• Title/Summary/Keyword: organic content

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Development of New Biodegradable CHITULOSE film from Composite of Chitin and Cellulose (Chitin과 Cellulose 복합체로부터 새로운 생분해성 CHITULOSE film의 개발)

  • 류영석;이충우홍범식윤정원
    • KSBB Journal
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    • v.8 no.3
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    • pp.230-236
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    • 1993
  • A Chitulose film was made by dissolving chitin and cellulose in a dimethylacetamide/LiCl solvent system This film was completely degraded in 20 days in soil and penetrated by soil microorganisms in 16-26 hours. A permeability analysis of the film showed that water permeability was in the range of 0-187.5 $1/m^2$/day, depending upon the ratio of chitin to cellulose and decreased with increasing a cellulose content in the Chitulose film The permeabilities of organic compounds, $Na^+$ and oxygen change with the composition of the Chitulose file The film was tested with a burned 2~3degree rat for exploring its use as artificial skin. The rat was completely cured within 31 days without inflammation.

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An Experimental Study on the Quality Estimation of the High-Quality of Recycled Sand by the differences between Small. Large Sand Flux Apparatus (샌드플럭스 장치의 대 . 소용량 차이에 따른 고품질 순환모래의 품질특성에 관한 연구)

  • Lee, Yun-Sung;Lee, Ji-Hwan;Bae, Kee-Sung;Lee, Sang-Soo;Song, Ha-Young
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2009.05b
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    • pp.81-85
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    • 2009
  • This study was to execute the basic property evaluation of recycled sand which produced by the sand flux device in order to evaluate the performance of differences between small large sand flux device. As a result, this study has found out that the recycled sand after passing the sand flux device had excellent quality characteristics compared with the One before passing the device. In additional experiment On the basic material properties, this study showed a tendency to improve the quality and performance significantly in case of fineness modulus, absolute surface dried density, 0.08mm sieve throughput, volume of clay lumps, and content of organic foreign matter. In conclusion, it was considered as various quality performances of recycled sand were improved through the production stage of prototype.

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Radiocarbon Dating (방사성탄소연대측정)

  • Leigh, Hyeon-Ju;Hwang, Jin-Ju;Paek, Hyun-Ju
    • 보존과학연구
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    • s.23
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    • pp.197-214
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    • 2002
  • It is very important to determine the age of the Cultural Properties in archeology. In about 1950, W.F. Libby and a team of scientists at the University of Chicago developed the Radiocarbon Dating technique. Radiocarbon($^14$C) Dating is probably one of the most widely used and best known absolute dating methods. Radiocarbon ages are conventionally specified to the year 1950. This year is 0 BP year. BP is the initial of Before Present. The $^14$C within an organism is continually decaying into stable carbon isotopes. When $^14$C decays, it emits a $\beta$ - particle with an energy content of 156 KeV and becomes 14N. Only the $\beta$ - particle is detected by Liquid Scintillation Counting. $^14$C has a half life of 5730 years. It has been used to date samples as old as 50,000 years. Radiocarbon determinations can be obtained on organic material : wood, charcoal, shell, etc. The results of radiocarbon dating using Benzene Synthesizer and Liquid Scintillation Counter are KCP539 $4030\pm60$BP year, KCP540 $3980\pm60$BP year, KCP575 $4870\pm50$, KCP576 $100\pm50$BP year, KCP577 $130\pm50$BP yea and KCP578 $210\pm70$BP year.

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Degradation of a Refractory Organic Contaminant by Photocatalytic Systems

  • Kim, Il-Kyu
    • Journal of Power System Engineering
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    • v.18 no.6
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    • pp.133-139
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    • 2014
  • In this research, the photocatalytic degradation of benzothiophene in $TiO_2$ aqueous suspension has been studied. $TiO_2$ photocatalysts are prepared by a sol-gel method. The dominant anatase-structure on $TiO_2$ particles is observed after calcining the $TiO_2$ gel at $500^{\circ}C$ for 1hr. Photocatalysts with various transition metals (Nd, Pd and Pt) loading are tested to evaluate the effect of transition metal impurities on photodegradation. The photocatalytic degradation in most cases follows first-order kinetics. The maximum photodegradation efficiency is obtained with $TiO_2$ dosage of 0.4g/L. The photodegradation efficiency with Pt-$TiO_2$ is higher than pure $TiO_2$ powder. The optimal content value of Pt is 0.5wt.%. Also we investigate the applicability of $H_2O_2$ to increase the efficiency of the $TiO_2$ photocatalytic degradation of benzothiophene. The optimal concentration of $H_2O_2$ is 0.05. The effect of pH is investigated; we obtain the maximum photodegradation efficiency at pH 9. Hydroxy-benzothiophenes and dihydroxy-benzothiophenes are identified as reaction intermediates. It is proposed that benzothiophene is oxidized by OH radical to sequentially form hydroxyl-benzothiophenes, dihydroxybenzothiophenes, and benzothiophenedione.

Considerations of Acid Decomposition System for the Analysis of Heavy Metals in Packaging-grade Paper (포장용지류에서의 중금속 분석을 위한 산분해 전처리 방법의 탐색)

  • Lee, Tai-Ju;Ko, Seung-Tae;Kim, Hyoung-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.1
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    • pp.65-73
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    • 2011
  • The fibrous raw materials in packaging-grade paper production in Korea were mainly obtained from waste paper. The use of recycled paper has both positive and negative impacts in papermaking process. The primary positive impacts are the environmental protection and manufacturing cost reduction, and the negative impacts are the quality reduction in paper quality and the accumulation of heavy metals and other pollutants in wet- and dry-end process. This study was carried out to consider the optimum acid decomposition system with the highest recovery rate for the analysis of heavy metals in packaging-grade paper. The open digestion system using Kjeldahl apparatus and the closed digestion system using microwave oven for decomposing the organic materials in paper were compared. In both open and closed digestion method, the combination of nitric acid, hydrochloric acid and hydrogen peroxide showed higher recovery rate than using only nitric acid alone because the presence of Cl- ions in hydrochloric acid stabilizes ligand formation with metal ions. KOCC was observed to have the highest heavy metal content among the recycled paper samples. The heavy metal contents decomposed with the closed digestion system were relatively higher than with open digestion system.

A Methylobacillus Isolate Growing Only on Methanol (메탄올만 이용하여 성장하는 Methylobacillus의 분리 및 특성)

  • 김시욱;김병홍;김영민
    • Korean Journal of Microbiology
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    • v.29 no.4
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    • pp.250-257
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    • 1991
  • An obligate methanol-oxidizing bacterium, Methylobacillus sp. strain SK1, which grows only on methanol was isolated from soil. The isolate was nonmotile Gram-negtive rod. It does not have internal membrane system. The colonies were small, whitish-yellow, and smooth. The guanine plus cytosine content of the DNA was 48 mol%. Cellular fatty acids consisted predominantly of large amounts of straight-chain saturated $C_{16:0}$ acid and unsaturated $C_{16:1}$ acid. The major ubiquinone was Q-8, and Q-10 was present as minor component. The cell was obligately aerobic and exhibited catalase, but no oxidase, activity. Poly-.betha.-hydroxybutyrate, endospores, or cysts were not observed. the isolate could grow only on methanol in mineral medium. Growth factors were not required. The isolate was unable to use methane, formaldehyde, formate, methylamine, and several other organic compounds tested as a sole source of carbon and energy. Growth was optimal at 35.deg.C and pH 7.5. It could not grow at 42.deg.C. The doubling time was 1.2h at 30.deg.C when grown with 1.0%(v/v) methanol. The growth was not affected by antibiotics inhibiting cell wall synthesis and carbon monoxide but was completely suppressed by those inhibiting protein synthesis. Methanol was found to be assimilated through the ribulose monophosphate pathway. Cytochromes of b-, c-, and o- types were found. Cell-free extracts contained a phenazine methosulfate-linked methanol dehydrogenase activity, which required ammonium ions as an activator. Cells harvested after the late exponential phase seemed to contain blue protein.ein.

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Inhibitory Effect of Polyporus umbellatus Extract on Melanogenesis (저령 추출물의 멜라닌 생성억제 작용)

  • Kang, Lea Minju;Park, Seol-a;Mun, Yeun-Ja;Woo, Won-Hong
    • Korean Journal of Acupuncture
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    • v.37 no.1
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    • pp.24-30
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    • 2020
  • Objectives : The purpose of this study was to investigate melanogenesis inhibition of ethanol extract of Polyporus (EP) by using B16F10 melanoma cells. Methods : We measured antioxidant effect of EP by using 1,1-Diphenyl-1-picrylhydrazyl (DPPH) assay and we confirmed melanin contents and tyrosinase activity of EP in cells. Additionally, the expression of tyrosinase-related protein-1 (TRP-1) and TRP-2 was observed by Western blot. Results : EP showed significantly high radical scavenging activity and inhibition of melanogenesis in dose-dependent manner by decreasing cellular tyrosinase activity and melanin content with or without α-melanin stimulating hormone. TRP-1 and TRP-2 expressions were also suppressed by EP in B16F10 cells. Conclusions : These results suggest that EP inhibits the melanogenesis and it could be a new organic ingredient for hyper-pigmentation.

Modern Sedimentary Environment of Jinhae Bay, SE Korea

  • Park, Soo-Chul;Lee, Kang-Wook
    • Journal of the korean society of oceanography
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    • v.31 no.2
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    • pp.43-54
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    • 1996
  • Jinhae Bay, one of the largest tidal bays on the southern coast of Korea, is an area with thick accumulations of recent, fine-grained sediments, mainly supplied from the Nakdong River. The preponderance of silt and clay particles reflects the large quantity of sediments transported in suspension. Although the clay mineral assemblage is similar to that derived from the nearby Nakdong River, relatively high concentration (3-9%) of smectite suggests some local input of fine particles from several streams around the bay or some contribution from the offshore water that may be influenced by the Tsushima Current. The content of organic matters in sediments is as high as 12%, and their C/N ratios imply that they are comprised of mixtures derived from marine plankton and terrestrial plants. $^{210}Pb$ excess activity profiles of sediment cores yield an average sedimentation rate (a 100-year time scale) of about 2-5 mm/yr, which coincides well with the long-term sedimentation rate (a 1000-year time scale) estimated from the sediment isopach map. On the basis of sediment bulk density and sedimentation rate, an annual sink of mud in the bay is estimated approximately 1.0 ${\times}$ $10^{6}$ tons per year.

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Surface modification of silica aerogel by surfactant adsorption and heat treatment methods (계면활성제 흡착 및 열처리를 이용한 실리카 에어로겔의 표면 개질)

  • Kim, Nam-Yi;Kim, Seong-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.3
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    • pp.282-289
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    • 2010
  • In preparation of silica aerogel-based hybrid coating materials, the combination of hydrophobic aerogel with organic polar binder material is shown to be very limited due to dissimilar surface property between two materials. Accordingly, the surface modification of the aerogel would be required to obtain compatibilized hybrid coating sols with homogeneous dispersion. In this study, the surface of silica aerogel particles was modified by using both surfactant adsorption and heat treatment methods. Four types of surfactants with different molecular weights and HLB values were used to examine the effect of chain length and hydrophilicity. The surface property of the modified aerogel was evaluated in terms of visible observation for aerogel dispersion in water, water contact angle measurement, and FT-IR analysis. In surface modification using surfactants, the effects of surfactant type and content, and mixing time as process parameter on the degree of hydrophilicity for the modified aerogel. In addition, the temperature condition in modification process via heat treatment was revealed to be significant factor to prepare aerogel with highly hydrophilic property.

Anomalous Photoluminescence and Persistent Photoconductivity of AlxGal-xN/GaN Epilayers (AlxGal-xN/GaN 에피층의 비정상적인 광발광과 Persistent Photoconductivity 현상)

  • Chung, S.J.;Jun, Y.K.
    • Korean Journal of Materials Research
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    • v.13 no.10
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    • pp.673-676
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    • 2003
  • We have investigated $Al_{x}$ $Ga_{l-x}$ N/GaN epilayers (x = 0.08, 0.15) grown by metal organic vapor phase epitaxy on sapphire with photoluminescence(PL), and persistent photoconductivity(PPC) experiments. An anomalous S-shaped shift behavior of temperature dependencies of PL peak energy is observed for the x = 0.15 sample. In PPC measurement, showed that the dark current recovery time of $Al_{x}$$Ga_{l-x}$ N/GaN epilayers mainly depends on the Al content. These behaviors are usually attributed to the presence of carrier localization states. All these phenomena are explained based on the alloy compositional fluctuations in the $Al_{x}$ /$Ga_{l-x}$ N/ epilayers. The photocurrent quenching observed in PPC measurements for $Al_{x}$ $Ga_{l-x}$ N/ epilayers less than 0.2 $\mu\textrm{m}$ thickness indicates that the presence of metastable state in the bandgap of GaN layer, and that the excess holes in the valence band recombine with free electrons.