• Title/Summary/Keyword: organic-inorganic hybrid materials

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Colloidally stable organic-inorganic hybrid nanoparticles prepared using alkoxysilane-functionalized amphiphilic polymer precursors and mechanical properties of their cured coating film

  • Kim, Nahae;Li, Xinlin;Kim, Se Hyun;Kim, Juyoung
    • Journal of Industrial and Engineering Chemistry
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    • v.68
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    • pp.209-219
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    • 2018
  • Colloidally stable organic-inorganic (O-I) hybrid nanoparticles could be prepared using an alkoxysilanefunctionalized amphiphilic polymer (AFAP) precursor. O-I hybrid sols could maintain colloidal stability for six months even at 45% solid content and be coated onto glass as well as PET film to form transparent O-I hybrid films. The formation of O-I hybrid nanoparticles dispersed in cured coating films could be confirmed using scanning electron microscopy. The cured coating film showed 3H and 5H pencil hardness on PET and glass, respectively. Nanoindentation measurements also showed that their modulus and hardness was varied with the type of AFAP used in its preparation.

Development of Organic-Inorganic Hybrid Insulating Materials with Semi-Non-Combustible Using by Recycling Gypsum (재활용 석고 부산물을 이용한 준불연 유무기 융합 단열재 개발 연구)

  • Ha, Joo-Yeon;Shin, Hyun-Gyoo;Song, Tae-Hyeob
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.4
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    • pp.431-437
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    • 2019
  • The purpose of this study is to develop an organic-inorganic hybrid insulation materials which has an economic feasibility of organic level and excellent adiabatic performance and fire stability by impregnating organic materials with inorganic binder solutions. The organic base was commercial polyurethane sponge, and the inorganic binder slurry was prepared by mixing water and additives into recycled gypsum byproducts. As a result of evaluation of the developed materials, it was confirmed that it not only has excellent insulation performance of a thermal conductivity of 0.051 W/mK or less but also it is a semi-non-combustible materials specified in the Ministry of Land, Infrastructure and Transport Notice No. 2015-744. The developed materials can also be controlled for thermal conductivity and flame retardance according to density control during manufacturing process, and thus it can be applied to various insulation materials.

Optimization Amorphous Silicon Tandem Cell for an applying Inorganic-organic Hybrid Cell (유무기 하이브리드 태양전지 적용을 위한 탠덤형 비정질 실리콘 태양전지 최적화 기술)

  • Jinjoo Park;Sangmin Yoo
    • Current Photovoltaic Research
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    • v.12 no.3
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    • pp.80-85
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    • 2024
  • Purpose of higher conversion efficiencies, thin-film silicon solar cells based on amorphous silicon have been developed with a multiple-stack structure to fully utilize the absorption spectrum. Microcrystalline silicon (µc-Si) is commonly used in the bottom cell of such tandem junction solar cells, offering improved conversion efficiencies. However, the requirement for a thicker absorption layer to generate sufficient photocurrent presents challenges, primarily due to the lower absorption coefficient of µc-Si, resulting in longer deposition times and greater material thickness. To address these limitations, we propose the development of inorganic-organic hybrid solar cells by integrating a-Si tandem with solution-processed organic photovoltaic cells (OPVs), using low-bandgap semiconducting polymers. The OPVs have garnered significant attention as promising candidates for next-generation photovoltaic technology. As part of this effort, we have optimized the a-Si tandem cell by exploring different materials for a tunnel recombination layer and high quality intrinsic layers. The hybrid approach combines the advantages of both inorganic and organic materials, potentially offering a pathway towards more efficient and cost-effective solar cell solutions.

Preparation and Characterization of Hybrid Silica-Poly(ethylene glycol) Sonogel

  • Jung, Hwa-Young;Gupta, Ravindra K.;Seo, Dong-Won;Kim, Yoo-Hang;Whang, Chin-Myung
    • Bulletin of the Korean Chemical Society
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    • v.23 no.6
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    • pp.884-890
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    • 2002
  • An inorganic-organic hybrid system, silica-poly(ethylene glycol) songel is reported. This system was prepared via sol-gel method by varying varous processing variables. e.g. ultrasonic radiation time, gelling temperanture, PEG content and its molecular weight. Various experimental techniques wee employed to analyze the morphological, mechanical and optical properties of the system. The results were discussed in the light of existing theories. The sonogel system exhibited the common features of inorganic-organic hybrids. $SiO_2-10$ wt% PEG sonogel exhibited the morphological and optical properties superior to those reported earlier for the classic gels and found suitable for device applications.

Synthesis and Etch Characteristics of Organic-Inorganic Hybrid Hard-Mask Materials (유-무기 하이브리드 하드마스크 소재의 합성 및 식각 특성에 관한 연구)

  • Yu, Je-Jeong;Hwang, Seok-Ho;Kim, Sang-Bum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.4
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    • pp.1993-1998
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    • 2011
  • Semiconductor industry needs to have fine patterns in order to fabricate the high density integrated circuit. For nano-scale patterns, hard-mask is used to multi-layer structure which is formed by CVD (chemical vaporized deposition) process. In this work, we prepared single-layer hard-mask by using organic-inorganic hybrid polymer for spin-on process. The inorganic part of hard-mask was much easier etching than photo resist layer. Beside, the organic part of hard-mask was much harder etching than substrate layer. We characterized the optical and morphological properties to the hard mask films using organic-inorganic hybrid polymer, and then etch rate of photo resist layer and hard-mask film were compared. The hybrid polymer prepared from organic and inorganic materials was found to be useful hard-mask film to form the nano-patterns.

High performance Organic-Inorganic Hybrid Materials for Application in OLED Barrier Coating

  • Jung, Kyung-Ho;Yun, Chang-Hun;Bae, Jun-Young;Yoo, Seung-Hyup;Bae, Byeong-Soo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.806-809
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    • 2009
  • Epoxy functionalized organic-inorganic hybrid materials (hybrimers) were synthesized by sol-gel reaction for application in OLED barrier coating. By using the calcium degradation method, the oxygen transition rate (OTR) and water vapor transition rate (WVTR) measured so far is $10^{-2}cc/m^2$-day for oxygen and $10^{-1}g/m^2$-day for water molecules with single hybrimer coating film, respectively. Encapsulated OLED devices have life time of 14hrs of a single hybrimer barrier coating and 29hrs of hybrimer/inorganic double barrier coatings at $25^{\circ}C$ and 60% relative humidity.

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Fabrication of PMMA-HfOx Organic-Inorganic Hybrid Resistive Switching Memory (PMMA-HfOx 유-무기 하이브리드 저항변화 메모리 제작)

  • Baek, Il-Jin;Cho, Won-Ju
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.3
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    • pp.135-140
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    • 2016
  • In this study, we developed the solution-processed PMMA-$HfO_x$ hybrid ReRAM devices to overcome the respective drawbacks of organic and inorganic materials. The performances of PMMA-$HfO_x$ hybrid ReRAM were compared to those of PMMA- and $HfO_x$-based ReRAMs. Bipolar resistive switching behavior was observed from these ReRAMs. The PMMA-$HfO_x$ hybrid ReRAMs showed a larger operation voltage margin and memory window than PMMA-based and $HfO_x$-based ReRAMs. The reliability and electrical instability of ReRAMs were remarkably improved by blending the $HfO_x$ into PMMA. An Ohmic conduction path was commonly generated in the LRS (low resistance state). In HRS (high resistance state), the PMMA-based ReRAM showed SCLC (space charge limited conduction). the PMMA-$HfO_x$ hybrid ReRAM and $HfO_x$-based ReRAM revealed the Pool-Frenkel conduction. As a result of flexibility test, serious defects were generated in $HfO_x$ film deposited on PI (polyimide) substrate. On the other hand, the PMMA and PMMA-$HfO_x$ films showed an excellent flexibility without defect generation.

Fabrication of Flexible Inorganic/Organic Hybrid Thin-Film Transistors by All Ink-Jet Printed Components on Plastic Substrate

  • Kim, Dong-Jo;Lee, Seong-Hui;Moon, Joo-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1463-1465
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    • 2008
  • We report all-ink-jet printed inorganic/organic hybrid TFTs on plastic substrates. We have investigated the optimal printing conditions to make uniform patterned layers of gate electrode, dielectrics, source/drain electrodes, and semiconductor as a coplanar type TFT in a successive manner. All ink-jet printed devices have good mechanical flexibility and current modulation characteristic even when bent.

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