• Title/Summary/Keyword: organic matrix composites

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Preparation of Ag/PVP Nanocomposites as a Solid Precursor for Silver Nanocolloids Solution

  • Hong, Hyun-Ki;Park, Chan-Kyo;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • v.31 no.5
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    • pp.1252-1256
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    • 2010
  • A polyvinylpyrrolidone (PVP)/Ag nanocomposites was prepared by the simultaneous thermal reduction and radical polymerization route. The in situ synthesis of the Ag/PVP nanocomposites is based on the finding that the silver n-propylcarbamate (Ag-PCB) complex can be directly dissolved in the NVP monomer, and decomposed by only heat treatment in the range of 110 to $130^{\circ}C$ to form silver metal. Silver nanoparticles with a narrow size distribution (5 - 40 nm) were obtained, which were well dispersed in the PVP matrix. A successful synthesis of Ag/PVP nanocomposites then proceeded upon heat treatment as low as $110^{\circ}C$. Moreover, important advantages of the in situ synthesis of Ag/PVP composites include that no additives (e.g. solvent, surface-active agent, or reductant of metallic ions) are used, and that the stable silver nanocolloid solution can be directly prepared in high concentration simply by dissolving the Ag/PVP nanocomposites in water or organic solvent.

Controlled Release Behavior of pH-Responsive Composite Hydrogel Containing Activated Carbon

  • Yun, Ju-Mi;Im, Ji-Sun;Oh, Ae-Ri;Lee, Young-Seak;Kim, Hyung-Il
    • Carbon letters
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    • v.10 no.1
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    • pp.33-37
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    • 2009
  • Activated carbon (AC) is one of the most effective adsorbents for organic compounds because of their extended surface area, high adsorption capacity, microporous structure and special surface reactivity. The composites of pH-sensitive hydrogel and activated carbon were prepared in order to improve the loading capacity of drug. The pH-sensitive hydrogel matrix swelled well in the basic condition to release the drug loaded in AC. The release of drug was controlled depending on both the pH due to the ionization of the carboxylic acid group and the AC due to the surface properties.

Brass fillers in friction composite materials: Tribological and brake squeal characterization for suitable effect evaluation

  • Kchaou, Mohamed;Sellami, Amira;Abu Bakar, Abd. Rahim;Lazim, Ahmad Razimi Mat;Elleuch, Riadh;Kumar, Senthil
    • Steel and Composite Structures
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    • v.19 no.4
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    • pp.939-952
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    • 2015
  • In this paper, brake pad performance of two organic matrix composites namely, Sample 1 (contains no brass filler) and Sample 2 (contains 1.5% brass filler), is studied based on tribological and squeal noise behavior. In the first stage, a pin-on-disc tribometer is used to evaluate the frictional behavior of the two pads. On the following stage, these pads are tested on squeal noise occurrence using a drag-type brake dynamometer. From the two type of tests, the results show that; (i) brass fillers play a dual role; firstly as reinforcing element of the brake pad providing primary contact sites, and secondly as solid lubricant by contributing to the formation of a layer of granular material providing velocity accommodation between the pad and the disc; (ii) brass fillers contribute to friction force stabilization and smooth sliding behavior; (iii) the presence of small weight quantity of brass filler strongly contributes to squeal occurrences; (iv) there is close correlation between pin-on-disc tribometer and brake dynamometer tests in terms of tribological aspect.

A Study on Electromagnetic Absorption Characteristics of the Anisotropic Composite Structure with Specific Thickness (특정두께를 갖는 이방성복합재 구조의 전자파 응답특성 연구)

  • 정헌달;김덕주;이윤상
    • Journal of the Korea Institute of Military Science and Technology
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    • v.1 no.1
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    • pp.114-127
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    • 1998
  • A user friendly computer code(EMCOMST; Electro-Magnetic response for COMposite STructures) was developed which provides with computations of the response characteristics such as reflectance and transmittance to the incident wave angles, frequencies, composite thicknesses, ply orientations, and types of backplate as the linearly polarized transverse electro-magnetic wave is emitted to the advanced composite structures. In this investigation were reviewed the electromagnetic characteristics of the continuous orthotropic fiber-reinforced organic matrix composites with or without ferrite fillers, which are actively applied to low-weight and high-strength aircraft structures. Also were calculated the response of the three layered compound structures which have appropriately stacked above-mentioned materials as transmitting layer, absorbing layer, reflection layer, respectively under the specific thickness constraints for mechanical strength design requirements. For the composite structures presented in this study, minimum reflectance value less than -5㏈ can be obtained in the frequency range of 4 to 12 ㎓. In addition, analysis of structures attached isotropic radar absorbing materials(RAM) is facilitated by putting the material properties in the material input card entries adequately.

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Study on the Chemical Treatment of Silica for SBR Reinforcement (화학처리(化學處理) Silica의 SBR에 대한 보강효과(補强效果)에 관(關)한 연구(硏究))

  • Park, Gun-Rok;Yoo, Chong-Sun;Choi, Sei-Young
    • Elastomers and Composites
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    • v.29 no.1
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    • pp.18-29
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    • 1994
  • The purpose of this study is to investigate reinforced effect between silica treated by coupling agents and rubber matrix under the configuration chemical bonds, and the effect of silica particles coated by organic polymers using aluminum chloride as the catalyst. In vulcanization characteristies were tested by Curastometer. The M-series vulcanizates were reached to the fastest optimum cure $time(t_{90})$ and R-series vulcanizates with the same formula had the shorted optimum cure times. Tensile characteristics measuring with a tensile tester revealed that the M-series vulcanizate was the best in the physical properties, such as tensile strength. In 100% modulus, however, the S-series vulcanizates appeared to be better than the other vulcanizates. Also, hardness showed the following order : S-series>R-series>M-series with the order of elongation R-series>M-series>S-series. In SEM test, shapes of chemical treated silicas were observed. The dispersion of filler in the SBR composite appeard uniformly. In RDS test for the dynamic characteristics, G' indicates that S-3 shows the highest value with the next order M-3>R-3, and the order of damping values are as followe: M-3>M-3>R-3.

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Thermal, Frictional and Wear Behavior of Carbon Nanofiber/Poly(methyl methacrylate) Composites (탄소나노섬유/폴리(메틸 메타크릴레이트) 복합재료의 열적 및 마찰 마모 거동 연구)

  • Park Soo-Jin;Im Se-Hyuk;Lee Jae-Rock;Rhee John-M.
    • Polymer(Korea)
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    • v.30 no.5
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    • pp.385-390
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    • 2006
  • In this work, the effect of carbon nanofiber (CNF) on thermal properties, and friction and wear behavior of CNF/PMMA composites were examined. While thermal properties of the composites were investigated with differential scanning calorimetry, thermograyimetric analyzer, and dynamic mechanical analyzer friction and wear behaviors were examined using a friction and wear tester. The glass transition temperature (Tg), integral procedural decomposition temperature (IPDT), storage modulus (E'), and tan ${\delta}$ appeared at higher temperatures with increasing CNF content, which were probably attributed to the presence of strong interactions between the carbonaceous fillers and the PMMA resins matrix. The wear loss in the composites decreased at 0.1 wt% CNF and then increased with 5-10 wt% CNF content. This was due to the existence of large aspect ratio CNF in PMMA which led to an alignment of PMMA chains and an increase of mechanical interlocking, resulting in the formation of crosslinked structures between CNF and PMMA in the composite.

Thermo-oxidation behaviour of organic matrix composite materials at high temperatures

  • Cinquin, Jacques;Colin, Xavier;Fayolle, Bruno;Mille, Marion;Terekhina, Svetlana;Chocinski-Arnault, Laurence;Gigliotti, Marco;Grandidier, Jean-Claude;Lafarie-Frenot, Marie-Christine;Minervino, Matteo;Cluzel, Christophe;Daghia, Federica;Ladeveze, Pierre;Zhang, Fangzouh
    • Advances in aircraft and spacecraft science
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    • v.3 no.2
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    • pp.171-195
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    • 2016
  • The present paper is a review of the main activities carried out within the context of the COMPTINN' program, a joint research project founded by a FUI program (Fonds $Unifi{\acute{e}}s$ $Interminist{\acute{e}}riels$) in which four research teams focused on the thermo-oxidation behaviour of HTS-TACTIX carbon-epoxy composite at 'high' temperatures ($120^{\circ}C-180^{\circ}C$). The scientific aim of the COMPTINN' program was to better identify, with a multi-scale approach, the link between the physico-chemical mechanisms involved in thermo-oxidation phenomena, and to provide theoretical and numerical tools for predicting the mechanical behaviour of aged composite materials including damage onset and development.

AE Application for Fracture Behavior of SiC Reinforced CFRP Composites (SiC 강화 CFRP 복합재의 파괴거동에 관한 음향방출 적용)

  • Ryu, Yeong Rok;Yun, Yu Seong;Kwon, Oh Heon
    • Journal of the Korean Society of Safety
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    • v.31 no.3
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    • pp.16-21
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    • 2016
  • Carbon Fiber Reinforced Plastic(CFRP) composite with a higher specific strength and rigidity is more excellent than conventional metallic materials or other organic polymer of FRP. It has been widely used in vehicles, aerospaces and high technology industries which are associated with nuclear power fields. However, CFRP laminated composite has several disadvantages as like a delamination, matrix brittleness and anisotropic fibers that are the weak points of the crack initiation. In this present work, the reinforced silicon carbide(SiC) particles were added to the interlayer of CFRP laminates in order to mitigate the physical vulnerability affecting the cracking and breaking of the matrix in the CFRP laminated composite because of excellent specific strength and thermal shock resistance characteristics of SiC. The 1wt% of SiC particles were spread into the CFRP prepreg by using a spray coating method. After that, CFRP prepregs were laminated for the specimen. Also, the twill woven type CFRP prepreg was used because it has excellent workability. Thus the mechanical and fracture behaviors of the twill woven CFRP laminated composite reinforced with SiC particles were investigated with the acoustic emission(AE) method under a fracture test. The results show that the SiC particles enhance the mechanical and fracture characteristics of the twill CFRP laminate composite.

Rheological Properties of Organic Fiber-Reinforced Thermoplastics (유기섬유 강화 열가소성 복합재료의 유변학적 특성)

  • Lee, Yong-Mu;Cha, Yun-Jong;Kim, Seong-Hyeon;Yun, Yeo-Seong;Yun, Ju-Ho;Choe, Hyeong-Gi
    • Korean Journal of Materials Research
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    • v.6 no.8
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    • pp.786-795
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    • 1996
  • The fiber reinforced thermoplastics(FRTP) were prepared with polypropylene fiber(PP) as matrix and polyvinyl alchol(VF), aramid(KF) or polyamide fiber(PAF) as the reinforcing materials using the integrated fiber mixing apparatus. The reinforced thermoplastic sheets were prepared by com¬pression molding and their morphology, rheological and mechanical properties were characterized. In the morphological properties of composites, the wettability of the reinforced thermoplastics were decreased in proportion to the content of fibers. At low angular frequency, the viscosity of PAF /PP and VF/PP composite was increased with the content of reinforced fiber. However at high frequency the viscosity of composite reinforced with 5~20wt% fiber, was shown the reduced values which approaches that of the neat matrix. The mechanical properties of the composite were changed with the content of reinforecd fiber, and VF/PP and KF/PP composite had better properties than PAF/PP system.

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Effects of Binder on the Mechanical Properties of Preform and MMCs (예비성형체 및 금속복합재료에 미치는 바인더의 영향에 관한 연구)

  • Nam, Hyun-Wook;Min, Byung-Ryoul;Lee, Jong-Hae;Han, Kyung-Seop
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.23 no.6 s.165
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    • pp.952-960
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    • 1999
  • The effects of binder on the mechanical properties of the preforms and metal matrix composites (MMCs) were studied. Fibers were $9Al_2O_3{\cdot}2B_2O_3(Alborex)$, HTZ and $Al_2O_3$ fibers(Saffil) and binders were organic binder, inorganic binder, polyacrylamide under various PH conditions. Compressive strength of the preform increased with the addition of inorganic binder. The polyacrylamide did not improve the permeability of the preforms. PH of the slurry should be controlled because it affects the viscosity of the slurry. Good preforms were obtained under following conditions : 3 wt% inorganic binder, 0.1 wt% organic binder, 0.1 wt% polyacrylamide and PH 9. Tensile tests of MMCs were conducted at $20^{\circ}C,\;150^{\circ}C,\;250^{\circ}C,\;350^{\circ}C$ using MTS(100KN USA). Wear tests were conducted under various sliding speeds. High temperature($250^{\circ}C$) tensile strengths of Alborex/Saffil/AC8A and HTZ/AC8A are 80% and 75% of the room temperature tensile strengths respectively. The tensile and wear properties of the Alborex/Saffil/AC8A are superior to that of the HTZ/AC8A. The wear behavior of HTZ/AC8A shows more orthotropic characteristic than that of Alborex/Saffil/AC8A.