• Title/Summary/Keyword: organic content

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Preparation of Organophilic MMT Modified with Various Aromatic Amines and Characterization of Polyimide Nanocomposite Films (다양한 구조의 방향족 아민으로 개질된 친유기성 MMT의 제조와 이를 이용한 폴리이미드 나노복합필름의 특성)

  • Han, Seung San;Choi, Kil-Yeong;Im, Seung Soon;Kim, Yong Seok
    • Applied Chemistry for Engineering
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    • v.17 no.2
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    • pp.177-182
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    • 2006
  • In this work, we have prepared organophilic MMT having thermal stability by ion exchange reaction of various aromatic ammonium salts with MMT containing sodium ion. The organic modifiers having alkyl side chains and amine functional group were successfully synthesized by effectively introducing the surfaces of MMT via ion exchange reaction to form organophilic MMTs with a view to improve the reactivity and thermal stability. The WAXD patterns of organophilic MMT showed the more increased gallery spacing by $3.3{\AA}$ than that of the pristine MMT and also the onset of initial decomposition of organophilic MMT was $275^{\circ}C$ as determined by a thermogravimetric analysis. The polyimide (PI) nanocomposite films based on poly(amic acid) and organophilic MMT were prepared by a solution blending followed by cyclodehydration reaction. We have investigated the dispersity of organophilic MMTs in PI matrix by using WAXD and the effect of the organophilic MMT content on the mechanical properties of PI nanocomposite films was studied.

Short-term Effects of Cultivars and Compost on Soil Microbial Activities and Diversities in Red Pepper Field (토양 미생물 활성과 다양성에 미치는 고추 품종과 퇴비의 단기적 효과)

  • Park, Kee-Choon;Kwon, Tae-Ryong;Jang, Kil-Soo;Kim, Yeong-Suk
    • Korean Journal of Environmental Agriculture
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    • v.27 no.2
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    • pp.139-144
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    • 2008
  • A field experiment was conducted to investigate the influence of cultivars and compost on soil microbial activities and diversities in a red pepper-grown field. Compost was applied with 0, 30, and 60M/T $ha^{-1}$ in April and then red pepper seedlings of "Yong-go 4" and "Koeun" were transplanted in May 2007. Soil samples were collected in early August 2007. Measurement of microbial activities was based on a dehydrogenase assay and a fluorescein diacetate hydrolysis. Soil microbial community was characterized with Biolog $EcoPlate^{TM}$ and phospholipid fatty acid(PLFA). Red pepper cultivars did not differentiate the selected soil chemical and microbial properties. Soil pH and soil microbial community changed by amending the soil with 30 and 60 M/T $ha^{-1}$ of compost, and the soil organic matter and potassium content, and soil microbial activities increased in soils amended with 60 M/T $ha^{-1}$ of compost. Red pepper cultivar induced a little different soil chemical properties and microbial activity in soils amended with 60 M/T $ha^{-1}$ of compost even though significant differences were not found in those properties. In conclusion the effects of compost on soil chemical and microbial properties were much higher than red pepper cultivars in short-term period but the effects of red pepper cultivars should be investigated in long-term field test.

Properties of Cheongkukjang Prepared with Admixed Medicinal Herb Powder (생약초(표고버섯, 더덕, 어성초)를 첨가한 청국장의 특성)

  • Park, Jung-Suk;Cho, Sang-Hyeok;Na, Hwan-Sik
    • Food Science and Preservation
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    • v.17 no.3
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    • pp.343-350
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    • 2010
  • Cheongkukjang was prepared by addition of medicinal herb powder (from Lentinus edodes, Codonopsis lanceolata BENTH et HOOK, or Houttuynia cordata THUNB) to improve Cheongkukjang quality and functional properties. Redness and yellowness (measured using Hunter’s color values) increased with increasing amounts of medicinal herb powder, whereas lightness (the third Hunter's color value) and pH decreased. Crude protein and lipid levels of Cheongkukjang decreased with increasing amounts of added medicinal herb powder, whereas powder addition did not affect either the moisture or crude ash content of Cheongkukjang. The major organic acids of Cheongkukjang were lactic acid, acetic acid, succinic acid, and citric acid, and acid levels increased as the proportion of medicinal herb powder in the Cheongkukjang preparation increased. The major amino acids of Cheongkukjang were glutamic acid, aspartic acid, leucine, arginine, and lysine and the principal fatty acids were linoleic acid, oleic acid, palmitic acid, and linolenic acid. Addition of medicinal herb powder to Cheongkukjang increased both crude saponin and quercetin contents. Sensory scores of Cheongkukjang containing 2% (w/v) medicinal herb powder were optimal in terms of both quality characteristics and sensory evaluation.

Effect of Sawdust Mixing Ratio on Composting of Animal Cadaver Residue Using Rendering Treatment Method (톱밥 혼합비율이 랜더링 처리 가축사체의 퇴비화에 미치는 영향)

  • Choi, Ik-Won;Seo, Dong-Cheol;Kang, Se-Won;Seo, Young-Jin;Lee, Sang-Gyu;Sung, Hwan-Hoo;Heo, Jong-Soo;Kang, Seog-Jin;Cho, Ju-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.3
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    • pp.404-409
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    • 2012
  • In order to obtain optimum mixing conditions with animal cadaver residue and sawdust for composting using rendering treatment method for agricultural recycling, changes of chemical characteristics and compost quality after composting were investigated. Initial mixing ratios with animal cadaver residue and sawdust were adjusted 100 : 0, 50 : 50 and 30 : 70. Temperature, pH, contents of ammonia and carbon dioxide were rapidly increased in 3 days and then decreased with time. Organic matter content was similar in all conditions. In mixing ratio of 50 : 50, the compost quality was satisfied with compost depending on official standard for product fertilizer. Thus, the optimum mixing ratio of animal cadaver residue and sawdust were 50 : 50.

Growth Environment and Vegetation Structure of Native Habitat of Corydalis cornupetala (쇠뿔현호색 (Corydalis cornupetala Y.H.Kim et J.H.Jeong) 자생지의 생육환경과 식생구조)

  • Sung, Jung-Won;Yi, Myung-Hoon;Yoon, Jung-Won;Kim, Gi-Song;Shin, Hyun-Tak;Kim, Yong-Shik
    • Korean Journal of Environment and Ecology
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    • v.27 no.3
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    • pp.271-279
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    • 2013
  • The species of Corydalis cornupetala Y.H.Kim et J.H.Jeong Which is belong to the Corydaliaceae is only distributed at the Gyaejeong Forest in Gyeongsan. As one of the spring ephemeral plants, this species has limited growing period. The present study is on site characteristics and vegetation structure in the wild habitats of Corydalis cornupetala Y.H.Kim et J.H.Jeong and offers basic information on habitat conservation including recovery plan. The soil texture is silty loam and soil acidity is ranged as pH 5.4~5.9. The electric conductivity was 0.22-0.50 ds/m and soil organic content is ranged as 7.61~15.78 %. Fifty nine vascular plants were identified from 5 quadrats. According to the two way cluster analysis applied by the PC-ORD, the community was classified as Acer ginnala, Vicia amoena and Stellaria aquatica. The habitat of Corydalis cornupetala Y.H.Kim et J.H.Jeong was determined by the dissimilarity indices rather than the species number of appearance. Species diversity was 1.26, and dominance and evenness were found to be 0.08 and 0.92, respectively.

Effects of Replacing Dry-rolled Corn with Increasing Levels of Corn Dried Distillers Grains with Solubles on Characteristics of Digestion, Microbial Protein Synthesis and Digestible Energy of Diet in Hair Lambs Fed High-concentrate Diets

  • Castro-Perez, B.I.;Garzon-Proano, J.S.;Lopez-Soto, M.A.;Barreras, A.;Gonzalez, V.M.;Plascencia, Alejandro;Estrada-Angulo, A.;Davila-Ramos, H.;Rios-Rincon, F.G.;Zinn, R.A.
    • Asian-Australasian Journal of Animal Sciences
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    • v.26 no.8
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    • pp.1152-1159
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    • 2013
  • Four male lambs (Katahdin; average live weight $25.9{\pm}2.9$ kg) with "T" type cannulas in the rumen and proximal duodenum were used in a $4{\times}4$ Latin square experiment to evaluate the influence of supplemental dry distillers grain with solubles (DDGS) levels (0, 10, 20 and 30%, dry matter basis) in substitution for dry-rolled (DR) corn on characteristics of digestive function and digestible energy (DE) of diet. Treatments did not influence ruminal pH. Substitution of DR corn with DDGS increased ruminal neutral detergent fiber (NDF) digestion (quadratic effect, p<0.01), but decreased ruminal organic matter (OM) digestion (linear effect, p<0.01). Replacing corn with DDGS increased (linear, $p{\leq}0.02$) duodenal flow of lipids, NDF and feed N. But there were no treatment effects on flow to the small intestine of microbial nitrogen (MN) or microbial N efficiency. The estimated UIP value of DDGS was 44%. Postruminal digestion of OM, starch, lipids and nitrogen (N) were not affected by treatments. Total tract digestion of N increased (linear, p = 0.04) as the DDGS level increased, but DDGS substitution tended to decrease total tract digestion of OM (p = 0.06) and digestion of gross energy (p = 0.08). However, it did not affect the dietary digestible energy (DE, MJ/kg), reflecting the greater gross energy content of DDGS versus DR corn in the replacements. The comparative DE value of DDGS may be considered similar to the DE value of the DR corn it replaced up to 30% in the finishing diets fed to lambs.

Study on Stratigraphy, Structural Geology and Hydrocarbon Potentials of the Cretaceous Strata, Northeastern Iraq (이라크 북동부 지역 백악기 퇴적층의 층서, 구조지질 및 탄화수소 부존 유망성 연구)

  • Lee, Taecheol;Han, Seungwoo;Ryu, In-Chang
    • Economic and Environmental Geology
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    • v.47 no.4
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    • pp.381-393
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    • 2014
  • Seismic reflection data are integrated with fieldwork data in order to understand startigraphy, structural geology and hydrocarbon potentials of Cretaceous strata in the Mesopotamian basin, Northeastern Iraq. Cretaceous strata in the basin divided into the Qamchuqa, Kometan, Bekhme and Shiranish formations, which are composed of carbonates deposited in shallow marine environment. The geological structures in these formations are mainly recognized as thrusts, detachment folds, fault propagation folds and fault bend folds. As well, NW-SE trending fractures are regularly developed, and are horizontal or perpendicular to the structures. The distribution and frequency of fractures are related to the development of the thrusts. In terms of hydrocarbon potentials, Cretaceous strata in the basin have limited capacities for source rocks and seal rocks due to the lack of organic carbon content and the well-developed fractures, respectively. Although these carbonates have limited primary porosity, however, development of the secondary porosity derived from the fractures contributes to enhance the reservoir quality. Most important factor for the reservoir quality of Cretaceous strata seems to be the frequency and connectivity of fractures relative to locations of folds and faults. The results delineated in this study will use as reference for recognizing stratigraphy and structures of Cretaceous strata and will provide useful information on hydrocarbon potentials of Cretaceous strata in the Mesopotamian basin, NE Iraq.

Estimation of Gas-particle partitioning Coefficients (Kp) of Carcinogenic polycyclic Aromatic hydrocarbons in Carbonaceous Aerosols Collected at Chiang - Mai, Bangkok and hat-Yai, Thailand

  • Pongpiachan, Siwatt;Ho, Kin Fai;Cao, Junji
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.4
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    • pp.2461-2476
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    • 2013
  • To assess environmental contamination with carcinogens, carbonaceous compounds, water-soluble ionic species and trace gaseous species were identified and quantified every three hours for three days st three different atmospheric layer at the heart of chiang-Mai, bangkok and hat-Yai from December 2006 to February 2007. A DRI model 2001 Themal/Optical Carbon Analyzer with the IMPROVE thermal/optical reflectance (TOR) protocol was used to quantify the organic carbon(OC) and elemental carbon content in $PM_{10}$. Diurnal and vertical variability was also carefully investigated. In general, OC and EC contenttration shoeed the highest values at the monitoring period o 21.00-00.00 as consequences of human activities at night bazaar coupled with reduction of mixing layer, decreased wind speed and termination of photolysis nighttime. Morning peaks of carboaceous compounds were observed during the sampling period of 06:00 -09:00, emphasizing the main contribution of traffic emission in the three cities. The estimation of incremental lifetime partculate matter exposure (ILPE) raises concern of high risk of carbonaceous accumulation over workers and residents living close to the observatory sites. The average values of incremental lifrtime particulate matter exposure (ILPE) of total carbon at Baiyoke Suit Hotel and Baiyoke Sky Hotel are approsimately ten time shigher then those air sample collected at prince of songkla University Hat-Yai campus corpse incinerator and fish-can maufacturing factory but only slightly higher than those of rice straw burnig in Songkla province. This indicates a high risk of developing lung cancer and other respiratory diseases across workers and residents living in high buildings located in Pratunam area. Using knowledge of carbonaceous fractions in $PM_{10}$, one can estimate the gas-particle partitioning of polycyclic aromatic hydrocarbons (PAHs). Dachs-Eisenreich model highlights the crucial role of adsorption in gas-particle partitioning of low molecular weight PAHs, whereas both absorption and adsorption tend to account for gas-particle partitioning of high molecular weight PAHs in urban residential zones of Thailand. Interestingly, the absorption mode alone plays a minor role in gas-partcle partitiining of PAHs in Chiang-Mai, Bangkok and hat-Yai.

Plant Species Selection Program for Ecological Restoration of Coastal Reclaimed Land -Focused on the Dumped Soil Area at Inchon Airport- (해안간척지의 생태적 환경복원을 위한 식물 선정에 관한 연구 -인천공항 사토장지역을 중심으로-)

  • Bae, Young-Hun;Lee, Dong-Kun
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.4 no.3
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    • pp.66-74
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    • 2001
  • The main purpose of this thesis is to select the appropriate plants for the ecological restoration of coastal land. The soil and vegetation environment survey of the beach where the halophytes live now was executed for the sake. Firstly, the soil survey was done by the physical and chemical survey of beach soil and dumped soil. The soil is mostly sandy loam and sandy clay loam which has silty much. The beach soil where the salt plants live has more organic matters in the content than dumped soil because of the influx of the dead halophytes, a pioneer plant to this area. Secondly the vegetation survey was executed by the halophytes survey in the beach area in order to select the appropriate plants for ecological restoration. The shows two different areas in the vegetation divided by the salt density of soil. Artemisia fukudo, Juncus haenkei, Carex pumila, Silene armeia, Polyponum aviculare etc live in the less salt density area and it doesnt show collected. Salicornia herbacea, Suaeda asparagoides, Aster tripolium, Limonium tetragonum, Suaeda maritima, Scirus fluvitilis, Phragmtes communis, Suaeda japonica, Zoysia sinica etc halophytes live in the more salt density area and there are a few advent plant but many collected. So the salt density of soil limits the vegetation. The selection of appropriate plants for the ecological restoration programs was designed with 3 different standards considering the salt density of soil in the dumped soil area. The plan selection guidelines of thick salt density due to the salt density of soil, and economical efficiency and maintenance because the area is large. The guidelines of middle salt density area were made considering economical efficiency and maintenance because there are salt as well, and it is effective for the scenery if they have normal ecology but their leaves have good color and the flowers are beautiful. However I suggest beautiful flowery plants for the neutral plan area because this area is the entry point of the airport so the view is very important.

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A Fundamental Study on the Effect to Build up a Vegetation Strip at Stream Confluence by Using Reed Mat (하천합류부에서 갈대매트를 이용한 하천식생대 조성에 대한 기초적 연구)

  • Chung, Kyung-Jin;Kim, Mi-Kyeong;An, Won-Yong
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.6 no.4
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    • pp.62-73
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    • 2003
  • The study was to apply a mat style reed planting method at confluence to improve plants growth conditions by relaxing disturbed topographical base due to water flow and was intended to review the effect to build up a vegetation strip by monitoring process after the construction. First off, We've attempted to construct reed mats on selected sites as confluences of Tan and Gaehwa stream and then examined and analyzed characteristics of soil and vegetation community. As the results of the examination, the soil texture was proven to be a mix of sand and loamy sand and be 6.3 ~ 7.0 soil pH. In addition, it contained 1.0 ~ 4.6% of organic matter, 0.04 ~ 0.22% of T-N and 27.8 ~ 41.2% of water content. For its vegetation structure, the Tan stream confluence was first actually a point bar without plants prior to the construction but 8 kinds of hygrophytes including Persicaria hydropiper and 9 kinds of terrestrial plants such as Potentilla supina, Artemisia annua, and Alopecurus aequalis var. amurensis. On the other hand, the Gaehwa stream confluence contained 6 kinds of hygrophytes such as Bidens frondosa and other 11 kinds of terrestrial plants prior to the construction while it produced 7 kinds of hygrophytes including Ranunculus ternatus as well as Phragmites australis and 9 kinds of terrestrial plants such as Potentilla supina after the construction. For the Phragmites australis, almost of them was weathered away in early days just after planting because of development period passed, but on May, six months later from planting, it was investigated that its length was approximated as 65 ~ 85cm with 75% coverage and that the number of it was 437 ~ 633/$m^2$. The study was shown that reed mats can improve environmental conditions of disturbed topographical base, enabling natural growth of various riparian vegetation including the introduced plant, reed. In the meantime, it was supposedly judged that to recover or build up a vegetarian strip, supplementary materials should be prepared to help produce and grow plants because it is not probable to expect river drift by water flow at confluence and that corrosion, burying or inundation owing to changes of water lever should be considered.