• Title/Summary/Keyword: organic nitrogen

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Treatment of Landfill Leachate using H2O2/O3 AOP and UASB Process (I) - Treatment Characteristics of Leachate depending on H2O2/O3 AOP Pretreatment and Available Nitrogen Form - (H2O2/O3 AOP와 UASB 공정을 이용한 매립지 침출수 처리(I) - H2O2/O3 AOP 전처리 및 질소원에 따른 침출수별 처리특성 -)

  • Jeong, Seung Hyun;Jeong, Byung Gon
    • Journal of Korean Society on Water Environment
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    • v.21 no.6
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    • pp.643-650
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    • 2005
  • In order to treat leachate from aged landfill site effectively, removal of biologically recalcitrant organic matter and denitrification efficiency were evaluated through the combination of $H_2O_2/O_3$ AOP pretreatment process and UASB process. The results can be summarized as follows. In case of leachate having low COD/N ratio from aged landfill site, it is possible to increase available COD for denitrification in nitrate utilizing denitrification and nitrite utilizing denitrification both by enhancing biodegradability of recalcitrant organic matter as applying $H_2O_2/O_3$ AOP to pretreatment process. In this experiment, it is found that available COD for denitrification can be increased to 1.0 and 0.4 g/day, respectively. Comparison has been made between requiring COD and available COD for denitrification in each experimental stages. It is expected that high rate of denitrification can be achieved with leachate from young landfill site because higher amount of available COD for denotrification is present in the leachate than the amount of requiring COD for denitrification. Especially, In leachate from aged landfill site with low COD/N ratio, it can be concluded that denitrification using nitrite nitrogen can enhance overall denitrification performance efficiently because denitrification using nitrite nitrogen requires less amount of carbon source than denitrification using nitrate nitrogen. Comparing the biogas production rate and nitrogen content of biogas under the condition of same amount of nitrate and nitrite addition, biogas production and nitrogen content of biogas are increased during denitrification after $H_2O_2/O_3$ AOP pretreatment process. Therefore, it can be confirmed that COD/N ratio in the leachate is increased. Applying $H_2O_2/O_3$ AOP as pretreatment system of landfill leachate seems to have little economic benefit because it requires additional carbon source to denitrify ammonia nitrogen in leachate coming from aged landfill site. However, it is possible to apply this pretreatment process to leachate from old landfill site in view of AOP process can achieve removal of biologically recalcitrant organic matter and increase of available COD for denitrification simultaneously.

Evaluation of Potentially Available Soil Nitrogen by Using Buffer Phosphote Solution of pH7 (답토양(畓土壤)의 인산완형액(燐酸緩衡液)에 의(依)한 지력질소(地力窒素) 평가(評價)에 관(關)한 연구(硏究))

  • Ahn, Sang-Bae
    • Korean Journal of Soil Science and Fertilizer
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    • v.19 no.4
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    • pp.327-332
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    • 1986
  • Laboratory experiments were conducted to estimate extractable nitrogen by buffer phosphate solution of pH 7. A series of experiment soils were a) Sandy soil applied with compost, lime, and Wallastonite every years for 32 years. b) Sandy soils with and without waterlogging for 70 days before transplanting. c) Normal soils produced high and common yields. The results were summarized as follows: 1. Extractable organic nitrogen by pH 7 phosphate buffer solution was increased in order of NPK + compost > NPK > NPK + compost + lime + Wollast-onite > NPK + compost + lime > NPK + wollastonite > no fertilizer plot. 2. Extractable organic nitrogens at plots of NPK and NPK + compost were decreased as the growth stage processed regardless of tretments. 3. In case of normal soils having high and common yields the content of total N, organic matter and $NH_4-N$ were increased in high productive soil, while, only $NO_3-N$ content was increased in common productive soil. Especially, there was a highly positive correlation between extractable total nitrogen and $NH_4-N$ content submerged for 4 weeks under incubated condition. 4. Organic nitrogen content of soil was increased on the condition of non-waterlogging, however, nitrogen uptake by rice plant was increased in waterlogged paddy. 5. The content of extractable total nitrogen increased in the order of normal soil, sandy soil, unmatured soil, saline soil, and estimation of optimum nitrogen rates by extracted organic nitrogen was in order of saline soil, unmatured soil, sandy soil, normal soil.

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Effect of Long-Term Annual Dressing of Organic Matter on Physico-Chemical Properties and Nitrogen Uptake in the Paddy Soil of Fluvio-Marine Deposit (하해혼성 평야지 논토양에서 유기물 장기 연용이 토양의 이화학적 특성 변화 및 질소 흡수에 미치는 영향)

  • Yang, Chang-Hyu;Jeong, Ji-Ho;Kim, Taek-Kyum;Kim, Sun;Baek, Nam-Hyun;Choi, Weon-Young;Kim, Young-Doo;Jung, Won-Kyo;Kim, Si-Ju
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.6
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    • pp.981-986
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    • 2010
  • This study was carried out to investigate the effects of fertilizer and organic resource annual dressing for 30 years of Jeonbug series (silt loam) on soil properties and rice N uptake in paddy field soil. In the study field, treatments including control (NPK), NPK+rice straw, NPK+rice straw compost and nitrogen fertilization levels at 0, 100, 150, 200, 250 kg $ha^{-1}$ have been imposed for 30 years. Soil hardness and bulk density decreased from 15.7 mm and 1.381 Mg $m^{-3}$ in the control to 12.5 mm and 1.244 Mg $m^{-3}$ in NPK+rice straw compost treatment, respectively, indicating improvement of soil physical conditions such as porosity. Co-application of straw compost with NPK also result in a better chemical properties than NPK alone as it increased available phosphate (from 96 to 133 mg $kg^{-1}$), available silicate (from 81 to 116 mg $kg^{-1}$), and cation exchange capacity (from 9.8 to 11.4 $cmol_c\;kg^{-1}$). Soil organic matter concentration of top soil (0 to 7.5 cm in depth) was higher in NPK+rice straw and NPK+rice straw compost than in control. Fertilizer N uptake amount was much higher in NPK+rice straw (nitrogen fertilization level; 250 kg $ha^{-1}$) and NPK+rice straw compost (nitrogen fertilization levels; 200, 250 kg $ha^{-1}$) plots compared to the control (nitrogen fertilization level; 100 kg $ha^{-1}$) plot. Nitrogen use efficiency was showed significantly high in the NPK+rice straw compost (nitrogen fertilization levels; 100, 150 kg $ha^{-1}$) plot compared to the control (nitrogen fertilization level; 100 kg $ha^{-1}$) plot. Therefore, it was suggested that application of organic inputs is helpful in improving soil fertility and physical conditions and thus in N uptake.

Effect of Nitrogen Source on the Growth of Azotobacter vinelandii UWD and Production of Biodegradable Plastics in the Mixture of Organic Acids and Glucose (유기산 및 포도당 혼합배지에서 Azotobacter vinelandii UWD의 생장 및 생분해성 고분자 생산에 대한 질소원의 영향)

  • 박창호
    • KSBB Journal
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    • v.13 no.5
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    • pp.626-630
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    • 1998
  • Ammonium limitation did not promote ply(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) production of Azotobacter vinelandii UWD. In acid phase, ammonium limitation during utilization of propionic acid and butyric acid led to 35% decrease in product yield. In glucose phase, both biomass yield and polymer yield decreased about 22% under ammonium limitation. However, in nitrogen-fixing culture glucose was consumed 25% faster and the final PHBV wt% decreased slightly. Under nitrogen limitation a portion of the carbon sources was used fro nitrogen fixation rather than biomass and polymer formation, resulting in a decrease in biomass yield and polymer yield.

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Effect of Different Carbon and Nitrogen Compounds on the Growth and Sporulation of Curvularia clavata (야자나무 고조병균(枯調病菌)의 생장(生長)과 포자형성(胞子形成)에 대한 탄소 및 질소의 효과)

  • Odigie, E.E.
    • The Korean Journal of Mycology
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    • v.18 no.2
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    • pp.109-114
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    • 1990
  • The effect of different carbon and nitrogen compounds on the growth and sporula­tion of Curvularia clavata Alcorn (Herberium No. IMI264075) has been studied. All the carbon sources tried were well utilized by the pathogen though glucose, and sucrose supported the best growth while glucose, maltose and sucrose the sporulation of the fungus. Of the nine nitrogen compounds, L-glutamic acid supported the best growth while aspartic acid and L-glutamic acid the sporulation of the fungus. Growth and sporulation were generally better with organic than inorganic nitrogen sources. Ammonium sulphate was the best inorganic source. A sudden drop of pH value of the culture media after 4 days of incubation did not favour good growth of the fungus.

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Application of Lime Stone, Sand, and Zeolite as Reactive Capping Materials for Marine Sediments Contaminated with Organic Matters and Nutrients (유기물 및 영양염류로 오염된 해양퇴적물 정화를 위한 석회석, 모래, 제올라이트의 반응성 피복 소재로서 적용성 평가)

  • Kang, Ku;Park, Seong-Jik
    • Journal of Korean Society of Environmental Engineers
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    • v.39 no.8
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    • pp.470-477
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    • 2017
  • In this study, the applicability of calcite, sand, and zeolite for the remediation of sediments contaminated with organics and nutrients were investigated. Sediments and seawater for water tank experiments were sampled from Pyeongtaek harbor, and 1 cm or 3 cm of calcite, sand, and zeolite were capped on the sampled sediments. pH, electric conductivity (EC), dissolved oxygen (DO), chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) were monitored for 63 days. The sampled sediments were highly contaminated with organic matter and total nitrogen. DO in uncapped condition was exhausted within 10 days but DO in capping condition except 3 cm of zeolite capping was prolonged above 2 mg/L. Capping efficiency for interrupting COD release from sediments was in the following order: zeolite 1 cm > calcite 1 cm > calcite 3 cm > sand 3 cm ${\cong}$ zeolite 3 cm ${\cong}$ sand 1 cm. Zeolite was found to be effective for interrupting nitrogen release. T-P was not observed in both uncapped and capped sediment, i.e., all experimental conditions. It can be concluded that zeolite can be effectively used for the remediation of sediments highly contaminated with organic matter and nitrogen.

Physico-chemical properties between organic and conventional kiwifruit orchards in Korea

  • Cho, Y.;Kim, B.;Cho, H.;Jeong, B.
    • Korean Journal of Organic Agriculture
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    • v.19 no.spc
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    • pp.242-246
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    • 2011
  • Organic kiwifruit orchard soils were compared with conventional ones in Korea. Soil structure of organic soil had higher gaseous and liquous phase as well as soil porosity in the surface soil. Although the nutritional level of each orchards were quite different among soils, the analysis of both system revealed that organic kiwifruit orchard soil had similar or even higher nutrient level (N and organic matter content in surface soil) compared to conventional ones. The organic matter content of deep soil also had the high tendency in deep soil of organic soil. Higher level of nitrogen in organic surface soil is presumably due to the excessive application of organic compost and liquid fertilizer rather than the contribution by grasses such as green manure. Available phosphorous level of organic system was quite high but similar in surface soil of both system, compared to the recommended level. Potassium, calcium and magnesium levels were also enough in organic kiwifruit orchard soils.

Nitrogen Balance and Biological Nitrogen Fixation of Soybean in Soybean-Barley Cropping System

  • Park Sei Joon;Kim Wook Han;Lee Jae Eun;Kwon Young Up;Shin Jin Chul;Ryu Yong Hwan;Seong Rak Chun
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.50 no.1
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    • pp.1-4
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    • 2005
  • This experiment was conducted to investigate the soil nitrogen credit of biological nitrogen fixation (BNF) and the nitrogen balance of soybean in soybean-barley cropping systems. Soybean cultivar, Shinpaldalkong2 and barley cultivar, Olbori, were used in soybean mono-cropping (SM), barley monocropping (BM), and barley­soybean double cropping system. The barley-soybean double cropping system was treated with two different levels of nitrogen fertilizers, 0 nitrogen fertilizer (BS-F0), and standard nitrogen fertilizer (BS-F1). Nitrogen and organic matter concentrations in soil of BS-F1 plot on October, 2001 were increased $4.8\%\;and\;5.9\%$, respectively, compared with those on October, 2000. The ranges of BNF rate in soybean were $69.1\~ 88.2\%$ in two years, and the rate was the highest in BS-F0 plot and the lowest in SM plot. The ranges of nitrogen harvest index (NHI) in all treatments were $83.9\~86.7\%$. The yield was 270 kg/10a in BS­F1 plot and 215 kg/10a in BS-F0 plot. However, the nitrogen balances were +0.6 kg/10a of gain of soil nitrogen in BS-F0 plot and -0.4 kg/10a of loss of soil nitrogen in BS-F1 plot. In comparisons of SM and BS-F1 plots, although the seed yields were similar in two plots, the loss of soil nitrogen was higher in SM than BS-F1 plot. Overall, our results suggest that barley-soybean double cropping system was more effective in respect to seed productivity and soil nitrogen conservation than soybean monocropping system, and the N credit to following crops by soybean cultivation was identified in soybean double cropping system.

Effect of Temperature Condition on Nitrogen Mineralization of Organic Matter and Soil Microbial Community Structure in non-Volcanic Ash Soil (온도가 유기물의 질소무기화와 미생물 군집구조에 미치는 영향)

  • Joa, Jae-Ho;Moon, Kyung-Hwan;Kim, Seong-Cheol;Moon, Doo-Gyung;Koh, Sang-Wook
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.3
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    • pp.377-384
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    • 2012
  • This study was carried out to evaluate effect of temperature condition on nitrogen mineralization of organic matter, distribution of microbial group by PLFA profiles, and soil microbial community in non-volcanic ash soil. Dried soil 30 g mixed well each 2 g of pellet (OFPE) organic fertilizers, pig manure compost (PMC), and food waste compost (FWC). And then had incubated at $10^{\circ}C$, $20^{\circ}C$, and $30^{\circ}C$, respectively. Nitrogen mineralization rate increased with increasing temperature and that was in the order of FWC>OFPE>PMC. Distribution ratio of microbial group by PLFA profiles showed that was different significantly according to incubation temperature and the type of organic matter. As incubating time passed, density of microbial group decreased gradually. The Gram-bacteria PLFA/Gram+ bacteria PLFA, Fungi PLFA/Bacteria PLFA, and Unsaturated PLFA/saturated PLFA ratios were decreased according to the increasing temperature gradually. Principal component analysis using PLFA profiles showed that microbial community structures were composed differently by temperature factor at both 75 days ($10^{\circ}C$) and 270 days ($30^{\circ}C$). In conclusion, Soil microbial community structure showed relative sensitivity and seasonal changes as affected by temperature and organic matter type.

Removal of Organic Matter, Nitrogen and Phosphorus in an UASB Sewage Treatment Process with Recycle of Aerated Bio-Filter Effluent (UASB를 이용한 혐기성 하수처리공정에서 ABF 유출수 반송에 따른 유기물질과 질소 및 인 제거)

  • Tian, Dong-Jie;Byun, Byeong-Su;Lim, Hyun-Suk;Jun, Hang-Bae
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.5
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    • pp.381-387
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    • 2013
  • Nitrogen and phosphorus removal was investigated in an UASB-ABF (Up-flow anaerobic sludge blanket - aerated bio-filter) anaerobic sewage treatment system. Successful removal of nitrogen and phosphorus with organic matters was possible in the UASB-ABF system from the results of 160 days operation with the influent raw domestic sewage. Removal efficiencies of organic matter (as TCOD) showed 64% in UASB without recycle of the ABF effluent, however, they increased to 92%, 95%, 96% with 120%, 180% and 240% recycle of the ABF effluent, respectively. Increasement of the organic matter removal was not prominent at recycle ratio above 180%. Apparent increase in TN removal occurred with recycle of the ABF effluent. TN removal efficiency was 18% without recycle, but it increased to 82% with 240% recycle of the ABF effluent. And stable nitrification above 95% was possible as a result of efficient removal of organic matter in the UASB with and without recycle of the effluent. Removal of both TP and $PO{_4}^{3-}$-P also increased remarkably with recycle of the effluent. Without recycle of the effluent, that is at strict anaerobic condition in UASB, TP was not removed, however, its removal efficiency increased to 51%, 63%, 71% at recycle ratios of 120%, 180%, 240%, respectively mainly at UASB.