• Title/Summary/Keyword: organic pigment

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Analysis of Paint Pigments on King's Silk Ceremonial Robe with Nine Symbols (은조사 구장복의 채색안료 분석)

  • Yun, Eunyoung;Kang, Hyungtae
    • Conservation Science in Museum
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    • v.15
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    • pp.66-77
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    • 2014
  • A gujangbok is a king's silk ceremonial robe embroidered with nine symbols that represent the essential virtues that a king needs to govern his country. The National Museum of Korea currently own a gujangbok worn by King Gojong in the late Joseon Dynasty. The robe is painted with various colors, including red, yellow, blue, green, and gray. μ-XRF and analysis was conducted on the pigments, and it was found that the red color was made from cinnabar, the yellow color was gold and brass, the blue color was a blue organic pigment and white lead, the green color was a synthetic pigment composed of copper and arsenic, and the gray color pigment was silver. Also, the pigments were compared to those used to make the patterns of a queen's ceremonial robe and a front cloth panel, both made around the same time and also owned by the National Museum of Korea. The comparative analysis revealed clear differences and similarities between the various pigments. The resulting data expect to serve as a useful foundation research for future studying of the pigments used by the Joseon royal court in the late nineteenth century.

Pigment production in Monascus anka (Monascus anka의 균주선발 및 색소생성 조건)

  • Kim, Soo-Un;Kim, Jeong-Gu
    • Applied Biological Chemistry
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    • v.33 no.3
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    • pp.239-246
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    • 1990
  • Monascus anka strains with higher pigment production were developed using UV mutation and natural selection. To obtain organic solvent soluble pigments from Monascus anka, the following culture conditions were compared : standing and shaking culture with Nishikawa's medium, and shaking culture with Lin's medium. Shaking culture in Lin's medium exhibited decrease in solvent-soluble intracellular pigments after initial increase. The decrease was accompanied by the increase in water-soluble extracellular pigments. Monascus anka preferred sucrose and ethanol among 7 carbon sources tested. Treatment of sterol biosynthesis inhibitors, $({\pm})$-miconazole and chlorocholine chloride(CCC) , directed carbon pool to the biosynthetic pathway leading to the pigments with CCC's more pronounced effect. Two dimensional TLC revealed at least 7 yellow pigments suggesting existence of hereto unreported pigment. One of the most abundant yellow pigments was isolated and found to be ankaflavin by NMR and MS analysis.

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Preparation and Coating of Artificial Pearl using Inorganic Pigment (무기안료를 이용한 인공진주 코팅 및 제조)

  • Shin, Cheol-Woo;Hyun, Mi-Ho;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.3
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    • pp.528-535
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    • 2015
  • Humanity has tended pursuing beauty. Pearls has been loved by many people for thousands of years as a symbol of wealth and status. Today, Artificial pearl were made using organic pigment due to bright colors and easy coating process. But the new coating technique is required due to low durability, weather resistance and difficulty of luxurious luster expression. This study, nitrocellulose and urethane were used as binder and inorganic pigment were used to expression of colors. Experimental variable of artificial pearl with nitrocellulose and solvent ratio, urethane and curing agent ratio, the amount of pearl number of coating, drying temperature and time, and coating technology was developed. The coated artificial pearl was evaluated with color-difference meter, ultraviolet ray resistance, promotion weathering. Urethane was better than nitrocellulose when compared with weather resistance, acid-alkalinity resistance.

Micron-Sized Hollow Plastic Pigment (마이크론 크기의 중공 유기 안료)

  • Choi, Gwang-Sik;Kim, Yang-Soo;Jung, Hoon-Sang;Jang, Seo-Won;Kim, Nam-Seon
    • Polymer(Korea)
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    • v.33 no.5
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    • pp.463-468
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    • 2009
  • Syntheses of monodisperse and micron-sized hollow plastic pigment (HPP) were carried out through the core-shell reaction. The effects of the reaction parameters, such as the particle size, molecular weight, the swelling time, agitation rate, and the solid contect were investigated. This micron-sized HPP could be made by using the alkali soluble core with at least bigger than 200 nm size. To obtain a higher opacity ratio, the swelling time and molecular weight of the core should be controlled. The agitation rate affected the particle's morphology. To prevent the shell destruction, the agitation rate must be sufficiently low in case of the syntheses of micron-sized HPP. In this study, micron-sized HPP exhibiting the high hiding power and narrow particle distribution could be obtained.

Characteristics and Stability of Pigments Produced by Monascus anka in a Jar Fermenter (Jar Fermenter에 의한 홍국의 배양, 색소특성 및 안정성)

  • 김선재;임종환;강성국;정순택
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.26 no.1
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    • pp.60-66
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    • 1997
  • The characteristics and stability of pigments produced by Monascus anka in a jar fermenter were examined The pigments produced by the mold were fractionated into four pigments, i.e., extracellular red pigment(ERP) extracellular yellow Pigment(EYP), intracellular red pigment(IRP) and intracellular yellow pigment(IYP) by the solvent fractionation method. These pigments showed characteristic absorption spectrum indicating that they were composed of different components of pigments. Each of these four pigments separated from Monascus anka were stable under ultraviolet light, fluorescent light and in dark conditions, but their color was faded rapidly under sun light. They were also very stable against temperature below 8$0^{\circ}C$, above which temperature the stability of the Pigments was decreased rapidly. Among the eight organic acids tested, tartaric and citric acids were found to be detrimental against the Monascus anka Pigments. And Cu$^{2+}$ ion showed the most deleterious effect on the color change of the pigments.s.

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Application of Handheld Raman Spectroscopy for Pigment Identification of a Hanging Painting at Janggoksa Temple(Maitreya Buddha) (장곡사 미륵불 괘불탱의 채색 재료 분석을 위한 휴대용 라만 분광기의 적용성 연구)

  • LEE Na Ra;YOO Youngmi;KIM Sojin
    • Korean Journal of Heritage: History & Science
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    • v.56 no.4
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    • pp.216-228
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    • 2023
  • The purpose of this study is to apply the handheld Raman spectrometer to identify the coloring materials used in a large Buddhist painting (of Maitreya Buddha) at Janggoksa Temple through cross-validation with HH-XRF. An in situ investigation was performed together with use of a digital microscope and HH-XRF analysis to verify the properties of pigments used in the gwaebul ("large Buddhist painting") via a non-destructive method. However, the identification of coloring materials composed of light elements and mixed or overlaid pigments is difficult using only non-destructive analysis data. Unlike in situ investigation, laboratory analysis often required samples yet the sampling is restricted to a small quantity due to the cultural heritage characteristic. Thus, it is necessary to develop a non-destructive in situ method to supplement the HH-XRF data. The large Buddhist painting at Janggoksa Temple was painted mainly using white, red, yellow, green, and blue colors. The Raman spectroscopy provides molecular information, while XRF spectroscopy provides information about elemental composition of the pigments. Analysis results identified various coloring materials: inorganic pigment, such as lead white, minium, cinnabar, and orpiment, as well as organic pigment such as gamboge and indigo. Therefore, it is possible to obtain more information for the identification of pigments; organic pigment and mixed or overlaid pigments, while at the same time minimizing the collection sample and simplifying the analysis procedure compared to previously used methods. The results of this study will be used as basic data for the analysis of painting cultural heritage through a non-destructive in situ method in the future.

A Strategy for Quality Poultry Egg Production II. Egg Interior Quality; Cholesterol Content, Egg Yolk Pigmentation, Controlling Egg weight and Organic Eggs (양질의 계란 생산전략 II. 계란내용물의 질, 콜레스테롤 함량, 난황색, 난중조절, 유기란)

  • 남기홍
    • Korean Journal of Poultry Science
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    • v.27 no.2
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    • pp.133-153
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    • 2000
  • The egg's interior quality is one of the most important criteria for commercial producers and consumers. Internal quality is complex, including aesthetic factors such as taste, freshness, nutritional and processing values, and the genetic influences upon these upon these factors ranges from none to considerable. The rate of cholesterol synthesis in the hen is very high compared to other animals and humans. Genetic selection, diet drugs and other chemicals can alter cholesterol concentration in the plasma of laying hen, but attempts to manipulate the cholesterol concentration in the egg yolk are generally unsuccessful since the cholesterol can only be changed to a small extent. Factors which may affect the degree of pigmentation of the yolk include the type of xanthophyll and its concentration in the feed, the feed composition, and the health of the hen. Several feed ingredients interact with carotenoid pigment to improve or reduce their deposition rates in yolks. Egg weight is determined by genetics, body size prior to first egg housing density, environmental temperature, lighting program, total feed consumption, calcium, phosphorus, niacin, water, methionine, total sulfur amino acids, energy, linoleic acid, fat and protein levels. Eggs need to be promote levels. Eggs need to be promoted a versatile commodity and new processed egg items need to be developed. Organic eggs are laid by hens which were raised in chemical and drug frdd environments. There are still difficulties in producing these eggs due to the availability of organic poultry feeds and cost of organic grains.

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Changes of Organic Acids, Polyphenols, Pigments and Fiber Concentration with a Different Stalk Position and Grade of Korean Flue-cured Leaf Tobacco

  • Volgger Dietmar;Hwang Keon-Joong
    • Journal of the Korean Society of Tobacco Science
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    • v.26 no.2 s.52
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    • pp.186-192
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    • 2004
  • This study was carried out to analyze the organic acids, polyphenols, pigments and fiber materials concentration with a different stalk position and grade of korean leaf tobaccos. Eight kinds of flue-cured leaf tobaccos which were different stalk position and grade were used for this study. Three kinds of major organic acids(citric, malic and oxalic), 2 kinds of polyphenols(chlorogenic acid and rutin), 3 kinds of pigments($\beta$-carotene, chlorophyll-a and chlorophyll-b), and 2 kinds of fiber components(pectin and lignin) were analyzed. All of these chemical components were changed with a different stalk position. When the citric acid, malic acid, $\beta-carotene$, chlorophyll-a, and lignin concentration were low in the middle stalk position and high in both bottom and upper position, oxalic acid and chlorogenic acid show the highest concentration in the middle stalk position. All of these chemical components also changed with a different grade of leaf tobaccos. As the citric acid, malic acid, $\beta-carotene$, chlorophyll-b, and lignin concentration decreased as the grade ascended, the oxalic acid and chlorogenic acid concentration increased as the grade ascended. This results assumed that the quality of korean leaf tobacco was directly proportional to oxalic acid and chlorogenic acid concentration but it was inversely proportional to citric acid, malic acid, $\beta-carotene$, chlorophyll-b and lignin concentration.

Design Research of the Natural Leather using a Marbling Technique (I) (Marbling 기법을 응용한 천연가죽의 디자인 연구 (I))

  • Lee, Sang-Chul;Shin, Eun-Chul;Kim, Won-Ju;Park, Soo-Min
    • Textile Coloration and Finishing
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    • v.20 no.1
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    • pp.1-7
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    • 2008
  • The study has attempted to introduce a new coating than the conventional standardized method of spray, padding and roll coating. The study has focused on finding condition for separating water and organic layer in marble bath and surface effects according to kind of raw hide. It was found that dyestuff-free was to be used in water layer and the input amount of initial insoluble pigment to be added in marble bath should be adjusted following the change of surface area of the marble bath in order to get efficient marble effect while preventing coagulation of water and organic layers. Eventually, amorphous high value-added leather could be obtained treated in process other than the conventional standardized method. Even raw hides of low grades($C{\sim}E$ grades) could be processed into amorphous marble effect that could conceal or shield surface scratches by the colorant, which eventually eliminated necessity of using excessive amount of chemicals in the coating process leading to achieving high quality marble leather of natural look.

A Study on the Effects of the Dissociation Constant of Edible Tar Pigment. I (혼합용매중(混合溶媒中)에서의 식용(食用) Tar색소(色素)의 해리정수(解離定數)에 관(關)한 연구(硏究) (제 1 보)(第 1 報) -2',4',5',7'- Tetraiodofluorescein Sodium염(鹽)에 대(對)하여-)

  • Kim, Bak-Kwang;Lee, Min-Hwa;Cho, Young-Mee;Kim, Kil-Su;Moon, Dong-Chul
    • Journal of Pharmaceutical Investigation
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    • v.10 no.3
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    • pp.14-19
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    • 1980
  • The dissociation constant of erythrosine in the mixed solvent systems of water-alcohols and water-acetone at various pH and in concentration media were determined by spectrophotometric method. Methanol, ethanol, and acetone were employed as solvents and studied the changes of pK values of erythrosine according to the kind and change of concentration of organic solvent which is mixed into water solution. The effect of organic solvent on pK is negligible at 40% while in the case of above 40% mixing, it is not negligible.

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