• Title/Summary/Keyword: organic growing

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Influence of surface morphology and thickness of molecular thin films on the performance of SubPc-$C_{60}$ photovoltaic devices

  • Kim, Jin-Hyun;Gong, Hye-Jin;Yim, Sang-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.336-336
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    • 2011
  • Over the past decades, organic semiconductors have been investigated intensely for their potential in a wide range of optoelectronic device applications since the organic materials have advantages for very light, flexible and low cost device fabrications. In this study, we fabricated small-molecule organic solar cells (OSCs) based on chloro[subphthalocyaninato]boron(III) (SubPc) as an electron donor and $C_{60}$ as an electron acceptor material. Recently SubPc, a cone-shaped molecule with $14{\pi}$-electrons in its aromatic system, has attracted growing attention in small-molecule OSC applications as an electron-donating material for its greater open-circuit voltage (VOC), extinction coefficient and dielectric constant compared to conventional planar metal phthalocyanines. In spite of the power conversion efficiency (PCE) enhancement of small-molecule OSC using SubPc and $C_{60}$, however, the study on the interface between donor-acceptor heterojunction of this system is limited. In this work, SubPc thin films at various thicknesses were deposited by organic molecular beam deposition (OMBD) and the evolution of surface morphology was observed using atomic force microscopy (AFM) and field emission scanning electron microscopy (FE-SEM). We also investigated the influence of film thickness and surface morphology on the PCE of small-molecule OSC devices.

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A Study on the Thickness Dependence of p-type Organic Layer on the Current of Small Molecule-based Organic Photodiode (저분자 유기 광다이오드 소자의 p형 유기물 두께에 따른 전류 특성에 관한 연구)

  • Young Woo Kim;Dong Woon Lee;Yongmin Jeon;Eou-sik Cho;Sang Jik Kwon
    • Journal of the Semiconductor & Display Technology
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    • v.22 no.3
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    • pp.101-105
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    • 2023
  • Organic photo Diodes (OPDi) give multiple advantages in the growing interest of the flexible optoelectronic devices. Organic semiconductors are freeform as they can deposit on any substrate, so it could be flexible. But the inorganic material photodiodes (PDs) are usually fabricated on silicon wafers which are solid. So, normally PDs are inflexible. By those reasons, we decided to make the vacuum deposited small molecule OPDi. We have investigated the OPDi's J-V characteristic by changing the thickness of p-type layer of OPDi. This device consists of indium-tin-oxide (ITO) / 2,3:6,7-dibenzanthracene (pentacene) / buckminsterfullerene (C60) / aluminum (Al). Its J-V characteristics were measured in the probe station(4156C) that can give dark condition while measuring. And for the luminance characteristics, the photocurrent was measured with the bright halogen lamp and a probe station.

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A Study on Vacuum-deposited Transparent OLED to Improve Its Transmittance and Luminescence Characteristics with a Mesh Electrode (진공 증착 투명 OLED 투과도 및 발광 특성 개선을 위한 Mesh 전극 연구)

  • Young Woo Kim;Yongmin Jeon;Eou-Sik Cho;Sang Jik Kwon
    • Journal of the Semiconductor & Display Technology
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    • v.23 no.2
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    • pp.82-86
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    • 2024
  • With the growing field and growing interest in transparent organic light-emitting diodes (TOLED) in the industry, various attempts are being made to improve the transmittance and performance of TOLED. TOLEDs are expected to be used in next-generation displays such as mixture reality (MR) displays, displayable windows, televisions, etc. This study presents a mesh TOLED with better transmittance and luminescence characteristics than existing TOLEDs through an in-situ vacuum deposition method that does not require additional processes such as photolithography and etching. In this study the mesh TOLED's cathode consists of Mg: Ag 1:9 electrode. Mesh patterns are interconnected with a 6 nm layer of interlayer. We approached transmittance improvement up to 30% at 555 nm at the cathode electrode with similar current injection character, also we improved lumination characteristics up to 23% at 7 V driving condition.

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Improved Efficiency and Lifetime for Organic Light-emitting Devices based on Mixed-hole Transporting Layer (혼합된 정공 수송 층을 이용한 유기발광소자의 효율 및 수명 개선)

  • Seo, Jl-Hyun;Park, Jung-Hyun;Park, Il-Hong;Kim, Jun-Ho;Kim, Young-Kwan
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.3
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    • pp.257-262
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    • 2007
  • Organic light-emitting diodes (OLEDs) with the high efficieney and long lifetime are of growing interest in next-generation displays. Among the factors influencing OLEDs properties, one of unstable factor is $Alq_3$ cationic species caused by the excess holes resided in $Alq_3$ layer. Therefore, we suppressed the accumulation of excess holes by using the mixed-hole transporting layer (MHTL) of NPB and CBP in multilayer green OLEDs. The devices with MHTL showed improved characteristics in the luminous efficiency and lifetime. More characteristics and the carrier transport mechanism will be discussed.

Backplane Technologies for Flexible Display (플렉시블 디스플레이 백플레인 기술)

  • Lee, Yong Uk
    • Vacuum Magazine
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    • v.1 no.2
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    • pp.24-29
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    • 2014
  • Display is a key component in electronic devices. OLED is growing very fast recently due to the explosion of the smart phone market although still LCD is the dominating display technology in the display market at the moment. Also needs for the large area and high resolution TVs and flexible displays are increasing these days. Especially flexible display is expected to be one of the key technologies in mobile devices requiring small device size and large display size. Contrary to the conventional displays, flexible display requires organic materials for the substrate, the active driving element and also for the display element. Plastic film as a substrate, organic semiconductor as an active component of the transistor and organic light emitting materials or electronic paper as a display element are studied actively. In this article, mainly backplane technologies such as substrates and the transistor materials for flexible display will be introduced.

Regioselective Enzymatic Acylation of Multi-hydroxyl Compounds in Organic Synthesis

  • Park, Hyun-Gyu;Do, Jin-Hwan;Chang, Ho-Nam
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.8 no.1
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    • pp.1-8
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    • 2003
  • With current developments in enzyme-catalyzed reactions and techniques available for rational redesign of natural biocatalysts, the enzymatic biosynthesis can become one of the most valuable Synthetic methods. Enzymatic regioselective catalysis in organic media has played a key role in pursuing asymmetric synthesis for active chiral compounds. Here, we shortly do-scribe some historical issues of the rapidly growing area, enzymatic catalysis in synthetic organic chemistry and then review researches that have been carried out in the regioselective enzymatic catalysis for the past two decades. An application of this technology to the modification of some potential target drug co m pound will be adios presented.

Characteristics and Status of Persistent Organic Pollutants and Heavy Metals in Ambient Air (대기 중 잔류성 유기오염물질과 중금속의 특성과 현황)

  • 김영성
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.2
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    • pp.113-132
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    • 2003
  • In May 2001, the Stockholm Convention on Persistent Organic Pollutants (POPs) for phasing out and eliminating POPs was signed by 90 countries at the Diplomatic Meeting in Stockholm. In 1998, three years before the Convention, the protocols on POPs and heavy metals were adopted by the United Nations Economic Commission for Europe under the Convention on Long-Range Transboundary Air Pollution. Growing attention on POPs and heavy metals during the past 10 years is primarily due to their toxicity in minute quantities. POPs and some metal compounds are even more toxic because of their bioaccumulation potentials associated with a high lipid solubility. Furthermore, owing to their persistence and semi - volatility, they are widely distributed in the environment, traveling great distances on wind and water currents. Recent international cooperation to address POPs and heavy metals has focused on these issues. Long -range transport of those pollutants are particularly concerned since Korea is located downwind of prevailing westerlies from China. In this paper, a review is provided to assess the properties, sources, emissions, and atmospheric concentrations on POPs and heavy metals.

Evaluation of VOCs in Kumi industrial Complex (공단지역에서의 휘발성유기화합물의 농도 평가)

  • 배상호;최우건;박덕신;정우성;김태오
    • Proceedings of the KSR Conference
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    • 2002.10b
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    • pp.943-947
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    • 2002
  • Volatile Organic Compounds(VOCs) contribute to the formation of ozone and PAN which are injurious to health through complex photochemical reactions. Growing consumption of fossil fuels results in significant emission of VOCs and other air pollutants into the atmosphere. This study was carried out to evaluate of Volatile Organic Compounds(VOCs) concentrations in Kumi industrial complex. Ambient air sampling was determined at five sites from August to September in 2002. The Volatile Organic Compounds samples were collected using the silicocan canisters, and were determined by GC/MS which connected preconcentrator system. The Kumi industrial complex of VOCs concentrations were generally similar with Yeochun's but some of VOCs concentrations of Kumi were higher than Yeochun industrial complex's. Also the industrial area was higher than downtown and residential district.

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Isolation and Characterization of a Phenol-Degrading Bacteria (Phenol 분해 균주의 분리 및 특성)

  • 정경훈;차진명;오인숙;고한철;정오진;이용보
    • KSBB Journal
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    • v.13 no.2
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    • pp.119-124
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    • 1998
  • Twelve bacterial strains capable of growing on phenol minimal medium were isolated from iron foundry activated sludge by enrichment culture, and amount them, one isolate which was the best in cell growth and phenol degradation was selected and identified as Acinetobacter junii POH. The optimal temperature, initial pH and phenol concentration in the above medium were 3$0^{\circ}C$, 7.5 and 1000 ppm, respectively. Cell growth of Acinetobacter junii POH dramatically increased 20 hrs cultivation-time and reached a almost stationary phsae 40 hrs cultivation-time then phenol was degraded about 98%. Cell growth was inhibited y phenol at concentrations over 1500 ppm. The isolate was resistant to several antibiotics as well as various heavy metal ions. The growth-limiting log P value of Acinetobacter junii POH on organic solvents was 2.9 in the LB medium. Therefore, it is suggested that Acinetobacter junii POH could be effectively used for the biological treatment of wastewater containing the presence of heavy metal ions and organic solvents.

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Tree Shape and Partial Dishcharge in LDPE Blended with Organic Compounds (유기화합물이 첨가된 LDPE에서의 트리 형상과 부분방전)

  • Kang, S.H.;Choi, H.S.;Shin, Y.S.;Jeong, D.Y.;Lim, K.J.;Park, D.H.
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.1130-1133
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    • 1993
  • In this paper, it is discussed the correlation between shape of tree and internal partial discharge in low density polyethylene(LDPE) blended with organic compounds that used to improve the effect of resistance to treeing. Initiation and growing of tree are retarded in specimens blended with organic compounds that comprised radical having large electron affinity, and also discharge magnitude and counts of discharging pulse per unit time in these samples are more than those in others. It is observed that the shape of tree in these samples is bush type, but in case of pure LDPE samples dendrite type.

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