• Title/Summary/Keyword: organic substances

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Groundwater Contamination by Cation, Anion and Pesticides (지하수중 음이온, 양이온, 및 금속의 함량)

  • 김형석;정세영;최중명
    • Journal of environmental and Sanitary engineering
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    • v.7 no.2
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    • pp.111-128
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    • 1992
  • According to the increase of population and industrialization, the quality of our drinking water are becoming worse by the contamination of resources, production of THM and other halogenated hydrocarbons during the purifying process, the problem of corroded water supplying pipeline, and the water reservoir tanks, Many people choose groundwater to drink instead of city tap water, but sometimes we get report about groundwater contamination by wastes, swage, septic tank, etc. It is reported that in U. S. over 20% of population are drinking groundwater, but U. S EPA reported the groundwater contamination by pesticides, herbicides, fungicides, fertilizer, and various chemical substances. Craun, et at announced the groundwater contamination by bacteria which are related with poor installation of septic tank. Johnson and Kross mentioned aboutmethemoglobinemia by NO3-N originated from human and animal feces, organic chemicals, and fertilizer, and as the results the infant mortality could be risen. Some scientist also reported the high concentration of metals in groundwaters and some cation and anions, and volatile organic compou nds. Authors investigated 80 groundwaters in urban, agricultural, and industrial area during last 3 month(June - August) to check any drinking water quality parameters are exceeding the standards. The results were as follow. 1, The average value of ammonia nitrate were within the standard, but 11.76% of urban area were exceeded the 10 rpm standard, in agricultural area 42.3175 were exceeded, and in industrial area 20.2% were exceeded the drinking water standard of 10 ppm. the highest concentration was 29.37 ppd in industrial area. 2. The mean value of metals is not exceeded the standard, but there were some groundwater whose Mn value was 0.424 ppm(standard is 0,3 ppm) in urban area, 0.737 rpm in agricultural area, and 5.188 ppm in industrial area. The highest Zn value was 1.221 ppm (standard is 1.0 ppm)was found in industrial area. 3. The percentage of contamination by general bacteria was 8.82% in urban area, 15.38% in agricultural area, and 15.00% in industrial area. Escherichia coil group was also contaminated by 35.29% in urban area, 30.76% in agricultural area, and 30.00% in industrial area. 4, The pH value was within the standard which means there was no influence by acid or alkali chemicals, nor acid rain Through the above results, all the groundwater should be tested to check the safety for drinking water and should make some alternative methods suitable for drink.

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A Study on the Improvement of Marine Pollution and Marine Litter Managements in Korea (우리나라 해양오염 및 해양폐기물관리 개선에 관한 연구)

  • Park, Kwang-Ha;Kwon, Young-Du;Kim, Jong-Sung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.21 no.4
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    • pp.33-43
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    • 2013
  • That occur in the ocean and the efficient management of marine litter on marine pollution oil spill response one step further strategies are needed. Marine pollution accidents occurred in 2011, a total of 287 and was found in runoff 369 kL, respectively compared to the previous year decreased by 13% and 39%. Average amount of marine materials during 5-years represent the oil flow of 310.5 kL (heavy fuel oil of 106.0 kL, diesel of 178.9 kL, oily bilge water of 22.3 kL, other oil of 7.7 kL) and the waste of 62.3 tons, the hazardous and noxious substances (HNS) was 510.6 kL. Marine emissions in 2011 by type of waste that a total amount of dumping 3,972 $m^3$, and livestock manure 795 $m^3$(20%), waste water 1,431 $m^3$(36%), sewage sludge 887 $m^3$(22%), wastewater sludge, 813 $m^3$(21%), manure 5 $m^3$(0.1%), other 41 $m^3$(0.9%), respectively. The concept of marine waste and needs to be more clearly defined. Integrated management of hazardous chemicals according to the incident management system should be established. To remove of coastal pollution, response officer needs korean coast response system. Like the marine pollution response, coastal pollution response systems also require step response.

Changes of the Physico-Chemical and Microbiological Properties during Composting for Composting of Sewage Sludge (하수슬러지의 퇴비화과정 중 이화학성 및 미생물상 변동)

  • Lee, Hong-Jae;Cho, Ju-Sik;Bahn, Kyeong-Nyeo;Heo, Jong-Soo;Shin, Won-Kyo
    • Korean Journal of Environmental Agriculture
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    • v.17 no.1
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    • pp.16-21
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    • 1998
  • To study the possibility of agricultural utilization of sewage sludge, the changes of the substances physico-chemical and microbiological properties composting periods such as inorganic matter, the form of organic matter and nitrogen and the kinds and the population number of microorganisms were investigated. The results were summarized as follows ; Temperature and $CO_2$ generation, they were the highest in the second day of composting periods and then were gradually fallen. pH value was not changed in first day during composting periods, but in second day was rapidly increased and then it was constant of the range of 8.4∼8.6. The contents of $P_2O,\;K_2O$, CaO and Fe were a little increased during composting periods, while that of ${SO_4}^{2-}$and Mn were big increased with 253${\sim}$331% and 191${\sim}$208% in late composting periods in comparing with early composting periods, respectively. The contents of ether extracted materials, water soluble polysaccharides, hemicellulose and cellulose were decreased but that of resins and lignin were not changed during composting periods. The contents of total and organic nitrogen during composting periods were decreased with 15${\sim}$20% and 22${\sim}$35%, respectively, while that of inorganic nitrogen was decreased with 75${\sim}$116%. The population numbers of microorganism during composting periods was much too changed according to the kinds of microorganism and composting periods.

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Oxidative Stability of the Pine Needle Extracted Oils and Sensory Evaluation of Savored Laver Made by Extracted Oils (솔잎추출유의 산화 안정성 및 추출유를 이용한 맛김의 관능적 평가)

  • Chung, Hae-Kyung;Choe, Chang-Suk;Lee, Ji-Hyun;Chang, Moon-Jeong;Kang, Myung-Hwa
    • Journal of the Korean Society of Food Culture
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    • v.18 no.2
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    • pp.89-95
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    • 2003
  • In order to evaluate the oxidative stability and sensory evaluation for the pine needle extracted oils, we prepared the pine needle extracted oils by the autoclave method with soybean and/or olive oils. The lipid peroxidation was monitored by measuring the formation of 2-thiobarbituric acid reactive substances(TBARS). In addition, the secondary reaction products of lipid oxidation were measured by fluorescence spectroscopy. A weight changing was decreased in oils added pine needle during storage periods. The formation of TBARS was the lowest in olive pine needle oils after 14 days storage, whereas it was the highest in soybean oil. The levels of fluorescent products in extracted oils added pine needle were also decreased in organic layers. According to the sensory evaluation, the scores of fragrance, taste and overall preference in savored laver using an pine needle extracted oils were no significant differences. Overall results suggest that the pine needle extracted oils can be developed to functional oil resources.

Monitoring of Pesticide Residues and Preservatives in Cosmetics Using Natural Materials (천연물질 사용 화장품의 잔류농약과 보존제 모니터링)

  • Park, Eun-Mi;Um, Mi-Na;Kim, Beom-Ho;Cho, Sang-Hun;Park, Sin-Hee;Jo, Hyun-Ye;Yoon, Mi-Hye;Lee, Jong-Bok
    • Journal of Food Hygiene and Safety
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    • v.27 no.3
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    • pp.257-263
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    • 2012
  • Cosmetics using natural materials which was purchased in retail stores, distributed in Gyeonggi province(32 samples) and online through internet(24 samples) were analyzed by pesticide residues and target preservatives for assessing the safety of it. Natural or organic certifications was identified in 22 samples among 56 samples and most of them were Ecocert. Pesticide residues was detected in 3 samples among 56 samples and each compound and concentration was permethrin(0.6 mg/kg), tricyclazole(11.7 mg/kg) and malathion(0.05 mg/kg). All of it was purchased through internet. Target preservatives was detected in 13 samples among 56 samples and one of them was over the maximum allowed concentration and the rest of them were within the maximum allowed concentration of the respective preservatives. The compound which was over the maximum allowed concentration was benzoic acid and compounds which were within the maximum allowed concentration were sorbic acid, benzoic acid and methylparaben. They were all identified substances in products and the number of detected preservatives in retail stores were higher than online samples purchased through internet. As a result of this study, The method of analyzing pesticide residues and limit in cosmetics using natural materials should be set up as soon as possible and the monitoring about preservatives in cosmetics using natural materials should be conducted on continuously.

Preparation of Natural Wall Paint by Using Sericite Clay (견운모를 이용한 벽마감용 천연페인트 제조)

  • Kim, Munui;Lalhmunsiama, Lalhmunsiama;Lee, Seung-Mok;Jin, Kang-Jung
    • Applied Chemistry for Engineering
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    • v.28 no.5
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    • pp.501-505
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    • 2017
  • Due to the rapid urbanization and increased population, there is an increase in airtight nature of buildings which causes serious indoor air pollution. Among several indoor air pollutants, volatile organic compounds (VOCs) emitted from paint are of major concern. Therefore, there is an urge for the development of environmental friendly paint products. In this wok, a natural wall paint (NWP) was prepared by utilizing a natural clay material "sericite" as a main component. A small chamber test was carried out to identify the toxic substances release from NWP and the results were compared with two eco-friendly commercial paints. The total VOCs were detected in trace level inside the test chamber and their concentrations were below the recommended indoor air quality standards. Toluene was not detected for NWP, whereas formaldehyde was observed in trace level. The toxicity index results were compared with two commercial paints and found that NWP exhibited less harmful gas emission. Based on certification rating of building materials, NWP can be classified as the first grade of building materials. Due to the above advantages, the use of sericite as a major component in NWP will be a useful technique to maintain the indoor air quality.

Antioxidation Activities of Organic Solvent Fractions Obtained from Seaweed, Hizikia fusiformis (톳(Hizikia fusiformis)에서부터 분리된 유기용매 분획물의 항산화활성)

  • Kim, Min-Jeong;Lee, Hye-Hyeon;Seo, Min-Jeong;Kang, Byoung-Won;Park, Jeong Uck;Jeong, Yong Kee
    • Journal of Life Science
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    • v.23 no.3
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    • pp.361-367
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    • 2013
  • Hizikia fusiformis has been widely used in Oriental herbal medicine and health food. To identify antioxidation properties that contain natural bioactive substances, we investigated the distribution of active compounds existing in batches of organic solvent fractionation. A dried form of H. fusiformis was subjected to sequential fractionation using n-hexane, ethyl acetate, n-BuOH, and aqueous n-BuOH. The results showed that among the four isolated fractions, the n-BuOH fraction showed the highest antioxidation activities. The n-BuOH fraction was applied to reserve-phase silica gel column chromatography, which produced three fractions: BA, BB, and BC. Among these fractions, BB showed the highest antioxidation activities, which increased in a concentration-dependent manner. At a concentration of 1.0 mg/ml n-BuOH fraction, the activities of DPPH (1,1-diphenyl-2-picrylhydrazyl) radical scavenging and reducing power were approximately $45{\pm}0.14%$ and $1.34{\pm}0.23$, respectively. In addition, the activities of ${\beta}$-carotene-linoleic acid, hydrogen peroxide scavenging, and ABTS (2,2'-azino-bis(3-ethylbenzothiazoline-6-sulphonic acid)) radical scavenging were $76{\pm}0.12%$, $82{\pm}0.06%$, and $65{\pm}0.17%$, respectively. These findings suggest that the BB fraction contains potent antioxidation properties and that it could be used in the production of natural and functional foods.

Characterization of Secondary Exposure to Chemicals and Indoor Air Quality in Fire Station (소방서 실내공간의 화학적 유해인자 2차노출과 실내공기질 특성)

  • Kim, Soo Jin;Ham, Seunghon;Jeon, Jeong Seok;Kim, Won
    • Fire Science and Engineering
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    • v.33 no.4
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    • pp.140-151
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    • 2019
  • It is to assess the indoor air quality of the chemical hazardous materials exposed to the fire after firefighters returned to the fire scene. The research subject randomly selected four fire stations located in Seoul, Korea. Two fire stations were set up as control groups after the return of the firefighting activities at the actual fire scene, and two other fire stations were set up as control groups to measure the air quality of the room at normal levels regardless of the action. We conducted 24-hour monitoring for all fire accidents that occurred in Seoul Metropolitan using fire safety map computer system. Also, indoor air quality was measured immediately after homecoming if the experiment group was to be dispatched due to an accident of intermediate or larger scale. 11 hazardous substance items such as fine dust, formaldehyde, volatile organic compounds, PAH, VCM, acidity, asbestos, CO2, NO2, O3 were measured according to the process test method. Three of 11 types of harmful substances exceeded domestic and foreign standards, and one of them was found to be close to foreign standards. In particular, total volatile organic compounds, carbon dioxide and sulfuric acids were 2.5 times, 2.2 times and 1.1 times higher than the standard. Also, for formaldehyde and sulfuric acid, it was measured higher in the control group than in the case group. This findings could be used in policies to improve indoor air quality in the fire station of the Seoul Metropolitan Government.

On the Chemical Properties of Nursery Soil in Cultivation of Panax ginseng (인삼포상토(人蔘圃床土)의 화학적(化學的) 성상(性狀)에 관(關)한 연구(硏究))

  • Lim, Sun-Uk
    • Applied Biological Chemistry
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    • v.18 no.2
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    • pp.65-70
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    • 1975
  • The cultivation of ginseng plant (Panax ginseng C.A. Meyer) in Korea as an eminent medicinal herb may be traced far back in history. However, the practices in cultivation have not much improved in terms of efficiency and scientific farming. In the present study some experiments were undertaken for the search of the soil and nutrition conditions, because of the nutritional requirement of ginseng plant shaws quite unique compared with other crops. In both the seed bed and the field 'Yakto' has been traditionally employed or the prime source of nutrition of the crop. Yakto is a complex matter prepared from raw foliage of the broad-leaved trees as the main portion with the admixture of a variety of organic nitrogen source through fermentative processes. The composition of Yakto may be classified coarsely into the decomposed and undecomposed substances, the former being further fractionated according their solubilities, comprising also various colloidal matters whose composition and structure are yet to be known. The Yakto-fractions were subjected to analyze for search of its nature and coarse composition in terms of the distribution of nitrogen, contents of organic functional groups such as -COOH, phenolic-OH, alcholic-OH and methoxyl and hydrolysable sugars. Furthermore, absorption-spectra of each fraction were determined in visible and infrared region and compared the results each other.

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Oxidative Coupling of Herbicide Propanil and Its Metabolite, DCA(3,4-dichloroaniline) to Humic Monomers (제초제 Propanil 및 그 분해산물인 DCA(3,4-dichloroaniline)와 Humic Monomer들과의 산화적 짝지움반응)

  • Kwon, Tae-Dong;Kim, Jang-Eok
    • Applied Biological Chemistry
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    • v.41 no.5
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    • pp.384-389
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    • 1998
  • The herbicide propanil and its metabolite, DCA were incubated with oxidative catalysts in the presence or absence of humic monomers to evaluate the incorporation of them into humic substances. Propanil and DCA underwent little or no transformation by oxidatve catalysts in the absence of humic monomers. In the presence of humic monomers, the most effective co-substrate for transformation of propanil was syringic acid by laccase and HRP, that of DCA was catechol by laccase and HRP, and protocatechuic acid by birnessite. The transformation of DCA was the highest when it was incubated with catechol at pH 8.0 during 24 hrs by laccase, and with catechol at pH 3.0 during 2 hrs by HRP, and with protocatechuic acid at pH 5.0 during 2 hrs by birnessite. The DCA transformation increased with increasing concentration of humic monomers. The transformation of DCA was increased with about 5 times when it was incubated with lactase and birnessite together than lactase alone, but that of it was not effected when it was incubated with HRP and birnessite together. When DCA was incubated with dissolved organic carbon in the presence of oxidative catalysts, the transformation of it was not increased by laccase and birnessite but increased by HRP.

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