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New Generation of Lead Free Solder Spheres 'Landal - Seal'

  • Walter H.;Trodler K. G.
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2004.09a
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    • pp.211-219
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    • 2004
  • A new alloy definition will be presented concerning increasing demands for the board level reliability of miniaturized interconnections. The damage mechanism for LFBGA components on different board finishes is not quite understood. Further demands from mobile phones are the drop test, characterizing interface performance of different package constructions in relation to decreased pad constructions and therefore interfaces. The paper discusses the characterization of interfaces based on SnPb, SnPbXYZ, SnAgCu and SnAgCuInNd ball materials and SnAgCuInNd as solder paste, the stability after accelerated tests and the description of modified interfaces stric시y related to the assembly conditions, dissolution behavior of finishes on board side and the influence of intermetallic formation. The type of intermetallic as well as the quantity of intermetallics are observed, primaliry the hardness, E modules describing the ability of strain/stress compensation. First results of board level reliability are presented after TCT-40/+150. Improvement steps from the ball formulation will be discussed in conjunction to the implementation of lead free materials. In order to optimize ball materials for area array devices accelareted aging conditions like TCTs were used to analyze the board level reliability of different ball materials for BGA, LFBGA, CSP, Flip Chip. The paper outlines lead-free ball analysis in comparison to conventional solder balls for BGA and chip size packages. The important points of interest are the description of processability related to existing ball attach procedures, requirements of interconnection properties and the knowledge gained the board level reliability. Both are the primary acceptance criteria for implementation. Knowledge about melting characteristic, surface tension depend on temperature and organic vehicles, wetting behavior, electrical conductivity, thermal conductivity, specific heat, mechanical strength, creep and relaxation properties, interactions to preferred finishes (minor impurities), intermetallic growth, content of IMC, brittleness depend on solved elements/IMC, fatigue resistance, damage mechanism, affinity against oxygen, reduction potential, decontamination efforts, endo-/exothermic reactions, diffusion properties related to finishes or bare materials, isothermal fatigue, thermo-cyclic fatigue, corrosion properties, lifetime prediction based on board level results, compatibility with rework/repair solders, rework temperatures of modified solders (Impurities, change in the melting point or range), compatibility to components and laminates.

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Distribution and Effect on Organisms of Butyltin Compounds Inside Songsan Harbor of Cheju Island (제주도 성산항내 부틸주석화합물의 분포와 생물체에 미치는 영향)

  • 김상규;안이선;고병철;조은일;이기호
    • Journal of Environmental Science International
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    • v.9 no.4
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    • pp.285-294
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    • 2000
  • Butyltin compounds (BTs) in seawater, sediments and organisms (Thais clavigera, Liolophura japonica and Cellana nigrolineata), were quantitatively determined to evaluate their distribution inside Songsan Harbor of Cheju Island. In addition, imposex in T. clavigera was used to assess the effect on organisms of BTs. Analysis of the samples collected in seawater, sediments (March, June and August) and organisms (May, July and August) in 1998, confirmed the contamination of BTs in the aquatic environment inside Songsan Harbor. The main BTs species in seawater and sediments was monobutyltin (MBT), tributyltin (TBT), respectively, irrespective of survey time. In oranisms, TBT and dibutyltin (DBT) were detected in similar concentrations for T. clavigera and L. japonica, but for C nigrolineata, DBt concentration was the highest. TBT, the most toxic to aquatic organisms among BTs, was found at concentrations which were sufficient to have a serious effect on the sensitive organisms upon chronic exposure, The relatively high correlations (r>0.83) between BTs indicated that DBT and MBT were mainly degraded from TBT based on antifouling paint and their sources were negligible. The sedimentary organic matters did not have influence on the distribution of BTs in marine environment, and lipid content in T. clavigera did not show a correlation with TBT concentrations. The rate of occurrence of imposex in T. clavigera was 100%, and the relative penis length index (RPLI) and the relative penis size index (RPSI) which represent the degree of imposex were 79.7%, 58.1%, respectively. Measurement of imposex in T. clavigera was expected to be a very helpful tool for preliminary survey of BTs prior to trace analysis of BTs.

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Skin safety of the UV Absorbers by Measurement Cytotoxicity High Functional Product with Water-in-Silicone System

  • In-Young Kim;Min
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.23 no.3
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    • pp.134-146
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    • 1997
  • Consumers have recently preferred to purchase extensive UV intercepting products, which are waterproof and free from side effects on skin. Testing Cytoroxicity in SR method, cell survivial ratio of UV-B interceptors decreased above 0.08W/V%, and so did that of UV-A interceptors above 0.06W/V%. Also, Patch-test of inorganic UV interceptors resulted in no skin irritation even below 10.0 and 11.25. UV interceptors in the sunlight showed yellowish discoloration in 5 to 14 days. In absorption curves, UV-B was most suitable for Octyl methoxycinnamate and UV-A for Butyl methoxy dibenzoylmethane. Fro this reason, Nylonpoly UVA/UVB the material of OMC and BMDM coated with Nylon & polyethylene, was used as the organic UV interceptor. And zinc oxide and titanium dioxide was used as inorganic UV ibterceptors. The appropriate mixture ratio of ZnO and TiO2 was 6 to 4.6% of ZnO, 4% of TiO2 and 5% of Nylonpoly UVA/UVB were all combined with our sunscreen cream. The SPF value of in-vivo applied to a guinea pig was 34.9 and that of in-vivo was 38.5. Cyclomerhicone and dimerthicone were used in water-in-Silicone system. Ceryl diverhicone and sorbitan sesquioleate were used as emulsifiers and MgSO4, 7H2O, Mg-stearate/Mg-Al-stearate copolymer as emulsification stabilizers. In practical application, each SPF duration of O/W type and W/S type containing sunscreen cream of the same content showed that W/S type of sunscreen cream was 5 times as durable as the other. This product is fit for using in swimming, climbing or skiing. This research is to minimize skin trouble used by UV interceptors and to make one with proper softness, skin safety and UV intercepting efficiency.

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Thermal Insulation Property of UV Cure Coatings Using Hollow Micro-Spheres (마이크로 중공구를 이용한 자외선 경화 코팅 박막의 단열 특성)

  • Kim, Nam Yi;Chang, Young-Wook;Kim, Seong Woo
    • Korean Chemical Engineering Research
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    • v.50 no.4
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    • pp.621-626
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    • 2012
  • In this study, the composite coating materials with improved thermal insulation property were prepared by incorporating the hollow micro-spheres with high heat transfer resistance. The UV curable resin system consisting of hexa aliphatic urethane acrylate (UP118), trimethylolpropane triacrylate (TMPTA), 1,6-hexanediol diacrylate (HDDA), and photoinitiator (Irgacure184) was employed as an organic binder. The glass substrates were coated by the prepared composites via bar coating method and cured under UV radiation. The optical transparency, thermal insulation property, adhesion, and surface hardness of the glass coated with composites containing different type of micro-spheres were investigated. The incorporation of micro-spheres with only 20 vol% of content resulted in remarkable improvement in the thermal insulation property of the coated glass. In addition, the transparent coated glass with light transmittance of about 80% could be obtained when silica micro-sphere (SP) was used as a thermal barrier.

The Effects of Additives in Napier Grass Silages on Chemical Composition, Feed Intake, Nutrient Digestibility and Rumen Fermentation

  • Bureenok, Smerjai;Yuangklang, Chalermpon;Vasupen, Kraisit;Schonewille, J. Thomas;Kawamoto, Yasuhiro
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.9
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    • pp.1248-1254
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    • 2012
  • The effect of silage additives on ensiling characteristics and nutritive value of Napier grass (Pennisetum purpureum) silages was studied. Napier grass silages were made with no additive, fermented juice of epiphytic lactic acid bacteria (FJLB), molasses or cassava meal. The ensiling characteristics were determined by ensiling Napier grass silages in airtight plastic pouches for 2, 4, 7, 14, 21 and 45 d. The effect of Napier grass silages treated with these additives on voluntary feed intake, digestibility, rumen fermentation and microbial rumen fermentation was determined in 4 fistulated cows using $4{\times}4$ Latin square design. The pH value of the treated silages rapidly decreased, and reached to the lowest value within 7 d of the start of fermentation, as compared to the control. Lactic acid content of silages treated with FJLB was stable at 14 d of fermentation and constant until 45 d of ensiling. At 45 d of ensiling, neutral detergent fiber (NDF) and acid detergent fiber (ADF) of silage treated with cassava meal were significantly lower (p<0.05) than the others. In the feeding trial, the intake of silage increased (p<0.05) in the cow fed with the treated silage. Among the treatments, dry matter intake was the lowest in the silage treated with cassava meal. The organic matter, crude protein and NDF digestibility of the silage treated with molasses was higher than the silage without additive and the silage treated with FJLB. The rumen parameters: ruminal pH, ammonia-nitrogen ($NH_3$-N), volatile fatty acid (VFA), blood urea nitrogen (BUN) and bacterial populations were not significantly different among the treatments. In conclusion, these studies confirmed that the applying of molasses improved fermentative quality, feed intake and digestibility of Napier grass.

Effects of Forage Sources on Rumen Fermentation Characteristics, Performance, and Microbial Protein Synthesis in Midlactation Cows

  • Xua, Jun;Houa, Yujie;Yang, Hongbo;Shi, Renhuang;Wu, Caixia;Huo, Yongjiu;Zhao, Guoqi
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.5
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    • pp.667-673
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    • 2014
  • Eight multiparous Holstein cows ($632{\pm}12$ kg BW; $135{\pm}16$ DIM) were used in a replicated $4{\times}4$ Latin square design to evaluate the effects of forage sources on rumen fermentation characteristics, performance, and microbial protein (MCP) synthesis. The forage portion of the diets contained alfalfa hay (AH), oat hay (OH), Leymus chinensis (LC), or rice straw (RS) as the primary source of fiber. Diets were isonitrogenous and isocaloric, and cows were fed four corn silages based total mixed rations with equivalent nonfiber carbohydrate (NFC) and forage neutral detergent fiber (NDF). Dry matter intake was not affected by the source of dietary forages, ranging from 18.83 to 19.20 kg/d, consequently, milk yield was similar among diets. Because of the numerical differences in milk fat and milk protein concentrations, 4% FCM and ECM yields were unchanged (p>0.05). Mean rumen pH, NH3-N content, and concentrations of volatile fatty acids in the rumen fluid were not affected by the treatments (p>0.05). Dietary treatments did not affect the total tract apparent digestibility of dry matter, organic matter, and crude protein (p>0.05); however, digestibility of NDF and acid detergent fiber in RS diet was higher compared with AH, OH, and LC diets (p<0.05). Total purine derivative excretion was higher in cows fed AH, OH, and LC diets compared with those fed RS diet (p<0.05), consequently, estimated MCP synthesis was 124.35 g/d higher in cows fed AH diet compared with those fed RS diet (p<0.05). The results indicated that cows fed AH, OH, LC, and RS diets with an equivalent forage NDF and NFC have no unfavourable effect on the ruminal fermentation and productive parameters.

Effects of dietary fermented spent coffee ground on nutrient digestibility and nitrogen utilization in sheep

  • Choi, Yongjun;Rim, Jong-su;Na, Youngjun;Lee, Sang Rak
    • Asian-Australasian Journal of Animal Sciences
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    • v.31 no.3
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    • pp.363-368
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    • 2018
  • Objective: The objective of the study was to determine the effect of fermented spent coffee ground (FSCG) on nutrient digestibility and nitrogen utilization in sheep. Methods: Fermentation of spent coffee ground (SCG) was conducted using Lactobacillus plantrum. Fermentation was performed at moisture content of 70% and temperature of $39^{\circ}C$ with anaerobic air tension for 48 h. Four adult rams (initial body weight = $56.8{\pm}0.4kg$) were housed in a respiration-metabolism chamber and the treatments were: i) control (Basal diet; 0% SCG or FSCG), ii) 10% level of SCG, iii) 10% level of FSCG, and iv) 20% level of FSCG in $4{\times}4$ Latin square design. Each dietary experiment period lasted for 18-d with a 14-d of adaptation period and a 4-d of sample collection period. Results: In SCG fermentation experimental result, acid detergent insoluble nitrogen (ADIN) concentration of FSCG (64.5% of total N) was lower than that of non-fermented SCG (78.8% of total N). Digestibility of dry matter and organic matter was similar among treatment groups. Although crude protein (CP) digestibility of the control was greater than FSCG groups (p<0.05), the 10% FSCG group showed greater CP digestibility and nitrogen retention than non-fermented 10% SCG group (p<0.05). Body weight gain and average daily gain were linearly decreased with increasing FSCG feeding level (p<0.05). When the feeding level of FSCG was increased, water intake was linearly increased (p<0.05). With an increasing FSCG level, dry matter intake did not differ among groups, although the gain to feed ratio tended to decrease with increasing level of FSCG (p<0.10). Conclusion: Microbial fermentation of SCG can improve protein digestibility, thereby increasing CP digestibility and nitrogen utilization in sheep. Fermentation using microorganisms in feed ingredients with low digestibility could have a positive effect on improving the quality of raw feed.

A Study on the Evalution after Urban Park Construction by Geographic Information System - Namsangol Park , Junggu , Seoul - (GIS를 활용한 도시공원 시공후 평가에 관한 연구 - 서울 중구 남산골공원을 중심으로 -)

  • 장동수;김남규
    • Spatial Information Research
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    • v.4 no.1
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    • pp.93-105
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    • 1996
  • The purpose of this study was to give some ideas to the improving direction and evaluation in order to solve physical' ecological problems appeared after urban park construction. This study selected Namsangol park as a site, because this park was constructed to the goal in order to rehabilitate the original landform as a part of "Namsan original landscape rehabilitation work". So this study was executed to investigate past and present landform change, soil condition, planting, water/climate etc., and then these were analyzed by GIS.- soil :pH, Ec, organic matter, the ability of moisture content, bulk density, porosity, etc.- planting:planting density, plant species- water/climate: the amount of rainfall, drainage and drainage-basin. And then this study overlayed soil+cut/fill, soil+pine tree, cut/fill + planting density, and cut/fill + plant species.t species.

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A Study on Isothermal Adsorption of VOCs onto Gypsum Mortar Incorporating Oyster Shell (굴패각 모르타르에의 휘발성 유기화합물 흡착에 대한 연구)

  • Kwon, Sung-Hyun;Cho, Daechul
    • Clean Technology
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    • v.19 no.2
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    • pp.134-139
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    • 2013
  • VOCs such as formaldehyde and benzene in a control chamber were adsorbed onto gypsum incorporating oyster shell powder, which was solidified and dried. VOC was first exposed in air and then gypsum mortar was placed in the chamber for 180 min for adsorption. The mortar was prepared with 0, 10, 30, and 50% of oyster shell powder. Two initial concentrations of VOCs including formaldehyde were $27.7{\sim}28.5mg/m^3$ or $175{\sim}150{\mu}g/m^3$. We found out that the initial concentrations did not seem to make any difference in adsorption performance but higher oyster content strongly led to higher adsorption. We used a convection-diffusion-adsorption model to compare the experiment. The model which considers diffusion coefficients of adsorbates and affinity of the adsorbents well represented the experimental data with a fair agreement.

Properties and fate of nitrogen in a reclaimed tidal soil (국내 간척지의 토양 특성과 질소 동태)

  • Kim, Hye-JIn;Kim, Gi-Rim;Woo, Hyun-Nyung;Park, Suk-Hyun;Shin, Ji-Hoon;Choi, Yoon-Chul;Chung, Doug-Young
    • Korean Journal of Agricultural Science
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    • v.38 no.2
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    • pp.301-307
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    • 2011
  • In this article, we reviewed properties of reclaimed tidal soil and fate of nitrogen in its soil. The results were summarized as followings. Most of the soil derived from the fluvio-marine deposit were silly textured soils. The EC of the Saemanguem soil were ranged from 14.7 to 33.9 dS $m^{-1}$, pH was 7.7. The organic matter content was low with 1.5 g $kg^{-1}$. The cation exchange capacity was 7.2 cmol $kg^{-1}$ and exchangeable sodium percent was high with range 45.1 % to 56.2%. High sodium concentration caused poor drainage. The salinity significantly affects efficiency of N fertilizer in reclaimed tidal soil.