• Title/Summary/Keyword: organic content

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Photoluminescence of willemite ($Zn_2SiO_4$ : Mn) phosphors prepared by the MOD process (MOD법에 의해 합성한 Willemite($Zn_2SiO_4$:Mn) 형광체의 발광 특성)

  • Lee, Byeong-Woo;Lee, Seon-Gil;Cho, Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.17 no.2
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    • pp.57-62
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    • 2007
  • Willemite green phosphor powders have been prepared by the metallo-organic decomposition (MOD) method, and the photoluminescence and phase formation were studied as a function of both the firing temperature ($800{\sim}1100^{\circ}C$) and the concentration of Mn activator ($4{\sim}12 mol%$). Under 254 nm excitation source, the emission intensity of the phosphors increased with increasing the firing temperature from 800 to $1000^{\circ}C$. From the XRD analysis, the powders heat-treated above $1000^{\circ}C$ showed willemite crystal structure. The maximum emission intensity was obtained far the phosphors heat-treated at $1000^{\circ}C$ with 8 mol% of Mn content. The concentration quenching was occurred when the Mn concentration exceeded 10 mol%. The phosphor particles showed spherical shapes with the average size of $0.4{\sim}0.5{\mu}m$ by the SEM morphology.

A Study on the Composting Process of Food Waste by Seeding the Isolated Effective Microorganism (음식폐기물 퇴비화에서 유효 미생물 분리 및 첨가에 관한 연구)

  • 이장훈;정준오;박승호
    • Journal of Environmental Health Sciences
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    • v.26 no.3
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    • pp.1-10
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    • 2000
  • Although microorganisms play an important role in composting process, researches on the effective microorganism (EM) in composting process are rarely reported. In this study, three stages of work performed 1) investigation of composting facility 2) sample collection and isolation of the EM 3) lab-scale composting by seeding the isolated EM. For this, purpose, physical, chemical, and biological characteristics, such as temperature, moisture content, organic matter, pH population of microorganism, etc., were investigated during the process and the results were compared with those of a control(non-seeded). In the composting facility, the most active degradation of food waste was suppsed to occur in 10-11th day of composting by observing the temperature and CO2 emission. The population of bacterial and fungi was highest in thermophilic stage. Meanwhile that of actinomycetes and yeast was relatively uniform during the process. In the lab-scale test, the thermophilic stage was maintained longer(more than 9 days in 17 days of experiment) in the seeded which was favored for the high reduction of organic matter and moisture. Reduction rates of lipids and salinity were also increased in the seeded. It confirmed these results that the population of microorganisms in the seeded was observed higher in several orders than the control. However, pH of the seeded was maintained as low as about 4.5 throughout the experiment except the final period of the process. Meanwhile, pH of the control rose in the early stage of the experiment. This was probably due that the seeded microorganisms collected from the composting facility was adapted to the low pH environment.

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Physicochemical water quality characteristics in relation to land use pattern and point sources in the basin of the Dongjin River and the ecological health assessments using a fish multi-metric model

  • Jang, Geon-Su;An, Kwang-Guk
    • Journal of Ecology and Environment
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    • v.40 no.1
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    • pp.34-44
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    • 2016
  • Background: Little is known about how chemical water quality is associated with ecological stream health in relation to landuse patterns in a watershed. We evaluated spatial characteristics of water quality characteristics and the ecological health of Dongjin-River basin, Korea in relation to regional landuse pattern. The ecological health was assessed by the multi-metric model of Index of Biological Integrity (IBI), and the water chemistry data were compared with values obtained from the health model. Results: Nutrient and organic matter pollution in Dongjin-River basin, Korea was influenced by land use pattern and the major point sources, so nutrients of TN and TP increased abruptly in Site 4 (Jeongeup Stream), which is directly influenced by wastewater treatment plants along with values of electric conductivity (EC), bacterial number, and sestonic chlorophyll-a. Similar results are shown in the downstream (S7) of Dongjin River. The degradation of chemical water quality in the downstream resulted in greater impairment of the ecological health, and these were also closely associated with the landuse pattern. Forest region had low nutrients (N, P), organic matter, and ionic content (as the EC), whereas urban and agricultural regions had opposite in the parameters. Linear regression analysis of the landuse (arable land; $A_L$) on chemicals indicated that values of $A_L$ had positive linear relations with TP ($R^2=0.643$, p < 0.01), TN ($R^2=0.502$, p < 0.05), BOD ($R^2=0.739$, p < 0.01), and suspended solids (SS; ($R^2=0.866$, p < 0.01), and a negative relation with TDN:TDP ratios ($R^2=0.719$, p < 0.01). Conclusions: Chemical factors were closely associated with land use pattern in the watershed, and these factors influenced the ecological health, based on the multimetric fish IBI model. Overall, the impairments of water chemistry and the ecological health in Dongjin-River basin were mainly attributes to point-sources and land-use patterns.

Changes in the Physiochemical Characteristics of Artificial Soil after Rooftop Planting (옥상녹화 후 인공토양의 이화학적 특성 변화)

  • 안원용;김동엽
    • Journal of the Korean Institute of Landscape Architecture
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    • v.28 no.6
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    • pp.77-83
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    • 2001
  • The purpose of this study is to provide the fundamental material and information for the plant maintenance after rooftop planting through physiochemical characteristics. The characteristics of artificial soils after rooftop planting from 1993 to 1999 was investigated. Fourteen investigation areas were selected from 4 cities(2 areas selected by each year). The analysis of the circumstances of the areas, the physical characteristics, and the chemical characteristics of the soil were conducted. The artificial soil pH ranged 5.26∼7.40 showing that after construction the soil pH tended to decrease. The soil bulk density of the site was lowest in 1999, 0.15g/㎤, and used to increase toward 1993. We found the fact that the soil bulk density increased gradually after rooftop application . The coefficients of permeability of the soils range from 0.016 to 0.052 cm/sec, which seemed to be in good permeability level. The artificial soils had relatively high water moisture capacity of 62.69∼71.36%. The soil organic matter content of the artificial soils ranged from 0.43 to 1.34%. The exchangeable caution concentration in the artificial soil ranged, Na, 2.36∼4.71mg·{TEX}$kg^{-1}${/TEX}, Mg 0.88∼2.84mg·{TEX}$kg^{-1}${/TEX},K 2.97∼9.61 mg·{TEX}$kg^{-1}${/TEX}, and Ca 9.39∼28.23 mg·{TEX}$kg^{-1}${/TEX}. The amount of total N ranged from 0.003 to 0.286% in study sites. Soil chemical properties varied year to year and showed little tend. The research results showed that some characteristics of the artificial soil were changed after rooftop planting, i.e., soil pH and soil bulk density. Soil bulk density had a negative relationship with the coefficient of permeability, showing that the drainage condition might be limited after some period. This study suggests that a diversity of the research in the changes of the plant growth basis on the areas after construction.

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Performance of an Intermittent Aerated Pilot-scale Reactor Vessel for Commercial Composting (상업용 퇴비화를 위한 간헐통기식 파이로트 규모 반응조의 성능)

  • Hong, Ji-Hyung
    • Journal of the Korea Organic Resources Recycling Association
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    • v.6 no.2
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    • pp.31-44
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    • 1998
  • Mixtures of hog manure slurry and sawdust were composted by an intermittent aeration method to verify the performance evaluation of pilot-scale reactor vessels during composting high rate (decomposition) process. Instrumentation was designed to measure temperatures in compost, oxygen and carbon dioxide concentration, air flow rates, and ammonia gas emitted. It was found that ammonia concentration during composting high rate decreased more quickly to the allowable range of 34-40 ppm after 14days at near the optimal levels (II) than in the case of lower levels (I). The influence of the optimal levels (II) such as moisture content (55-65%), C/N ratio (20-40), pH (7-8) and temperature in compost (<$60^{\circ}C$) on the reduction of ammonia gas was considerable for commercial composting.

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A Study on the Extraction of Collagen and Separation of Chrome Ion from Leather Waste (피혁 폐기물로부터 collagen 추출과 크롬이온 분리에 관한 연구)

  • Lim, Bong-Ju;Lim, Nam-Uoong;Lim, Han-Jin
    • Journal of the Korea Organic Resources Recycling Association
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    • v.6 no.1
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    • pp.43-52
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    • 1998
  • The objective of this study is to investigate the optimum conditions of extracting collagen without chrome ion from the leather waste. The effect of temperature, pH, and the concentration of alkaline solution on the collagen extraction has been studied. The result indicated that the incipient denatured temperature of collagen measured by viscosity was $25^{\circ}C$ and the complete denatured temperature was $31.5^{\circ}C$. The optimum solubilization condition for temperature was between $15^{\circ}C$ and $20^{\circ}C$, pH was 1.5, the concentration of alkaline solution was 3% of sodium hydroxide. The almost complete chrome ion separation was possible around the pH of 1.5. The separation efficiency of chrome ion from tannery waste was more than 99.5%. Extraction efficiency of crude protein from leather waste was about 89.5%. The hydroxyproline and collagen content in the extracted crude protein were 8.53% and 63.62%, respectively.

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The experiment of process efficiency and salt elimination in food waste compost using triple salt (삼중염을 이용한 음식물 쓰레기 퇴비 중 염분제거 및 공정효율화 실험)

  • Kim, Nam-Cheon;Jang, Byung-Man
    • Journal of the Korea Organic Resources Recycling Association
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    • v.14 no.2
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    • pp.83-90
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    • 2006
  • The NaCl contents of food waste composts made by various techniques known up to now were under the level of 1% by fresh weight basis. But these techniques has some problem that is environment pollution from treated water and high equipment cost. The application to agricultural land of food waste compost that is not sufficiently removed NaCl was considered to be improper due to salt accumulation in soils and plant growth inhibition by salt stress. The purpose of this study is to decompose NaCl in food waste compost using triple salt and this method is differ from existing chemical method. Also, reaction of NaCl with triple salt produced KCl that is basic material of potassium fertilizer. Moreover Also, there was temperature rise of average $5^{\circ}C$ as result that apply triple salt in food waste 600 ton in food wast composting productive capacity. Obvious odious smell reduction effect appeared pretreatment process and fermentation process with temperature rise and this is because triple salt activation of aerobe and removes odious smell cause material by salt content decrease effectively.

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Basic Study on the in-situ Biogenic Methane Generation from Low Grade Coal Bed (저품위 석탄의 원지반에서의 생물학적 메탄가스 생산에 관한 기초연구)

  • Wang, Fei;Jeon, Ji-Young;Lim, Hak-Sang;Yoon, Seok-Pyo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.23 no.4
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    • pp.11-20
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    • 2015
  • In the present work, a basic study on the in-situ biogenic methane generation from low grade coal bed was conducted. Lignite from Indonesia was used as a sample feedstock. A series of BMP (Biochemical Methane Potential) tests were carried out under the different experimental conditions. Although nutrients and anaerobic digester sludge were added to the coal, the produced amount of methane was limited. Both temperature control and particle size reduction showed little effect on the increase of methane potential. When rice straw was added to lignite as an external carbon source, methane yield of 94.4~110.4 mL/g VS was obtained after 60 days of BMP test. The calorific value of lignite after BMP test decreased (4.5~12.1 %) as increasing the content of rice straw (12.5~50 wt % of lignite), implying that anaerobic digestion of rice straw led to partial degradation of lignite. Therefore, rice straw could be used as an external carbon source for the start-up of in-situ biogas generation from low grade coal bed.

The Study of combustion characteristic and kinetic study of wastes and RDF (폐기물 및 RDF에 대한 연소특성 및 반응속도에 관한 연구)

  • Lee, Keon Joo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.21 no.1
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    • pp.76-84
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    • 2013
  • In this study, thermal weight loss, non-isothermally experiment, chemical composition analysis, calorific value, activation energy (E) were investigated to analysis the kinetic study of RDF, wood pellets, waste wood, waste textile and waste vinyl. When the chemical composition of solidification fuel was compared, the moisture content of RDF was less than the wood pellet and when the kinetic study was compared, the combustion reaction rate of the waste vinyl was higher than any other solidification fuels. However when the combustion efficiency was compared by the activation energy, the RDF had the higher efficiency than other wastes. RDF can be found that the reaction takes place between $320{\sim}720^{\circ}C$ depending on the heating rate.

Effects of Foliar Application of Chitosan and Wood Extraction on Rooting and Tuber Formation of Plug Seedlings in Potatoes (Chitosan과 목초액 엽면살포에 의한 감자 플러그 삽목표의 발근 및 괴경형성효율)

  • 송창길;강태균
    • Korean Journal of Organic Agriculture
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    • v.8 no.1
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    • pp.89-99
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    • 1999
  • To do mass multiplication of plug seedlings in potatoes, apical stem cuttings originated from virus-free microtubers were cut to one-two internodes and transplanted into the plug-tray. After 10days, we applied Chitosan and Wood Extraction on rooting and tuber formation of plug seedlings. To improve field adaptability of plug seedlings, rooted cuttings with a height of 20cm after 20days of cutting were transplanted ito the fields, We applied 500~2000ppm Chitosan on growth characteristics and tuber formation of that. The above and underground growths, such as plant height and number of leaves were significantly more vigorous after treatment with 500~1,000ppm Chitosan and 2,000ppm Wood Extraction, the spray treatment was carried out five times at intervals of four days after ten days of transplanting. T-N, K, P, Mg and Na, were higher as the concentrations of chitosan and Wood Extraction were higher. The growth and tuber yield in plug seedlings planting plot and seed potatoes planting plot were effectively highter as foliar application of Chitosan(500~2,000ppm) was done after planting the plot. T-N content in leaves and tuber was higher as the concentration of Chitosan was high. A similar tendency was shown in K, P and Mg. In the small tuber(under 30g), the number of tubers and tuber yield were relatively increased in the seed potatoes planting plot, but the large tubers(over 80g) yield was higher in the plug seedlings planting plot, and in order to increase tuber yield in plug seedlings it was necessary to add plant density to the field.

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