentally friendly nature of amino acids as compared to conventional inhibitors means that damage to ecological systems and the environment could be minimized. Second, the loss of amino acids in recovery process would be considerably reduced because amino acids are non-volatile. Third, amino acids have great potential as a model system in which to investigate the inhibition mechanism on the molecular level, since the structure and chemical properties of amino acids are well understood.

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Ni 나노 분말을 이용한 안정한 현탁액 제조 및 특성 (Preparation and Characterization of Stable Suspensions of Ni Nanoparticles)

  • 이은희;이민구;이창규
    • 한국분말재료학회지
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    • 제13권2호
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    • pp.138-143
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    • 2006
  • In this study, the effects of the dispersants, i.e., Hypermer KD-2 and poly(l-vinyl-2-pyrrolidone) (PVP), and their concentration on the dispersion stability of Ni nanoparticles ($10nm{\sim}40nm$) in ethanol were investigated by using a visual inspection, a transmission profile (Turbiscan), and a zeta potential measurement. The transmission profiles measured by Turbiscan showed that the particle size increased over the entire height of the sample for suspensions with both the dispersants without showing any particle coalescence and sedimentation. The visual inspection also confirmed that the Ni suspensions with Hypermer KD-2 and PVP were very stable for more than a year. The zeta potential values varied from positive to negative with increasing the dispersant's concentration. The dispersion stability of the suspensions was not affected by both the dispersant's concentration and the zeta potential values. The observed suspension stability of Ni nanoparticles was attributed to the steric effect for the Hypermer KD-2 and to the bridging effect for the PVP.

Structure and Vorticity of the Current Observed Across the Western Channel of the Korea Strait in September of 1987-1989

  • Byun, Sang-Kyung;Kaneko, Arata
    • Ocean and Polar Research
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    • 제21권2호
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    • pp.99-108
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    • 1999
  • With sectional data obtained in September of 1987, 1988 and 1989 by quadrireciprocal ADCP measurement and CTD cast, the current structure, volume transport and vorticity in the Western Channel of the Korea Strait were studied. The characteristics of Tsushima Current water persisted throughout the summer especially in the homogeneous water of temperature $14-16^{\circ}C$ located at the depth of 50-100m below seasonal termocline. Thickness and velocity of the homogeneous layer are about 10-170m and 20-60cm/s. and the relative vorticity for this layer is shown to be nearly constant and it is smaller than the planetary vorticity. Potential vorticity of $2.70-7.10{\times}10^{-6}m^{-1}s^{-1}$ is found to be dependent mainly on planetary rather than on the relative vorticities. The Tsushima Current water represented by the homogeneous layer R14-16^{\circ}C$ may keep the potential vorticity at the area of strong current in the Strait. The ADCP current structure is similar to geostrophic current and the core of the current with the speed of 30-50cm/s is situated in the middle layer over the deep trough. With large tidal fluctuation the volume transport has mean value of 1.17sv which was about 40% larger than that of geostrophic calculation.

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초공동(超空洞) 유동 문제의 형상 설계민감도 해석 (Shape Design Sensitivity Analysis of Supercavitating Flow Problem)

  • 최주호;곽현구
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2004년도 춘계학술대회
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    • pp.1047-1052
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    • 2004
  • An efficient boundary-based technique is developed for addressing shape design sensitivity analysis in supercavitating flow problem. An analytical sensitivity formula in the form of a boundary integral is derived based on the continuum formulation for a general functional defined in potential flow problems. The formula, which is expressed in terms of the boundary solutions and shape variation vectors, can be conveniently used for gradient computation in a variety of shape design in potential flow problems. While the sensitivity can be calculated independent of the analysis means, such as the finite element method (FEM) or the boundary element method (BEM), the FEM is used for the analysis in this study because of its popularity and easy-touse features. The advantage of using a boundary-based method is that the shape variation vectors are needed only on the boundary, not over the whole domain. The boundary shape variation vectors are conveniently computed by using finite perturbations of the shape geometry instead of complex analytical differentiation of the geometry functions. The supercavitating flow problem is chosen to illustrate the efficiency of the proposed methodology. Implementation issues for and optimization procedure are addressed in this flow problem.

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3 차원 시간영역 전진속도 자유표면 Green 함수와 2 차 경계요소법을 사용한 선체의 방사포텐셜 수치계산 (Numerical Study of the Radiation Potential of a Ship Using the 3D Time-Domain Forward-Speed Free-Surface Green Function and a Second-Order BEM)

  • 홍도천;홍사영
    • 대한조선학회논문집
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    • 제45권3호
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    • pp.258-268
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    • 2008
  • The radiation potential of a ship advancing in waves is studied using the 3D time-domain forward-speed free-surface Green function and the Green integral equation. Numerical solutions are obtained by making use of the 2nd order BEM(Boundary Element Method) which make it possible to take account of the line integral along the waterline in a rigorous manner. The 6 degree of freedom motion memory functions of a hemisphere and the Wigley seakeeping model obtained by direct integration of the time-domain 3D potentials over the wetted surface are presented for various Froude numbers.

Antiviral Potential of the Silkworm Deoxynojirimycin against Hepatitis B Virus

  • You, Jung-Eun;Seong, Su-Il;Kim, Young-Ho
    • International Journal of Industrial Entomology and Biomaterials
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    • 제7권2호
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    • pp.139-144
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    • 2003
  • Over 350 million people worldwide are chronic carriers of hepatitis B virus (HBV). Chronic viral infections of the liver can progress to cirrhosis, which may ultimately lead to hepatic failure or the development of hepatocellular carcinoma. There are two antiviral drugs on the market approved for clinical management of chronic HBV infections; interferon-alpha and the nucleoside analog lamivudine. However, they showed adverse side-effects. In the rational drug design for such therapies we would like to utilize antiviral drugs that inhibit the HBV replication in the liver. Investigation of natural extracts of silkworm exhibiting antiviral potential was held in the functional HBV polymerase activity and the release of virion particle in the HepG2.2.15 cell lines. HBV-producing transgenic mouse fed with silkworm DNJ molecule was shown as an inhibitor of serum HBV particles. We could represent this DNJ molecule as an antiviral potential complementing conventional therapies after preclinical tests against WHBV-infected animal model, woodchuck.

봉상접지전극의 접지임피던스의 주파수의존성의 분석 (Analysis of the Frequency Dependent Characteristics of Ground Impedance of a Ground Rod)

  • 이복희;엄주홍
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제53권8호
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    • pp.426-432
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    • 2004
  • This paper presents a systematic approach of measurement, modeling and analysis of grounding system impedance in the field of lightning protection system and intelligent power equipments. The measurement and analysis system of ground impedance is based on a computer aided technique. The magnitude and phase of ground impedance were determined by the novel measurement and analysis using the revised fall-of-potential method. The ground impedances of the ground rod of 50 m long are considerably dependent on the frequency. The ground impedance is mainly resistive in the frequency range of 3-20 kHz. At higher frequencies, the reactive components of the ground impedances are no longer negligible and the inductance of the ground rod was found to be the core factor deciding the ground impedance. Although the steady-state ground resistance of the ground rod of 50 m was less than that of the ground rod of 10 m, the ground impedances of the ground rod of 50 m over the frequency range of more than 60 kHz were much greater than those of the ground rod of 10 m. Furthermore, the equivalent circuit model based on the measured data was proposed. and the calculated results were in approximately agreement with the measured data.

Heliocentric Potential (HCP) Prediction Model for Nowscast of Aviation Radiation Dose

  • Hwang, Junga;Kim, Kyung-Chan;Dokgo, Kyunghwan;Choi, Enjin;Kim, Hang-Pyo
    • Journal of Astronomy and Space Sciences
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    • 제32권1호
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    • pp.39-44
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    • 2015
  • It is well known that the space radiation dose over the polar route should be carefully considered especially when the space weather shows sudden disturbances such as CME and flares. The National Meteorological Satellite Center (NMSC) and Korea Astronomy and Space Science Institute (KASI) recently established a basis for a space radiation service for the public by developing a space radiation prediction model and heliocentric potential (HCP) prediction model. The HCP value is used as a critical input value of the CARI-6 and CARI-6M programs, which estimate the aviation route dose. The CARI-6/6M is the most widely used and confidential program that is officially provided by the U.S. Federal Aviation Administration (FAA). The HCP value is given one month late in the FAA official webpage, making it difficult to obtain real-time information on the aviation route dose. In order to overcome this limitation regarding time delay, we developed a HCP prediction model based on the sunspot number variation. In this paper, we focus on the purpose and process of our HCP prediction model development. Finally, we find the highest correlation coefficient of 0.9 between the monthly sunspot number and the HCP value with an eight month time shift.

단일 경화 모델의 검증 (Verification of Single Hardening Model)

  • 김대규
    • 한국산학기술학회논문지
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    • 제8권4호
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    • pp.821-825
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    • 2007
  • 본 연구에서는 응력이력 의존적 소성포텐셜을 도입한 단일 경화 모델의 검증을 정규압밀, 약간 과압밀, 심한 과압밀 점토시료에 대하여 수행하였다. 단일 경화 모델은 한계상태 토질역학을 기본으로 비교적 적은 매개변수를 채택하여 최근에 개발된 탄소성 모델이다. 삼축압축시험이 정밀하게 수행되었으며 시험결과는 모델의 예측결과와 전반적으로 잘 부합하였다. 시험결과와의 차이는 단일 경화 모델이 주로 주응력 회전을 강조하기 때문이다. 그러나 소성일 H 및 주응력 회전각 변수를 통하여 지반재료에서 응력이력을 효과적으로 소성일에 반영할 수 있다는 사실이 검증되었다.

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Gibbs Ensemble Monte Carlo Simulation for Vapor-Liquid Equilibrium of Binary Mixtures $CO_2/C_3H_8$, $CO_2/CH_3OCH_3$, and $CO_2/CH_3COCH_3$

  • 문성두;문병기
    • Bulletin of the Korean Chemical Society
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    • 제21권11호
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    • pp.1133-1137
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    • 2000
  • Gibbs ensemble Monte Carlo simulations were performed to calculate the vapor- liquid coexistence properties for the binary mixtures $CO_2/C_3H8$, $CO_2/CH_3OCH_3$, and $CO_2/CH_3COCH_3.$ For all the molecules the potential between sites in different molecules was simply calculated by the Lennard-Jones potential. Density of the mixture, composition of the mixture, the pressure-composition diagram, the chemical potential of component, and the radial distribution function were calculated at vapor- liquid equilibrium. The composition and the density of both vapor and liquid from simulation agreed considerably well with the experimental values over a wide range of pressures. The radial distribution functions in the liquid mixtures showed that $CO_2$ molecules tended to form cluster with each other and $C_3H8$ molecules also aggregated each other due to the weak interaction between $CO_3$ and $C_3H8$ molecule. However the interaction potentials between the same components were similar to those between the different components in the liquid mixtures $CO_2/CH_3OCH_3$ and $CO_2/CH_3COCH_3$.