• Title/Summary/Keyword: organic structure

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Electronic Structure of Organic/organic Interface Depending on Heteroepitaxial Growth Using Templating Layer

  • Lim, Hee Seon;Kim, Sehun;Kim, Jeong Won
    • Applied Science and Convergence Technology
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    • v.23 no.6
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    • pp.351-356
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    • 2014
  • The electronic structure at organic-organic interface gives essential information on device performance such as charge transport and mobility. Especially, the molecular orientation of organic material can affect the electronic structure at interface and ultimately the device performance in organic photovoltaics. The molecular orientation is examined by the change in ionization potential (IP) for metal phthalocyanines (MPc, M=Zn, Cu)/fullerene ($C_{60}$) interfaces on ITO by adding the CuI templating layer through ultraviolet photoelectron spectroscopy measurement. On CuPc/$C_{60}$ bilayer, the addition of CuI templating layer represents the noticeable change in IP, while it hardly affects the electronic structure of ZnPc/$C_{60}$ bilayer. The CuPc molecules on CuI represent relatively lying down orientation with intermolecular ${\pi}-{\pi}$ overlap being aligned in vertical direction. Consequently, in organic photovoltaics consisting of CuPc and $C_{60}$ as donor and acceptor, respectively, the carrier transport along the direction is enhanced by the insertion of CuI templaing layer. In addition, optical absorption in CuPc molecules is increased due to aligned transition matrix elements. Overall the lying down orientation of CuPc on CuI will improve photovoltaic efficiency.

Organic field-effect transistors with step-edge structure

  • Kudo, Kazuhiro
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.91-93
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    • 2008
  • The organic field-effect transistors with step-edge structure were fabricated. Source and drain electrodes were obliquely deposited by vacuum evaporation. The step-edge of the gate electrode serve as a shadow mask, and the short channel is formed at the step-edge. The excellent device performances were obtained.

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A Study on the Efficiency Effects of Capping Layer on the Top Emission Organic Light Emitting Diode (전면 유기발광 다이오드 기능층 캐핑레이어 적용에 따른 효율상승에 관한 연구)

  • Lee, DongWoon;Cho, Eou Sik;Jeon, Yongmin;Kwon, Sang Jik
    • Journal of the Semiconductor & Display Technology
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    • v.21 no.3
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    • pp.119-124
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    • 2022
  • Top emission organic light-emitting diode (TEOLED) is commonly used because of high efficiency and good color purity than bottom - emission organic light-emitting device (BEOLED). Unlike BEOLED, TEOLED contain semitransparent metal cathode and capping layer. Because there are many characteristics to consider just simple thickness change, optimizing organic thickness of TEOLED for microcavity is difficult. So, in this study, we optimized Device capping layer at unoptimized micro-cavity structure TEOLED device. And we compare only capping layer with unoptimized microcavity structure can overcome optimized micro-cavity structure device. We used previous our optimized micro-cavity structure to compare each other. As a result, it has been found that the efficiency can be obtained almost the same or higher only capping layer, which is stacked on top of the device and controls only the thickness and refractive index, without complicated structural calculations. This means that higher efficiencies can be obtained more easily in laboratories with limited organic materials or when optimizing new structures etc.

Fabrication of Patchable Organic Lasing Sheets via Soft Lithography

  • Kim, Ju-Hyung
    • Clean Technology
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    • v.22 no.3
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    • pp.203-207
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    • 2016
  • Here, we report a novel fabrication technique for patchable organic lasing sheet based on non-volatile liquid organic semiconductors and freestanding polymeric film with high flexibility and patchability. For this work, we have fabricated the second-order DFB grating structure, which leads to surface emission, embedded in the freestanding polymeric film. Using an ultra-violet (UV) curable polyurethaneacrylate (PUA) mixture, the periodic DFB grating structure can be easily prepared on the freestanding polymeric film via a simple UV curing process. Due to unsaturated acrylate remained in the PUA mixture after UV curing, the freestanding PUA film provides adhesive properties, which enable mounting of the patchable organic lasing sheet onto non-flat surfaces with conformal contact. To achieve laser actions in the freestanding resonator structure, a composite material of liquid 9-(2-ethylhexyl)carbazole (EHCz) and organic laser dyes was used as the laser medium. Since the degraded active materials can be easily refreshed by a simple injection of the liquid composite, such a non-volatile liquid organic semiconducting medium has degradation-free and recyclable characteristics in addition to other strong advantages including tunable optoelectronic responses, solvent-free processing, and ultimate mechanical flexibility and uniformity. Lasing properties of the patchable organic lasing sheet were also investigated after mounting onto non-flat surfaces, showing a mechanical tunability of laser emission under variable surface curvature. It is anticipated that these results will be applied to the development of various patchable optoelectronic applications for light-emitting displays, sensors and data communications.

Japanese Organic Standards and the Private Effort to Build Domestic Structure to Strengthen Organic and Environment-friendly Agriculture

  • Tokue, Michiaki
    • Proceedings of the Korean Society of Organic Agriculture Conference
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    • 2001.10a
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    • pp.219-227
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    • 2001
  • First, I'd like to express my great respect to the highly developed environment-friendly and organic agriculture in South Korea, especially in this region of Yangpyong. I've heard that rural farmers and city people cooperated together to develop the environment-friendly agriculture in Yangpyong. I believe Japanese farmers and people can learn a lot from the experience of your people. We'd like to exchange our knowledge and experience to develop environment-friendly and organic agriculture in both countries, for we share a lot in common. In this paper, I'd like to introduce how the Japanese have been developing organic and environment-friendly agriculture, and how we are working with the official organic standard and building the social structure to encourage the overall development of organic and environment-friendly agriculture.

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Chaotic phenomena in the organic solar cell under the impact of small particles

  • Jing, Pan;Zhe, Jia;Guanghua, Zhang
    • Steel and Composite Structures
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    • v.46 no.1
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    • pp.15-31
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    • 2023
  • Organic solar cells utilized natural polymers to convert solar energy to electricity. The demands for green energy production and less disposal of toxic materials make them one of the interesting candidates for replacing conventional solar cells. However, the different aspects of their properties including mechanical strength and stability are not well recognized. Therefore, in the present study, we aim to explore the chaotic responses of these organic solar cells. In doing so, a specific type of organic solar cell constructed from layers of material with different thicknesses is considered to obtain vibrational and chaotic responses under different boundaries and initial conditions. A square plate structure is examined with first-order shear deformation theory to acquire the displacement field in the laminated structure. The bounding between different layers is considered to be perfect with no sliding and separation. On the other hand, nonlocal elasticity theory is engaged in incorporating the structural effects of the organic material into calculations. Hamilton's principle is adopted to obtain governing equations with regard to boundary conditions and mechanical loadings. The extracted equations of motion were solved using the perturbation method and differential quadrature approach. The results demonstrated the significant effect of relative glass layer thickness on the chaotic behavior of the structure with higher relative thickness leading to less chaotic responses. Moreover, a comprehensive parameter study is presented to examine the effects of nonlocality and relative thicknesses on the natural frequency of square organic solar cell structure.

Preparation and Characteristics of Organic Electroluminescence Devices Using Multilayer structure with Carrier Transport Materials (다층막 구조를 이용한 유기 EL소자의 제작과 특성에 관한 연구)

  • 이상윤;김태완;최종선;김영관;김정수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.249-252
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    • 1997
  • Electroluminescence(EL) devices based on organic thin layers have attracted lot of interests because of their possible application as large-area display-emitting display. One of the problems of such devices is lifetime of the cell, where the degradation of the cell is partially due to the crystalliyzation of organic layers. In large part, this problem can be solved by using a multilayer device structure prepared by vapor deposition technique. In this study, blue light-emitting multilayer organic electroluminescence devices were fabricated vsing Poly (9-vinylcarbaEole) (PVK) and 2- (4-tert-butylphenyl)-5-(4$^{#}$-bis-phenyl) 1,3,4-oxadiazole (PBO) as hole trasport and electron transport material, respectively, where trim(8-hyd roxyquinolinate) aluminum (Al $q_3$) was used as a luminescenct material. A cell structure of glass sub- strate/indume-tin-oxide(ITO)/PCK/Al $q_3$/PBD/Mg:In was employed. Blue emission peak at 510nm was observed with this cell structure.e.

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Improved Performance of White Phosphorescent Organic Light-Emitting Diodes through a Mixed-Host Structure

  • Lee, Jong-Hee;Lee, Jeong-Ik;Chu, Hye-Yong
    • ETRI Journal
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    • v.31 no.6
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    • pp.642-646
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    • 2009
  • Highly efficient white phosphorescent organic light-emitting diodes with a mixed-host structure are developed and the device characteristics are studied. The introduction of a hole-transport-type host (N, N'-dicarbazolyl-3-3-benzen (mCP)) into an electron-transport-type host (m-bis-(triphenylsilyl)benzene (UGH3)) as a mixed-host emissive layer effectively achieves higher current density and lower driving voltage. The peak external quantum and power efficiency with the mixed-host structure improve up to 18.9% and 40.9 lm/W, respectively. Moreover, this mixed-host structure device shows over 30% enhanced performance compared with a single-host structure device at a luminance of 10,000 $cd/m^2$ without any change in the electroluminescence spectra.

White Organic Light-emitting Diodes using the Tandem Structure Incorporating with Organic p/n Junction

  • Lee, Hyun-Koo;Kwon, Do-Sung;Lee, Chang-Hee
    • Journal of Information Display
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    • v.8 no.2
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    • pp.20-24
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    • 2007
  • Efficient white organic light-emitting diodes are fabricated with the blue and red electroluminescent (EL) units electrically connected in a stacked tandem structure by using a transparent doped organic p/n junction. The blue and red EL units consist of the light-emitting layer of 1,4-bis(2,2-diphenyl vinyl)benzene (DPVBi) and 4-dicyanomethylene-2-methyl-6-[2-(2,3,6,7-tetrahydro-1H,5H-benzo[i,j] quinolizin-8-yl)vinyl]-4H-pyran) (DCM2) doped tris(8-hydroxyquinoline) aluminum $(Alq_3)$, respectively. The organic p-n junction consists of ${\alpha}-NPD$ doped with $FeCl_3$ (15 % by weight ratio) and $Alq_3$ doped with Li (10 %). The EL spectra exhibit two peaks at 448 and 606 nm, resulting in white light-emission with the Commission Internationale d'Eclairage (CIE) chromaticity coordinates of (0.36, 0.24). The tandem device shows the quantum efficiency of about 2.2 % at a luminance of 100 $cd/m^2$, higher than individual blue and red EL devices.