• Title/Summary/Keyword: organic method

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Synthesis of Highly Concentrated ZnO Nanorod Sol by Sol-gel Method and their Applications for Inverted Organic Solar Cells

  • Kim, Solee;Kim, Young Chai;Oh, Seong-Geun
    • Korean Chemical Engineering Research
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    • v.53 no.3
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    • pp.350-356
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    • 2015
  • The effects of the zinc oxide (ZnO) preparing process on the performance of inverted organic photovoltaic cells (OPVs) were explored. The morphology and size of ZnO nanoparticles were controlled, leading to more efficient charge collection from device and higher electron mobility compared with nanospheres. Nanosized ZnO particles were synthesized by using zinc acetate dihydrate and potassium hydroxide in methanol. Also, water was added into the reaction medium to control the morphology of ZnO nanocrystals from spherical particles to rods, and $NH_4OH$ was used to prevent the gelation of dispersion. Solution-processed ZnO thin films were deposited onto the ITO/glass substrate by using spin coating process and then ZnO films were used as an electron transport layer in inverted organic photovoltaic cells. The analyses were carried out by using TEM, FE-SEM, AFM, DLS, UV-Vis spectroscopy, current density-voltage characteristics and solar simulator.

Preparation of PZI Tapes by Solvent Washing Dry Method (용매세척건조법에 의한 PZT 테입 제조)

  • 신효순;윤석진;김현재
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.300-303
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    • 1999
  • For the fast dry of the aqueous tape, the process which water was replaced by organic solvent was proposed. So-called, it was the solvent washing dry, Three organic solvents (methanol, ethanol, and acetone) were selected for the washing solvent. The weight loss of the washed tapes was measured to evaluate the dry rate of the tapes and dried tapes were examined the generation of the cracks with the variations of the organic solvent and the washing time. Methanol, ethanol, and acetone were all available organic solvents for this method. The tapes washed in methanol, ethanol, and acetone were dried rapidly for twenty minutes. After thirty minutes, the weight losses were not any more. The solvent of the lower surface tension can decreases the crack of dried tape. If solvent substitutes water completely, though it was fast dried, crack can be eliminated. The tape casting system was designed for the solvent washing dry and prepared. An homogeneous tape was established by continuous tape casting process.

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Study on Optimization of the Vacuum Evaporation Process for OLED (Organic Electro-luminescent Emitting Display) (유기EL 디스플레이의 진공 성막 공정의 최적화에 관한 연구)

  • Lee, Eung-Ki
    • Journal of the Semiconductor & Display Technology
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    • v.7 no.1
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    • pp.35-40
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    • 2008
  • In OLED vacuum evaporation process, the essential requirements include good uniformity of the film thickness over a glass substrate. And, it is commercially significant to improve the consuming efficiency of material of the evaporant which is deposited on the substrate because of high price of organic materials. In this paper, to achieve the better thickness uniformity and the better organic material consuming rate, a process optimization algorithm was developed by understanding vacuum evaporation process parameters that affect the material consuming efficiency and the uniformity of film thickness. Based on the method developed in this study, the vacuum evaporation process of OLED was successfully controlled. The developed method allowed the manufacture of high quality OLED displays with cheaper fabrication cost.

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Measurement of Permeability of Food Packaging Polymer Films to Organic Vapors

  • Kim, Jong-Kyoung;Lee, Jun-Ho;Ha, Young-Sun
    • Preventive Nutrition and Food Science
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    • v.6 no.4
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    • pp.247-252
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    • 2001
  • The need to determine the permeability of organic vapors to polymeric films such as aromas, flavors, etc. has significantly increased in the food industry because of preservation and safety issues along with migration problems. However, due to the complex nature of the permeation process, there have been few investigations compared to nonorganic compounds. In this paper, we review the history of permeability studies and typical methods of permeability measurement such as the isostatic method and quasi-isostatic method for organic vapors. New instrumental developments and significant findings are also introduced and discussed.

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Characterization of Natural Organic Matter in Spring Water

  • Yoo, Hee-Jin;Choi, Yoon-Ji;Cho, Kun
    • Mass Spectrometry Letters
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    • v.11 no.4
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    • pp.90-94
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    • 2020
  • Interest in aspects of industrialization relating to human health has increased. Accordingly, the use of labels such as 'natural foods' and 'organic ingredients' has become more widespread, and greater emphasis is being placed on improving quality of life. Water is an essential element for human life, and water quality has a significant impact on human health. However, technology that can precisely determine the substances present in water is still lacking. This study was conducted to establish a complete mass spectrometry process, from pretreatment to analysis, to measure and characterize natural organic matter (NOM) in Korean spring water samples. Salts and other matrices were removed from the samples using solid-phase extraction (SPE) with two different columns (PPL and C18). After establishing an accurate analysis method, the experimental results were evaluated based on Van Krevelen diagrams and analysis of molar O/C and H/C ratios. The method for characterizing NOM introduced herein should facilitate evaluation of water quality.

Recommendable Methods for Effective Improvement of Management System on Organic Materials based on the Analysis of Unintentional Contamination Investigation and Recognition Survey collected from Organic Farmer and so on (유기농업자재중 비의도적 오염원 조사분석 및 친환경농업인 등 인식조사에 근거한 유기농업자재 관리제도의 효율적 개선방안)

  • Ahn, In;Lee, In-Ae;Sim, Mi-Jin
    • Korean Journal of Organic Agriculture
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    • v.23 no.4
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    • pp.659-682
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    • 2015
  • This study was conducted to suggest ideal management system for organic materials. As the performing method of the study, surveyed results on understanding of related persons (organic farmer 846, organic materials manufacture 70 and Organic materials Auditors 7) with eco-friendly farming were used. And the opinion on unintentional pollution source contained in organic materials was surveyed additionally. The issues pointed out by organic farmers on product of organic materials were high price (60% to total), poor efficacy (16%), disorder on distribution system (13%) and containing chemicals as a pesticide (10%). And notification system for organic materials was accepted in general (positive and so so 76%) while most interviewees preferred (89%) unification of certification system dominantly. As unintentional contamination source, pollution on imported row material was indicated as major reason, and other causes were confirmed as insertion during manufacturing process, agricultural by-products using as product additive et al. Based on these surveyed results, authors suggest bellows as considerable methods for effective improvement of management system on organic material. First, establish new integrated certification system which contains standard of quality certification and notification system on organic material. Second, for evaluation of efficacy, apply relative evaluation system of significance such as Duncan's multiple test instead of existing absolute evaluation system. Third, constitute and operate selection of standard comparison subcommittee in organic Agro-materials committee in RDA.

Development of Nondestructive Grouping System for Soil Organic Matter Using VIS and NIR Spectral Reflectance

  • Sung J.H.
    • Agricultural and Biosystems Engineering
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    • v.6 no.1
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    • pp.15-21
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    • 2005
  • This study was conducted to develop a nondestructive grouping system for soil organic matter using visible (VIS) and near infrared (NIR) spectroscopic method. The artificial light was irradiated on the cut soil surface at 15 to 20 cm depths to reduce the errors of light at open field. The reflectance energy from the cut soil surface was measured to group the soil organic matter using VIS/NIR light sensor with narrow band pass filter. From reflectance spectra of soil samples, the sensitive wavelengths for measuring the soil organic matter were selected and compared to previous research results. The grouping system for soil organic matter consisted of light sensor with band pass filter measuring the reflectance energy of the cut soil surface, global positing system (GPS), analog-to-digital (AD) converter, computer and operating software. The regression models to predict the soil organic matter were developed and evaluated. From field test, the accuracies of the developed light sensor system were 81.3% for five-stage grouping of the soil organic matters and 91.0% for three-stages grouping of the soil organic matters, respectively. It could be possible to support the decision making for variable rate applications with the developed grouping system for soil organic matter in precision agriculture.

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Properties, Structure and Crystallization of Poly Lactic Acid/Zinc Oxide Pillared Organic Saponite Nanocomposites (폴리락틱산/산화아연 기둥구조의 유기사포나이트 나노복합체의 특성, 구조 및 결정화)

  • Zhen, Weijun;Sun, Jinlu
    • Polymer(Korea)
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    • v.38 no.3
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    • pp.299-306
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    • 2014
  • ZnO pillared saponite was synthesized via a microwave hydrolysis method. To enhance interfacial compatibility between zinc oxide (ZnO) pillared saponite and poly lactic acid (PLA), ZnO pillared organic saponite was prepared by intercalation modification of cetyltrimethylammonium bromide. Moreover, PLA/ZnO pillared organic saponite nanocomposites were prepared by melting processing. The microstructure analysis of PLA/ZnO pillared organic saponite nanocomposites showed that ZnO pillared organic saponite was exfoliated and homogeneouslydispersed in PLA matrix. The property results showed that ZnO pillared organic saponite improved the mechanical properties and thermal stabilities of PLA/ZnO pillared organic saponite nanocomposites. Differential scanning calorimetry (DSC) demonstrated that ZnO pillared organic saponite restrained the appearance of cold crystallization, lowered the glass transition temperature and melting temperature of PLA, and improved the crystallinity of PLA. The results demonstrated that ZnO pillared organic saponite had a good interfacial compatibility and heterogeneous nucleation effect in PLA matrix, and also played an active role in accelerating the crystallization process of PLA.

Relevance between Total Volatile Organic Compound (TVOC) Exposure Level and Environmental Diseases Within Residential Environments (주거환경 내의 Total Volatile Organic Compounds (TVOC) 노출수준과 환경성질환과의 관련성)

  • Lee, Dong-Hyun;Chung, Jin-Do
    • Journal of Environmental Health Sciences
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    • v.37 no.3
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    • pp.193-200
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    • 2011
  • Objective: The purpose of this study is to compare and analyze the level of exposure to volatile organic compounds for different kinds of households in apartments or houses and analyze the relation between atopy-related symptoms and concentration of volatile organic compounds in order to improve indoor air quality and start to build a process to prevent environmental diseases. Method: From July 2010 to November 2010, TVOC concentration levels were measured and analyzed in 402 general households and 236 weak households, totalling 638 households. Residents were asked to fill out a survey on environmental disease. All resources were analyzed using SPSS 12.0 program. Result: In comparing the differences in concentration levels of volatile organic compounds for different types of households, including existing apartments and houses, the type of housing did not affect the concentration level of volatile organic compounds, but the relevance with skin trouble, diagnosed atopy, and atopy systems all had statistical similarities. Moreover, above-limit volatile organic compounds showed statistical relevance with amount of ventilation, time of construction, skin trouble, diagnosed atopy and atopy symptoms. Conclusion: The study concludes that as the time of construction recedes further into the past and as the amount of ventilation is higher, the exposure level to volatile organic compounds was lower and the group that were suffering from atopy symptoms had higher exposure to volatile organic compounds.

Biological control of Botrytis cinerea on tomato using antagonistic bacteria

  • Hong, Sung-Jun;Kim, Yong-Ki;Jee, Hyeong-Jin;Park, Jong-Ho;Han, Eun-Jung;An, Nan-Hee;Kim, Jung-Hyun;Goo, Hyung-Jin
    • Korean Journal of Organic Agriculture
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    • v.19 no.spc
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    • pp.251-254
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    • 2011
  • Botrytis cinerea infects stems and leaves of greenhouse tomatoes and can cause serious economic losses. This study was conducted to develop environment-friendly control method against tomato gray mold. Antagonistic microorganisms (bacteria) were screened for control activity against Botrytis cinerea, both in vitro and in vivo, using stem sections. One hundred bacterial strains were isolated from the rhizospheric soil of various plants including tomato. These strains were screened for growth inhibition of Botrytis cinerea on agar plate by the dual culture and thirty strains showing strongly inhibitory effect against the pathogen were selected first. Among thirty strains, JB 5-12, JB 22-2, JB 22-3, U 4-8 and U46-6 reduced significantly disease incidence, when applied simultaneously with the pathogen. These results suggested that five antagonistic bacteria strains selected have the potential to control tomato gray mold in organic farming.