• Title/Summary/Keyword: organic matter (OM)

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Effect of Dissolved Effluent Organic Matter on Adsorption and Estrogenic Activity of Bisphenol A (용존성 방류수 유기물질이 비스페놀 A의 흡착 및 에스트로겐 활성에 미치는 영향)

  • Yoo, Jisu;Na, Joorim;Jung, Jinho
    • Ecology and Resilient Infrastructure
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    • v.6 no.2
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    • pp.128-135
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    • 2019
  • This study evaluates the effect of dissolved effluent organic matter (SE-dEfOM) from sewage wastewater treatment plants on the adsorption and estrogenic activity of bisphenol A (BPA). Specific ultraviolet absorbance and fluorescence index analyses indicated that SE-dEfOM was mainly microbially derived non-humic substances differed from Suwannee River natural organic matter (SR-NOM) as reference. Both Langmuir and Freundlich models successfully explained the adsorption of BPA onto both SE-dEfOM and SR-NOM. Additionally, the SE-dEfOM showed higher binding capacities and affinities for BPA than those of SR-NOM, resulting in better reduction of the estrogenic activity of BPA. These findings suggest that the binding and toxicity of BPA are largely dependent on the source of organic matters.

Algal Contribution to the Occurrence of Refractory Organic Matter in Lake Paldang, South Korea: Inferred from Dual Stable Isotope (13C and 15N) Tracer Experiment (팔당호 난분해성 유기물에 대한 조류기원 유기물의 기여)

  • Lee, Yeonjung;Ha, Sun-Yong;Hur, Jin;Shin, Kyung-Hoon
    • Korean Journal of Ecology and Environment
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    • v.52 no.3
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    • pp.192-201
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    • 2019
  • While a fairly large amount of organic matter is produced daily via phytoplankton photosynthesis in Lake Paldang, South Korea, knowledge of the role of algal-derived organic matter (OM) as a refractory OM source is not adequate. To understand the contribution of algal-derived OM to the refractory pool, biodegradation experiment and $KMnO_4$ oxidation experiment were conducted for 60 days using $^{13}C$ and $^{15}N$ labeled natural phytoplankton assemblage. The assemblage was collected from Lake Paldang on May 20, 2010. The photosynthetically produced total organic carbon ($TO^{13}C$), particulate organic carbon ($PO^{13}C$), and particulate nitrogen ($P^{15}N$) remained at 26%, 20%, and 17% of the initial concentrations, respectively, in the form of non-biodegradable organic matter. In addition, 12% and 38% of $PO^{13}C$ remained after $KMnO_4$ treatment on Day 0 and 60, respectively. These results indicate that photosynthetic products could be an important source of refractory organic matter after microbial degradation. Moreover, the microbially transformed algal-derived OM could contribute to the oxidation rate of the chemical oxygen demand.

Estimating the Relative Contribution of Organic Phosphorus to Organic Matters with Various Sources Flowing into a Reservoir Via Fluorescence Spectroscopy (형광스펙트럼을 이용한 유역 하류 저수지의 유입 유기물 내 유기인 기여도 평가)

  • Mi-Hee Lee;Seungyoon Lee;Jin Hur
    • Journal of Korean Society on Water Environment
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    • v.40 no.2
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    • pp.67-78
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    • 2024
  • The introduction of a significant amount of phosphorous into aquatic environments can lead to eutrophication, which can in turn result in algal blooms. For the effective management of watersheds and the prevention of water quality problems related to nonpoint organic matter (OM) sources, it is essential to pinpoint the predominant OM sources. Several potential OM sources were sampled from upper agricultural watersheds, such as fallen leaves, riparian reeds, riparian plants, paddy soil, field soil, riparian soil, cow manure, and swine manure. Stream samples were collected during two storm events, and the concentrations of dissolved organic carbon (DOC) and phosphorous (DOP) from these OM sources and stream samples were assessed. DOM indicators using fluorescence spectroscopy, including HIX, FI, BIX, and EEM-PARAFAC, were evaluated in terms of their relevance in discerning DOM sources during storm events. Representative DOM descriptors were chosen based on specific criteria, such as value ranges and pronounced differences between low and high-flow periods. Consequently, the spectral slope ratio (SR) paired with fluorescence index (FI) using end-member mixing analysis (EMMA) proved to be suitable for estimating the contribution of organic carbon (OC). The contribution of each organic phosphorous (OP) in stream samples was determined using the phosphorous-to-carbon (P/C) ratio in conjunction with the OC contribution. Notably, OP derived from swine manure in stream samples was found to make the most dominant contribution, ranging from 61.3% to 94.2% (average 78.1% ± 12.7%). The results of this research offer valuable insights into the selection of suitable indicators to recognize various OM sources and highlight the main sources of OP in forested-agricultural watersheds.

Effect of Effluent Organic Matters on Estrogenic Activity Reduction of Bisphenol A by Photolysis (광분해 반응에 의한 비스페놀 A의 에스트로겐 활성 저감에 미치는 방류수 유기물질의 영향)

  • Yoo, Jisu;Na, Joolim;Jung, Jinho
    • Korean Journal of Environmental Biology
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    • v.34 no.1
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    • pp.48-55
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    • 2016
  • This study investigates the effect of effluent organic matter (EfOM) from sewage wastewater treatment plants on estrogenic activity reduction of bisphenol A (BPA) by UV photolysis. The EfOM and Suwannee River natural organic matter (SR-NOM) as reference were isolated into hydrophobic (HPO), transphilic (TPI) and hydrophilic (HPI) fractions depending on polarity. The specific ultraviolet absorbance (SUVA) analysis indicated that EfOM showed similar properties to microbially derived organic matters with low hydrophobicity, which is different from SR-NOM having high hydrophobicity. UV irradiation upto 3 hr significantly reduced SUVA values of both EfOM and SR-NOM (p<0.0001), depending on the polarity of organic matters. In the absence of organic matters, the relative estrogenic activity (REA) of BPA ($5.0{\times}10^{-5}M$) was decreased from 86% to 63% by UV photolysis (2 hr). However, the decrease of mean REA was from 68% to 37% in the presence of organic matters, which was significantly independent on the type (EfOM or SR-NOM) and polarity (HPO, TPI or HPI) of organic matters (p>0.05). As a result, the reduced REA by UV photolysis of BPA with and without organic matters was 31% and 23%, respectively, suggesting that both EfOM and SR-NOM accelerated the photolytic reduction of BPA estrogenic activity.

Growth of Lettuce and Young Radish and Changes of Soil Chemical Properties after Application of Soldier Fly Compost (동애등에분 처리 시 상추와 무의 생육 및 토양화학성 변화)

  • Young-Sun Kim;Geung-Joo Lee
    • Korean Journal of Environmental Agriculture
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    • v.42 no.2
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    • pp.152-158
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    • 2023
  • This study was conducted to evaluate the effects on soil chemical properties and plant growth after applying soldier fly compost (SFC). Treatments were as follows. No fertilizer (NF), control, SFC1 (SFC 250 kg/10a), SFC2 (SFC 500 kg/10a) and SFC3 (SFC 1,000 kg/10a). As compared to control in the pot test, organic matter (OM) and exchangeable sodium (Ex-Na) of SFC3 treatment were increased, and growth and nutrient uptake of young radish were not significantly different. Correlation coefficient between soil chemical factors like total nitrogen (T-N), OM, and CEC and uptake of nitrogen (N) and phosphorus (P) was significantly positive (p≤0.05). Compared to control in the field test, electrical conductivity, T-N, OM, Av.-P2O5, and CEC was increased, and lettuce growth was not significantly different. Correlation coefficient between application amount of SFC and T-N, OM, and Av.-P2O5 was significant positively (p≤0.05). These results indicated that the application of SFC improved nutrient availability of soil by increasing OM and CEC.

Advanced Characterization Techniques of Organic Matter in Aqueous Solutions (물 속 유기물의 고도 특성 분석)

  • Shon, Ho Kyong;Vigneswaran, Saravanamuthu;Kandasamy, Jaya;Kim, Jong Beom;Kim, Jong-Ho
    • Applied Chemistry for Engineering
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    • v.22 no.1
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    • pp.1-14
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    • 2011
  • Water is the most precious resource to human being, but it is polluted by different organic compounds. Organic matter (OM) in aqeous solutions is one of the important parameters of concern for human and environmental impact, and thus, it is essential to better characterize specifically targeted organic matter in aggregated and individual level of concentrations. This review presents different analytical tools and protocols to investigate detailed properties and characterization. Physical, chemical and biological aspects of OM are envisaged in terms of traditional and advanced measurement methods.

Correlation analysis between TOC and organic matter indices in influent and effluent of public sewage treatment facilities (공공하수처리시설 유입수 및 방류수에서 TOC와 유기물질 관리지표간의 상관성 분석)

  • Son, Dong-Jin;Jeong, Dong-Hwan;Park, Kyoo-Hong
    • Journal of Convergence for Information Technology
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    • v.11 no.4
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    • pp.122-129
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    • 2021
  • As the total organic carbon (TOC) becomes a new water quality standard as an organic matter (OM) index for public sewage treatment facilities (PSTFs) in Korea from 2021, a comparison study needs to be conducted by examining the correlation between TOC and the existing OM indices (DOC, BOD5, CODMn, CODCr). 500 PSTFs were categorized by process configuration and capacity, and correlation between OM indices in influent and effluent was analyzed. The CODMn/TOC showed higher correlation than other OM indices. This results can be used to basic data for various research associated with TOC.

PHYSIOLOGY OF DIGESTION OF UREA-TREATED RICE STRAW IN SWAMP BUFFALO

  • Hart, F.J.;Wanapat, M.
    • Asian-Australasian Journal of Animal Sciences
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    • v.5 no.4
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    • pp.617-622
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    • 1992
  • Four rumen-fistulated swamp buffaloes steers were used in a change-over experiment. This experiment was designed to provide a comparison of the effect of urea-ammonia treatment of rice straw with untreated rice straw. Nitrogen, mineral and trace elements were supplied at adequate levels to both diets in order to overcome deficiencies which may have otherwise confounded a direct comparison. There was a 46% increase in the intake of digestible organic matter (OM) with the urea-ammonia treated diet. This was contributed by a 17% increase in the digestibility of OM and a 25% increase in the voluntary intake of OM. Of the cell wall fraction, the digestibility of hemicellulose increased by the greatest amount (26%). There was an increased rate of passage of particulate matter out of the rumen for the treated straw, along with the increased rate of OM fermentation resulted in a 9% decrease in the amount of digesta dry matter (DM) contained in the rumen. The volatile fatty acid (VFA) pool in the rumen was 24% higher for the treated diet.

Analysis on Food Waste Compost by Near Infrared Reflectance Spectroscopy(NIRS) (Near Infrared Reflectance Spectroscopy(NIRS)에 의한 음식물 쓰레기 퇴비 분석에 관한 연구)

  • Lee Hyo-Won;Kil Dong-Yong
    • Korean Journal of Organic Agriculture
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    • v.13 no.3
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    • pp.281-289
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    • 2005
  • In order to find out an alternative way of analysis of food waste compost, the Near Infrared Reflectance Spectroscopy(NIRS) was used for the compost assessment because the technics has been known as non-detructive, cost-effective and rapid method. One hundred thirty six compost samples were collected from Incheon food waste compost factory at Namdong Indurial Complex. The samples were analyzed for nitrogen, organic matter (OM), ash, P, and K using Kjedahl, ignition method, and acid extraction with spectrophotometer, respectively. The samples were scanned using FOSS NIRSystem of Model 6500 scanning mono-chromator with wavelength from $400\~2,400nm$ at 2nm interval. Modified partial Least Squares(MPLS) was applied to develop the most reliable calibration model between NIR spectra and sample components such as nitrogen, ash, OM, P, and K. The regression was validated using validation set(n=30). Multiple correlation coefficient($R^2$) and standard error of prediction(SEP) for nitrogen, ash, organic matter, OM/N ratio, P and K were 0.87, 0.06, 0.72, 1.07, 0.68, 1.05, 0.89, 0.31, 0.77, 0.06, and 0.64, 0.07, respectively. The results of this experiment indicates that NIRS is reliable analytical method to assess some components of feed waste compost, also suggests that feasibility of NIRS can be Justified in case of various sample collection around the year.

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Ruminal Behavior of Protein and Starch Free Organic Matter of Lupinus Albus and Vicia Faba in Dairy Cows

  • Yu, P.;Leury, B.J.;Egan, A.R.
    • Asian-Australasian Journal of Animal Sciences
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    • v.15 no.7
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    • pp.974-981
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    • 2002
  • Faba beans (vicia faba) (FB) and lupin seeds (Lupinus Albus) (LS) were dry roasted at three temperatures (110, 130, $150^{\circ}C$) for 15, 30 or 45 min to determine the effects of dry roasting on rumen degradation of crude protein and starch free organic matter ($^{PSF}OM$). Rumen degradation characteristics of $^{PSF}OM$ were determined by the nylon bag incubation technique in dairy cows fed 60% hay and 40% concentrate. Measured characteristics of $^{PSF}OM$ were undegradable fraction (U), degradable fraction (D), soluble fraction (S), lag time (T0), and the rate of degradation (Kd). Based on the measured characteristics, rumen availability ($RA^{PSF}OM$) and bypass $^{PSF}OM$ ($B^{PSF}OM$) were calculated. Dry roasting did not have a greater impact on rumen degradation characteristics of $^{PSF}OM$ (p>0.05). S varied from 32.1 (raw) to 30.0, 27.8, 30.8% (LS) and 15.4 (raw) to 14.4, 20.8, 20.9% (FB); D varied from 65.4 (raw) to 66.3, 66.9, 55.9% (LS) and 54.9 (raw) to 55.0, 51.0, 64.7% (FB); U varied from 2.6 (raw) to 7.3, 7.0, 7.7% (LS) and 29.7 (raw) to 30.6, 28.2, 14.4% (FB); Kd varied from 6.0 (raw) to 7.3, 7.0, 7.7% (LS) and 22.4 (raw) to 24.4, 21.1, 7.9% (FB); $B^{PSF}OM$ varied from 35.5 (raw) to 33.8, 36.6, 38.2% (LS) and 41.3 (raw) to 41.5, 39.7, 47.6% (FB) at 110, 130 and $150^{\circ}C$, respectively. Therefore dry roasting did not significantly affect $RA^{PSF}OM$, which were 353.7, 367.9, 349.6, 336.9 (g/kg DM) (LS) and 12.82, 127.0, 133.7, 117.1 (g/kg DM) (FB) at 110, 130 and $150^{\circ}C$, respectively. These results alone with our previously published reports indicate dry roasting had the differently affected pattern of rumen degradation characteristics of various components in LS and FB. It strongly increased bypass crude protein (BCP) and moderately increased starch (BST) with increasing temperature and time but least affected $^{PSF}OM$. Such desirable degradation patterns in dry roasted LS and FB might be beneficial to the high yielding cows which could use more dry roasted $^{PSF}OM$ as an energy source for microbial protein synthesized in the rumen and absorb more amino acids and glucose in the small intestine.