• Title/Summary/Keyword: organic matter pollution

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Improvement of Channel Water Quality Module in SWAT (SWAT 모형의 하도 수질 모듈의 개선)

  • Kim, Nam-Won;Shin, Ah-Hyun
    • Journal of Korean Society on Water Environment
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    • v.25 no.6
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    • pp.902-909
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    • 2009
  • With various reservoirs, dams and reduction of water velocity in downstream, rivers in Korea often have characteristics of accumulation of pollutants. Therefore, the main focus of water quality modeling in Korea needs to be shifted from DO to algae and organic matter. Moreover the structures of water quality models should be modified to have capability of simulating BOD which is a key factor of total water pollution load management in Korea as laboratory experiment BOD (Bottle $BOD_5$). In the SWAT model which is one of the widely used water quality models in Korea, the channel water quality module is using main algorithm of the QUAL2E model which has limitations in simulating algae, organic matter and Bottle BOD5 etc. To overcome this hindrance, in this study, the improved channel water quality module of the SWAT model (Q-SWAT) was proposed by linking the algorithms of the QUAL-NIER model which was developed based on the QUAL2E model to the SWAT model. The algorithms estimating the increase of internal organic matter by fractionization algal metabolism process and calculating Bottle $BOD_5$ were added and the results of proposed model were compared to those of the original SWAT model. The results of comparison test are showing that more accurate BOD values can be obtained with the Q-SWAT model and it is anticipated that the Q-SWAT model can be used as an effective tool of decision support through the water quality simulation and long term pollution source analysis.

Relationship between Pollutant and Influence Factors in Highway runoff (강우시 고속도로 노면 유출 오염부하 발생 특성 분석)

  • Kang, Hee-Man;Lee, Doo-Jin;Bae, Woo-Keun;Kang, Hye-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.1
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    • pp.47-54
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    • 2012
  • This study analyzed influence factors and the correlation among pollutants which affect occurrence of leaked pollution based on the long-term runoff flow and water quality investigation results to understand the characteristics of highway rainfall runoff pollution load. According to the result of correlation analysis on TSS (Total Suspended Solid) concentration, anteceded dry days, rainfall intensity, traffic volume and etc. as major influence factors of highway rainfall runoff pollution loads, the correlations were weak or scarce in most items. These results might be attributed that runoff pollutant concentration changes vary severely on changes of rainfall intensity and rainfall duration within rainfall and it is affected by disturbances of vehicles and street cleaning and etc. as characteristics of the highway. While Cu, Fe and Zn which are discharged with high concentrations out of heavy metals showed high correlation with particulate matter, organic matter(COD), nutrient(TN, TP), Ni and Pb showed relatively low correlation in a correlation evaluation by pollutant. Significant correlation with traffic volumes was not shown and TSS concentration even decreased in accordance with increase of the traffic volume. In the comparison with precedent studies, it was considered necessary additional analysis of the effects of rainfall section analysis, road type, disturbances of surface contaminants by vehicles, rainfall and climate conditions, surrounding terrains etc.

Characteristics of Changes in DOC Concentration according to Concentrations of Organic Matter and Suspended Solids in the Nakdong River (낙동강에서 유기오염 및 SS 농도 변화에 따른 DOC 농도 변화의 특성)

  • Lee, Kyu-Yeol;Kim, Ju-Eon;Lee, Kwon-Chul;Lee, Kyung-Lak;Lee, In-Jung;Im, Tae-Hyo
    • Journal of Korean Society on Water Environment
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    • v.29 no.4
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    • pp.540-550
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    • 2013
  • Temporal increase of SS induces concentrations in various forms of organic matter including BOD, COD, TOC. Consequently, it causes hard to identify sources of water pollution during or after precipitation. The objective of this study is to investigate variations of DOC concentration caused by increase of flow and changes of external factors in river by comparing to SS concentration. In results, monitoring sites (e.g., Banbyeonchen) consisting of hard riverbed showed high correlation between SS and organic matters, except BOD. On the contrary, other sites (e.g., Naesungcheon) where riverbed consists of sand were found in a wide range of annual fluctuation in SS level, whereas these sites showed a narrow range in annual DOC fluctuation. In Gumhogang and Namgang, a lower correlation between SS and other factors was found most likely because of high concentration in organic matter. However, lower annual fluctuation values of DOC were observed in comparison to those of COD and TOC. Similar results were also confirmed in main river sites, Sangju and Mulgeum. In conclusion, DOC concentration is better indicator for monitoring organic matter which cannot be provided by BOD, COD, TOC in the Nakdong river basin.

Physicochemical Characteristics of Particulate Matter Emissions of Different Vehicles' Fuel Types (자동차 연료유형에 따른 배출 입자상 물질의 화학적 특성)

  • Son, Jihwan;Kim, Jounghwa;Park, Gyutae;Kim, Sunmoon;Hong, Heekyoung;Moon, Sunhee;Park, Taehyun;Kang, Seokwon;Sung, Kijae;Chung, Taekho;Kim, Ingu;Kim, KyungHoon;Yu, Dong-Gil;Choi, Kwangho;Kim, Jeong Soo;Lee, Taehyoung
    • Journal of Korean Society for Atmospheric Environment
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    • v.32 no.6
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    • pp.593-602
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    • 2016
  • The physicochemical characteristics of particulate matter emissions from various vehicle's fuel types were studied at the facility of Transport Pollution Research Center(TPRC), National Institute of Environmental Research (NIER), Korea. Three different types of fuels such as gasoline, liquefied petroleum gas (LPG) and diesel were tested on the NIER driving mode and the constant speed modes(30, 70, and 110 km/h). Chemical composition of submicron particles from vehicle emissions was measured by the High Resolution Time of Flight Aerosol Mass Spectrometer (HR-ToF-AMS) during running cycles. Organics were dominant chemical species of particulate matter emissions for all three different vehicles' fuel types. Moreover, regardless of fuel types, emission rate of organics and inorganics decreased as the average speed of vehicle increased. The portion of fully oxidized fragment families of $C_xH_yO_z$ accounted for over 98% of organic aerosol(OA) in LPG and diesel vehicles, while the relatively high fraction of $C_xH_y$ in OA was observed in gasoline vehicle.

Development of Regression Models for Estimation of Unmeasured Dissolved Organic Carbon Concentrations in Mixed Land-use Watersheds (복합토지이용 유역의 수질 관리를 위한 미측정 용존유기탄소 농도 추정)

  • Min Kyeong Park;Jin a Beom;Minhyuk Jeung;Ji Yeon Jeong;Kwang Sik Yoon
    • Journal of Korean Society on Water Environment
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    • v.39 no.2
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    • pp.162-174
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    • 2023
  • In order to prevent water pollution caused by organic matter, Total Organic Carbon(TOC) has been adopted indicator and monitored. TOC can be divided into Dissolved Organic Carbon(DOC) and Particulate Organic Carbon(POC). POC is largely precipitated and removed during stream flow, which making DOC environmentally significant. However, there are lack of studies to define spatio-temporal distributions of DOC in stream affected by various land use. Therefore, it is necessary to estimate the past DOC concentration using other water quality indicators to evaluate status of watershed management. In this study, DOC was estimated by correlation and regression analysis using three different organic matter indicators monitored in mixed land-use watersheds. The results of correlation analysis showed that DOC has the highest correlation with TOC. Based on the results of the correlation analysis, the single- and multiple-regression models were developed using Biochemical Oxygen Demand(BOD), Chemical Oxygen Demand(COD), and TOC. The results of the prediction accuracy for three different regression models showed that the single-regression model with TOC was better than those of the other multiple-regression models. The trend analysis using extended average concentration DOC data shows that DOC tends to decrease reflecting watershed management. This study could contribute to assessment and management of organic water pollution in mixed land-use watershed by suggesting methods for assessment of unmeasured DOC concentration.

Distribution of Organic Matter and Trace Metals in Surface Sediments and Ecological Risk Assessment in the Tongyeong Coast (통영연안 표층퇴적물에서의 유기물과 미량금속 분포 특성 및 생태위해성 평가)

  • YANG, WON HO;LEE, HYO JIN;KIM, GI BEUM
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.21 no.4
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    • pp.125-133
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    • 2016
  • We investigated the distribution of organic matter and trace metals in surface sediment from Tonyeong coast. To determine the status of trace metal pollution, we also conducted an ecological risk assessment. Relatively high concentration of TN (total nitrogen), TOC (total organic carbon), and AVS (acid volatile sulfide) was found in surface sediment located in the narrow channel (site 35-38). Spatial distribution of Cd, Cr, Ni, Co, Hg, and Zn in surface sediment was similar and high Cu concentrations were found in narrow channel. The assessment of heavy metal pollution was derived using the Enrichment factors (EF). The enrichment factor indicated that Cd was no enrichment (EF<1), Pb, Cr, Ni, Co, Zn, and Hg were minor enrichment (1

Pollution Assessment of Sediment in Lakes of Buk-han River Basin (북한강 수계 호소퇴적물 오염도 평가)

  • Lee, Bo-Mi;Seon, Seong-Ki;Kim, Guk-Hui;Moon, Gwon-Young;Shin, Myoung-Chul;Hong, Jung-Ki;Kim, Kap-Soon;Yu, Soon-Ju;Huh, In-Ae;Noh, Hye-Ran
    • Journal of Korean Society on Water Environment
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    • v.35 no.2
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    • pp.105-114
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    • 2019
  • The objective of this study was to investigate the pollution assessment of organic matters, nutrients, and metals in sediment in major lakes (5 lakes and 17 sites) of Buk-han river using various sediment pollution assessment guidelines and indices. The concentrations of organic matters and nutrients were lower than class IV (Sediment pollution assessment guidelines of Korea) and Severe Effect Level (SEL, Sediment pollution assessment guidelines of Ontario). This results indicated that the lakes sediments were unpolluted and tolerable level for sediment dwelling organisms by organic matters and nutrients. However, several sites of Chuncheon and Soyang lakes were evaluated "heavily polluted" level by organic index (Org-index). The order of lakes by metals concentrations from the one with the highest concentration was Hwacheon, Chuncheon, Cheongpyeong, Uiam, Soyang. All lakes except Hwacheon were assessed unpolluted to marginally and tolerable level for sediment dwelling organisms by metals based on sediment pollution assessment guidelines (Korean and Ontario), indices of geoaccumulation ($I_{geo}$), pollution loading (PLI) and ecological risk (RI). In Lake Hwacheon, every investigated sites were polluted with metals, especially Hg, based on sediment pollution assessment guideline of Korea and indices ($I_{geo}$, PLI and RI). The dwelling organisms in sediment of Hwacheon Lake were likely to be severed by metals.

The geochemical characteristic and quality assessment of surface sediments in Sihwa Lake (시화호 표층퇴적물의 특성과 오염도 평가)

  • Ju, Jae Sik;Son, Moonho;Cho, Hyeon-Seo;Kim, Pyoung-Joong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.12
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    • pp.333-338
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    • 2016
  • The purpose of this study was to understand the pollution level of the surface sediment of Sihwa Lake by assessing its geochemical characteristics and investigating the spatial distribution of trace metals and organic matter. In the surface sediment of Sihwa lake, the mean grain size was between 2.94 and 6.35 Ø and the main type of sediment was sandy silt. The concentrations of As, Co, Cr, Ni, V and Li among the metal elements in the surface sediment were correlated with the mean crust concentration (p<0.05). Based on the strong correlation between the metals (Cd, Cu, Pb and Zn) and organic matter (Ignition Loss), the concentrations of these metal elements seem to be controlled by the organic matter dilution effect. The trace metal pollution level, determined by applying the Republic of Korea Marine environmental standard and the US National Oceanic and Atmospheric Administration's sediment quality guidelines, showed the pollution level of As to be either close to or in excess of the above-mentioned standards at almost all levels. The enrichment factor and geoaccumulation index of As showed that there was an incremental increase of pollution by elements other than V, Cr, Co, Fe, Al and Mn. Moreover, the nearby industrial area and dike were more polluted than the other areas, so the surface sediments in Sihwa lake should be monitored by taking into consideration the geological variations.

Selection of the Optimum Organic Matter Index for Surface Water Quality Management (지표수 수질관리를 위한 적정 유기물질지표 선정)

  • Han, Dae Ho;Choi, Ji-Yong
    • Journal of Environmental Policy
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    • v.10 no.4
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    • pp.61-80
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    • 2011
  • Through concentrated investments in environmental regulations centered around BOD, which is a biodegradable matter index, and basic environmental infrastructures, national BOD pollution level has continuously improved. Nonetheless, limitations of BOD management system has become evident through nation-wide stagnation and/or increases of refractory organic matters, such as COD, at main drinking water sources, and the need for a new index, which can easily indicate different environmental conditions, has increased. Therefore, this study suggests a new organic management index for a proper management of surface water. $COD_{Cr}$ and TOC were examined as candidates for surface water quality management index, and it was found that TOC was more appropriate than $COD_{Cr}$ as an organic matter management index. Through this study, it was found that TOC possesses following qualities: a more representative index; international acceptability; monitoring program is easier; better availability of analysis techniques; better accuracy and precision of analysis; less time required for analysis; ease of operation; management of disinfection byproducts; connection with present policies; existence of foreign and domestic application case studies; and correlation with water ecosystem.

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Characteristics of TOC Distribution in Lake Hapcheon (합천호의 TOC 분포 특성)

  • Seong, Jin-Uk;Kim, Hyung-Jin;Park, Jae-Chul
    • Journal of Environmental Science International
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    • v.20 no.6
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    • pp.711-719
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    • 2011
  • This study was conducted to estimate the distribution characteristics and budget of organic matter in the Lake Hapcheon. In the dry season, the concentration ranges of organic carbons were similar, but in the rainfall season, it showed about double concentrations. Changes of vertical water quality in the lake, there were no big differences with the concentration by the depth. However, it tends to be relatively high on the surface, a little low on the mid-depth and high in the lake bottom. DOC rate at TOC, it was lower than POC rate at inflow and DOC rate was higher than POC rate in the lake and discharging water. R-DOC accounted for more 80% of DOC rate in all investigated areas, therefore we judge that this R-DOC is to increase the organic carbon pollution gradually. As the result of the calculated organic carbon budget in the Lake Hapcheon, the amount of allochthonous, autochthonous and release were 3,552, 3,288, 228 tonC/year, respectively. the amount of discharge, decomposition and sedimentation were 504, 1,344, 5,520 tonC/year, respectively. According to this investigation, the changed amount of organic matter in the Lake Hapcheon recorded -300 tonC/year with the increase of 7,068 tonC/year and the decrease of 7,368 tonC/year.