• Title/Summary/Keyword: organic dye

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Observation of Morphology, Surface potential and Optical Transmission Images in the Thin Film Using SPM (SPM을 이용한 박막의 모폴로지, 표면전위와 광투과이미지 관찰)

  • Shin, Hoon-Kyu;Kwon, Young-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.327-330
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    • 2000
  • The scanning Maxwell-stress microscopy (SMM) is a dynamic noncontact electric force microscopy that allows simultaneous access to the electrical properties of molecular system such as surface potential, surface charge, dielectric constant and conductivity along with the topography. The Scanning near-field optical / atomic force microscopy (SNOAM) is a new tool for surface imaging which was introduced as one application of the atomic force microscope (AFM). Operated with non-contact forces between the optical fiber and sample as well as equipped with the piezoscanners, the instrument reports on surface topology without damaging or modifying the surface for measuring of optical characteristic in the films. We report our recent results of its application to nanoscopic study of domain structures and electrical functionality in organic thin films by SMM. Furthermore, we have illustrated the SNOAM image in obtaining the merocyanine dye films as well as the optical image.

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Design of a Water Reuse System Combined with a Fiber Filtration and Electrolysis (섬유여과기와 전기분해조를 병합한 물 재이용 시스템 설계)

  • Shin, Choon-Hwan
    • Journal of Environmental Science International
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    • v.24 no.11
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    • pp.1385-1391
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    • 2015
  • A water reuse system was designed for a demonstration plant by combining fiber filtration and electrolysis. A discharged dye wastewater after treated with biomedia was used in this study. It was found that an additional removal of suspended solids (SS) was feasible with 2-stage filtration while electrolysis was not effective. Also, $COD_{cr}$ and $COD_{Mn}$ were not removed with 2 -stage filtration but electrolysis resulted in about 26.9% additional removal. This indicates that electrolysis play an important role in organic removal. Removal of T-N and T-P was negligible with 1 and 2-stage fiber filtration and low-level electrolyte. However, with 2000 ppm of electrolyte, their removal efficiencies were about 83.1 and 60%, respectively, suggesting that the removal rates are well associated with the electrolyte concentrations. With high-level electrolyte, colority was removed about 82% while chlorine ions were removed only about 10%. Therefore, to treat underground water containing high-level salinity in the follow-up study, based on the results in this paper, a combined system with selection of additional unit process and reverse osmosis will be designed.

RGB Light Emissions from ZnSe Based Nanocrystals: ZnSe, ZnSe:Cu, and ZnSe:Mn

  • Song, Byungkwan;Heo, Jeongho;Hwang, Cheong-Soo
    • Bulletin of the Korean Chemical Society
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    • v.35 no.12
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    • pp.3601-3608
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    • 2014
  • RGB light emitting ZnSe based nanocrystals: ZnSe (blue), ZnSe:Cu (green) and ZnSe:Mn (red) were synthesized by capping the surface of the nanocrystals with oleic acid. The obtained nanocrystal powders were characterized by using XRD, HR-TEM, ICP-AES, FT-IR, and FT-Raman spectroscopies. The optical properties were also measured by UV/Vis and photoluminescence (PL) spectroscopies. The PL spectra showed broad emission peaks at 471 nm (ZnSe), 530 nm (ZnSe:Cu) and 665 nm (ZnSe:Mn), with relative PL efficiencies in the range of 0.7% to 5.1% compared to a reference organic dye standard. The measured average particle sizes from the HR-TEM images for those three nanocrystals were 4.5 nm on average, which were also supported well by the Debye-Scherrer calculations. The elemental compositions of the ZnSe based nanocrystals were determined by ICP-AES analyses. Finally, the drawn CIE diagram showed the color coordinates of (0.15, 0.16) for ZnSe, (0.22, 0.57) for ZnSe:Cu, and (0.62, 0.35) for ZnSe:Mn respectively, which were fairly well matched to that of the RGB color standards.

Quantum Yield of Photoinduced Electron Transfer Across Microemulsion Interfaces (마이크로 에멀젼 계면을 통과하는 광유발전자의 양자수득률)

  • Yong-Tae Park
    • Journal of the Korean Chemical Society
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    • v.27 no.3
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    • pp.213-217
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    • 1983
  • Devices that mimic the natural photosynthetic pathway are of considerable interest as fuel sources. Quantum yield of viologen radical formation in several water-in-oil microemulsion system were measured. The yield of hexadecylviologen radical formation in microemulsion system using EDTA as an electron donor, ruthenium bipyridinium complex as photosensitizer, and hexadecylviologen as an electron acceptor was 12%. When benzylnicotinamide was inserted in the interface of the microemulsion and azo compound was dissolved in oil face, the quantum yield of hydroazo compound was 0.16. Organic dye (Rose bengal) was used as photosensitizer for the photoinduced electron transfer reaction. In anionic microemulsion no electrontransfer was observed.

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Efficient white organic light-emitting diodes with a doped hole-blocking layer

  • Ahn, Young-Joo;Kang, Gi-Wook;Lee, Nam-Heon;Lee, Mun-Jae;Kang, Hee-Young;Lee, Chang-Hee
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.780-783
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    • 2002
  • We report very efficient white OLEDs consisting of a blue-emitting 4,4'bis[N-(1-napthyl)-N-phenyl-amino]-biphenyl (${\alpha}$-NPD), a hole-blocking layer of 2,9-dimethyl-4, 7-diphenyl-1, 10-phenanthroline (BCP) doped with red fluorescent dye of 4-dicyanomethylene-2-methyl-6-[2-(2,3,6,7-tetrahydro- 1H, 5H-benzo[i,j]quinolizin-8-yl) vinyl]-4H-pyran) (DCM2), and green-emitting tris(8-hydroxyquinoline) aluminum ($Alq_3$). The device with the structure of ITO/${\alpha}$-NPD (50 nm)/BCP:DCM2 (0.8 %, 4 nm)/$Alq_3$ (50 nm)/LiF (0.5 nm)/Al shows a white emission with the CIE coordinates (0.329, 0.333). The maximum luminance of 20,800 cd/$m^2$ is obtained at 15.4 V. The power efficiency is 2.6lm/W and the external quantum efficiency is 2.1 % at a luminance of 100 cd/$m^2$ at the bias voltage of 6 V.

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Fluorescent White OLEDs with a High Color-rendering Index Using a Silicon-Cored Anthracene Derivative as a Blue Host

  • Kwak, Jeong-Hun;Lyu, Yi-Yeol;Lee, Hyun-Koo;Char, Kook-Heon;Lee, Chang-Hee
    • Journal of Information Display
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    • v.11 no.3
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    • pp.123-127
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    • 2010
  • Fluorescent white organic light-emitting diodes showing high color-rendering indices (CRIs) of up to 81 was demonstrated, with a silicon-cored anthracene derivative (PATSPA) doped with DPAVBi utilized as the deep-blue host and dye materials, and the commercial dyes rubrene and DCM2 utilized as the orange- and red-light-emitting dyes. The devices, consisting of three emissive layers, showed bright-white-light emission, but the ratio of the blue peak to the orange and red peaks changed with the current density and the thickness of the blue emissive layer. A high CRI was achieved with the use of a deep-blue emitter doped in a novel host and by optimizing the blue-layer thickness. The device with a blue-layer thickness of 10 nm showed the Commission Internationale de l'Eclairage (CIE) color coordinate of (0.33, 0.35), a high CRI of 81, and a moderate external quantum efficiency of 2% at a current density of $2.5\;mA/cm^2$.

The Physical Properties of Polycarbonate Films Coated with Hard and Color Coating Materials (내마모성 색상코팅제를 코팅한 폴리카보네이트 필름의 물리적 특성)

  • Kim, Hyunjoon
    • Korean Chemical Engineering Research
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    • v.47 no.3
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    • pp.316-320
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    • 2009
  • UV curable hard and color coatings were formed on polycarbonate(PC) films. The coating materials were composed of a commercially available end-capped polyester(EB830), diacrylate monomer(HDDA), silicon acrylate, photoinitiator, and organic dye as a coloring agent. The surface properties of coating films were evaluated, and the influences of the compositions of coating materials were investigated. The coating films showed high transmission and good adhesion between coating layer and PC substrate. And the coating films exhibited higher hardness than bare PC film. The coating films with various colors were obtained by wet process, and the clear and color window lenses for mobile phone were prepared successfully.

Spectroscopic Characterization on the Aggregation Behavior of Pyronin G with Tetraphenylborate anion (Tetraphenylborate 음이온과 Pyronin G의 회합에 관한 분광학적 특성)

  • Lee, Beom-Gyu;Kim, Kang-Jin
    • Analytical Science and Technology
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    • v.8 no.1
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    • pp.47-53
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    • 1995
  • The aggregation of Pyronin G($PG^+$) with tetraphenylborate($TPB^-$) anion has been investigated in aqueous solution by absorption and fluorescence spectrophotometries. The addition of 1,4-dioxane in aqueous solution of $PG^+$ and $TPB^-$ dissociates the aggregates of PG-TPB due to the increased hydrophobicity of the mixed solvent as compared to pure water, and yields higher $PG^+$ momomer concentration than aqueous $PG^+$ solution. The aggregation is not observed in any organic solvents except in water. The absorption maxima of $PG^+$ are correlated relatively well with ${\pi}^*$ scale and $(n^2-1)/(2n^2+1)$ funtion. But better linear relationship was obtained with ${\pi}^*$ scale for alcohols.

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Nutritional Effects on the Environmental Health (영양과 환경과의 관계)

  • 문현경
    • Journal of environmental and Sanitary engineering
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    • v.6 no.2
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    • pp.17-31
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    • 1991
  • The effects of environmental agents on health are great concern for all. It was recognized that each human has differential susceptibility to environmental effects. Susceptibility are changed by many factors includin gdevelopmpntal processes, genetic factors, nutritional stratus, preexisting disease conditions, life style and personal habits. Of all factors nutritional factors seem to be the area most modifiable. Consequently, It is an area that must be more thoroughly evaluated. In this paper, nutrient and environment interactions are reviewed briefly with published literatures. This paper deals with the influence of micronutrients(energy, protein and fat), Vitamins (vitamin 4, vitamin B-complex, vitamin C, vitamin D and vitamin I) and Minerals(calcium, iron, selenium, zinc and other minerls) on environmental effects. The role of arch nutrient was assessed in modifyine the expression of environmental pollutant toxicity with available litertures. In each nutrient section, the effect of environment was considered in following agents : heavy metals(lead, cadmium, mercury, silver and etc), inorganic agents(nitwits, sulfite, fluoride and etc), organic agents(benzene, carbon tatra-chloride, aflatoxin, auto dye, dialbrin etc), Irritant gas(ozone, carbon monooxide and etc), physical agents(X-irradiation, ultra violet, temperature and noise) and insectcides. The extent to which nutritional status modifies environmental effects 3nd its converse, how envirollments affects nutritional status is very complex. In deed, at the present time there are more than 50 chelnical/phycical agents that affect the nutrient metabolism and/or have their toxicity either directly diminished or enhanced by nutrients of those agents, small number of agents for each nutrients have sufficient evidence to warrant any reasonable degree of confidence in their hypothesized associtation. With these information at this present time it is hard to conclude that the recommended dietary allowance for each nutrient should be reconsidered.

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Study of Minimalism of Contemporary Furniture Based on Environment-fiendly Aspect (환경 친화적 관점에 기초한 현대 가구의 Minimalism적 고찰)

  • 문선옥;김종만
    • Journal of the Korea Furniture Society
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    • v.13 no.1
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    • pp.71-83
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    • 2002
  • This study was carried out to develop colored-wood furniture using veneer, small-round log and fiberboard to protect forest resources through the study of minimalism. which advocates the environmental issue inherent to contemporary furniture in the postmodern era. Based on the historical and theoretical context of minimalism closely related to the environmental protection, this study suggested the technical way how to produce the environment-friendly furniture with the least use of valuable and natural log. Finally, the color-wooden furniture was developed based on the asceticism, simplification, and repetition of the minimalism in a trend of contemporary furniture design. By soaking a veneer, Psuedotsuga menziesii and small-round log, Pinus densiflora into a very-diluted organic dye, the environment-friendly and colored-wood furniture could be created in harmony with contemporary interior space, which has showed various colors such as yellow, blue, red, and green with a pastel tone. The spring wood of the colored softwood was deeply stained, while the summer wood was lightly done. By utilizing such valueless used woods which have been little in furniture production, it was possible to decrease the consumption of precious raw log such as zelkova, ebony, rose, maple, cherry, mahogany and so on. Thus, it became obvious to be able for contemporary furniture designers to produce beautiful furniture with dyed fiberboard and small-round logs pregnant with minimalism.

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